DE3329048A1 - Verfahren zur thermischen crackung von schweroel - Google Patents

Verfahren zur thermischen crackung von schweroel

Info

Publication number
DE3329048A1
DE3329048A1 DE19833329048 DE3329048A DE3329048A1 DE 3329048 A1 DE3329048 A1 DE 3329048A1 DE 19833329048 DE19833329048 DE 19833329048 DE 3329048 A DE3329048 A DE 3329048A DE 3329048 A1 DE3329048 A1 DE 3329048A1
Authority
DE
Germany
Prior art keywords
thermal cracking
heavy oil
fluid
water vapor
range
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE19833329048
Other languages
German (de)
English (en)
Inventor
Toshihiro Ishida
Katsutoshi Kikuchi
Atsushi Mobara Moriya
Takayuki Chiba Sakamoto
Tadayoshi Yokohama Kanagawa Tomita
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyo Engineering Corp
Original Assignee
Toyo Engineering Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Engineering Corp filed Critical Toyo Engineering Corp
Publication of DE3329048A1 publication Critical patent/DE3329048A1/de
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts with external heating of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/14—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils in pipes or coils with or without auxiliary means, e.g. digesters, soaking drums, expansion means
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0816—Heating by flames
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0866—Methods of heating the process for making hydrogen or synthesis gas by combination of different heating methods
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
    • C01B2203/1017—Packed bed of catalytic structures, e.g. particles, packing elements characterised by the form of the structure
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258—Pre-treatment of the feed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1276—Mixing of different feed components
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Hydrogen, Water And Hydrids (AREA)
DE19833329048 1982-08-13 1983-08-11 Verfahren zur thermischen crackung von schweroel Ceased DE3329048A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57140595A JPS5930702A (ja) 1982-08-13 1982-08-13 重質油の熱分解の方法

Publications (1)

Publication Number Publication Date
DE3329048A1 true DE3329048A1 (de) 1984-02-16

Family

ID=15272345

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19833329048 Ceased DE3329048A1 (de) 1982-08-13 1983-08-11 Verfahren zur thermischen crackung von schweroel

Country Status (8)

Country Link
US (1) US4740290A (enExample)
JP (1) JPS5930702A (enExample)
KR (1) KR890001962B1 (enExample)
CA (1) CA1222715A (enExample)
DD (1) DD214858A5 (enExample)
DE (1) DE3329048A1 (enExample)
GB (1) GB2125430B (enExample)
MX (1) MX162720A (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2780649C2 (ru) * 2020-09-22 2022-09-28 Закрытое акционерное общество Научно-проектное производственно-строительное объединение "Грантстрой" (ЗАО НППСО "Грантстрой") Способ и установка переработки тяжелых нефтепродуктов с парами воды

Families Citing this family (27)

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Publication number Priority date Publication date Assignee Title
JPS5930702A (ja) * 1982-08-13 1984-02-18 Toyo Eng Corp 重質油の熱分解の方法
JPH07119422B2 (ja) * 1987-11-27 1995-12-20 日本石油化学株式会社 重質炭化水素の気化装置
US5264115A (en) * 1987-12-30 1993-11-23 Compagnie De Raffinage Et De Distribution Total France Process and apparatus for fluidized bed hydrocarbon conversion
JP2542115Y2 (ja) * 1991-10-28 1997-07-23 株式会社くろがね工作所 ユニットバス用吊り戸
US6045772A (en) * 1998-08-19 2000-04-04 International Fuel Cells, Llc Method and apparatus for injecting a liquid hydrocarbon fuel into a fuel cell power plant reformer
US6379534B1 (en) * 1999-02-19 2002-04-30 Halliburton Energy Services, Inc. Pour point depression unit using mild thermal cracker
US6199768B1 (en) * 1999-03-18 2001-03-13 Exxon Research And Engineering Company Process and apparatus for atomizing FCC feed oil
US6783662B2 (en) 1999-03-18 2004-08-31 Exxonmobil Research And Engineering Company Cavitation enhanced liquid atomization
US6607678B2 (en) 1999-08-17 2003-08-19 Battelle Memorial Institute Catalyst and method of steam reforming
US6284217B1 (en) * 1999-08-17 2001-09-04 Battelle Memorial Institute Method and catalyst structure for steam reforming of a hydrocarbon
US7335346B2 (en) 1999-08-17 2008-02-26 Battelle Memorial Institute Catalyst and method of steam reforming
WO2001014500A1 (en) 1999-08-26 2001-03-01 Exxonmobil Research And Engineering Company Superheating atomizing steam with hot fcc feed oil
JP4830197B2 (ja) 2000-09-13 2011-12-07 トヨタ自動車株式会社 燃料改質装置
US20030066239A1 (en) * 2001-10-05 2003-04-10 Iraj Parchamazad Portable cogeneration fuel-cell power generator with high-yield, low pressure reformer for recreational vehicles
US7722854B2 (en) * 2003-06-25 2010-05-25 Velocy's Steam reforming methods and catalysts
US8277773B2 (en) 2004-02-13 2012-10-02 Velocys Corp. Steam reforming method
DE10344845A1 (de) * 2003-09-26 2005-04-14 Basf Ag Vorrichtung zum Mischen, Trocknen und Beschichten von pulvrigem, körnigem oder geformtem Schüttgut in einem Fließbett und Verfahren zur Herstellung von Trägerkatalysatoren unter Verwendung einer solchen Vorrichtung
JP2010093023A (ja) * 2008-10-07 2010-04-22 Hitachi Kokusai Electric Inc 半導体装置の製造方法
FR2955865B1 (fr) 2010-02-01 2012-03-16 Cotaver Procede de recyclage du dioxyde de carbone (co2)
FR2955866B1 (fr) 2010-02-01 2013-03-22 Cotaver Procede et systeme d'approvisionnement en energie thermique d'un systeme de traitement thermique et installation mettant en oeuvre un tel systeme
FR2955854B1 (fr) 2010-02-01 2014-08-08 Cotaver Procede et systeme de production d'hydrogene a partir de matiere premiere carbonee
FR2955918B1 (fr) 2010-02-01 2012-08-03 Cotaver Procede et systeme de production d'une source d'energie thermodynamique par la conversion de co2 sur des matieres premieres carbonees
US8715616B2 (en) * 2011-02-11 2014-05-06 Phillips 66 Company Soak and coke
FR2986800B1 (fr) * 2012-02-09 2015-01-30 Cotaver Procede, systeme et installation de traitement de matieres hydrocarbonees liquides et/ou pateuses
EP3515859A1 (en) 2016-09-19 2019-07-31 SABIC Global Technologies B.V. Steam reforming system and process
WO2021148942A1 (en) * 2020-01-22 2021-07-29 Nova Chemicals (International) S.A. High gas velocity start-up of an ethylene cracking furnace
CN115216329A (zh) * 2021-04-21 2022-10-21 中国石油大学(北京) 一种利用电供能的蒸汽裂解方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3711568A (en) * 1970-09-24 1973-01-16 H Cooper Pyrolysis process
US4065379A (en) * 1975-01-22 1977-12-27 Shell Oil Company Process for the production of normally gaseous olefins
US4214979A (en) * 1977-02-04 1980-07-29 Kureha Kagaku Kogyo Kabushiki Kaisha Method of thermally cracking heavy petroleum oil
US4242196A (en) * 1978-10-27 1980-12-30 Kureha Kagaku Kogyo Kabushiki Kaisha Mass production system of highly aromatic petroleum pitch
US4321130A (en) * 1979-12-05 1982-03-23 Exxon Research & Engineering Co. Thermal conversion of hydrocarbons with low energy air preheater

