DE602006004911D1 - Gasphasenoxidationskatalysator und dessen Verwendung zur Herstellung von Acrylsäure - Google Patents

Gasphasenoxidationskatalysator und dessen Verwendung zur Herstellung von Acrylsäure

Info

Publication number
DE602006004911D1
DE602006004911D1 DE602006004911T DE602006004911T DE602006004911D1 DE 602006004911 D1 DE602006004911 D1 DE 602006004911D1 DE 602006004911 T DE602006004911 T DE 602006004911T DE 602006004911 T DE602006004911 T DE 602006004911T DE 602006004911 D1 DE602006004911 D1 DE 602006004911D1
Authority
DE
Germany
Prior art keywords
production
acrylic acid
gas phase
oxidation catalyst
phase oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
DE602006004911T
Other languages
English (en)
Inventor
Naohiro Fukumoto
Michio Tanimoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Shokubai Co Ltd
Original Assignee
Nippon Shokubai Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Shokubai Co Ltd filed Critical Nippon Shokubai Co Ltd
Publication of DE602006004911D1 publication Critical patent/DE602006004911D1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12Silica and alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/28Molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/888Tungsten
    • B01J23/8885Tungsten containing also molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE602006004911T 2005-04-18 2006-04-18 Gasphasenoxidationskatalysator und dessen Verwendung zur Herstellung von Acrylsäure Active DE602006004911D1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005120243A JP4646684B2 (ja) 2005-04-18 2005-04-18 気相酸化触媒およびそれを用いたアクリル酸の製造方法

Publications (1)

Publication Number Publication Date
DE602006004911D1 true DE602006004911D1 (de) 2009-03-12

Family

ID=36632015

Family Applications (1)

Application Number Title Priority Date Filing Date
DE602006004911T Active DE602006004911D1 (de) 2005-04-18 2006-04-18 Gasphasenoxidationskatalysator und dessen Verwendung zur Herstellung von Acrylsäure

Country Status (6)

Country Link
US (1) US7456129B2 (de)
EP (1) EP1714696B1 (de)
JP (1) JP4646684B2 (de)
KR (1) KR100910788B1 (de)
CN (1) CN1853786A (de)
DE (1) DE602006004911D1 (de)

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JP4947917B2 (ja) * 2005-04-18 2012-06-06 株式会社日本触媒 気相接触酸化用の固定床反応器およびアクロレインまたはアクリル酸の製造方法
EP2295136A4 (de) * 2008-06-30 2011-12-28 Nippon Catalytic Chem Ind Verfahren zur verpackung einer feststoffpartikelsubstanz in einem mehrröhren-festbettreaktor
JP5387297B2 (ja) * 2009-09-30 2014-01-15 住友化学株式会社 複合酸化物触媒の製造方法
US9149799B2 (en) * 2010-04-28 2015-10-06 Basf Se Eggshell catalyst consisting of a hollow cylindrical support body and a catalytically active oxide material applied to the outer surface of the support body
CN103521235A (zh) * 2012-07-03 2014-01-22 中国石油化工股份有限公司 由丙烯醛氧化制备丙烯酸催化剂及其制备方法
CN104646056B (zh) * 2013-11-18 2017-01-11 上海华谊丙烯酸有限公司 一种钼磷系杂多酸盐催化剂及其制备方法和用途
CN105664959B (zh) * 2014-11-20 2018-05-11 中国石油化工股份有限公司 不饱和酸催化剂及其制备方法
JP6456204B2 (ja) * 2015-03-24 2019-01-23 千代田化工建設株式会社 芳香族炭化水素の水素化触媒及びそれを用いた水素化処理方法
CN107282055B (zh) * 2016-04-13 2020-11-03 中国石油化工股份有限公司 生产丙烯醛和丙烯酸的催化剂
CN105921154B (zh) * 2016-05-11 2018-06-12 万华化学集团股份有限公司 一种多金属复合氧化物催化剂的制备方法及其制备的催化剂及其用途
CN107442141B (zh) * 2016-06-01 2019-10-11 杭州诚洁环保有限公司 一种固体超强酸用于催化双氧水/臭氧的用途及方法
CN109304155B (zh) * 2017-07-28 2021-07-30 中国石油化工股份有限公司 丙烯酸合成用催化剂
CN109305905B (zh) * 2017-07-28 2021-06-18 中国石油化工股份有限公司 丙烯酸合成的方法
CN109304181A (zh) * 2017-07-28 2019-02-05 中国石油化工股份有限公司 用于丙烯醛氧化制丙烯酸的催化剂
US10828621B2 (en) * 2017-08-28 2020-11-10 Uchicago Argonne, Llc Supported multimetallic catalysts for oxidative dehydrogenation of alkanes

