DE602004004904T2 - Nuancierungsmittel - Google Patents
Nuancierungsmittel Download PDFInfo
- Publication number
- DE602004004904T2 DE602004004904T2 DE602004004904T DE602004004904T DE602004004904T2 DE 602004004904 T2 DE602004004904 T2 DE 602004004904T2 DE 602004004904 T DE602004004904 T DE 602004004904T DE 602004004904 T DE602004004904 T DE 602004004904T DE 602004004904 T2 DE602004004904 T2 DE 602004004904T2
- Authority
- DE
- Germany
- Prior art keywords
- alkyl
- formula
- alkoxy
- und
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 claims description 212
- -1 cyano, carboxyl Chemical group 0.000 claims description 166
- 239000000975 dye Substances 0.000 claims description 85
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 80
- 239000008187 granular material Substances 0.000 claims description 76
- 229910052739 hydrogen Inorganic materials 0.000 claims description 75
- 239000001257 hydrogen Substances 0.000 claims description 70
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 56
- 238000009472 formulation Methods 0.000 claims description 54
- 150000001875 compounds Chemical class 0.000 claims description 53
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 51
- 239000003599 detergent Substances 0.000 claims description 48
- 125000000217 alkyl group Chemical group 0.000 claims description 46
- 239000000987 azo dye Substances 0.000 claims description 46
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 claims description 46
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 45
- 229910052736 halogen Inorganic materials 0.000 claims description 44
- 150000003839 salts Chemical class 0.000 claims description 44
- 150000002367 halogens Chemical class 0.000 claims description 42
- 239000000654 additive Substances 0.000 claims description 34
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 31
- 125000003118 aryl group Chemical group 0.000 claims description 29
- 229910052757 nitrogen Inorganic materials 0.000 claims description 28
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 26
- 239000011941 photocatalyst Substances 0.000 claims description 26
- 125000003342 alkenyl group Chemical group 0.000 claims description 24
- 230000000996 additive effect Effects 0.000 claims description 23
- 239000002979 fabric softener Substances 0.000 claims description 20
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 19
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 18
- 150000002978 peroxides Chemical class 0.000 claims description 17
- 150000001450 anions Chemical class 0.000 claims description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 15
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 14
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 14
- 239000012190 activator Substances 0.000 claims description 12
- 125000003545 alkoxy group Chemical group 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 11
- 125000002947 alkylene group Chemical group 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- 239000003945 anionic surfactant Substances 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- 150000007942 carboxylates Chemical class 0.000 claims description 8
- 150000004820 halides Chemical class 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 7
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910001413 alkali metal ion Chemical group 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 claims description 5
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 5
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
- 125000001624 naphthyl group Chemical group 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 230000003381 solubilizing effect Effects 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 150000001768 cations Chemical class 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- ORTFAQDWJHRMNX-UHFFFAOYSA-M oxidooxomethyl Chemical compound [O-][C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-M 0.000 claims description 3
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 3
- 125000004434 sulfur atom Chemical group 0.000 claims description 3
- 125000002373 5 membered heterocyclic group Chemical group 0.000 claims description 2
- 125000004070 6 membered heterocyclic group Chemical group 0.000 claims description 2
- 150000001449 anionic compounds Chemical class 0.000 claims description 2
- 125000001246 bromo group Chemical group Br* 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 229910001412 inorganic anion Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 150000002891 organic anions Chemical class 0.000 claims description 2
- 230000009467 reduction Effects 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 description 45
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 30
