ATE260289T1 - Verbrückte bisindenyl substituierte metallocen- verbindungen - Google Patents

Verbrückte bisindenyl substituierte metallocen- verbindungen

Info

Publication number
ATE260289T1
ATE260289T1 AT01937633T AT01937633T ATE260289T1 AT E260289 T1 ATE260289 T1 AT E260289T1 AT 01937633 T AT01937633 T AT 01937633T AT 01937633 T AT01937633 T AT 01937633T AT E260289 T1 ATE260289 T1 AT E260289T1
Authority
AT
Austria
Prior art keywords
alkenyl
aryl
alkyl
metallocene compound
arylalkenyl
Prior art date
Application number
AT01937633T
Other languages
German (de)
English (en)
Inventor
Matthew C Kuchta
Udo M Stehling
Robert T Li
William T Haygood
Terry J Burkhardt
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/620,302 external-priority patent/US6376411B1/en
Priority claimed from US09/619,757 external-priority patent/US6380334B1/en
Priority claimed from US09/620,046 external-priority patent/US6380122B1/en
Priority claimed from US09/620,359 external-priority patent/US6376413B1/en
Priority claimed from US09/619,751 external-priority patent/US6380121B1/en
Priority claimed from US09/619,750 external-priority patent/US6380120B1/en
Priority claimed from US09/619,764 external-priority patent/US6376409B1/en
Priority claimed from US09/620,198 external-priority patent/US6380330B1/en
Priority claimed from US09/620,613 external-priority patent/US6380331B1/en
Priority claimed from US09/620,303 external-priority patent/US6414095B1/en
Priority claimed from US09/619,749 external-priority patent/US6376407B1/en
Priority claimed from US09/620,341 external-priority patent/US6380123B1/en
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Application granted granted Critical
Publication of ATE260289T1 publication Critical patent/ATE260289T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Indole Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
AT01937633T 2000-06-30 2001-05-21 Verbrückte bisindenyl substituierte metallocen- verbindungen ATE260289T1 (de)

Applications Claiming Priority (15)

Application Number Priority Date Filing Date Title
US21545900P 2000-06-30 2000-06-30
US21559700P 2000-06-30 2000-06-30
US09/620,359 US6376413B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,751 US6380121B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,750 US6380120B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,302 US6376411B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,749 US6376407B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,198 US6380330B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,303 US6414095B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,757 US6380334B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,341 US6380123B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,613 US6380331B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,764 US6376409B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,046 US6380122B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
PCT/US2001/016425 WO2002002575A1 (en) 2000-06-30 2001-05-21 Metallocenes with a bridged 4-phenyl-indenyl-ligand for olefin polymerization

Publications (1)

Publication Number Publication Date
ATE260289T1 true ATE260289T1 (de) 2004-03-15

Family

ID=27585093

Family Applications (2)

Application Number Title Priority Date Filing Date
AT01937633T ATE260289T1 (de) 2000-06-30 2001-05-21 Verbrückte bisindenyl substituierte metallocen- verbindungen
AT03027480T ATE309259T1 (de) 2000-06-30 2001-05-21 Überbrückte bisindenylmetallocenverbindungen

Family Applications After (1)

Application Number Title Priority Date Filing Date
AT03027480T ATE309259T1 (de) 2000-06-30 2001-05-21 Überbrückte bisindenylmetallocenverbindungen

Country Status (6)

Country Link
EP (2) EP1411058B1 (enExample)
JP (1) JP2004502698A (enExample)
AT (2) ATE260289T1 (enExample)
DE (2) DE60114896T8 (enExample)
ES (2) ES2247473T3 (enExample)
WO (1) WO2002002575A1 (enExample)

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US9249239B2 (en) 2013-07-17 2016-02-02 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
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ES2703344T3 (es) 2013-07-17 2019-03-08 Exxonmobil Chemical Patents Inc Metalocenos y composiciones catalíticas derivadas de ellos
EP3022236B1 (en) 2013-07-17 2017-11-15 ExxonMobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
US9944665B2 (en) 2013-12-19 2018-04-17 Exxonmobil Chemical Patents Inc. Bridged bis(indenyl) transitional metal complexes, production, and use thereof
CN105829326B (zh) * 2013-12-19 2019-11-08 埃克森美孚化学专利公司 桥连双(茚基)过渡金属络合物、其制备与应用
CN110483670B (zh) * 2014-03-20 2021-11-30 日本聚丙烯株式会社 茂金属配合物和生产烯烃聚合物的方法
JP6201853B2 (ja) * 2014-03-25 2017-09-27 日本ポリプロ株式会社 メタロセン錯体及びオレフィン重合体の製造方法
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US11292156B2 (en) 2014-12-08 2022-04-05 Borealis Ag Process for producing pellets of copolymers of propylene
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US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
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US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
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US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
EP3303422B1 (en) 2015-06-05 2021-03-17 ExxonMobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
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JP6613987B2 (ja) * 2016-03-28 2019-12-04 日本ポリプロ株式会社 メタロセン錯体、オレフィン重合用触媒、およびオレフィン重合体の製造方法
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US20210277290A1 (en) 2018-08-06 2021-09-09 Borealis Ag Propylene random copolymer based hot melt adhesive composition
EP3608364A1 (en) 2018-08-06 2020-02-12 Borealis AG Multimodal propylene random copolymer based composition suitable as hot melt adhesive composition
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CN114929761A (zh) 2019-08-22 2022-08-19 埃克森美孚化学专利公司 用c1对称的茂金属催化剂生产的全同立构的丙烯均聚物和共聚物
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
US20230416418A1 (en) 2020-11-23 2023-12-28 Exxonmobil Chemical Patents Inc. Metallocene polypropylene prepared using aromatic solvent-free supports
EP4144435A1 (en) 2021-09-01 2023-03-08 Borealis AG Gas phase polymerization process with improved gas recycling
US20250002617A1 (en) 2021-09-02 2025-01-02 ExxonMobil Technology and Engineering Company C1 symmetric metallocene catalysts tailored for production of vinyl-terminated polypropylene oligomers and macromonomers
EP4568980A1 (en) 2022-08-09 2025-06-18 ExxonMobil Chemical Patents Inc. Methods for preparing diphenylsilane bridged c1 symmetric catalysts and polymers made therefrom
EP4389776A1 (en) 2022-12-20 2024-06-26 Borealis AG Process
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TW294669B (enExample) * 1992-06-27 1997-01-01 Hoechst Ag

Also Published As

Publication number Publication date
DE60114896D1 (de) 2005-12-15
DE60102156D1 (de) 2004-04-01
JP2004502698A (ja) 2004-01-29
EP1411058B1 (en) 2005-11-09
ES2247473T3 (es) 2006-03-01
DE60114896T2 (de) 2006-07-27
DE60102156T2 (de) 2004-12-09
DE60102156T8 (de) 2005-06-23
EP1411058A1 (en) 2004-04-21
EP1294733B1 (en) 2004-02-25
WO2002002575A1 (en) 2002-01-10
ES2211808T3 (es) 2004-07-16
DE60114896T8 (de) 2007-04-26
ATE309259T1 (de) 2005-11-15
EP1294733A1 (en) 2003-03-26

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