JP2004502698A - オレフィン重合に用いる架橋４−フェニル−インデニル−配位子を有するメタロセン - Google Patents

オレフィン重合に用いる架橋４−フェニル−インデニル−配位子を有するメタロセン Download PDF

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Publication number
JP2004502698A
JP2004502698A JP2002507827A JP2002507827A JP2004502698A JP 2004502698 A JP2004502698 A JP 2004502698A JP 2002507827 A JP2002507827 A JP 2002507827A JP 2002507827 A JP2002507827 A JP 2002507827A JP 2004502698 A JP2004502698 A JP 2004502698A
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Japan
Prior art keywords
group
racemic
indenyl
silafluorenediyl
zirconium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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JP2002507827A
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English (en)
Japanese (ja)
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JP2004502698A5 (enExample
Inventor
クーチタ、マシュー・シー
ステイリング、ウド・エム
リー、ロバート・ティ
ヘイグッド、ウィリアム・ティ
バークハート、テリー・ジェイ
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エクソンモービル・ケミカル・パテンツ・インク
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Priority claimed from US09/620,613 external-priority patent/US6380331B1/en
Priority claimed from US09/619,757 external-priority patent/US6380334B1/en
Priority claimed from US09/619,749 external-priority patent/US6376407B1/en
Priority claimed from US09/620,198 external-priority patent/US6380330B1/en
Priority claimed from US09/620,359 external-priority patent/US6376413B1/en
Priority claimed from US09/620,046 external-priority patent/US6380122B1/en
Priority claimed from US09/620,341 external-priority patent/US6380123B1/en
Priority claimed from US09/620,303 external-priority patent/US6414095B1/en
Priority claimed from US09/619,764 external-priority patent/US6376409B1/en
Priority claimed from US09/620,302 external-priority patent/US6376411B1/en
Priority claimed from US09/619,750 external-priority patent/US6380120B1/en
Priority claimed from US09/619,751 external-priority patent/US6380121B1/en
Application filed by エクソンモービル・ケミカル・パテンツ・インク filed Critical エクソンモービル・ケミカル・パテンツ・インク
Publication of JP2004502698A publication Critical patent/JP2004502698A/ja
Publication of JP2004502698A5 publication Critical patent/JP2004502698A5/ja
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Indole Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
JP2002507827A 2000-06-30 2001-05-21 オレフィン重合に用いる架橋４−フェニル−インデニル−配位子を有するメタロセン Pending JP2004502698A (ja)

Applications Claiming Priority (15)

Application Number Priority Date Filing Date Title
US21559700P 2000-06-30 2000-06-30
US21545900P 2000-06-30 2000-06-30
US09/620,198 US6380330B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,359 US6376413B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,046 US6380122B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,303 US6414095B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,302 US6376411B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,613 US6380331B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,757 US6380334B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,750 US6380120B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,751 US6380121B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,764 US6376409B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,341 US6380123B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,749 US6376407B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
PCT/US2001/016425 WO2002002575A1 (en) 2000-06-30 2001-05-21 Metallocenes with a bridged 4-phenyl-indenyl-ligand for olefin polymerization

Publications (2)

Publication Number Publication Date
JP2004502698A true JP2004502698A (ja) 2004-01-29
JP2004502698A5 JP2004502698A5 (enExample) 2008-07-17

Family

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JP2002507827A Pending JP2004502698A (ja) 2000-06-30 2001-05-21 オレフィン重合に用いる架橋４−フェニル−インデニル−配位子を有するメタロセン

Country Status (6)

Country Link
EP (2) EP1294733B1 (enExample)
JP (1) JP2004502698A (enExample)
AT (2) ATE260289T1 (enExample)
DE (2) DE60114896T8 (enExample)
ES (2) ES2211808T3 (enExample)
WO (1) WO2002002575A1 (enExample)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005126679A (ja) * 2003-09-30 2005-05-19 Japan Polypropylene Corp オレフィン重合用触媒成分、α−オレフィン重合用触媒及びα−オレフィン重合体の製造方法
JP2008509277A (ja) * 2004-08-09 2008-03-27 ダウ グローバル テクノロジーズ インコーポレイティド ポリマーの製造のための担持ビス（ヒドロキシアリールアリールオキシ）触媒
JP2009525375A (ja) * 2006-02-02 2009-07-09 バーゼル・ポリオレフィン・ゲーエムベーハー プロピレンメルトブローン樹脂、プロピレンメルトブローン樹脂繊維及びそれから製造される不織布、並びにその製造方法
JP2015182984A (ja) * 2014-03-25 2015-10-22 日本ポリプロ株式会社 メタロセン錯体及びオレフィン重合体の製造方法
JP2015193605A (ja) * 2014-03-20 2015-11-05 日本ポリプロ株式会社 メタロセン錯体およびオレフィン重合体の製造方法
JP2017178786A (ja) * 2016-03-28 2017-10-05 日本ポリプロ株式会社 メタロセン錯体、オレフィン重合用触媒、およびオレフィン重合体の製造方法

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US7122498B2 (en) 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
JP2005522406A (ja) * 2001-06-29 2005-07-28 エクソンモービル・ケミカル・パテンツ・インク メタロセン及び該メタロセン由来の触媒組成物
DE10158656A1 (de) * 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
WO2003091265A1 (en) * 2002-04-23 2003-11-06 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
AU2003273400A1 (en) * 2002-10-10 2004-05-04 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
TW200932770A (en) 2007-10-22 2009-08-01 Univation Tech Llc Metallocene catalysts and their use in polymerization processes
CN102686613B (zh) 2009-11-13 2014-08-13 博瑞立斯有限公司 用于回收过渡金属化合物的方法
ES2424958T3 (es) 2009-11-13 2013-10-10 Borealis Ag Proceso para polimerización de olefinas
EP2322568B1 (en) 2009-11-13 2013-05-15 Borealis AG Process for producing an olefin polymerization catalyst
EP2499168B1 (en) 2009-11-13 2017-05-10 Borealis AG Process for recovering a transition metal compound
EP2330136B1 (en) 2009-12-07 2013-08-28 Borealis AG Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins
HUE052511T2 (hu) 2011-03-02 2021-05-28 Borealis Ag Eljárás polimerek elõállítására
PT2495037T (pt) 2011-03-02 2020-09-15 Borealis Ag Montagem de reator de alto rendimento para a polimerização de olefinas
EP2532687A3 (en) 2011-06-10 2013-04-10 Borealis AG Bridged Metallocene Catalysts
ES2605429T3 (es) 2011-06-15 2017-03-14 Borealis Ag Mezcla del reactor in situ de un polipropileno nucleado catalizado por Ziegler-Natta y un polipropileno catalizado por metaloceno
ES2796856T3 (es) 2012-08-29 2020-11-30 Borealis Ag Conjunto de reactor y procedimiento para la polimerización de olefinas
US9321914B2 (en) * 2012-10-31 2016-04-26 Exxonmobil Chemical Patents Inc. Propylene copolymer compositions and processes to produce them
EP2745927A1 (en) 2012-12-21 2014-06-25 Borealis AG Fluidized bed reactor with internal moving bed reaction unit
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EP2745926A1 (en) 2012-12-21 2014-06-25 Borealis AG Gas phase polymerization and reactor assembly comprising a fluidized bed reactor and an external moving bed reactor
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
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ES2703344T3 (es) 2013-07-17 2019-03-08 Exxonmobil Chemical Patents Inc Metalocenos y composiciones catalíticas derivadas de ellos
US9834628B2 (en) 2013-07-17 2017-12-05 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
US9458254B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
CN105829326B (zh) * 2013-12-19 2019-11-08 埃克森美孚化学专利公司 桥连双(茚基)过渡金属络合物、其制备与应用
US9944665B2 (en) 2013-12-19 2018-04-17 Exxonmobil Chemical Patents Inc. Bridged bis(indenyl) transitional metal complexes, production, and use thereof
EP3023450B1 (en) 2014-11-21 2017-07-19 Borealis AG Process for producing pellets of soft copolymers
CN106715067A (zh) 2014-12-08 2017-05-24 博里利斯股份公司 丙烯共聚物粒料的制备方法
WO2016196339A2 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
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TW202438539A (zh) 2022-12-23 2024-10-01 奧地利商柏列利斯股份公司 高流動性聚丙烯均聚物的製造方法
WO2024133046A1 (en) 2022-12-23 2024-06-27 Borealis Ag Process for producing a polypropylene copolymer
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WO2025003435A1 (en) 2023-06-30 2025-01-02 Borealis Ag Process
WO2025219533A1 (en) 2024-04-18 2025-10-23 Borealis Gmbh Process for the preparation of a propylene homopolymer
WO2025219537A1 (en) 2024-04-18 2025-10-23 Borealis Gmbh Process for propylene polymerization with optimized prepolymerization conditions

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TW294669B (enExample) * 1992-06-27 1997-01-01 Hoechst Ag

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005126679A (ja) * 2003-09-30 2005-05-19 Japan Polypropylene Corp オレフィン重合用触媒成分、α−オレフィン重合用触媒及びα−オレフィン重合体の製造方法
JP2008509277A (ja) * 2004-08-09 2008-03-27 ダウ グローバル テクノロジーズ インコーポレイティド ポリマーの製造のための担持ビス（ヒドロキシアリールアリールオキシ）触媒
JP2009525375A (ja) * 2006-02-02 2009-07-09 バーゼル・ポリオレフィン・ゲーエムベーハー プロピレンメルトブローン樹脂、プロピレンメルトブローン樹脂繊維及びそれから製造される不織布、並びにその製造方法
JP2015193605A (ja) * 2014-03-20 2015-11-05 日本ポリプロ株式会社 メタロセン錯体およびオレフィン重合体の製造方法
US9963522B2 (en) 2014-03-20 2018-05-08 Japan Polypropylene Corporation Metallocene complex and method for producing olefin polymer
JP2015182984A (ja) * 2014-03-25 2015-10-22 日本ポリプロ株式会社 メタロセン錯体及びオレフィン重合体の製造方法
JP2017178786A (ja) * 2016-03-28 2017-10-05 日本ポリプロ株式会社 メタロセン錯体、オレフィン重合用触媒、およびオレフィン重合体の製造方法

Also Published As

Publication number Publication date
DE60114896D1 (de) 2005-12-15
ATE309259T1 (de) 2005-11-15
DE60102156D1 (de) 2004-04-01
DE60114896T8 (de) 2007-04-26
EP1294733B1 (en) 2004-02-25
EP1411058A1 (en) 2004-04-21
WO2002002575A1 (en) 2002-01-10
EP1411058B1 (en) 2005-11-09
ATE260289T1 (de) 2004-03-15
DE60102156T8 (de) 2005-06-23
EP1294733A1 (en) 2003-03-26
DE60114896T2 (de) 2006-07-27
DE60102156T2 (de) 2004-12-09
ES2247473T3 (es) 2006-03-01
ES2211808T3 (es) 2004-07-16

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