- 239000004744 fabric Substances 0.000 description 29
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical group C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 24
- 239000002253 acid Substances 0.000 description 24
- 239000012669 liquid formulation Substances 0.000 description 23
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 22
- 239000003795 chemical substances by application Substances 0.000 description 21
- 150000007513 acids Chemical class 0.000 description 20
- 125000004093 cyano group Chemical group *C#N 0.000 description 19
- 238000000034 method Methods 0.000 description 19
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 description 17
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 description 16
- 102000004190 Enzymes Human genes 0.000 description 16
- 108090000790 Enzymes Proteins 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 16
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical group C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 16
- 229940088598 enzyme Drugs 0.000 description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 15
- 229910052783 alkali metal Inorganic materials 0.000 description 15
- 229920001577 copolymer Polymers 0.000 description 15
- 239000002270 dispersing agent Substances 0.000 description 15
- 239000002736 nonionic surfactant Substances 0.000 description 14
- 239000011734 sodium Substances 0.000 description 14
- 125000000129 anionic group Chemical group 0.000 description 13
- 239000011575 calcium Substances 0.000 description 13
- 229910052799 carbon Inorganic materials 0.000 description 13
- 235000014113 dietary fatty acids Nutrition 0.000 description 13
- 239000000194 fatty acid Substances 0.000 description 13
- 229930195729 fatty acid Natural products 0.000 description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 13
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 12
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 12
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 12
- 239000007859 condensation product Substances 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- 150000003254 radicals Chemical class 0.000 description 12
- 239000007787 solid Substances 0.000 description 12
- 238000005406 washing Methods 0.000 description 12
- 150000001340 alkali metals Chemical class 0.000 description 11
- 230000003287 optical effect Effects 0.000 description 11
- 150000004760 silicates Chemical class 0.000 description 11
- 159000000000 sodium salts Chemical class 0.000 description 11
- 125000001424 substituent group Chemical group 0.000 description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 10
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 10
- 239000000460 chlorine Substances 0.000 description 10
- 150000002191 fatty alcohols Chemical class 0.000 description 10
- 150000004665 fatty acids Chemical class 0.000 description 9
- 239000003205 fragrance Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 150000007524 organic acids Chemical class 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 238000001694 spray drying Methods 0.000 description 9
- 125000001931 aliphatic group Chemical group 0.000 description 8
- 229910052731 fluorine Inorganic materials 0.000 description 8
- 239000000049 pigment Substances 0.000 description 8
- 239000003760 tallow Substances 0.000 description 8
- 239000004753 textile Substances 0.000 description 8
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 7
- 150000001298 alcohols Chemical class 0.000 description 7
- 239000007844 bleaching agent Substances 0.000 description 7
- 229910052801 chlorine Inorganic materials 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 7
- 150000003138 primary alcohols Chemical class 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 7
- 0 CC1(C=CC(C)=CC=C1)N* Chemical compound CC1(C=CC(C)=CC=C1)N* 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 6
- 239000002518 antifoaming agent Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 6
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 6
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
- 230000009021 linear effect Effects 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 229920005646 polycarboxylate Polymers 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 5
- 102000005575 Cellulases Human genes 0.000 description 5
- 108010084185 Cellulases Proteins 0.000 description 5
- 239000004375 Dextrin Substances 0.000 description 5
- 229920001353 Dextrin Polymers 0.000 description 5
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 5
- AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 description 5
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 5
