DE3246151A1 - Verfahren zur herstellung von 4-nitrodiphenylaminen - Google Patents

Verfahren zur herstellung von 4-nitrodiphenylaminen

Info

Publication number
DE3246151A1
DE3246151A1 DE19823246151 DE3246151A DE3246151A1 DE 3246151 A1 DE3246151 A1 DE 3246151A1 DE 19823246151 DE19823246151 DE 19823246151 DE 3246151 A DE3246151 A DE 3246151A DE 3246151 A1 DE3246151 A1 DE 3246151A1
Authority
DE
Germany
Prior art keywords
compounds
copper
cesium
rubidium
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19823246151
Other languages
German (de)
English (en)
Other versions
DE3246151C2 (ko
Inventor
Willi Dipl.-Chem. Dr. 5090 Leverkusen Müller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Priority to DE19823246151 priority Critical patent/DE3246151A1/de
Priority to IN751/DEL/83A priority patent/IN160179B/en
Priority to KR1019830005642A priority patent/KR910002370B1/ko
Priority to JP58231624A priority patent/JPS59112947A/ja
Priority to SU833673464A priority patent/SU1158038A3/ru
Priority to DD83257811A priority patent/DD215536A5/de
Priority to CS839327A priority patent/CS236898B2/cs
Priority to BR8306844A priority patent/BR8306844A/pt
Publication of DE3246151A1 publication Critical patent/DE3246151A1/de
Application granted granted Critical
Publication of DE3246151C2 publication Critical patent/DE3246151C2/de
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/52Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring the carbon skeleton being further substituted by halogen atoms or by nitro or nitroso groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20Carbon compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20Carbon compounds
    • B01J27/232Carbonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24Nitrogen compounds
    • B01J27/26Cyanides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00Other general methods
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/06Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms
    • C07C209/10Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms with formation of amino groups bound to carbon atoms of six-membered aromatic rings or from amines having nitrogen atoms bound to carbon atoms of six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/54Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings
    • C07C211/55Diphenylamines
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/54Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings
    • C07C211/56Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings the carbon skeleton being further substituted by halogen atoms or by nitro or nitroso groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE19823246151 1982-12-14 1982-12-14 Verfahren zur herstellung von 4-nitrodiphenylaminen Granted DE3246151A1 (de)

Priority Applications (8)

Application Number Priority Date Filing Date Title
DE19823246151 DE3246151A1 (de) 1982-12-14 1982-12-14 Verfahren zur herstellung von 4-nitrodiphenylaminen
IN751/DEL/83A IN160179B (ko) 1982-12-14 1983-11-10
KR1019830005642A KR910002370B1 (ko) 1982-12-14 1983-11-29 4-니트로디페닐아민의 제조방법
JP58231624A JPS59112947A (ja) 1982-12-14 1983-12-09 4−ニトロジフエニルアミンの製法
SU833673464A SU1158038A3 (ru) 1982-12-14 1983-12-12 Способ получени 4-нитродифениламина
DD83257811A DD215536A5 (de) 1982-12-14 1983-12-12 Verfahren zur herstellung von 4-nitrodiphenylaminen
CS839327A CS236898B2 (en) 1982-12-14 1983-12-12 Processing of 4-nitrodiphenylamine
BR8306844A BR8306844A (pt) 1982-12-14 1983-12-13 Processo para a preparacao de 4-nitrodifenilaminas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19823246151 DE3246151A1 (de) 1982-12-14 1982-12-14 Verfahren zur herstellung von 4-nitrodiphenylaminen

Publications (2)

Publication Number Publication Date
DE3246151A1 true DE3246151A1 (de) 1984-06-14
DE3246151C2 DE3246151C2 (ko) 1988-06-30

Family

ID=6180570

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19823246151 Granted DE3246151A1 (de) 1982-12-14 1982-12-14 Verfahren zur herstellung von 4-nitrodiphenylaminen

Country Status (8)

Country Link
JP (1) JPS59112947A (ko)
KR (1) KR910002370B1 (ko)
BR (1) BR8306844A (ko)
CS (1) CS236898B2 (ko)
DD (1) DD215536A5 (ko)
DE (1) DE3246151A1 (ko)
IN (1) IN160179B (ko)
SU (1) SU1158038A3 (ko)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6235937B1 (en) 1999-09-06 2001-05-22 Bayer Aktiengesellschaft Process for the preparation of nitrodiphenylamines
EP1123916A1 (de) * 2000-02-09 2001-08-16 Bayer Ag Verfahren zur Herstellung von Aminodiphenylaminen
EP1437340A1 (de) 2003-01-07 2004-07-14 Bayer Aktiengesellschaft Verfahren zur Herstellung von Aminodiphenylaminen
US6815562B2 (en) 2003-01-07 2004-11-09 Bayer Aktiengesellschaft Process for the preparation of nitrodiphenylamines