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JPS5250788B2 (de) * 1973-01-25 1977-12-27
IT1048472B (it) * 1975-10-23 1980-11-20 Montedison Spa Procedimento per la preparazione di acidi carbossilici insaturi per ossidazione catalitica in fase gassosa delle corrispondenti aldeidi
IT1063376B (it) * 1976-05-20 1985-02-11 Montedison Spa Procedimento per la preparazione di acidi carbossilici insaturi per ossidazione catalitica in fase gassosa delle corrispondenti aldeidi
US4440872A (en) * 1978-07-25 1984-04-03 Exxon Research And Engineering Co. Transition metal oxide acid catalysts
FR2481146A1 (fr) * 1980-04-25 1981-10-30 Rhone Poulenc Ind Procede pour la preparation de catalyseurs a base d'oxydes de molybdene et/ou de tungstene et d'oxydes d'autres metaux
US4390736A (en) * 1980-11-26 1983-06-28 Sumitomo Chemical Company, Limited Process for producing phenols
JPS6044039A (ja) * 1983-08-17 1985-03-08 シ−ビ−エムエム・インタ−ナシヨナル・リミタ−ダ 含水酸化ニオブ固体酸触媒
JPS60174739A (ja) * 1984-02-20 1985-09-09 Mitsubishi Petrochem Co Ltd 第三−アミルフエノ−ル類の製造法
JPS6226245A (ja) * 1985-07-25 1987-02-04 Toagosei Chem Ind Co Ltd アクリル酸またはメタクリル酸の製造方法
JPS63208545A (ja) * 1987-02-23 1988-08-30 Mitsubishi Petrochem Co Ltd パラクミルフエノ−ルの製造法
JPH04238806A (ja) * 1990-12-28 1992-08-26 Mizusawa Ind Chem Ltd 水性バインダーへの分散性に優れたシリカ系顔料及び            その用途
JP2944463B2 (ja) * 1994-05-31 1999-09-06 株式会社日本触媒 メタクリル酸製造用触媒およびこの触媒を用いたメタクリル酸の製造方法
JP2988849B2 (ja) * 1994-05-31 1999-12-13 株式会社日本触媒 アクリル酸製造用触媒およびこの触媒を用いたアクリル酸の製造方法
JPH0847441A (ja) * 1994-08-08 1996-02-20 Fuji Electric Co Ltd ショーケースの商品棚
EP0811597B1 (de) * 1994-11-14 2000-08-23 Nippon Shokubai Co., Ltd. Verfahren zur Herstellung von Acrylsäure
ATE211947T1 (de) * 1996-09-05 2002-02-15 Japan Energy Corp Saurer katalysator in fester form und verfahren zur herstellung desselben
WO1999044738A1 (fr) * 1998-03-04 1999-09-10 Japan Energy Corporation Catalyseur acide solide, procede de preparation dudit catalyseur et reaction mettant en oeuvre ledit catalyseur
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JP4813758B2 (ja) * 2003-02-27 2011-11-09 株式会社日本触媒 複合酸化物触媒およびそれを用いたアクリル酸の製造方法
JP2005224660A (ja) * 2004-02-10 2005-08-25 Nippon Shokubai Co Ltd アクロレインの接触気相酸化反応用触媒、及び該触媒を用いた接触気相酸化方法によるアクリル酸の製造方法

Also Published As

Publication number Publication date
EP1714696A1 (de) 2006-10-25
KR100910788B1 (ko) 2009-08-04
KR20060109831A (ko) 2006-10-23
CN1853786A (zh) 2006-11-01
US20060234861A1 (en) 2006-10-19
JP4646684B2 (ja) 2011-03-09
US7456129B2 (en) 2008-11-25
JP2006297232A (ja) 2006-11-02
EP1714696B1 (de) 2009-01-21

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