DE3050303C2 - Aus Butadien-(1,3)- und Styroleinheiten aufgebautes kautschukartiges Copolymeres mit bis zu 30 Gewichtsprozent an Styroleinheiten und Verfahren zu dessen Herstellung - Google Patents

Aus Butadien-(1,3)- und Styroleinheiten aufgebautes kautschukartiges Copolymeres mit bis zu 30 Gewichtsprozent an Styroleinheiten und Verfahren zu dessen Herstellung

Info

Publication number
DE3050303C2
DE3050303C2 DE3050303A DE3050303A DE3050303C2 DE 3050303 C2 DE3050303 C2 DE 3050303C2 DE 3050303 A DE3050303 A DE 3050303A DE 3050303 A DE3050303 A DE 3050303A DE 3050303 C2 DE3050303 C2 DE 3050303C2
Authority
DE
Germany
Prior art keywords
trans
butadiene
styrene
polymerization
rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE3050303A
Other languages
German (de)
English (en)
Inventor
Sundar L. Akron Ohio Aggarwal
Robert E. Cuyahoga Falls Ohio Bingham
Richard R. Stow Ohio Durst
Hubert J. Akron Ohio Fabris
Ivan G. Tallmadge Ohio Hargis
Russell A. Akron Ohio Livigni
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aerojet Rocketdyne Holdings Inc
Original Assignee
General Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Tire and Rubber Co filed Critical General Tire and Rubber Co
Application granted granted Critical
Publication of DE3050303C2 publication Critical patent/DE3050303C2/de
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/06—Preparatory processes
    • C08G77/08—Preparatory processes characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08—Saturated oxiranes
    • C08G65/10—Saturated oxiranes characterised by the catalysts used
    • C08G65/12—Saturated oxiranes characterised by the catalysts used containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/14—Unsaturated oxiranes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Polyethers (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
DE3050303A 1980-02-25 1980-06-25 Aus Butadien-(1,3)- und Styroleinheiten aufgebautes kautschukartiges Copolymeres mit bis zu 30 Gewichtsprozent an Styroleinheiten und Verfahren zu dessen Herstellung Expired DE3050303C2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/124,373 US4302568A (en) 1980-02-25 1980-02-25 Solution polymerization

Publications (1)

Publication Number Publication Date
DE3050303C2 true DE3050303C2 (de) 1986-08-07

Family

ID=22414480

Family Applications (2)

Application Number Title Priority Date Filing Date
DE3050303A Expired DE3050303C2 (de) 1980-02-25 1980-06-25 Aus Butadien-(1,3)- und Styroleinheiten aufgebautes kautschukartiges Copolymeres mit bis zu 30 Gewichtsprozent an Styroleinheiten und Verfahren zu dessen Herstellung
DE3023785A Expired DE3023785C2 (de) 1980-02-25 1980-06-25 Katalysatorkomplex und seine Verwendung zur Polymerisation von Butadien-(1,3), Isopren oder Styrol, oder eines Gemisches aus Butadien-(1,3) und Styrol

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE3023785A Expired DE3023785C2 (de) 1980-02-25 1980-06-25 Katalysatorkomplex und seine Verwendung zur Polymerisation von Butadien-(1,3), Isopren oder Styrol, oder eines Gemisches aus Butadien-(1,3) und Styrol

Country Status (16)

Country Link
US (1) US4302568A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (2) JPS56118403A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AU (1) AU521746B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
BE (1) BE887676A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
BR (1) BR8006812A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (2) DE3050303C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
ES (1) ES8204444A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
FR (1) FR2476653B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
GB (1) GB2070034B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
IN (1) IN154853B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
IT (1) IT1193538B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
LU (1) LU83119A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
MX (1) MX154769A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
MY (1) MY8500367A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
NL (1) NL180751C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
ZA (1) ZA807656B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4355156A (en) * 1980-02-25 1982-10-19 The General Tire & Rubber Company Solution polymerization
FR2567135B1 (fr) * 1984-07-03 1989-01-13 Asahi Chemical Ind Polymere ou copolymere de butadiene et procede de preparation
JPS62275114A (ja) * 1986-05-23 1987-11-30 Asahi Chem Ind Co Ltd 結晶性ブロック共重合体
US4933401A (en) * 1988-02-26 1990-06-12 Japan Synthetic Rubber Co., Ltd. Catalyst composition for polymerization of conjugated diene and process for producing conjugated diene polymer
US5189110A (en) * 1988-12-23 1993-02-23 Asahi Kasei Kogyo Kabushiki Kaisha Shape memory polymer resin, composition and the shape memorizing molded product thereof
ES2020484A6 (es) * 1990-06-29 1991-08-01 Repsol Quimica Sa Procedimiento de preparacion de homopolimeros de dienos conjugados y de copolimeros de dienos conjugados con otros dienos o compuestos vinil aromaticos.
US5100965A (en) * 1991-04-08 1992-03-31 The Goodyear Tire & Rubber Company Process for synthesizing high trans polymers
US5753579A (en) * 1995-12-26 1998-05-19 The Goodyear Tire & Rubber Company Trans microstructure directing initiator system
US6018007A (en) 1997-09-22 2000-01-25 Bridgestone Corporation Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
WO2003037946A2 (fr) * 2001-10-31 2003-05-08 Societe De Technologie Michelin Procede de preparation de copolymeres a blocs pour compositions de bande de roulement de pneumatique
US6758251B2 (en) * 2002-08-21 2004-07-06 The Goodyear Tire & Rubber Company Pneumatic tire having a component containing high trans styrene-butadiene rubber
US6889737B2 (en) * 2002-12-05 2005-05-10 The Goodyear Tire & Rubber Company Pneumatic tire having a component containing high trans styrene-butadiene rubber
US20050061418A1 (en) * 2003-08-25 2005-03-24 Bates Kenneth Allen Pneumatic tire having a component containing high trans isoprene-butadiene rubber
KR101157295B1 (ko) * 2004-08-06 2012-06-15 제이에스알 가부시끼가이샤 공액 디엔계 공중합 고무의 제조 방법
US7285605B1 (en) 2006-08-30 2007-10-23 The Goodyear Tire & Rubber Company Batch process for synthesizing rubbery polymers having a high trans microstructure content
JP6897144B2 (ja) * 2017-02-22 2021-06-30 横浜ゴム株式会社 コンベアベルト用ゴム組成物、コンベアベルト及びベルトコンベア
CN109485791B (zh) * 2017-09-13 2021-10-19 中国石油化工股份有限公司 线形丁苯共聚物及其制备方法和组合物以及芳族乙烯基树脂及其制备方法

