DE60003185T2 - Verfahren zur herstellung von kalthärtenden flexiblen schäumen, polyolzusammensetzung und dafür nützliches reaktionssystem, damit erhaltene schäume - Google Patents
Verfahren zur herstellung von kalthärtenden flexiblen schäumen, polyolzusammensetzung und dafür nützliches reaktionssystem, damit erhaltene schäumeInfo
- Publication number
- DE60003185T2 DE60003185T2 DE60003185T DE60003185T DE60003185T2 DE 60003185 T2 DE60003185 T2 DE 60003185T2 DE 60003185 T DE60003185 T DE 60003185T DE 60003185 T DE60003185 T DE 60003185T DE 60003185 T2 DE60003185 T2 DE 60003185T2
- Authority
- DE
- Germany
- Prior art keywords
- polyol
- polyols
- polyisocyanate
- process according
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920005862 polyol Polymers 0.000 title claims description 94
- 150000003077 polyols Chemical class 0.000 title claims description 93
- 239000000203 mixture Substances 0.000 title claims description 43
- 239000006260 foam Substances 0.000 title claims description 33
- 238000006243 chemical reaction Methods 0.000 title claims description 10
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000005056 polyisocyanate Substances 0.000 claims description 35
- 229920001228 polyisocyanate Polymers 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 33
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 26
- 150000001412 amines Chemical class 0.000 claims description 23
- 239000003054 catalyst Substances 0.000 claims description 17
- -1 polyoxyethylene Polymers 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 229920001451 polypropylene glycol Polymers 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 7
- 239000011496 polyurethane foam Substances 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 40
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 25
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 21
- 239000012948 isocyanate Substances 0.000 description 15
- 150000002513 isocyanates Chemical class 0.000 description 15
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 8
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 8
- 229920000768 polyamine Chemical class 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
- 230000006835 compression Effects 0.000 description 6
- 125000005442 diisocyanate group Chemical group 0.000 description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 6
- 239000003999 initiator Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 239000004202 carbamide Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 229920005903 polyol mixture Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000004970 Chain extender Substances 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000013016 damping Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 3
- 239000003190 viscoelastic substance Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 229920000265 Polyparaphenylene Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical group NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 2
- 150000001718 carbodiimides Chemical class 0.000 description 2
- 230000001413 cellular effect Effects 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- 125000005702 oxyalkylene group Chemical group 0.000 description 2
- 125000006353 oxyethylene group Chemical group 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 2
- MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical class O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 description 1
- RTTZISZSHSCFRH-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC(CN=C=O)=C1 RTTZISZSHSCFRH-UHFFFAOYSA-N 0.000 description 1
- AGJCSCSSMFRMFQ-UHFFFAOYSA-N 1,4-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=C(C(C)(C)N=C=O)C=C1 AGJCSCSSMFRMFQ-UHFFFAOYSA-N 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical compound NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241001425800 Pipa Species 0.000 description 1
- 241000120020 Tela Species 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003335 secondary amines Chemical group 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6688—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/482—Mixtures of polyethers containing at least one polyether containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP99114600 | 1999-07-26 | ||
