TWI384104B - 遮蔽組成物 - Google Patents
遮蔽組成物 Download PDFInfo
- Publication number
- TWI384104B TWI384104B TW093123329A TW93123329A TWI384104B TW I384104 B TWI384104 B TW I384104B TW 093123329 A TW093123329 A TW 093123329A TW 93123329 A TW93123329 A TW 93123329A TW I384104 B TWI384104 B TW I384104B
- Authority
- TW
- Taiwan
- Prior art keywords
- alkyl
- group
- formula
- alkoxy
- ion
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 208
- -1 halide ion Chemical class 0.000 claims description 207
- 239000000975 dye Substances 0.000 claims description 83
- 229910052739 hydrogen Inorganic materials 0.000 claims description 73
- 239000001257 hydrogen Substances 0.000 claims description 70
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 66
- 150000001875 compounds Chemical class 0.000 claims description 63
- 125000000217 alkyl group Chemical group 0.000 claims description 58
- 238000009472 formulation Methods 0.000 claims description 53
- 239000003599 detergent Substances 0.000 claims description 47
- 150000003839 salts Chemical class 0.000 claims description 46
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 45
- 239000002245 particle Substances 0.000 claims description 42
- 239000008187 granular material Substances 0.000 claims description 39
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 claims description 39
- 239000000987 azo dye Substances 0.000 claims description 38
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 36
- 239000000654 additive Substances 0.000 claims description 34
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 34
- 229910052736 halogen Inorganic materials 0.000 claims description 34
- 150000002367 halogens Chemical group 0.000 claims description 34
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 33
- 229910052757 nitrogen Inorganic materials 0.000 claims description 31
- 125000003342 alkenyl group Chemical group 0.000 claims description 26
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 26
- 230000000996 additive effect Effects 0.000 claims description 25
- 125000003118 aryl group Chemical group 0.000 claims description 24
- 239000012669 liquid formulation Substances 0.000 claims description 24
- 239000011941 photocatalyst Substances 0.000 claims description 24
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 17
- 150000001450 anions Chemical class 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 14
- 125000003545 alkoxy group Chemical group 0.000 claims description 13
- 150000002148 esters Chemical class 0.000 claims description 11
- 229940045799 anthracyclines and related substance Drugs 0.000 claims description 10
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 10
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 8
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 8
- 239000000460 chlorine Substances 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 125000002947 alkylene group Chemical group 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 6
- 150000004056 anthraquinones Chemical class 0.000 claims description 6
- 125000004122 cyclic group Chemical group 0.000 claims description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 4
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 4
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 claims description 4
- CKHJYUSOUQDYEN-UHFFFAOYSA-N gallium(3+) Chemical compound [Ga+3] CKHJYUSOUQDYEN-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
- 125000001624 naphthyl group Chemical group 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- 150000001449 anionic compounds Chemical class 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 229910001412 inorganic anion Inorganic materials 0.000 claims description 3
- 150000002891 organic anions Chemical class 0.000 claims description 3
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 3
- 125000004434 sulfur atom Chemical group 0.000 claims description 3
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims description 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 125000006570 (C5-C6) heteroaryl group Chemical group 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 description 44
