DE60105032T2 - Chirale verbindungen iii - Google Patents
Chirale verbindungen iii Download PDFInfo
- Publication number
- DE60105032T2 DE60105032T2 DE60105032T DE60105032T DE60105032T2 DE 60105032 T2 DE60105032 T2 DE 60105032T2 DE 60105032 T DE60105032 T DE 60105032T DE 60105032 T DE60105032 T DE 60105032T DE 60105032 T2 DE60105032 T2 DE 60105032T2
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- chiral
- phe
- cyc
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- 239000000047 product Substances 0.000 description 1
- 125000006410 propenylene group Chemical group 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical class O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000001629 stilbenes Chemical class 0.000 description 1
- 150000001911 terphenyls Chemical class 0.000 description 1
- 150000001608 tolans Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
- C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
- C09K19/3402—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having oxygen as hetero atom
- C09K19/3405—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having oxygen as hetero atom the heterocyclic ring being a five-membered ring
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Crystal Substances (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Cosmetics (AREA)
- Hydrogenated Pyridines (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00115249 | 2000-07-13 | ||
| EP00115249 | 2000-07-13 | ||
| PCT/EP2001/007218 WO2002006265A1 (en) | 2000-07-13 | 2001-06-25 | Chiral compounds iii |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60105032D1 DE60105032D1 (de) | 2004-09-23 |
| DE60105032T2 true DE60105032T2 (de) | 2005-08-18 |
Family
ID=8169247
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60105032T Expired - Lifetime DE60105032T2 (de) | 2000-07-13 | 2001-06-25 | Chirale verbindungen iii |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7041345B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP1299375B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5111715B2 (cg-RX-API-DMAC7.html) |
| CN (1) | CN1264835C (cg-RX-API-DMAC7.html) |
| AT (1) | ATE273968T1 (cg-RX-API-DMAC7.html) |
| AU (1) | AU2001281885A1 (cg-RX-API-DMAC7.html) |
| DE (1) | DE60105032T2 (cg-RX-API-DMAC7.html) |
| TW (1) | TWI224130B (cg-RX-API-DMAC7.html) |
| WO (1) | WO2002006265A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (96)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001096494A1 (en) * | 2000-06-09 | 2001-12-20 | Kent Displays, Inc. | Chiral additives for cholesteric displays |
| JP2003161835A (ja) | 2001-07-02 | 2003-06-06 | Merck Patent Gmbh | 光学可変マーキング |
| DE10257711B4 (de) | 2001-12-27 | 2019-09-26 | Merck Patent Gmbh | Polymerisierbare monocyclische Verbindungen enthaltende Flüssigkristallmischungen |
| DE60332784D1 (de) * | 2002-02-13 | 2010-07-15 | Merck Patent Gmbh | Verfahren zur Herstellung von einem anisotropen Polymerfilm auf einem Substrat mit einer strukturierten Oberfläche |
