DE3518974C2 - - Google Patents
Info
- Publication number
- DE3518974C2 DE3518974C2 DE3518974A DE3518974A DE3518974C2 DE 3518974 C2 DE3518974 C2 DE 3518974C2 DE 3518974 A DE3518974 A DE 3518974A DE 3518974 A DE3518974 A DE 3518974A DE 3518974 C2 DE3518974 C2 DE 3518974C2
- Authority
- DE
- Germany
- Prior art keywords
- iron
- washing solution
- iii
- reducing agent
- washing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005406 washing Methods 0.000 claims description 9
- 239000003638 chemical reducing agent Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical group [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000002485 combustion reaction Methods 0.000 claims description 2
- 239000003546 flue gas Substances 0.000 claims description 2
- 230000000873 masking effect Effects 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 235000010265 sodium sulphite Nutrition 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/60—Simultaneously removing sulfur oxides and nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/68—Halogens or halogen compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/46—Sulfates
- C01F11/464—Sulfates of Ca from gases containing sulfur oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/48—Sulfites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Treating Waste Gases (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19853518974 DE3518974A1 (de) | 1985-05-25 | 1985-05-25 | Waschloesung zur simultanen waschung von so(pfeil abwaerts)2(pfeil abwaerts) und no(pfeil abwaerts)x(pfeil abwaerts) in rauchgasen hinter kraftwerken und anderen fossilen verbrennungsanlagen |
DE19853519198 DE3519198A1 (de) | 1985-05-25 | 1985-05-29 | Waschfluessigkeit zur waschung von so(pfeil abwaerts)2(pfeil abwaerts) und no(pfeil abwaerts)x(pfeil abwaerts) aus rauchgasen hinter fossil-kraftwerken |
DE19853520377 DE3520377A1 (de) | 1985-05-25 | 1985-06-07 | Reduktionsmittelbevorratung fuer die waschloesung zur simultanen waschung von so(pfeil abwaerts)2(pfeil abwaerts) und no(pfeil abwaerts)x(pfeil abwaerts) |
DE19853524047 DE3524047A1 (de) | 1985-05-25 | 1985-07-05 | Waschfluessigkeit und verfahren zur abscheidung von so(pfeil abwaerts)2(pfeil abwaerts) und no(pfeil abwaerts)x(pfeil abwaerts) aus rauchgasen von fossil-kraftwerken mit gleichzeitiger n(pfeil abwaerts)2(pfeil abwaerts)o-abscheidung |
PCT/EP1986/000317 WO1986006981A1 (en) | 1985-05-25 | 1986-05-24 | METHOD FOR SIMULTANEOUSLY REMOVING BY WASHING SO2, NOx AND OPTIONALLY OTHER NOXIOUS SUBSTANCES CONTAINED IN FLUE GASES IN HEATING INSTALLATIONS SUPPLIED WITH FOSSILE FUELS |
EP86903350A EP0223803A1 (de) | 1985-05-25 | 1986-05-24 | VERFAHREN ZUM GLEICHZEITIGEN AUSWASCHEN VON SO 2?, NO x? UND GGF. WEITEREN SCHADSTOFFEN AUS DEN RAUCHGASEN VON MIT FOSSILEN BRENNSTOFFEN BETRIEBENEN FEUERUNGSANLAGEN |
JP61503502A JPS63500781A (ja) | 1985-05-25 | 1986-05-24 | 化石燃料動作燃焼炉の煙道ガスからのSO↓2、NO↓xおよび場合により他の有害物質の同時洗浄方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19853518974 DE3518974A1 (de) | 1985-05-25 | 1985-05-25 | Waschloesung zur simultanen waschung von so(pfeil abwaerts)2(pfeil abwaerts) und no(pfeil abwaerts)x(pfeil abwaerts) in rauchgasen hinter kraftwerken und anderen fossilen verbrennungsanlagen |
Publications (2)
Publication Number | Publication Date |
---|---|
DE3518974A1 DE3518974A1 (de) | 1986-11-27 |
DE3518974C2 true DE3518974C2 (enrdf_load_stackoverflow) | 1987-07-09 |
Family
ID=6271722
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19853518974 Granted DE3518974A1 (de) | 1985-05-25 | 1985-05-25 | Waschloesung zur simultanen waschung von so(pfeil abwaerts)2(pfeil abwaerts) und no(pfeil abwaerts)x(pfeil abwaerts) in rauchgasen hinter kraftwerken und anderen fossilen verbrennungsanlagen |
Country Status (2)
Country | Link |
---|---|
JP (1) | JPS63500781A (enrdf_load_stackoverflow) |
DE (1) | DE3518974A1 (enrdf_load_stackoverflow) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3524047A1 (de) * | 1985-05-25 | 1987-01-15 | Hoelter Heinz | Waschfluessigkeit und verfahren zur abscheidung von so(pfeil abwaerts)2(pfeil abwaerts) und no(pfeil abwaerts)x(pfeil abwaerts) aus rauchgasen von fossil-kraftwerken mit gleichzeitiger n(pfeil abwaerts)2(pfeil abwaerts)o-abscheidung |