- 239000002979 fabric softener Substances 0.000 description 34
- 239000002253 acid Substances 0.000 description 27
- 239000011734 sodium Substances 0.000 description 26
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 24
- 125000001309 chloro group Chemical group Cl* 0.000 description 23
- 239000003795 chemical substances by application Substances 0.000 description 20
- 239000004744 fabric Substances 0.000 description 19
- 108090000790 Enzymes Proteins 0.000 description 17
- 102000004190 Enzymes Human genes 0.000 description 17
- 239000002585 base Substances 0.000 description 17
- 125000004093 cyano group Chemical group *C#N 0.000 description 17
- 229940088598 enzyme Drugs 0.000 description 17
- 239000011777 magnesium Substances 0.000 description 17
- 238000000034 method Methods 0.000 description 17
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 16
- 239000007788 liquid Substances 0.000 description 16
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 15
- 239000002270 dispersing agent Substances 0.000 description 15
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 15
- 239000002736 nonionic surfactant Substances 0.000 description 15
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 14
- 229920001577 copolymer Polymers 0.000 description 14
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 description 13
- 229910052783 alkali metal Inorganic materials 0.000 description 13
- 239000011575 calcium Substances 0.000 description 13
- 235000014113 dietary fatty acids Nutrition 0.000 description 13
- 239000000194 fatty acid Substances 0.000 description 13
- 229930195729 fatty acid Natural products 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- 229910052708 sodium Inorganic materials 0.000 description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
- 239000007859 condensation product Substances 0.000 description 12
- 150000002978 peroxides Chemical class 0.000 description 12
- 239000007787 solid Substances 0.000 description 12
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 11
- 239000004615 ingredient Substances 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 11
- 125000001424 substituent group Chemical group 0.000 description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 10
- 239000012190 activator Substances 0.000 description 10
- 125000000129 anionic group Chemical group 0.000 description 10
- 239000003945 anionic surfactant Substances 0.000 description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 10
- 150000002191 fatty alcohols Chemical class 0.000 description 10
- 239000000835 fiber Substances 0.000 description 10
- 230000003287 optical effect Effects 0.000 description 10
- 239000003760 tallow Substances 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 9
- 125000001931 aliphatic group Chemical group 0.000 description 9
- 239000007844 bleaching agent Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 238000001694 spray drying Methods 0.000 description 9
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 150000004665 fatty acids Chemical class 0.000 description 8
- 239000006081 fluorescent whitening agent Substances 0.000 description 8
- 150000007524 organic acids Chemical class 0.000 description 8
- 239000000049 pigment Substances 0.000 description 8
- 159000000000 sodium salts Chemical class 0.000 description 8
- 239000002689 soil Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 7
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 7
- 150000001340 alkali metals Chemical class 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 239000002304 perfume Substances 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 239000002518 antifoaming agent Substances 0.000 description 6
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
- 239000003112 inhibitor Substances 0.000 description 6
- BQJCRHHNABKAKU-KBQPJGBKSA-N morphine Chemical group O([C@H]1[C@H](C=C[C@H]23)O)C4=C5[C@@]12CCN(C)[C@@H]3CC5=CC=C4O BQJCRHHNABKAKU-KBQPJGBKSA-N 0.000 description 6
