KR840007560A - 4-니트로디페닐아민의 제조방법 - Google Patents
4-니트로디페닐아민의 제조방법 Download PDFInfo
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- KR840007560A KR840007560A KR1019830005642A KR830005642A KR840007560A KR 840007560 A KR840007560 A KR 840007560A KR 1019830005642 A KR1019830005642 A KR 1019830005642A KR 830005642 A KR830005642 A KR 830005642A KR 840007560 A KR840007560 A KR 840007560A
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- rubidium
- cesium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
- B01J27/232—Carbonates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
- B01J27/26—Cyanides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B61/00—Other general methods
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
- C07C209/06—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms
- C07C209/10—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms with formation of amino groups bound to carbon atoms of six-membered aromatic rings or from amines having nitrogen atoms bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
- C07C211/52—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring the carbon skeleton being further substituted by halogen atoms or by nitro or nitroso groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/54—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings
- C07C211/55—Diphenylamines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/54—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings
- C07C211/56—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings the carbon skeleton being further substituted by halogen atoms or by nitro or nitroso groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 탄산칼슘 및 구리 화합물의 존재하에서, 루비듐 또는 세슘 화합물 또는 둘의 혼합물을 반응 혼합물에 첨가하는 것을 특징으로 하여, 1급 방향족 아민과 4-니트로 할로겐 벤젠을 반응시켜서 4-니트로 디페닐아민을 제조하는 방법.
- 제1항에 있어서, 4-니트로디페닐아민이 다음 일반식에 상당하는 것을 특징으로 하는 방법.여기에서 R1, R2, R3및 R4는 각기 같거나 또는 다르며 수소 또는 1 내지 9 탄소원자를 갖고 있는 알킬라디칼이다.
- 제1항에 있어서, 4-니트로클로로벤젠이 4-니트로디페닐아민을 생성하기 위해서 아니린과 반응하는 것을 특징으로 하는 방법.
- 제1항에 있어서, 약유기 또는 무기산의 염이 루비듐 또는 세슘 화합물로 쓰이는 것을 특징으로 하는 방법.
- 제1 내지 4항의 어느 하나에 있어서 세슘 화합물이 사용되는 것을 특징으로 하는 방법.
- 제1항에 있어서, 각 경우에, 사용된 할로겐니트로 벤젠의 1몰에 대해서, 루비듐 또는 세슘 화합물이 탄산세슘의 0.05 내지 5g에 상당하는 몰량으로 쓰이고 구리촉매는 0.001 내지 0.1몰량이 쓰이는 것을 특징으로 하는 방법.
- 제1항에 있어서, 각 경우에, 사용된 할로겐니트로 벤젠의 1몰에 대하여, 루비듐 또는 세슘 화합물이 탄산 세슘의 0.1 내지 1g에 상당하는 몰량으로 쓰이고, 구리 촉매는 0.01 내지 0.05몰량이 쓰이는 것을 특징으로 하는 방법.
- 제1항에 있어서, 반응이 140°내지 225℃에서 실시되는 것을 특징으로 하는 방법.
- 제1항에 있어서, 반응이 180 내지 210℃에서 실시되는 것을 특징으로 하는 방법.