| WO2005095544A1 (en) | 2004-03-25 | 2005-10-13 | Merck Patent Gmbh | Liquid crystal compounds, liquid crystal medium and liquid crystal display |
| CN101080480B (zh) | 2004-12-17 | 2017-08-08 | 默克专利股份有限公司 | 液晶体系和液晶显示器 |
| US7782438B2 (en) * | 2006-06-13 | 2010-08-24 | Kent State University | Fast switching electro-optical devices using banana-shaped liquid crystals |
| US8574454B2 (en) | 2006-12-22 | 2013-11-05 | Rolic Ag | Patternable liquid crystal polymer comprising thio-ether units |
| EP2065361B1 (de) | 2007-11-30 | 2014-12-17 | Merck Patent GmbH | Polymerisierbare Verbindungen |
| ATE528377T1 (de) | 2008-03-05 | 2011-10-15 | Merck Patent Gmbh | Flüssigkristallines medium und flüssigkristallanzeige mit verdrehtem garn |
| DE102009055829A1 (de) | 2008-12-22 | 2010-06-24 | Merck Patent Gmbh | Flüssigkristallanzeige |
| DE102010006691A1 (de) | 2009-02-06 | 2010-10-28 | Merck Patent Gmbh | Flüssigkristallines Medium und Flüssigkristallanzeige |
| EP2218764B1 (en) | 2009-02-13 | 2012-01-18 | Merck Patent GmbH | Chiral reactive mesogen mixture |
| DE102010012900A1 (de) | 2009-04-23 | 2010-11-25 | Merck Patent Gmbh | Flüssigkristallanzeige |
| DE102011011836A1 (de) | 2010-03-09 | 2011-09-15 | Merck Patent Gmbh | Polymerisierbare Verbindungen und ihre Verwendung in Flüssigkristallmedien und Flüssigkristallanzeigen |
| DE102011015546A1 (de) | 2010-04-26 | 2012-01-26 | Merck Patent Gmbh | Polymerisierbare Verbindungen und ihre Verwendung in Flüssigkristallmedien und Flüssigkristallanzeigen |
| EP2399972B1 (en) | 2010-06-25 | 2015-11-25 | Merck Patent GmbH | Liquid-crystalline medium and liquid-crystal display having high twist |
| WO2012084200A1 (en) | 2010-12-21 | 2012-06-28 | Stichting Dutch Polymer Institute | Process for coating a curved article |
| DE102012003796A1 (de) | 2011-03-18 | 2012-09-20 | Merck Patent Gmbh | Flüssigkristallines Medium |
| KR20240056652A (ko) | 2011-03-29 | 2024-04-30 | 메르크 파텐트 게엠베하 | 액정 매질 |
| JP6073296B2 (ja) | 2011-05-27 | 2017-02-01 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツングＭｅｒｃｋ Ｐａｔｅｎｔ Ｇｅｓｅｌｌｓｃｈａｆｔ ｍｉｔ ｂｅｓｃｈｒａｅｎｋｔｅｒ Ｈａｆｔｕｎｇ | 重合性化合物、および、液晶媒体および液晶ディスプレイにおけるそれらの使用 |
| KR101986858B1 (ko) | 2011-06-01 | 2019-06-07 | 메르크 파텐트 게엠베하 | 액정 매질 및 액정 디스플레이 |
| KR20140041721A (ko) * | 2011-07-08 | 2014-04-04 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 액정 조성물, 액정 소자, 및 액정 표시 장치 |
| WO2013017197A1 (en) | 2011-08-01 | 2013-02-07 | Merck Patent Gmbh | Liquid crystal medium and liquid crystal display |
| EP2568032B1 (en) | 2011-09-06 | 2014-11-26 | Merck Patent GmbH | Liquid crystal medium and liquid crystal display |
| WO2013034219A1 (en) | 2011-09-06 | 2013-03-14 | Merck Patent Gmbh | Liquid crystal medium and liquid crystal display |
| EP2607451B8 (de) | 2011-12-20 | 2019-03-27 | Merck Patent GmbH | Flüssigkristallines Medium |
| EP2623927A1 (en) | 2012-02-02 | 2013-08-07 | Stichting Dutch Polymer Institute | Optical strain sensor |
| KR20150002847A (ko) | 2012-04-20 | 2015-01-07 | 메르크 파텐트 게엠베하 | 액정 매질 및 액정 디스플레이 |
| EP2708587B1 (en) | 2012-09-18 | 2015-07-15 | Merck Patent GmbH | Liquid crystal medium and liquid crystal display |
| CN104685025B (zh) | 2012-10-02 | 2018-02-27 | 默克专利股份有限公司 | 液晶介质和液晶显示器 |
| US9612445B2 (en) | 2012-11-27 | 2017-04-04 | Merck Patent Gmbh | Lens element |
| US9809749B2 (en) | 2013-04-19 | 2017-11-07 | Merck Patent Gmbh | Mesogenic compound, liquid-crystal medium and liquid crystal display |
| JP6505388B2 (ja) | 2013-07-31 | 2019-04-24 | 株式会社半導体エネルギー研究所 | ジオキソラン誘導体、液晶組成物及び液晶表示装置 |
| EP3090033B1 (en) | 2013-12-30 | 2018-07-04 | Merck Patent GmbH | Liquid crystal medium and liquid crystal display |
| EP3105302B1 (en) | 2014-02-13 | 2020-08-05 | Merck Patent GmbH | Reactive mesogen based polymer particles |
| KR20170032408A (ko) | 2014-07-18 | 2017-03-22 | 메르크 파텐트 게엠베하 | 액정 매질 및 이를 포함하는 고주파 부품 |
| EP2990460B1 (de) | 2014-08-22 | 2019-04-03 | Merck Patent GmbH | Flüssigkristallines medium |
| DE102015015108A1 (de) | 2014-12-17 | 2016-06-23 | Merck Patent Gmbh | Flüssigkristallines Medium |
| WO2016107670A1 (en) | 2014-12-29 | 2016-07-07 | Merck Patent Gmbh | Liquid-crystalline medium and high-frequency components comprising same |
| US10676670B2 (en) | 2014-12-30 | 2020-06-09 | Merck Patent Gmbh | Liquid-crystalline medium and high-frequency components comprising same |
| EP3124573B1 (en) | 2015-07-31 | 2018-03-28 | Merck Patent GmbH | Liquid crystal medium and liquid crystal display |
| CN108603121B (zh) | 2016-02-08 | 2023-02-10 | 默克专利股份有限公司 | 液晶介质及含有其的高频组件 |
| TW201807165A (zh) | 2016-04-13 | 2018-03-01 | 馬克專利公司 | 包含液晶介質之用於奈米膠囊化的組合物及奈米膠囊 |
| US20190177618A1 (en) | 2016-08-24 | 2019-06-13 | Merck Patent Gmbh | Liquid crystalline medium and liquid crystal display |
| EP3312257B1 (en) | 2016-10-18 | 2019-11-20 | Merck Patent GmbH | Liquid-crystalline medium and high-frequency components comprising same |
| JP7097878B2 (ja) | 2016-10-24 | 2022-07-08 | メルク・パテント・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | 液晶媒体 |
| DE112017005490T5 (de) | 2016-10-31 | 2019-10-17 | Merck Patent Gmbh | Nanokapseln enthaltend ein fluessigkristallines medium |
| CN110392726B (zh) | 2017-03-16 | 2023-11-03 | 默克专利股份有限公司 | 液晶介质 |
| WO2018189068A1 (en) | 2017-04-10 | 2018-10-18 | Merck Patent Gmbh | Composition for nanoencapsulation and nanocapsules comprising a liquid-crystalline medium |
| WO2018192896A1 (en) | 2017-04-20 | 2018-10-25 | Merck Patent Gmbh | Light modulation element |
| KR20190039639A (ko) | 2017-10-05 | 2019-04-15 | 메르크 파텐트 게엠베하 | 작용화된 폴리비닐 알콜을 포함하는 조성물 및 액정 매질을 함유하는 나노캡슐 |
| EP3720925B1 (en) | 2017-12-06 | 2023-02-15 | Merck Patent GmbH | Window element |
| KR102726774B1 (ko) | 2017-12-06 | 2024-11-07 | 메르크 파텐트 게엠베하 | 스위칭 소자에 사용하기 위한 액정 매질 |
| EP3502210B1 (en) | 2017-12-20 | 2020-09-09 | Merck Patent GmbH | Liquid-crystal medium |
| EP3543314B1 (en) | 2018-03-23 | 2020-09-09 | Merck Patent GmbH | Liquid-crystalline medium |