- MXBDBLBKBBAYGD-UHFFFAOYSA-N P(O)(O)=O.C Chemical compound P(O)(O)=O.C MXBDBLBKBBAYGD-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 238000005054 agglomeration Methods 0.000 description 5
- 230000002776 aggregation Effects 0.000 description 5
- 239000003513 alkali Substances 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 235000010980 cellulose Nutrition 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 5
- 235000019425 dextrin Nutrition 0.000 description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 238000005469 granulation Methods 0.000 description 5
- 230000003179 granulation Effects 0.000 description 5
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 5
- 150000007522 mineralic acids Chemical class 0.000 description 5
- 229920000620 organic polymer Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000000600 sorbitol Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 235000021286 stilbenes Nutrition 0.000 description 5
- 239000010457 zeolite Substances 0.000 description 5
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- NSMMFSKPGXCMOE-UHFFFAOYSA-N 2-[2-(2-sulfophenyl)ethenyl]benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1C=CC1=CC=CC=C1S(O)(=O)=O NSMMFSKPGXCMOE-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 102000035195 Peptidases Human genes 0.000 description 4
- 108091005804 Peptidases Proteins 0.000 description 4
- 239000004365 Protease Substances 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 4
- 239000002216 antistatic agent Substances 0.000 description 4
- ZSIQJIWKELUFRJ-UHFFFAOYSA-N azepane Chemical group C1CCCNCC1 ZSIQJIWKELUFRJ-UHFFFAOYSA-N 0.000 description 4
- 238000004061 bleaching Methods 0.000 description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 125000000068 chlorophenyl group Chemical group 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000002657 fibrous material Substances 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 4
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 4
- 150000004967 organic peroxy acids Chemical class 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- GJVFBWCTGUSGDD-UHFFFAOYSA-L pentamethonium bromide Chemical compound [Br-].[Br-].C[N+](C)(C)CCCCC[N+](C)(C)C GJVFBWCTGUSGDD-UHFFFAOYSA-L 0.000 description 4
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 125000001453 quaternary ammonium group Chemical group 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 4
- 239000000375 suspending agent Substances 0.000 description 4
- 125000003944 tolyl group Chemical group 0.000 description 4
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 3
- PTHCMJGKKRQCBF-UHFFFAOYSA-N Cellulose, microcrystalline Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC)C(CO)O1 PTHCMJGKKRQCBF-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical class O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 229930006000 Sucrose Chemical class 0.000 description 3
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 230000002528 anti-freeze Effects 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 239000003125 aqueous solvent Substances 0.000 description 3
- 235000010290 biphenyl Nutrition 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 229920006317 cationic polymer Polymers 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- GXGAKHNRMVGRPK-UHFFFAOYSA-N dimagnesium;dioxido-bis[[oxido(oxo)silyl]oxy]silane Chemical compound [Mg+2].[Mg+2].[O-][Si](=O)O[Si]([O-])([O-])O[Si]([O-])=O GXGAKHNRMVGRPK-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 229920000159 gelatin Polymers 0.000 description 3
- 235000019322 gelatine Nutrition 0.000 description 3
- 235000011852 gelatine desserts Nutrition 0.000 description 3
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- 229940043348 myristyl alcohol Drugs 0.000 description 1
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical class C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- DOKHEARVIDLSFF-UHFFFAOYSA-N prop-1-en-1-ol Chemical group CC=CO DOKHEARVIDLSFF-UHFFFAOYSA-N 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229940032147 starch Drugs 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 238000002371 ultraviolet--visible spectrum Methods 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0004—Non aqueous liquid compositions comprising insoluble particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0063—Photo- activating compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03102447 | 2003-08-06 | ||
| EP03102447 | 2003-08-06 | ||
| PCT/EP2004/051627 WO2005014769A1 (en) | 2003-08-06 | 2004-07-28 | Shading composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE602004004904D1 DE602004004904D1 (de) | 2007-04-05 |
| DE602004004904T2 true DE602004004904T2 (de) | 2007-10-31 |
Family