DE3725715C2 (de) * | 1987-08-04 | 1994-12-01 | Karl Clemens Dipl Che Kaeuffer | Verfahren und Vorrichtung zur Verminderung der Stickoxide in Abgasen, vorzugsweise in Rauchgasen |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1446973A (en) * | 1973-09-24 | 1976-08-18 | Asahi Chemical Ind | Method of removing nitrogen monoxide from a nitrogen mono xide-containing gas |
JPS5096478A (enrdf_load_stackoverflow) * | 1973-12-27 | 1975-07-31 |
-
1985
- 1985-05-25 DE DE19853518974 patent/DE3518974A1/de active Granted
-
1986
- 1986-05-24 JP JP61503502A patent/JPS63500781A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
DE3518974A1 (de) | 1986-11-27 |
JPS63500781A (ja) | 1988-03-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE3130921C2 (de) | Stabilisierte wässrige Lösung mit einem Gehalt an Chloroxidverbindungen | |
DE2641204A1 (de) | Verfahren zur entfernung von schwefeloxyden aus industriellen abgasen | |
DE3518974C2 (enrdf_load_stackoverflow) | ||
DE1280219B (de) | Verfahren zur Entfernung von Stickoxyden aus stickoxydhaltigen Gasen unter gleichzeitiger Gewinnung von Sulfaten und/oder Bisulfaten | |
DE2436124B2 (de) | Verfahren zur Herstellung eines Polyeisen (IH)-sulfat enthaltenden Flockungsmittels | |
DE648981C (de) | Verfahren zur Herstellung von Alkalilaugen oder Alkalisalzen durch Zersetzung von Alkaliamalgam | |
DE3504157C2 (enrdf_load_stackoverflow) | ||
EP0912441B1 (de) | VERFAHREN ZUM ENTFERNEN VON NO x? AUS NITROSYL-SCHWEFELSÄURE | |
DE3409526C2 (de) | Verfahren zur Abscheidung von Stickoxyden aus dem Rauchgas von Verbrennungsanlagen | |
DE2100268C3 (de) | Verfahren zur Verhinderung der Oxydation von Alkalisulfiten und/oder -bisulfiten | |
DE747030C (de) | Zweistufiges Verfahren zur Herstellung von Thomas-Stahl mit niedrigem Schwefel- und Phosphorgehalt | |
DE3433396A1 (de) | Abgasentschwefelungsverfahren | |
DE3520377C2 (enrdf_load_stackoverflow) | ||
DE3427297C1 (de) | Verfahren zur Herstellung einer Natriumdithionitlösung | |
DE2335520A1 (de) | Verfahren zur behandlung von entschwefeltem abwasser mit ozon | |
DE3445163C2 (enrdf_load_stackoverflow) | ||
DE3427550C2 (de) | Verfahren zur Aktivierung von inaktiven EDTA-Lösungen | |
AT272039B (de) | Verfahren zur anodischen elektrolytischen Entzunderung von Materialien aus Eisen und Stahl | |
DE3308648A1 (de) | Waschfluessigkeit zur waschung von sauren gasen wie so(pfeil abwaerts)2(pfeil abwaerts), hcl, hf, no(pfeil abwaerts)x(pfeil abwaerts) usw. | |
DE496833C (de) | Verfahren zur Verbesserung der Haltbarkeit von Diazoverbindungen in Gegenwart von Eisen | |
DE143595C (enrdf_load_stackoverflow) | ||
DE395033C (de) | Verfahren zur Umwandlung von Kupfersulfid in loesliche Kupferverbindungen | |
DE368650C (de) | Verfahren zur Gewinnung von Ammoniumaluminiumsulfat aus eisenoxydhaltigen Aluminiumsulfatloesungen | |
DE894080C (de) | Verfahren zur Bindung des freien Sauerstoffs in Waessern durch Zusatz von Reduktionsmitteln und Reaktionsbeschleunigern | |
CH122808A (de) | Verfahren zur Gewinnung von Schwefelwasserstoff aus Erdalkalisulfaten. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
OM8 | Search report available as to paragraph 43 lit. 1 sentence 1 patent law | ||
OP8 | Request for examination as to paragraph 44 patent law | ||
AG | Has addition no. |
Ref country code: DE Ref document number: 3519198 Format of ref document f/p: P Ref country code: DE Ref document number: 3520377 Format of ref document f/p: P |
|
AG | Has addition no. |
Ref country code: DE Ref document number: 3524047 Format of ref document f/p: P |
|
Q176 | The application caused the suspense of an application |
Ref document number: 3520377 Country of ref document: DE |
|
AG | Has addition no. |
Ref country code: DE Ref document number: 3524047 Format of ref document f/p: P Ref country code: DE Ref document number: 3519198 Format of ref document f/p: P Ref country code: DE Ref document number: 3520377 Format of ref document f/p: P |
|
D2 | Grant after examination | ||
8364 | No opposition during term of opposition | ||
AG | Has addition no. |
Ref country code: DE Ref document number: 3520377 Format of ref document f/p: P |
|
8339 | Ceased/non-payment of the annual fee |