DE60114896T8 - Überbrückte Bisindenylmetallocenverbindungen - Google Patents

Überbrückte Bisindenylmetallocenverbindungen Download PDF

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Publication number
DE60114896T8
DE60114896T8 DE60114896T DE60114896T DE60114896T8 DE 60114896 T8 DE60114896 T8 DE 60114896T8 DE 60114896 T DE60114896 T DE 60114896T DE 60114896 T DE60114896 T DE 60114896T DE 60114896 T8 DE60114896 T8 DE 60114896T8
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DE
Germany
Prior art keywords
alkenyl
aryl
alkyl
metallocene compound
arylalkenyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
DE60114896T
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German (de)
English (en)
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DE60114896D1 (de
DE60114896T2 (de
Inventor
Matthew C. Kuchta
Udo M. Stehling
Robert T. Li
William T. Haygood
Terry J. Burkhardt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Priority claimed from US09/619,751 external-priority patent/US6380121B1/en
Priority claimed from US09/620,046 external-priority patent/US6380122B1/en
Priority claimed from US09/619,749 external-priority patent/US6376407B1/en
Priority claimed from US09/620,302 external-priority patent/US6376411B1/en
Priority claimed from US09/620,341 external-priority patent/US6380123B1/en
Priority claimed from US09/620,359 external-priority patent/US6376413B1/en
Priority claimed from US09/620,303 external-priority patent/US6414095B1/en
Priority claimed from US09/620,198 external-priority patent/US6380330B1/en
Priority claimed from US09/619,764 external-priority patent/US6376409B1/en
Priority claimed from US09/620,613 external-priority patent/US6380331B1/en
Priority claimed from US09/619,757 external-priority patent/US6380334B1/en
Priority claimed from US09/619,750 external-priority patent/US6380120B1/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of DE60114896D1 publication Critical patent/DE60114896D1/de
Application granted granted Critical
Publication of DE60114896T2 publication Critical patent/DE60114896T2/de
Publication of DE60114896T8 publication Critical patent/DE60114896T8/de
Active legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Indole Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
DE60114896T 2000-06-30 2001-05-21 Überbrückte Bisindenylmetallocenverbindungen Active DE60114896T8 (de)

Applications Claiming Priority (28)

Application Number Priority Date Filing Date Title
US21559700P 2000-06-30 2000-06-30
US21545900P 2000-06-30 2000-06-30
US215597P 2000-06-30
US215459P 2000-06-30
US620046 2000-07-19
US620198 2000-07-19
US09/620,359 US6376413B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US619749 2000-07-19
US620613 2000-07-19
US09/620,303 US6414095B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,198 US6380330B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,613 US6380331B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US620302 2000-07-19
US09/619,757 US6380334B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US619764 2000-07-19
US09/620,046 US6380122B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US620359 2000-07-19
US620341 2000-07-19
US09/619,750 US6380120B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US620303 2000-07-19
US619750 2000-07-19
US09/619,751 US6380121B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US619757 2000-07-19
US09/619,764 US6376409B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,341 US6380123B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US619751 2000-07-19
US09/620,302 US6376411B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,749 US6376407B1 (en) 2000-06-30 2000-07-19 Metallocene compositions

Publications (3)

Publication Number Publication Date
DE60114896D1 DE60114896D1 (de) 2005-12-15
DE60114896T2 DE60114896T2 (de) 2006-07-27
DE60114896T8 true DE60114896T8 (de) 2007-04-26

Family

ID=27585093

Family Applications (2)

Application Number Title Priority Date Filing Date
DE60114896T Active DE60114896T8 (de) 2000-06-30 2001-05-21 Überbrückte Bisindenylmetallocenverbindungen
DE60102156T Active DE60102156T8 (de) 2000-06-30 2001-05-21 Verbrückte Bisindenyl Substituierte Metallocen-Verbindungen

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE60102156T Active DE60102156T8 (de) 2000-06-30 2001-05-21 Verbrückte Bisindenyl Substituierte Metallocen-Verbindungen

Country Status (6)

Country Link
EP (2) EP1294733B1 (enExample)
JP (1) JP2004502698A (enExample)
AT (2) ATE260289T1 (enExample)
DE (2) DE60114896T8 (enExample)
ES (2) ES2211808T3 (enExample)
WO (1) WO2002002575A1 (enExample)

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HUE052511T2 (hu) 2011-03-02 2021-05-28 Borealis Ag Eljárás polimerek elõállítására
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EP3848401A1 (en) 2013-07-17 2021-07-14 ExxonMobil Chemical Patents Inc. Isotactic propylene polymers
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US9834628B2 (en) 2013-07-17 2017-12-05 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
US9458254B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
CN105829326B (zh) * 2013-12-19 2019-11-08 埃克森美孚化学专利公司 桥连双(茚基)过渡金属络合物、其制备与应用
US9944665B2 (en) 2013-12-19 2018-04-17 Exxonmobil Chemical Patents Inc. Bridged bis(indenyl) transitional metal complexes, production, and use thereof
JP6398814B2 (ja) * 2014-03-20 2018-10-03 日本ポリプロ株式会社 メタロセン錯体およびオレフィン重合体の製造方法
JP6201853B2 (ja) * 2014-03-25 2017-09-27 日本ポリプロ株式会社 メタロセン錯体及びオレフィン重合体の製造方法
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CN106715067A (zh) 2014-12-08 2017-05-24 博里利斯股份公司 丙烯共聚物粒料的制备方法
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US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
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WO2016196331A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
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JP6613987B2 (ja) * 2016-03-28 2019-12-04 日本ポリプロ株式会社 メタロセン錯体、オレフィン重合用触媒、およびオレフィン重合体の製造方法
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US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
EP3608364A1 (en) 2018-08-06 2020-02-12 Borealis AG Multimodal propylene random copolymer based composition suitable as hot melt adhesive composition
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US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
CN116670146A (zh) 2020-11-23 2023-08-29 埃克森美孚化学专利公司 使用不含芳族溶剂的载体制备的茂金属聚丙烯
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US20250002617A1 (en) 2021-09-02 2025-01-02 ExxonMobil Technology and Engineering Company C1 symmetric metallocene catalysts tailored for production of vinyl-terminated polypropylene oligomers and macromonomers
JP2025526711A (ja) 2022-08-09 2025-08-15 エクソンモービル ケミカル パテンツ インコーポレイテッド ジフェニルシラン架橋c1対称触媒及びそれから製造するポリマー
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TW202438539A (zh) 2022-12-23 2024-10-01 奧地利商柏列利斯股份公司 高流動性聚丙烯均聚物的製造方法
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Also Published As

Publication number Publication date
DE60114896D1 (de) 2005-12-15
ATE309259T1 (de) 2005-11-15
DE60102156D1 (de) 2004-04-01
EP1294733B1 (en) 2004-02-25
EP1411058A1 (en) 2004-04-21
WO2002002575A1 (en) 2002-01-10
EP1411058B1 (en) 2005-11-09
ATE260289T1 (de) 2004-03-15
DE60102156T8 (de) 2005-06-23
EP1294733A1 (en) 2003-03-26
DE60114896T2 (de) 2006-07-27
DE60102156T2 (de) 2004-12-09
JP2004502698A (ja) 2004-01-29
ES2247473T3 (es) 2006-03-01
ES2211808T3 (es) 2004-07-16

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