- 150000003138 primary alcohols Chemical class 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- ZUGAOYSWHHGDJY-UHFFFAOYSA-K 5-hydroxy-2,8,9-trioxa-1-aluminabicyclo[3.3.2]decane-3,7,10-trione Chemical compound [Al+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O ZUGAOYSWHHGDJY-UHFFFAOYSA-K 0.000 description 5
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 5
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 5
- MXBDBLBKBBAYGD-UHFFFAOYSA-N P(O)(O)=O.C Chemical compound P(O)(O)=O.C MXBDBLBKBBAYGD-UHFFFAOYSA-N 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000003513 alkali Substances 0.000 description 5
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 150000001860 citric acid derivatives Chemical class 0.000 description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 230000000855 fungicidal effect Effects 0.000 description 5
- 239000000417 fungicide Substances 0.000 description 5
- 230000000873 masking effect Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 125000002757 morpholinyl group Chemical group 0.000 description 5
- 229920000620 organic polymer Polymers 0.000 description 5
- 229920005646 polycarboxylate Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 241000894007 species Species 0.000 description 5
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 4
- 108010059892 Cellulase Proteins 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 108091005804 Peptidases Proteins 0.000 description 4
- 102000035195 Peptidases Human genes 0.000 description 4
- 239000004365 Protease Substances 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 239000002216 antistatic agent Substances 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 229940106157 cellulase Drugs 0.000 description 4
- 125000000068 chlorophenyl group Chemical group 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000002657 fibrous material Substances 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 4
- 150000007522 mineralic acids Chemical class 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- GJVFBWCTGUSGDD-UHFFFAOYSA-L pentamethonium bromide Chemical compound [Br-].[Br-].C[N+](C)(C)CCCCC[N+](C)(C)C GJVFBWCTGUSGDD-UHFFFAOYSA-L 0.000 description 4
- 150000004965 peroxy acids Chemical class 0.000 description 4
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 4
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- 125000001453 quaternary ammonium group Chemical group 0.000 description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 4
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- 125000003944 tolyl group Chemical group 0.000 description 4
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 description 3
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- ZMLPKJYZRQZLDA-PHEQNACWSA-N 1-[(e)-2-phenylethenyl]-4-[4-[(e)-2-phenylethenyl]phenyl]benzene Chemical group C=1C=CC=CC=1/C=C/C(C=C1)=CC=C1C(C=C1)=CC=C1\C=C\C1=CC=CC=C1 ZMLPKJYZRQZLDA-PHEQNACWSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
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- 235000015165 citric acid Nutrition 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 235000019425 dextrin Nutrition 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
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- 239000003205 fragrance Substances 0.000 description 3
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- 235000019322 gelatine Nutrition 0.000 description 3
- 235000011852 gelatine desserts Nutrition 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 3
- 229910017053 inorganic salt Inorganic materials 0.000 description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 3
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 3
- 239000008108 microcrystalline cellulose Substances 0.000 description 3
- 229940016286 microcrystalline cellulose Drugs 0.000 description 3
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- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
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- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- GVWISOJSERXQBM-UHFFFAOYSA-N n-methylpropan-1-amine Chemical compound CCCNC GVWISOJSERXQBM-UHFFFAOYSA-N 0.000 description 1
- 239000006199 nebulizer Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 125000004287 oxazol-2-yl group Chemical group [H]C1=C([H])N=C(*)O1 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N penta-1,3-diene Chemical compound CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
- CTYRPMDGLDAWRQ-UHFFFAOYSA-N phenyl hydrogen sulfate Chemical compound OS(=O)(=O)OC1=CC=CC=C1 CTYRPMDGLDAWRQ-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229940085991 phosphate ion Drugs 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- INAAIJLSXJJHOZ-UHFFFAOYSA-N pibenzimol Chemical class C1CN(C)CCN1C1=CC=C(N=C(N2)C=3C=C4NC(=NC4=CC=3)C=3C=CC(O)=CC=3)C2=C1 INAAIJLSXJJHOZ-UHFFFAOYSA-N 0.000 description 1
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- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
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- 229920000768 polyamine Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 229940048914 protamine Drugs 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
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- 230000000717 retained effect Effects 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 229940037001 sodium edetate Drugs 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- YPPQYORGOMWNMX-UHFFFAOYSA-L sodium phosphonate pentahydrate Chemical compound [Na+].[Na+].[O-]P([O-])=O YPPQYORGOMWNMX-UHFFFAOYSA-L 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 125000006296 sulfonyl amino group Chemical group [H]N(*)S(*)(=O)=O 0.000 description 1
- BZWKPZBXAMTXNQ-UHFFFAOYSA-N sulfurocyanidic acid Chemical compound OS(=O)(=O)C#N BZWKPZBXAMTXNQ-UHFFFAOYSA-N 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 150000003510 tertiary aliphatic amines Chemical class 0.000 description 1
- 150000003569 thioglycosides Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- NRWCNEBHECBWRJ-UHFFFAOYSA-M trimethyl(propyl)azanium;chloride Chemical compound [Cl-].CCC[N+](C)(C)C NRWCNEBHECBWRJ-UHFFFAOYSA-M 0.000 description 1
- 150000003648 triterpenes Chemical class 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0004—Non aqueous liquid compositions comprising insoluble particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0063—Photo- activating compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03102447 | 2003-08-06 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200517553A TW200517553A (en) | 2005-06-01 |
| TWI384104B true TWI384104B (zh) | 2013-02-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW093123329A TWI384104B (zh) | 2003-08-06 | 2004-08-04 | 遮蔽組成物 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US8293695B2 (https=) |
| EP (1) | EP1651745B1 (https=) |
| JP (1) | JP5189288B2 (https=) |
| KR (1) | KR101175638B1 (https=) |
| CN (1) | CN1863900B (https=) |
| AR (1) | AR046403A1 (https=) |
| AT (1) | ATE354631T1 (https=) |
| AU (1) | AU2004263673B2 (https=) |
| BR (1) | BRPI0412669B1 (https=) |
| DE (1) | DE602004004904T2 (https=) |
| ES (1) | ES2281002T3 (https=) |
| MX (1) | MXPA06001368A (https=) |
| PL (1) | PL1651745T3 (https=) |
| TW (1) | TWI384104B (https=) |
| WO (1) | WO2005014769A1 (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| GB0314210D0 (en) | 2003-06-18 | 2003-07-23 | Unilever Plc | Laundry treatment compositions |
| GB0421145D0 (en) * | 2004-09-23 | 2004-10-27 | Unilever Plc | Laundry treatment compositions |
| ES2322864T3 (es) * | 2004-09-23 | 2009-06-30 | Unilever N.V. | Composiciones de tratamiento de ropa sucia. |
| PL1975226T3 (pl) * | 2007-03-20 | 2013-07-31 | Procter & Gamble | Płynna kompozycja do obróbki |
| ATE512201T1 (de) * | 2007-11-26 | 2011-06-15 | Procter & Gamble | Verbessertes schattierungsverfahren |
| BRPI0910682B1 (pt) * | 2008-05-02 | 2020-09-24 | Unilever N.V. | Grânulo de corante tonalizante que produzem menos manchas, e, composição detergente granular para lavar roupas |
| GB0810881D0 (en) | 2008-06-16 | 2008-07-23 | Unilever Plc | Improvements relating to fabric cleaning |
| JP5491513B2 (ja) * | 2008-10-24 | 2014-05-14 | コグニス・アイピー・マネージメント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | アルキルスルホスクシネート混合物およびその使用 |
| US8449626B2 (en) | 2009-11-11 | 2013-05-28 | The Procter & Gamble Company | Cleaning method |
| EP2343359A1 (en) | 2010-01-07 | 2011-07-13 | Unilever PLC | Detergent formulation containing spray dried granule |
| ES2530522T3 (es) | 2010-02-12 | 2015-03-03 | Unilever Nv | Composición de tratamiento para el lavado de ropa, que comprende colorantes de matizado bis-azoicos |
| CA2797139C (en) * | 2010-05-07 | 2015-06-23 | Basf Se | Dyes and blends for shading during laundry |
| GB201011511D0 (en) | 2010-07-08 | 2010-08-25 | Unilever Plc | Composions comprising optical benefits agents |
| AR082329A1 (es) * | 2010-07-23 | 2012-11-28 | Clariant Int Ltd | Metodo para preparar papel blanco |
| PH12013501439A1 (en) | 2011-01-31 | 2019-09-02 | Unilever Nv | Alkaline liquid detergent compositions |
| EP2476743B1 (en) | 2011-04-04 | 2013-04-24 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Method of laundering fabric |
| WO2012156250A1 (en) | 2011-05-13 | 2012-11-22 | Unilever Plc | Aqueous concentrated laundry detergent compositions |
| EP2522714A1 (en) | 2011-05-13 | 2012-11-14 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Aqueous concentrated laundry detergent compositions |
| EP2522715A1 (en) | 2011-05-13 | 2012-11-14 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Aqueous concentrated laundry detergent compositions |
| EP2557128B1 (en) * | 2011-08-11 | 2015-02-25 | Clariant International Ltd. | Improved aqueous compositions for whitening and shading in coating applications |
| BR112014013942B1 (pt) | 2011-12-20 | 2021-03-02 | Unilever Ip Holdings B.V | composição detergente líquida isotrópica |
| CN104334705A (zh) * | 2012-04-03 | 2015-02-04 | 巴斯夫欧洲公司 | 包含酞菁颗粒的组合物 |
| JP2015519429A (ja) * | 2012-04-27 | 2015-07-09 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | フタロシアニン粒子及びその使用 |
| EP2850166B1 (en) | 2012-05-16 | 2015-10-21 | Unilever PLC | Laundry detergent compositions comprising polyalkoxylated polyethyleneimine |
| EP2948535B1 (en) | 2013-01-23 | 2018-03-07 | Unilever Plc. | An uncoloured laundry additive material for promotion of anti redeposition of particulate soil |
| EP2770044A1 (en) | 2013-02-20 | 2014-08-27 | Unilever PLC | Lamellar gel with amine oxide |
| EP3097173B1 (en) * | 2014-01-22 | 2020-12-23 | The Procter and Gamble Company | Fabric treatment composition |
| TR201819563T4 (tr) | 2015-01-09 | 2019-01-21 | Unilever Nv | Bir boya içeren çamaşır arıtma bileşimi. |
| WO2016155993A1 (en) | 2015-04-02 | 2016-10-06 | Unilever Plc | Composition |
| WO2017121714A1 (en) | 2016-01-15 | 2017-07-20 | Unilever Plc | Dye |
| ES2985315T3 (es) | 2016-05-17 | 2024-11-05 | Unilever Ip Holdings B V | Composiciones de detergente líquidas para el lavado de ropa |
| CN109196083A (zh) | 2016-05-17 | 2019-01-11 | 荷兰联合利华有限公司 | 液体洗衣洗涤剂组合物 |
| WO2017202923A1 (en) | 2016-05-27 | 2017-11-30 | Unilever Plc | Laundry composition |
| MX2019005120A (es) | 2016-11-01 | 2019-06-20 | Procter & Gamble | Colorantes leuco como agentes de azulado en composiciones para el cuidado de la ropa. |
| WO2018127390A1 (en) | 2017-01-06 | 2018-07-12 | Unilever N.V. | Stain removing composition |
| WO2019038186A1 (en) | 2017-08-24 | 2019-02-28 | Unilever Plc | IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS |
| WO2019038187A1 (en) | 2017-08-24 | 2019-02-28 | Unilever Plc | IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5211719A (en) * | 1990-10-04 | 1993-05-18 | Ciba-Geigy Corporation | Concentrated acqueous solutions of anionic disazo dyes with polyglycol-amine |
| CN1251126A (zh) * | 1997-01-24 | 2000-04-19 | 普罗格特-甘布尔公司 | 对脏织物有效的光漂白组合物 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB916532A (en) * | 1960-04-29 | 1963-01-23 | Basf Ag | Water-soluble dyes of the phthalocyanine-azo series |