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2434203A1 (de) * 1973-07-16 1975-02-06 Gen Tire & Rubber Co Herstellung von loesungspolymeren unter verwendung eines barium-di-tert.-alkoxidund di-butylmagnesium-katalysatorkomplexes
DE2524849A1 (de) * 1974-06-05 1975-12-11 Michelin & Cie Verfahren zur herstellung von elastomeren, sterisch modifizierten dienpolymerisaten oder -copolymerisaten
DE2607721A1 (de) * 1975-02-27 1976-09-09 Michelin & Cie Verfahren zur herstellung von polymerisaten aus konjugierten dienen oder kopolymerisaten aus konjugierten dienen entweder untereinander oder mit vinylaromatischen verbindungen
DE2628380A1 (de) * 1975-06-24 1976-12-30 Michelin & Cie Verfahren zur herstellung von elastomeren dienpolymerisaten oder -copolymerisaten
DE2630568A1 (de) * 1975-07-07 1977-01-13 Gen Tire & Rubber Co Herstellung von loesungspolymeren
DE2704763A1 (de) * 1974-06-05 1977-08-18 Michelin & Cie Verfahren zur herstellung von elastomeren butadienpolymerisaten oder -copolymerisaten
US4080492A (en) * 1974-06-05 1978-03-21 Compagnie Generale Des Etablissements Michelin Butadiene polymerization process
GB2029426A (en) * 1978-08-18 1980-03-19 Asahi Chemical Ind Isoprene-butadiene copolymers
GB2030995A (en) * 1978-09-13 1980-04-16 Asahi Chemical Ind Process for producing polymers or copolymers of conjugateddienes

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB970799A (en) * 1961-11-13 1964-09-23 Monsanto Co Process for the anionic polymerization of acrylonitrile
US3526604A (en) * 1965-09-01 1970-09-01 Cities Service Co Polymerization of unsaturated monomers with catalysts formed from the reaction of metals and derivatives of groups i-a and ii-a with compounds of group iii-a
US3631006A (en) * 1965-09-01 1971-12-28 Cities Service Co Process for the anionic polymerization of unsaturated hydrocarbon monomers
US3687916A (en) * 1968-12-16 1972-08-29 Phillips Petroleum Co Organoaluminum compounds as adjuvants in an organocalcium initiated polymerization of conjugated dienes and/or monovinyl aromatic compounds
US3578642A (en) * 1968-12-18 1971-05-11 Phillips Petroleum Co Polymerization of alkene oxides with an organoalkaline earth complex and an organoaluminum catalyst system
US4112210A (en) * 1975-02-27 1978-09-05 Compagnie Generale Des Etablissements Michelin Polymerization process
US4052267A (en) * 1975-07-07 1977-10-04 Mcfee Richard Water distiller