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2502724C1 (ru) * 2012-10-22 2013-12-27 Российская Федерация, От Имени Которой Выступает Министерство Промышленности И Торговли Российской Федерации Способ получения нитродифениламинов

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1056619B (de) * 1956-11-29 1959-05-06 Bayer Ag Verfahren zur Herstellung von 4-Nitro-diarylaminen
US2927943A (en) * 1955-12-07 1960-03-08 Us Rubber Co Preparation of p-nitrodiphenylamine
DE1090225B (de) * 1957-11-05 1960-10-06 Us Rubber Co Verfahren zur Herstellung von p-Nitrodiphenylaminen
US3155727A (en) * 1960-07-25 1964-11-03 Goodyear Tire & Rubber Reaction of aromatic amines with para halo nitrobenzenes using copper cyanide condensation catalyst
US3277175A (en) * 1963-11-26 1966-10-04 Eastman Kodak Co Preparation of p-nitrodiphenylamines
US3313854A (en) * 1961-11-20 1967-04-11 Universal Oil Prod Co Preparation of para-nitrodiphenylamines utilizing a copper oxide catalyst
DE2850680A1 (de) * 1977-11-23 1979-05-31 Monsanto Co Verfahren zur herstellung von nitrodiarylamin
DE2855764A1 (de) * 1977-12-27 1979-06-28 Monsanto Co Verfahren zur herstellung von nitrodiarylamin unter verwendung eines promotors
DE2855762A1 (de) * 1977-12-27 1979-06-28 Monsanto Co Verfahren zur herstellung von nitrodiarylamin unter verwendung eines protonenabstraktors und eines promotors

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4228103A (en) * 1978-03-13 1980-10-14 Monsanto Company Effecting condensation of nitrohaloarene and formyl derivative of a primary aromatic amine with alkali metal hydroxide

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2927943A (en) * 1955-12-07 1960-03-08 Us Rubber Co Preparation of p-nitrodiphenylamine
DE1056619B (de) * 1956-11-29 1959-05-06 Bayer Ag Verfahren zur Herstellung von 4-Nitro-diarylaminen
DE1090225B (de) * 1957-11-05 1960-10-06 Us Rubber Co Verfahren zur Herstellung von p-Nitrodiphenylaminen
US3155727A (en) * 1960-07-25 1964-11-03 Goodyear Tire & Rubber Reaction of aromatic amines with para halo nitrobenzenes using copper cyanide condensation catalyst
US3313854A (en) * 1961-11-20 1967-04-11 Universal Oil Prod Co Preparation of para-nitrodiphenylamines utilizing a copper oxide catalyst
US3277175A (en) * 1963-11-26 1966-10-04 Eastman Kodak Co Preparation of p-nitrodiphenylamines
DE2850680A1 (de) * 1977-11-23 1979-05-31 Monsanto Co Verfahren zur herstellung von nitrodiarylamin
DE2855764A1 (de) * 1977-12-27 1979-06-28 Monsanto Co Verfahren zur herstellung von nitrodiarylamin unter verwendung eines promotors
DE2855762A1 (de) * 1977-12-27 1979-06-28 Monsanto Co Verfahren zur herstellung von nitrodiarylamin unter verwendung eines protonenabstraktors und eines promotors

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Org. Reaktions 14, 1965, S. 19-24 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6235937B1 (en) 1999-09-06 2001-05-22 Bayer Aktiengesellschaft Process for the preparation of nitrodiphenylamines
EP1123916A1 (de) * 2000-02-09 2001-08-16 Bayer Ag Verfahren zur Herstellung von Aminodiphenylaminen
US6316673B2 (en) 2000-02-09 2001-11-13 Bayer Aktiengesellschaft Process for producing aminodiphenylamines
EP1437340A1 (de) 2003-01-07 2004-07-14 Bayer Aktiengesellschaft Verfahren zur Herstellung von Aminodiphenylaminen
US6815562B2 (en) 2003-01-07 2004-11-09 Bayer Aktiengesellschaft Process for the preparation of nitrodiphenylamines
CN100457713C (zh) * 2003-01-07 2009-02-04 朗盛德国有限责任公司 氨基二苯胺的生产方法

Also Published As

Publication number Publication date
DE3246151C2 (ko) 1988-06-30
IN160179B (ko) 1987-06-27
SU1158038A3 (ru) 1985-05-23
DD215536A5 (de) 1984-11-14
BR8306844A (pt) 1984-07-24
CS236898B2 (en) 1985-05-15
JPS59112947A (ja) 1984-06-29
KR840007560A (ko) 1984-12-08
JPS6323184B2 (ko) 1988-05-16
KR910002370B1 (ko) 1991-04-20

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Legal Events

Date Code Title Description
8110 Request for examination paragraph 44
D2 Grant after examination
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee