DE60024252D1 - Polymermembran und verfahren zu deren herstellung - Google Patents

Polymermembran und verfahren zu deren herstellung

Info

Publication number
DE60024252D1
DE60024252D1 DE60024252T DE60024252T DE60024252D1 DE 60024252 D1 DE60024252 D1 DE 60024252D1 DE 60024252 T DE60024252 T DE 60024252T DE 60024252 T DE60024252 T DE 60024252T DE 60024252 D1 DE60024252 D1 DE 60024252D1
Authority
DE
Germany
Prior art keywords
membrane
meq
sulfonation
sulfonic acid
irradiated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60024252T
Other languages
English (en)
Other versions
DE60024252T2 (de
Inventor
Mikael Paronen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of DE60024252D1 publication Critical patent/DE60024252D1/de
Application granted granted Critical
Publication of DE60024252T2 publication Critical patent/DE60024252T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2287—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0289—Means for holding the electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1053—Polymer electrolyte composites, mixtures or blends consisting of layers of polymers with at least one layer being ionically conductive
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1067—Polymeric electrolyte materials characterised by their physical properties, e.g. porosity, ionic conductivity or thickness
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1086—After-treatment of the membrane other than by polymerisation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1086—After-treatment of the membrane other than by polymerisation
    • H01M8/1088—Chemical modification, e.g. sulfonation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2381/08—Polysulfonates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Fuel Cell (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • External Artificial Organs (AREA)
  • Materials For Medical Uses (AREA)
  • Conductive Materials (AREA)
DE60024252T 1999-02-16 2000-02-16 Polymermembran und verfahren zu deren herstellung Expired - Lifetime DE60024252T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI990324A FI107932B (fi) 1999-02-16 1999-02-16 Polymeerikalvo ja menetelmä sen valmistamiseksi
FI990324 1999-02-16
PCT/FI2000/000117 WO2000049069A1 (en) 1999-02-16 2000-02-16 Polymer membrane and a process for the production thereof

Publications (2)

Publication Number Publication Date
DE60024252D1 true DE60024252D1 (de) 2005-12-29
DE60024252T2 DE60024252T2 (de) 2006-06-29

Family

ID=8553804

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60024252T Expired - Lifetime DE60024252T2 (de) 1999-02-16 2000-02-16 Polymermembran und verfahren zu deren herstellung

Country Status (11)

Country Link
US (2) US6630518B1 (de)
EP (1) EP1177246B1 (de)
JP (1) JP2002537428A (de)
AT (1) ATE310766T1 (de)
AU (1) AU2674700A (de)
CA (1) CA2362853C (de)
DE (1) DE60024252T2 (de)
ES (1) ES2253206T3 (de)
FI (1) FI107932B (de)
NO (1) NO20013898L (de)
WO (1) WO2000049069A1 (de)