ID=34130282
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE602004004904T Expired - Lifetime DE602004004904T2 (de) | 2003-08-06 | 2004-07-28 | Nuancierungsmittel |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US8293695B2 (https=) |
| EP (1) | EP1651745B1 (https=) |
| JP (1) | JP5189288B2 (https=) |
| KR (1) | KR101175638B1 (https=) |
| CN (1) | CN1863900B (https=) |
| AR (1) | AR046403A1 (https=) |
| AT (1) | ATE354631T1 (https=) |
| AU (1) | AU2004263673B2 (https=) |
| BR (1) | BRPI0412669B1 (https=) |
| DE (1) | DE602004004904T2 (https=) |
| ES (1) | ES2281002T3 (https=) |
| MX (1) | MXPA06001368A (https=) |
| PL (1) | PL1651745T3 (https=) |
| TW (1) | TWI384104B (https=) |
| WO (1) | WO2005014769A1 (https=) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0314210D0 (en) | 2003-06-18 | 2003-07-23 | Unilever Plc | Laundry treatment compositions |
| GB0421145D0 (en) * | 2004-09-23 | 2004-10-27 | Unilever Plc | Laundry treatment compositions |
| ES2322864T3 (es) * | 2004-09-23 | 2009-06-30 | Unilever N.V. | Composiciones de tratamiento de ropa sucia. |
| PL1975226T3 (pl) * | 2007-03-20 | 2013-07-31 | Procter & Gamble | Płynna kompozycja do obróbki |
| ATE512201T1 (de) * | 2007-11-26 | 2011-06-15 | Procter & Gamble | Verbessertes schattierungsverfahren |
| BRPI0910682B1 (pt) * | 2008-05-02 | 2020-09-24 | Unilever N.V. | Grânulo de corante tonalizante que produzem menos manchas, e, composição detergente granular para lavar roupas |
| GB0810881D0 (en) | 2008-06-16 | 2008-07-23 | Unilever Plc | Improvements relating to fabric cleaning |
| JP5491513B2 (ja) * | 2008-10-24 | 2014-05-14 | コグニス・アイピー・マネージメント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | アルキルスルホスクシネート混合物およびその使用 |
| US8449626B2 (en) | 2009-11-11 | 2013-05-28 | The Procter & Gamble Company | Cleaning method |
| EP2343359A1 (en) | 2010-01-07 | 2011-07-13 | Unilever PLC | Detergent formulation containing spray dried granule |
| ES2530522T3 (es) | 2010-02-12 | 2015-03-03 | Unilever Nv | Composición de tratamiento para el lavado de ropa, que comprende colorantes de matizado bis-azoicos |
| CA2797139C (en) * | 2010-05-07 | 2015-06-23 | Basf Se | Dyes and blends for shading during laundry |
| GB201011511D0 (en) | 2010-07-08 | 2010-08-25 | Unilever Plc | Composions comprising optical benefits agents |
| AR082329A1 (es) * | 2010-07-23 | 2012-11-28 | Clariant Int Ltd | Metodo para preparar papel blanco |
| PH12013501439A1 (en) | 2011-01-31 | 2019-09-02 | Unilever Nv | Alkaline liquid detergent compositions |
| EP2476743B1 (en) | 2011-04-04 | 2013-04-24 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Method of laundering fabric |
| WO2012156250A1 (en) | 2011-05-13 | 2012-11-22 | Unilever Plc | Aqueous concentrated laundry detergent compositions |
| EP2522714A1 (en) | 2011-05-13 | 2012-11-14 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Aqueous concentrated laundry detergent compositions |
| EP2522715A1 (en) | 2011-05-13 | 2012-11-14 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Aqueous concentrated laundry detergent compositions |
| EP2557128B1 (en) * | 2011-08-11 | 2015-02-25 | Clariant International Ltd. | Improved aqueous compositions for whitening and shading in coating applications |
| BR112014013942B1 (pt) | 2011-12-20 | 2021-03-02 | Unilever Ip Holdings B.V | composição detergente líquida isotrópica |
| CN104334705A (zh) * | 2012-04-03 | 2015-02-04 | 巴斯夫欧洲公司 | 包含酞菁颗粒的组合物 |
| JP2015519429A (ja) * | 2012-04-27 | 2015-07-09 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | フタロシアニン粒子及びその使用 |
| EP2850166B1 (en) | 2012-05-16 | 2015-10-21 | Unilever PLC | Laundry detergent compositions comprising polyalkoxylated polyethyleneimine |
| EP2948535B1 (en) | 2013-01-23 | 2018-03-07 | Unilever Plc. | An uncoloured laundry additive material for promotion of anti redeposition of particulate soil |
| EP2770044A1 (en) | 2013-02-20 | 2014-08-27 | Unilever PLC | Lamellar gel with amine oxide |
| EP3097173B1 (en) * | 2014-01-22 | 2020-12-23 | The Procter and Gamble Company | Fabric treatment composition |
| TR201819563T4 (tr) | 2015-01-09 | 2019-01-21 | Unilever Nv | Bir boya içeren çamaşır arıtma bileşimi. |
| WO2016155993A1 (en) | 2015-04-02 | 2016-10-06 | Unilever Plc | Composition |
| WO2017121714A1 (en) | 2016-01-15 | 2017-07-20 | Unilever Plc | Dye |
| ES2985315T3 (es) | 2016-05-17 | 2024-11-05 | Unilever Ip Holdings B V | Composiciones de detergente líquidas para el lavado de ropa |
| CN109196083A (zh) | 2016-05-17 | 2019-01-11 | 荷兰联合利华有限公司 | 液体洗衣洗涤剂组合物 |
| WO2017202923A1 (en) | 2016-05-27 | 2017-11-30 | Unilever Plc | Laundry composition |
| MX2019005120A (es) | 2016-11-01 | 2019-06-20 | Procter & Gamble | Colorantes leuco como agentes de azulado en composiciones para el cuidado de la ropa. |