| PCT/EP2000/006186 WO2001007521A1 (en) | 1999-07-26 | 2000-07-03 | Process for making cold-setting flexible foams, polyol composition and reaction system useful therefor, foams thus obtained |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60003185D1 DE60003185D1 (de) | 2003-07-10 |
| DE60003185T2 true DE60003185T2 (de) | 2003-12-18 |
Family
ID=8238659
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60003185T Expired - Lifetime DE60003185T2 (de) | 1999-07-26 | 2000-07-03 | Verfahren zur herstellung von kalthärtenden flexiblen schäumen, polyolzusammensetzung und dafür nützliches reaktionssystem, damit erhaltene schäume |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6506813B1 (enExample) |
| EP (1) | EP1198519B1 (enExample) |
| JP (2) | JP2003505570A (enExample) |
| CN (1) | CN1138831C (enExample) |
| AU (1) | AU6154000A (enExample) |
| DE (1) | DE60003185T2 (enExample) |
| ES (1) | ES2200896T3 (enExample) |
| WO (1) | WO2001007521A1 (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1234843A1 (en) * | 2001-02-26 | 2002-08-28 | Huntsman International Llc | Process for preparing a flexible polyurethane foam |
| ITMI20010619A1 (it) * | 2001-03-23 | 2002-09-23 | Enichem Spa | Procedimento per la preparazione di schiume poliuretaniche |
| SI1527114T1 (sl) * | 2002-08-02 | 2008-02-29 | Huntsman Int Llc | Predpolimer, poliolni sestavek za izdelavo fleksibilne pene |
| US20050131095A1 (en) * | 2002-08-02 | 2005-06-16 | Jianming Yu | Novel polyols |
| US20040154718A1 (en) * | 2003-02-06 | 2004-08-12 | Doesburg Van I. | Polyurethane filled tire and method of making same |
| US7238730B2 (en) * | 2003-06-26 | 2007-07-03 | Basf Corporation | Viscoelastic polyurethane foam |
| US7078443B2 (en) * | 2003-10-22 | 2006-07-18 | Intellectual Property Holdings, Llc | Viscoelastic foam layer and composition |
| US20080125507A1 (en) * | 2006-11-28 | 2008-05-29 | Bayer Materialscience Llc | Reduction of VOC emissions from low density cavity filling NVH polyurethane foams |
| RU2339663C1 (ru) * | 2007-06-05 | 2008-11-27 | Федеральное казенное предприятие (ФКП) "Пермский пороховой завод" | Полиоловая композиция для получения жестких пенополиуретанов теплоизоляционного назначения |
| US20090012195A1 (en) | 2007-07-05 | 2009-01-08 | Neff Raymond A | Resin composition for use in forming a polyurethane article with increased comfort |
| DE102007061883A1 (de) * | 2007-12-20 | 2009-06-25 | Bayer Materialscience Ag | Viskoelastischer Polyurethanschaumstoff |
| US8901187B1 (en) | 2008-12-19 | 2014-12-02 | Hickory Springs Manufacturing Company | High resilience flexible polyurethane foam using MDI |
| US8604094B2 (en) | 2008-12-23 | 2013-12-10 | Basf Se | Flexible polyurethane foam and method of producing same |
| US8906975B1 (en) | 2009-02-09 | 2014-12-09 | Hickory Springs Manufacturing Company | Conventional flexible polyurethane foam using MDI |
| US8784518B2 (en) * | 2011-01-17 | 2014-07-22 | 3M Innovative Properties Company | Method of making polyurethane foam |
| EP2628756B1 (de) * | 2012-02-15 | 2015-01-28 | Bayer Intellectual Property GmbH | Halbharte Schaumstoffe auf Polyurethanbasis, deren Herstellung und Verwendung |
| FR2991686B1 (fr) * | 2012-06-08 | 2015-05-01 | Michelin & Cie | Bandage pneumatique dont la paroi interne est pourvue d'une couche de mousse polyurethane specifique |
| AU2013329491A1 (en) | 2012-10-10 | 2015-04-30 | Basf Se | Viscoelastic polyurethane foam |
| JP6446460B2 (ja) | 2013-09-13 | 2018-12-26 | ダウ グローバル テクノロジーズ エルエルシー | Ｐｉｐａポリオール系粘弾性フォーム |
| HUE051672T2 (hu) | 2013-09-13 | 2021-03-29 | Dow Global Technologies Llc | Pipa-alapú, égés-módosított poliuretán hab |
| WO2015038825A1 (en) | 2013-09-13 | 2015-03-19 | Dow Global Technologies Llc | Polyisocyanate polyaddition polyol manufacturing process using stabilizers |
| CN106632985B (zh) * | 2015-11-04 | 2019-04-23 | 万华化学（北京）有限公司 | 一种聚氨酯泡沫材料及其制备方法和用途 |
| WO2017104608A1 (ja) * | 2015-12-16 | 2017-06-22 | 株式会社ブリヂストン | 軟質ポリウレタンフォーム、及びシート用パッド |
| JP6928427B2 (ja) * | 2016-07-08 | 2021-09-01 | 株式会社イノアックコーポレーション | ウレタンフォーム製造方法、ウレタンフォームの組成物、シートクッション、寝具、および衣料用パッド |
| MX2021014865A (es) * | 2019-06-05 | 2022-01-18 | Basf Se | Una composicion reactiva para espuma de poliuretano y su uso en partes de automovil. |