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EP1474839B1 (de) * 2002-02-06 2010-04-07 Battelle Memorial Institute Polymerelektrolytmembranen zur verwendung in brennstoffzellen
DE10209419A1 (de) 2002-03-05 2003-09-25 Celanese Ventures Gmbh Verfahren zur Herstellung einer Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
ES2292993T3 (es) 2002-03-06 2008-03-16 Basf Fuel Cell Gmbh Membrana electrolitica conductora de protones con permeabilidad reducida de metanol y su aplicacion en pilas de combustible.
CN100358178C (zh) 2002-04-25 2007-12-26 佩密斯股份有限公司 多层电解质膜
US6936551B2 (en) * 2002-05-08 2005-08-30 Applied Materials Inc. Methods and apparatus for E-beam treatment used to fabricate integrated circuit devices
DE10220817A1 (de) * 2002-05-10 2003-11-27 Celanese Ventures Gmbh Verfahren zur Herstellung einer gepfropften Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
AU2003244261A1 (en) * 2002-06-19 2004-01-06 Ube Industries, Ltd. Polyelectrolyte membrane and production method therefor
DE10230477A1 (de) 2002-07-06 2004-01-15 Celanese Ventures Gmbh Funktionalisierte Polyazole, Verfahren zu ihrer Herstellung sowie ihre Verwendung
ATE314735T1 (de) 2002-08-02 2006-01-15 Protonenleitende polymembran, welche sulfonsäuregruppen enthaltende polymere umfasst, und deren anwendung in brennstoffzellen
DE10239701A1 (de) 2002-08-29 2004-03-11 Celanese Ventures Gmbh Polymerfolie auf Basis von Polyazolen und deren Verwendung
JP4794170B2 (ja) * 2002-09-20 2011-10-19 株式会社カネカ プロトン伝導性高分子膜、それを用いた膜−電極接合体およびこれらを用いた燃料電池
DE10246373A1 (de) 2002-10-04 2004-04-15 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Sulfonsäuregruppen enthaltende Polyazole und deren Anwendung in Brennstoffzellen
DE10246459A1 (de) 2002-10-04 2004-04-15 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Phosphonsäuregruppen enthaltende Polyazole und deren Anwendung in Brennstoffzellen
WO2005004258A2 (en) 2003-06-27 2005-01-13 Ultracell Corporation Portable fuel cartridge for fuel cells
US7820314B2 (en) 2003-07-27 2010-10-26 Basf Fuel Cell Research Gmbh Proton-conducting membrane and use thereof
US7301002B1 (en) 2003-10-14 2007-11-27 Sandia Corporation Sulfonated polyphenylene polymers
US7655331B2 (en) 2003-12-01 2010-02-02 Societe Bic Fuel cell supply including information storage device and control system
US7329348B2 (en) * 2003-12-01 2008-02-12 Societe Bic Fuel cell system including an ion filter
US7399509B2 (en) 2003-12-23 2008-07-15 Kari Virtanen Thin polyethylene pressure sensitive labels
US7217470B2 (en) * 2004-05-11 2007-05-15 Societe Bic Cartridge with fuel supply and membrane electrode assembly stack
US7968250B2 (en) 2004-06-25 2011-06-28 Ultracell Corporation Fuel cartridge connectivity
US7648792B2 (en) 2004-06-25 2010-01-19 Ultracell Corporation Disposable component on a fuel cartridge and for use with a portable fuel cell system
KR100639017B1 (ko) * 2005-03-07 2006-10-25 삼성에스디아이 주식회사 연료 전지 시스템
GB0511841D0 (en) * 2005-06-10 2005-07-20 Itm Fuel Cells Ltd Polymer formulations
JP5514440B2 (ja) 2005-09-30 2014-06-04 バトル、メモリアル、インスティテュート 燃料電池構成要素に使用するポリマー
WO2007044353A2 (en) * 2005-10-04 2007-04-19 Ballard Power Systems Inc. Methods for making sulfonated non-aromatic polymer electrolyte membranes
US20070218334A1 (en) * 2006-03-16 2007-09-20 Bonorand Lukas M Methods for making sulfonated non-aromatic polymer electrolyte membranes
WO2007092437A2 (en) * 2006-02-07 2007-08-16 University Of South Carolina Method for increasing the permeability of polymer film
EP1986257B1 (de) * 2006-02-13 2012-05-23 Kuraray Co., Ltd. Polyelektrolytfilm, filmelektrodenbaugruppe und brennstoffzelle des festpolymertyps
JP5194433B2 (ja) * 2006-03-29 2013-05-08 株式会社豊田中央研究所 電解質膜の製造方法
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US9534097B2 (en) 2014-04-25 2017-01-03 Sandia Corporation Poly(phenylene alkylene)-based lonomers

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Also Published As

Publication number Publication date
EP1177246A1 (de) 2002-02-06
FI990324A0 (fi) 1999-02-16
AU2674700A (en) 2000-09-04
NO20013898L (no) 2001-10-11
WO2000049069A1 (en) 2000-08-24
ATE310766T1 (de) 2005-12-15
US6630518B1 (en) 2003-10-07
EP1177246B1 (de) 2005-11-23
CA2362853C (en) 2008-09-23
NO20013898D0 (no) 2001-08-10
US6902849B2 (en) 2005-06-07
JP2002537428A (ja) 2002-11-05
FI107932B (fi) 2001-10-31
US20040086764A1 (en) 2004-05-06
ES2253206T3 (es) 2006-06-01
FI990324A (fi) 2000-08-17
DE60024252T2 (de) 2006-06-29
CA2362853A1 (en) 2000-08-24

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