| WO2018127390A1 (en) | 2017-01-06 | 2018-07-12 | Unilever N.V. | Stain removing composition |
| WO2019038186A1 (en) | 2017-08-24 | 2019-02-28 | Unilever Plc | IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS |
| WO2019038187A1 (en) | 2017-08-24 | 2019-02-28 | Unilever Plc | IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB916532A (en) * | 1960-04-29 | 1963-01-23 | Basf Ag | Water-soluble dyes of the phthalocyanine-azo series |
| US3762859A (en) * | 1971-03-15 | 1973-10-02 | Colgate Palmolive Co | Enhancing the apparent whiteness of fabrics by applying an effective amount of an alkali and heat stable water soluble disazo blue dyestuff fabric softening and detergent composition therefor |
| EP0041239A3 (de) * | 1980-06-04 | 1982-05-12 | Ciba-Geigy Ag | Stabile konzentrierte flüssige Zubereitungen von metallfreien Farbstoffen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE3125495A1 (de) * | 1980-07-02 | 1982-05-19 | CIBA-GEIGY AG, 4002 Basel | "verwendung von farbstoffen zur nuancierung von optischen aufhellungen" |
| JPS5725365A (en) * | 1980-07-22 | 1982-02-10 | Showa Kagaku Kogyo Kk | Dyestuff salt-containing fluorescent brightener composition |
| JPS57155299A (en) * | 1981-03-23 | 1982-09-25 | Kao Corp | Detergent bleaching agent |
| JPS6225171A (ja) * | 1985-07-25 | 1987-02-03 | Fuji Photo Film Co Ltd | 青色系染料組成物 |
| DK690187A (da) * | 1986-12-31 | 1988-07-01 | Albright & Wilson | Beskyttet system, som er egnet til anvendelse i rensemidler, samt produkter indeholdende systemet |
| GB8806016D0 (en) * | 1988-03-14 | 1988-04-13 | Danochemo As | Encapsulated photoactivator dyes for detergent use |
| EP0479726B1 (de) * | 1990-10-04 | 1996-08-14 | Ciba-Geigy Ag | Konzentrierte wässrige Lösungen anionischer Disazofarbstoffe |
| US5853929A (en) * | 1993-06-28 | 1998-12-29 | Zeneca Limited | Trichromatic set of colored toners |
| US5916481A (en) * | 1995-07-25 | 1999-06-29 | The Procter & Gamble Company | Low hue photobleaches |
| DE69815064D1 (de) | 1997-01-24 | 2003-07-03 | Univ Case Western Reserve | Photobleichzusammensetzungen mit wirkung auf angeschmutzte gewebe |
| ATE272104T1 (de) * | 1998-05-18 | 2004-08-15 | Ciba Sc Holding Ag | Wasserlösliche granulate von phthalocyaninverbindungen |
| ES2254776T3 (es) | 2001-08-20 | 2006-06-16 | Unilever N.V. | Mota de fotoblanqueador y composiciones detergentes de lavanderia que la contienen. |
| GB0120160D0 (en) * | 2001-08-20 | 2001-10-10 | Unilever Plc | Photobleach speckle and laundry detergent compositions containing it |
| BRPI0514747A (pt) * | 2004-08-30 | 2008-06-24 | Ciba Sc Holding Ag | processo de gradação de cor |
-
2004
- 2004-07-28 AT AT04766337T patent/ATE354631T1/de not_active IP Right Cessation
- 2004-07-28 US US10/567,203 patent/US8293695B2/en not_active Expired - Fee Related
- 2004-07-28 JP JP2006522347A patent/JP5189288B2/ja not_active Expired - Fee Related
- 2004-07-28 WO PCT/EP2004/051627 patent/WO2005014769A1/en not_active Ceased
- 2004-07-28 DE DE602004004904T patent/DE602004004904T2/de not_active Expired - Lifetime
- 2004-07-28 AU AU2004263673A patent/AU2004263673B2/en not_active Expired - Fee Related
- 2004-07-28 PL PL04766337T patent/PL1651745T3/pl unknown
- 2004-07-28 EP EP04766337A patent/EP1651745B1/en not_active Expired - Lifetime
- 2004-07-28 KR KR1020067001982A patent/KR101175638B1/ko not_active Expired - Fee Related
- 2004-07-28 BR BRPI0412669A patent/BRPI0412669B1/pt not_active IP Right Cessation
- 2004-07-28 MX MXPA06001368A patent/MXPA06001368A/es active IP Right Grant
- 2004-07-28 ES ES04766337T patent/ES2281002T3/es not_active Expired - Lifetime
- 2004-07-28 CN CN2004800293083A patent/CN1863900B/zh not_active Expired - Fee Related
- 2004-08-04 TW TW093123329A patent/TWI384104B/zh not_active IP Right Cessation
- 2004-08-04 AR ARP040102779A patent/AR046403A1/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| ATE354631T1 (de) | 2007-03-15 |
| EP1651745A1 (en) | 2006-05-03 |
| AU2004263673B2 (en) | 2010-05-13 |
| DE602004004904D1 (de) | 2007-04-05 |
| KR20060063925A (ko) | 2006-06-12 |
| MXPA06001368A (es) | 2006-05-15 |
| JP2007501306A (ja) | 2007-01-25 |
| US8293695B2 (en) | 2012-10-23 |
| US20060205624A1 (en) | 2006-09-14 |
| BRPI0412669B1 (pt) | 2015-11-24 |
| ES2281002T3 (es) | 2007-09-16 |
| TWI384104B (zh) | 2013-02-01 |
| WO2005014769A1 (en) | 2005-02-17 |
| AU2004263673A1 (en) | 2005-02-17 |
| AR046403A1 (es) | 2005-12-07 |
| JP5189288B2 (ja) | 2013-04-24 |
| CN1863900B (zh) | 2011-01-26 |
| PL1651745T3 (pl) | 2007-07-31 |
| TW200517553A (en) | 2005-06-01 |
| EP1651745B1 (en) | 2007-02-21 |
| KR101175638B1 (ko) | 2012-08-22 |
| CN1863900A (zh) | 2006-11-15 |
| BRPI0412669A (pt) | 2006-09-26 |
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