| US3762859A (en) * | 1971-03-15 | 1973-10-02 | Colgate Palmolive Co | Enhancing the apparent whiteness of fabrics by applying an effective amount of an alkali and heat stable water soluble disazo blue dyestuff fabric softening and detergent composition therefor |
| EP0041239A3 (de) * | 1980-06-04 | 1982-05-12 | Ciba-Geigy Ag | Stabile konzentrierte flüssige Zubereitungen von metallfreien Farbstoffen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE3125495A1 (de) * | 1980-07-02 | 1982-05-19 | CIBA-GEIGY AG, 4002 Basel | "verwendung von farbstoffen zur nuancierung von optischen aufhellungen" |
| JPS5725365A (en) * | 1980-07-22 | 1982-02-10 | Showa Kagaku Kogyo Kk | Dyestuff salt-containing fluorescent brightener composition |
| JPS57155299A (en) * | 1981-03-23 | 1982-09-25 | Kao Corp | Detergent bleaching agent |
| JPS6225171A (ja) * | 1985-07-25 | 1987-02-03 | Fuji Photo Film Co Ltd | 青色系染料組成物 |
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| GB8806016D0 (en) * | 1988-03-14 | 1988-04-13 | Danochemo As | Encapsulated photoactivator dyes for detergent use |
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| ATE272104T1 (de) * | 1998-05-18 | 2004-08-15 | Ciba Sc Holding Ag | Wasserlösliche granulate von phthalocyaninverbindungen |
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| GB0120160D0 (en) * | 2001-08-20 | 2001-10-10 | Unilever Plc | Photobleach speckle and laundry detergent compositions containing it |
| BRPI0514747A (pt) * | 2004-08-30 | 2008-06-24 | Ciba Sc Holding Ag | processo de gradação de cor |
-
2004
- 2004-07-28 AT AT04766337T patent/ATE354631T1/de not_active IP Right Cessation
- 2004-07-28 US US10/567,203 patent/US8293695B2/en not_active Expired - Fee Related
- 2004-07-28 JP JP2006522347A patent/JP5189288B2/ja not_active Expired - Fee Related
- 2004-07-28 WO PCT/EP2004/051627 patent/WO2005014769A1/en not_active Ceased
- 2004-07-28 DE DE602004004904T patent/DE602004004904T2/de not_active Expired - Lifetime
- 2004-07-28 AU AU2004263673A patent/AU2004263673B2/en not_active Expired - Fee Related
- 2004-07-28 PL PL04766337T patent/PL1651745T3/pl unknown
- 2004-07-28 EP EP04766337A patent/EP1651745B1/en not_active Expired - Lifetime
- 2004-07-28 KR KR1020067001982A patent/KR101175638B1/ko not_active Expired - Fee Related
- 2004-07-28 BR BRPI0412669A patent/BRPI0412669B1/pt not_active IP Right Cessation
- 2004-07-28 MX MXPA06001368A patent/MXPA06001368A/es active IP Right Grant
- 2004-07-28 ES ES04766337T patent/ES2281002T3/es not_active Expired - Lifetime
- 2004-07-28 CN CN2004800293083A patent/CN1863900B/zh not_active Expired - Fee Related
- 2004-08-04 TW TW093123329A patent/TWI384104B/zh not_active IP Right Cessation
- 2004-08-04 AR ARP040102779A patent/AR046403A1/es not_active Application Discontinuation
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| US5211719A (en) * | 1990-10-04 | 1993-05-18 | Ciba-Geigy Corporation | Concentrated acqueous solutions of anionic disazo dyes with polyglycol-amine |
| CN1251126A (zh) * | 1997-01-24 | 2000-04-19 | 普罗格特-甘布尔公司 | 对脏织物有效的光漂白组合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE354631T1 (de) | 2007-03-15 |
| EP1651745A1 (en) | 2006-05-03 |
| AU2004263673B2 (en) | 2010-05-13 |
| DE602004004904D1 (de) | 2007-04-05 |
| DE602004004904T2 (de) | 2007-10-31 |
| KR20060063925A (ko) | 2006-06-12 |
| MXPA06001368A (es) | 2006-05-15 |
| JP2007501306A (ja) | 2007-01-25 |
| US8293695B2 (en) | 2012-10-23 |
| US20060205624A1 (en) | 2006-09-14 |
| BRPI0412669B1 (pt) | 2015-11-24 |
| ES2281002T3 (es) | 2007-09-16 |
| WO2005014769A1 (en) | 2005-02-17 |
| AU2004263673A1 (en) | 2005-02-17 |
| AR046403A1 (es) | 2005-12-07 |
| JP5189288B2 (ja) | 2013-04-24 |
| CN1863900B (zh) | 2011-01-26 |
| PL1651745T3 (pl) | 2007-07-31 |
| TW200517553A (en) | 2005-06-01 |
| EP1651745B1 (en) | 2007-02-21 |
| KR101175638B1 (ko) | 2012-08-22 |
| CN1863900A (zh) | 2006-11-15 |
| BRPI0412669A (pt) | 2006-09-26 |
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| MM4A | Annulment or lapse of patent due to non-payment of fees |