| EP3543313B1 (en) | 2018-03-23 | 2020-10-07 | Merck Patent GmbH | Liquid-crystalline medium |
| EP3739020B1 (en) | 2018-05-16 | 2023-08-23 | Merck Patent GmbH | Liquid-crystalline medium |
| US12102781B2 (en) | 2018-06-29 | 2024-10-01 | Biosense Webster (Israel) Ltd. | Reinforcement for irrigated electrophysiology balloon catheter with flexible-circuit electrodes |
| US12458436B2 (en) | 2018-07-30 | 2025-11-04 | Biosense Webster (Israel) Ltd. | Flexible-circuit tip for a split-tip catheter |
| WO2020120353A1 (en) | 2018-12-12 | 2020-06-18 | Merck Patent Gmbh | Polymerizable liquid crystal ink formulations |
| DE102019008592A1 (de) | 2018-12-12 | 2020-06-18 | Merck Patent Gmbh | Komponenten für die Hochfrequenztechnik und Flüssigkristallmedium |
| EP3894415A1 (en) | 2018-12-13 | 2021-10-20 | Merck Patent GmbH | Liquid-crystal medium |
| US11952528B2 (en) | 2018-12-19 | 2024-04-09 | Merck Patent Gmbh | Switching layers for use in a switching element |
| WO2020152206A1 (en) | 2019-01-25 | 2020-07-30 | Merck Patent Gmbh | Liquid-crystalline medium |
| IL274057B2 (en) | 2019-04-30 | 2024-03-01 | Merck Patent Gmbh | Isothiocyantotoluenes |
| EP3969540A1 (en) | 2019-05-15 | 2022-03-23 | Merck Patent GmbH | Method for preparing a liquid crystal-based switching element |
| GB2589659B (en) | 2019-05-28 | 2023-04-05 | Merck Patent Gmbh | Compositions comprising polymerizable oligoethyleneglycol derivatives and nanocapsules containing a liquid-crystalline medium |
| CN114008176A (zh) | 2019-06-17 | 2022-02-01 | 默克专利股份有限公司 | 基于液晶的光阀 |
| IL290782B2 (en) | 2019-08-28 | 2025-09-01 | Merck Patent Gmbh | Aromatic isothiocyanates |
| CN114502691B (zh) | 2019-10-10 | 2025-02-25 | 默克专利股份有限公司 | 氟化芳族化合物 |
| WO2021116080A1 (en) | 2019-12-10 | 2021-06-17 | Merck Patent Gmbh | Aromatic isothiocyanates |
| KR20210077615A (ko) | 2019-12-17 | 2021-06-25 | 메르크 파텐트 게엠베하 | 액정 매질 |
| EP4153700B1 (en) | 2020-05-18 | 2025-02-26 | Merck Patent GmbH | Liquid-crystalline medium |
| US12258510B2 (en) | 2020-07-03 | 2025-03-25 | Merck Patent Gmbh | Liquid crystal medium |
| JP7709473B2 (ja) | 2020-07-03 | 2025-07-16 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | 液晶媒体 |
| EP3933009B1 (en) | 2020-07-03 | 2023-08-16 | Merck Patent GmbH | Liquid crystal medium |
| KR20230037041A (ko) | 2020-07-08 | 2023-03-15 | 메르크 파텐트 게엠베하 | 광학 컴포넌트 |
| EP3940040B1 (en) | 2020-07-16 | 2024-10-16 | Merck Patent GmbH | Liquid-crystalline medium |
| IL299921A (en) | 2020-08-28 | 2023-03-01 | Merck Patent Gmbh | aromatic isothiocyanates |
| CN114525139B (zh) | 2020-10-07 | 2025-07-25 | 默克专利股份有限公司 | 液晶介质 |
| US20230392076A1 (en) | 2020-10-28 | 2023-12-07 | Merck Patent Gmbh | Aromatic isothiocyanates |
| EP4263750B1 (en) | 2020-12-16 | 2025-06-04 | Merck Patent GmbH | Heteroaromatic isothiocyanates |
| JP2023553699A (ja) | 2020-12-17 | 2023-12-25 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | ヘテロ芳香族イソチオシアネート類 |
| US11802243B2 (en) | 2021-02-26 | 2023-10-31 | Merck Patent Gmbh | Liquid-crystal medium |
| WO2022207584A2 (en) | 2021-03-31 | 2022-10-06 | Merck Patent Gmbh | Aromatic isothiocyanates |
| KR20240004668A (ko) | 2021-04-29 | 2024-01-11 | 메르크 파텐트 게엠베하 | 액정 매질 |
| TW202317855A (zh) | 2021-08-06 | 2023-05-01 | 德商馬克專利公司 | 用於窗元件之切換層 |
| US12114905B2 (en) | 2021-08-27 | 2024-10-15 | Biosense Webster (Israel) Ltd. | Reinforcement and stress relief for an irrigated electrophysiology balloon catheter with flexible-circuit electrodes |
| EP4399258A1 (en) | 2021-09-08 | 2024-07-17 | Merck Patent GmbH | Liquid-crystal medium |
| EP4306615A1 (en) | 2022-07-11 | 2024-01-17 | Merck Patent GmbH | Liquid-crystal medium |
| CN120787252A (zh) | 2023-02-24 | 2025-10-14 | 默克专利股份有限公司 | 二氢萘衍生物 |
| WO2024260902A1 (en) | 2023-06-20 | 2024-12-26 | Merck Patent Gmbh | Liquid crystal medium |
| WO2025061649A1 (en) | 2023-09-20 | 2025-03-27 | Merck Patent Gmbh | Liquid crystal medium |
| US20250154412A1 (en) | 2023-11-08 | 2025-05-15 | Merck Patent Gmbh | Liquid crystal medium |
| WO2025196107A1 (en) | 2024-03-22 | 2025-09-25 | Merck Patent Gmbh | Indene derivatives |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02155932A (ja) * | 1988-12-07 | 1990-06-15 | Nippon Paint Co Ltd | 複合化粒子ならびにその製法 |
| DE19611101A1 (de) | 1996-03-21 | 1997-09-25 | Basf Ag | Chirale Verbindungen |
| GB9812800D0 (en) | 1998-06-12 | 1998-08-12 | Rolic Ag | Optically active compounds |
| DE69907579T2 (de) * | 1998-07-15 | 2004-04-01 | Merck Patent Gmbh | Polymerisierbare mesogene Fluorphenylene |
| WO2001096494A1 (en) * | 2000-06-09 | 2001-12-20 | Kent Displays, Inc. | Chiral additives for cholesteric displays |
-
2001
- 2001-06-25 CN CNB018127274A patent/CN1264835C/zh not_active Expired - Lifetime
- 2001-06-25 DE DE60105032T patent/DE60105032T2/de not_active Expired - Lifetime
- 2001-06-25 WO PCT/EP2001/007218 patent/WO2002006265A1/en not_active Ceased
- 2001-06-25 JP JP2002512169A patent/JP5111715B2/ja not_active Expired - Fee Related
- 2001-06-25 EP EP01960377A patent/EP1299375B1/en not_active Expired - Lifetime
- 2001-06-25 AT AT01960377T patent/ATE273968T1/de not_active IP Right Cessation
- 2001-06-25 AU AU2001281885A patent/AU2001281885A1/en not_active Abandoned
- 2001-06-25 US US10/332,807 patent/US7041345B2/en not_active Expired - Lifetime
- 2001-06-29 TW TW090116198A patent/TWI224130B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JP5111715B2 (ja) | 2013-01-09 |
| CN1264835C (zh) | 2006-07-19 |
| CN1441797A (zh) | 2003-09-10 |
| EP1299375A1 (en) | 2003-04-09 |
| AU2001281885A1 (en) | 2002-01-30 |
| US7041345B2 (en) | 2006-05-09 |
| TWI224130B (en) | 2004-11-21 |
| WO2002006265A1 (en) | 2002-01-24 |
| US20030189189A1 (en) | 2003-10-09 |
| EP1299375B1 (en) | 2004-08-18 |
| JP2004504314A (ja) | 2004-02-12 |
| ATE273968T1 (de) | 2004-09-15 |
| DE60105032D1 (de) | 2004-09-23 |
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