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US2772955A (en) * 1952-07-11 1956-12-04 Montedison Spa Process for the production of hydrogen and carbon monoxide from liquid fuels
US3097935A (en) * 1957-01-12 1963-07-16 Basf Ag Production of unsaturated gaseous hydrocarbons and of synthesis gas
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US3306844A (en) * 1964-07-27 1967-02-28 Monsanto Co Hydrocarbon thermal cracking in a tubular reactor
US3479298A (en) * 1964-08-04 1969-11-18 Lummus Co Production of hydrogen
US3579601A (en) * 1968-06-10 1971-05-18 Exxon Research Engineering Co Pyrolysis of hydrocarbons
US3579438A (en) * 1970-04-20 1971-05-18 Monsanto Co Thermal cracking
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JPS5278901A (en) * 1975-12-26 1977-07-02 Mitsui Toatsu Chem Inc Gacification method
JPS54101804A (en) * 1978-01-27 1979-08-10 Tokyo Gas Co Ltd Manufacturing gas from heavy oil
RO89083A (ro) * 1981-08-29 1986-04-30 Toyo Engineering Corp,Us Procedeu de cracare cu aburi a hidrocarburilor grele si instalatia pentru acesta
JPS5930702A (ja) * 1982-08-13 1984-02-18 Toyo Eng Corp 重質油の熱分解の方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3711568A (en) * 1970-09-24 1973-01-16 H Cooper Pyrolysis process
US4065379A (en) * 1975-01-22 1977-12-27 Shell Oil Company Process for the production of normally gaseous olefins
US4214979A (en) * 1977-02-04 1980-07-29 Kureha Kagaku Kogyo Kabushiki Kaisha Method of thermally cracking heavy petroleum oil
US4242196A (en) * 1978-10-27 1980-12-30 Kureha Kagaku Kogyo Kabushiki Kaisha Mass production system of highly aromatic petroleum pitch
US4321130A (en) * 1979-12-05 1982-03-23 Exxon Research & Engineering Co. Thermal conversion of hydrocarbons with low energy air preheater

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2780649C2 (ru) * 2020-09-22 2022-09-28 Закрытое акционерное общество Научно-проектное производственно-строительное объединение "Грантстрой" (ЗАО НППСО "Грантстрой") Способ и установка переработки тяжелых нефтепродуктов с парами воды
RU2841364C1 (ru) * 2024-10-16 2025-06-06 Ольга Владимировна Баширова Лабораторный реактор для моделирования процессов коксообразования на его стенках

Also Published As

Publication number Publication date
JPS5930702A (ja) 1984-02-18
DD214858A5 (de) 1984-10-24
GB2125430A (en) 1984-03-07
KR850001918A (ko) 1985-04-10
CA1222715A (en) 1987-06-09
GB2125430B (en) 1987-01-21
KR890001962B1 (ko) 1989-06-05
US4740290A (en) 1988-04-26
GB8321720D0 (en) 1983-09-14
JPH044962B2 (enExample) 1992-01-30
MX162720A (es) 1991-06-18

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