- 제1항에 있어서, 엔트레이너를 사용하여 증류시켜서 반응중에 생긴 물을 제거하는 것을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP3246151.8 | 1982-12-14 | ||
DE19823246151 DE3246151A1 (de) | 1982-12-14 | 1982-12-14 | Verfahren zur herstellung von 4-nitrodiphenylaminen |
Publications (2)
Publication Number | Publication Date |
---|---|
KR840007560A true KR840007560A (ko) | 1984-12-08 |
KR910002370B1 KR910002370B1 (ko) | 1991-04-20 |
Family
ID=6180570
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019830005642A KR910002370B1 (ko) | 1982-12-14 | 1983-11-29 | 4-니트로디페닐아민의 제조방법 |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS59112947A (ko) |
KR (1) | KR910002370B1 (ko) |
BR (1) | BR8306844A (ko) |
CS (1) | CS236898B2 (ko) |
DD (1) | DD215536A5 (ko) |
DE (1) | DE3246151A1 (ko) |
IN (1) | IN160179B (ko) |
SU (1) | SU1158038A3 (ko) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19942394C1 (de) | 1999-09-06 | 2001-02-01 | Bayer Ag | Verfahren zur Herstellung von Nitrodiphenylaminen |
DE10005601A1 (de) * | 2000-02-09 | 2001-08-16 | Bayer Ag | Verfahren zur Herstellung von Aminodiphenylaminen |
DE10300126A1 (de) | 2003-01-07 | 2004-07-15 | Bayer Aktiengesellschaft | Verfahren zur Herstellung von Aminodiphenylaminen |
DE10300125A1 (de) | 2003-01-07 | 2004-07-15 | Bayer Ag | Verfahren zur Herstellung von Nitrodiphenylaminen |
RU2502724C1 (ru) * | 2012-10-22 | 2013-12-27 | Российская Федерация, От Имени Которой Выступает Министерство Промышленности И Торговли Российской Федерации | Способ получения нитродифениламинов |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL97645C (ko) * | 1955-12-07 | |||
DE1056619B (de) * | 1956-11-29 | 1959-05-06 | Bayer Ag | Verfahren zur Herstellung von 4-Nitro-diarylaminen |
DE1090225B (de) * | 1957-11-05 | 1960-10-06 | Us Rubber Co | Verfahren zur Herstellung von p-Nitrodiphenylaminen |
US3155727A (en) * | 1960-07-25 | 1964-11-03 | Goodyear Tire & Rubber | Reaction of aromatic amines with para halo nitrobenzenes using copper cyanide condensation catalyst |
US3313854A (en) * | 1961-11-20 | 1967-04-11 | Universal Oil Prod Co | Preparation of para-nitrodiphenylamines utilizing a copper oxide catalyst |
US3277175A (en) * | 1963-11-26 | 1966-10-04 | Eastman Kodak Co | Preparation of p-nitrodiphenylamines |
US4187248A (en) * | 1977-11-23 | 1980-02-05 | Monsanto Company | Making a nitrodiarylamine by reacting an alkali metal salt of a formamide with a nitrohaloarene |
US4209463A (en) * | 1977-12-27 | 1980-06-24 | Monsanto Company | Promoting the formation of nitrodiarylamines from nitrohaloarenes, activated aryl amines and sodium carbonates |
US4187249A (en) * | 1977-12-27 | 1980-02-05 | Monsanto Company | Promoting the reaction of sodium salts of formyl derivatives of aromatic amines to form nitrodiarylamines |
US4228103A (en) * | 1978-03-13 | 1980-10-14 | Monsanto Company | Effecting condensation of nitrohaloarene and formyl derivative of a primary aromatic amine with alkali metal hydroxide |
-
1982
- 1982-12-14 DE DE19823246151 patent/DE3246151A1/de active Granted
-
1983
- 1983-11-10 IN IN751/DEL/83A patent/IN160179B/en unknown
- 1983-11-29 KR KR1019830005642A patent/KR910002370B1/ko not_active IP Right Cessation
- 1983-12-09 JP JP58231624A patent/JPS59112947A/ja active Granted
- 1983-12-12 DD DD83257811A patent/DD215536A5/de not_active IP Right Cessation
- 1983-12-12 SU SU833673464A patent/SU1158038A3/ru active
- 1983-12-12 CS CS839327A patent/CS236898B2/cs unknown
- 1983-12-13 BR BR8306844A patent/BR8306844A/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
KR910002370B1 (ko) | 1991-04-20 |
SU1158038A3 (ru) | 1985-05-23 |
IN160179B (ko) | 1987-06-27 |
DE3246151C2 (ko) | 1988-06-30 |
BR8306844A (pt) | 1984-07-24 |
DD215536A5 (de) | 1984-11-14 |
JPS59112947A (ja) | 1984-06-29 |
CS236898B2 (en) | 1985-05-15 |
JPS6323184B2 (ko) | 1988-05-16 |
DE3246151A1 (de) | 1984-06-14 |
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