| JP2021181538A (ja) * | 2020-05-19 | 2021-11-25 | 株式会社イノアック技術研究所 | 低膨潤親水性ウレタンフォーム |
| US20220235168A1 (en) * | 2021-01-22 | 2022-07-28 | Covestro Llc | Processes for making molded flexible foams and flexible foams produced thereby |
| US11738487B2 (en) * | 2021-01-22 | 2023-08-29 | Covestro Llc | Processes for making molded flexible foams and flexible foams produced thereby |
| WO2023084651A1 (ja) * | 2021-11-10 | 2023-05-19 | 株式会社イノアック技術研究所 | 発泡体形成用組成物及びウレタンフォーム |
| CN114716638B (zh) * | 2022-04-14 | 2023-12-01 | 佳化化学科技发展（上海）有限公司 | 一种聚氨酯自结皮泡沫及其制备方法和应用 |
| KR20250068743A (ko) * | 2022-09-30 | 2025-05-16 | 이노악 코포레이션 | 저반발성 폴리우레탄 폼 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61151224A (ja) | 1984-12-20 | 1986-07-09 | ソシエテ シミツク デ シヤルボナ−ジユ エス．ア−． | ヒドロキシル基含有ポリイソシアネ−トの安定なプレポリマ−、その製造方法、そのポリウレタン製造への利用 |
| DE3806476A1 (de) * | 1988-03-01 | 1989-09-14 | Bayer Ag | Verfahren zur herstellung von kalthaertenden polyurethan-weichformschaumstoffen mit hervorragenden daempfungseigenschaften |
| JPH0284421A (ja) * | 1988-06-04 | 1990-03-26 | Achilles Corp | 衝撃吸収性ポリウレタンフォーム及びその製造方法 |
| DE3942330A1 (de) * | 1989-12-21 | 1991-06-27 | Basf Ag | Verfahren zur herstellung von flexiblen polyurethan-weichschaumstoffen mit viskoelastischen, koerperschalldaempfenden eigenschaften und hierzu verwendbare polyoxyalkylen-polyol-mischungen |
| JPH03239716A (ja) * | 1990-02-19 | 1991-10-25 | Sanyo Chem Ind Ltd | 軟質ポリウレタンフォーム形成組成物および製法 |
| DE4135588A1 (de) | 1991-10-29 | 1993-05-06 | Basf Ag, 6700 Ludwigshafen, De | Hochreaktive, tertiaere aminogruppen gebunden enthaltende polyoxyalkylenpolyole, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von polyisocyanat-polyadditionsprodukten |
| DE4204395A1 (de) * | 1992-02-14 | 1993-08-19 | Bayer Ag | Verfahren zur herstellung von kalthaertenden polyurethan-weichformschaumstoffen |
| JPH06211978A (ja) * | 1992-10-28 | 1994-08-02 | Takeda Chem Ind Ltd | 新規ポリエーテルポリオール及びそれを用いる軟質ウレタンフォームの製造法 |
| JP3281662B2 (ja) * | 1993-02-01 | 2002-05-13 | 三井化学株式会社 | 部分プレポリマー及びこれを用いた軟質ポリウレタンフォーム |
| DE4437878A1 (de) * | 1994-10-22 | 1996-04-25 | Basf Ag | Verfahren zur Herstellung von fogging-armen Polyurethan-Schaumstoffen und hierfür verwendbare spezielle Polyoxyalkylen-polyole |
| TR199800687T2 (xx) * | 1995-10-19 | 1998-07-21 | Imperial Chemical Industries Plc | Sert poliüretan köpükler. |
| JP3610138B2 (ja) * | 1995-12-22 | 2005-01-12 | 三井武田ケミカル株式会社 | 低密度高弾性軟質ポリウレタンフォームの製造方法 |
| DE19742012A1 (de) * | 1997-09-24 | 1999-03-25 | Basf Ag | Temperaturstabile Hartschaumstoffe auf Isocyanatbasis mit geringer Sprödigkeit und niedriger Wärmeleitfähigkeit |
| US5874485A (en) | 1997-11-10 | 1999-02-23 | Bayer Corporation | Flexible foams and flexible molded foams based on allophanate-modified diphenylmethane diisocyanates and processes for the production of these foams |
| US6034197A (en) * | 1998-07-27 | 2000-03-07 | Sealed Air Corporation | Polyol blend, multi-component system for producing polyurethane foam, and foam produced thereby |
| JP3992869B2 (ja) * | 1999-04-07 | 2007-10-17 | 三井化学株式会社 | エネルギー吸収軟質ポリウレタン発泡体及びその製造方法 |
-
2000
- 2000-07-03 JP JP2001512795A patent/JP2003505570A/ja not_active Withdrawn
- 2000-07-03 ES ES00947914T patent/ES2200896T3/es not_active Expired - Lifetime
- 2000-07-03 EP EP00947914A patent/EP1198519B1/en not_active Expired - Lifetime
- 2000-07-03 DE DE60003185T patent/DE60003185T2/de not_active Expired - Lifetime
- 2000-07-03 CN CNB008105804A patent/CN1138831C/zh not_active Expired - Fee Related
- 2000-07-03 WO PCT/EP2000/006186 patent/WO2001007521A1/en not_active Ceased
- 2000-07-03 US US10/030,385 patent/US6506813B1/en not_active Expired - Fee Related
- 2000-07-03 AU AU61540/00A patent/AU6154000A/en not_active Abandoned
-
2011
- 2011-01-14 JP JP2011006138A patent/JP2011094154A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| AU6154000A (en) | 2001-02-13 |
| US6506813B1 (en) | 2003-01-14 |
| CN1138831C (zh) | 2004-02-18 |
| JP2003505570A (ja) | 2003-02-12 |
| DE60003185D1 (de) | 2003-07-10 |
| CN1361811A (zh) | 2002-07-31 |
| EP1198519B1 (en) | 2003-06-04 |
| WO2001007521A1 (en) | 2001-02-01 |
| EP1198519A1 (en) | 2002-04-24 |
| ES2200896T3 (es) | 2004-03-16 |
| JP2011094154A (ja) | 2011-05-12 |
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