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2434203A1 (de) * 1973-07-16 1975-02-06 Gen Tire & Rubber Co Herstellung von loesungspolymeren unter verwendung eines barium-di-tert.-alkoxidund di-butylmagnesium-katalysatorkomplexes
DE2524849A1 (de) * 1974-06-05 1975-12-11 Michelin & Cie Verfahren zur herstellung von elastomeren, sterisch modifizierten dienpolymerisaten oder -copolymerisaten
DE2704763A1 (de) * 1974-06-05 1977-08-18 Michelin & Cie Verfahren zur herstellung von elastomeren butadienpolymerisaten oder -copolymerisaten
US4080492A (en) * 1974-06-05 1978-03-21 Compagnie Generale Des Etablissements Michelin Butadiene polymerization process
GB1516861A (en) * 1974-06-05 1978-07-05 Michelin & Cie Catalyst composition for polymerization of conjugated dienes
DE2607721A1 (de) * 1975-02-27 1976-09-09 Michelin & Cie Verfahren zur herstellung von polymerisaten aus konjugierten dienen oder kopolymerisaten aus konjugierten dienen entweder untereinander oder mit vinylaromatischen verbindungen
DE2628380A1 (de) * 1975-06-24 1976-12-30 Michelin & Cie Verfahren zur herstellung von elastomeren dienpolymerisaten oder -copolymerisaten
DE2630568A1 (de) * 1975-07-07 1977-01-13 Gen Tire & Rubber Co Herstellung von loesungspolymeren
GB2029426A (en) * 1978-08-18 1980-03-19 Asahi Chemical Ind Isoprene-butadiene copolymers
GB2030995A (en) * 1978-09-13 1980-04-16 Asahi Chemical Ind Process for producing polymers or copolymers of conjugateddienes

Also Published As

Publication number Publication date
NL8003688A (nl) 1981-09-16
GB2070034B (en) 1983-11-30
NL180751C (nl) 1987-04-16
NL180751B (nl) 1986-11-17
ES499755A0 (es) 1982-05-01
DE3023785C2 (de) 1986-07-24
JPS60228511A (ja) 1985-11-13
BR8006812A (pt) 1981-08-25
AU521746B2 (en) 1982-04-29
LU83119A1 (fr) 1981-09-10
FR2476653B1 (fr) 1986-06-20
MX154769A (es) 1987-12-11
JPS6235401B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1987-08-01
ES8204444A1 (es) 1982-05-01
AU6453880A (en) 1981-09-17
ZA807656B (en) 1981-11-25
GB2070034A (en) 1981-09-03
JPH03403B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1991-01-08
IT1193538B (it) 1988-07-08
FR2476653A1 (fr) 1981-08-28
IT8022883A0 (it) 1980-06-18
US4302568A (en) 1981-11-24
MY8500367A (en) 1985-12-31
IN154853B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1984-12-15
DE3023785A1 (de) 1981-09-03
JPS56118403A (en) 1981-09-17
BE887676A (fr) 1981-06-15

Similar Documents

Publication Publication Date Title
DE3050303C2 (de) Aus Butadien-(1,3)- und Styroleinheiten aufgebautes kautschukartiges Copolymeres mit bis zu 30 Gewichtsprozent an Styroleinheiten und Verfahren zu dessen Herstellung
DE69005683T2 (de) Verfahren zur Herstellung von konjugierten Dien-(Co)Polymeren mit hohem Transgehalt und niedrigem Vinylgehalt.
US5159022A (en) Crystalline block copolymer and process for producing the same
DE2630568C2 (de) Kautschukartige Polybutadiene, Verfahren zu deren Herstellung und dafür geeignete Katalysatorkomplexe
DE3853340T2 (de) Dien-Blockpolymer und Polymerzusammensetzung.
DE3611405C2 (de) Elastomere Block-Copolymere und Mischungen auf Butadienbasis mit hohem trans-Anteil
DE2932871C2 (de) Aus Butadien- und Isopreneinheiten bzw. aus Butadien-, Isopren- und Styroleinheiten aufgebauter copolymerer Kautschuk, dessen Butadieneinheiten zu 70 bis 90% in trans-1,4-Verknüpfung und zu 2 bis 8% in Vinylverknüpfung eingebaut sind
DE69720138T2 (de) Herstellung von macrocyclischen Polymeren mit niedriger Hysteresis
DE1928856C3 (de) Verfahren zur Herstellung von Homo- oder Copolymerisaten von konjugierten Dienen
DE3103202A1 (de) Polybutadiene und ihre herstellung
DE2434203C3 (de) Verfahren zum Polymerisieren von Vinylmonomeren und Katalysator zu seiner Durchführung
HK1000512B (en) Crystaline block copolymer and process for producing the same
DE1224045B (de) Verfahren zur Herstellung von Blockmischpolymerisaten
DE2524849A1 (de) Verfahren zur herstellung von elastomeren, sterisch modifizierten dienpolymerisaten oder -copolymerisaten
US4297240A (en) Solution polymerization
DE3020283C2 (de) Barium-t-alkoxidsalze, sie enthaltende Katalysatorzusammensetzungen und Verfahren zu ihrer Herstellung
US4307218A (en) Solution polymerization
US4355156A (en) Solution polymerization
DE1921017C3 (de) Verfahren zur Herstellung von kautschukartigen Polymeren
KR101174454B1 (ko) 분자량 조절이 가능한 고 1,4-트랜스 폴리부타디엔 제조용 촉매
DE2429249A1 (de) Organische verstaerkungsfuellstoffe fuer kautschuk und verfahren zu deren herstellung
JP2712612B2 (ja) 共役ジエン系重合体の製造方法
JPH0794517B2 (ja) トランスブタジエン系複合重合体及び複合重合体組成物
DE19727768A1 (de) Thermoplastische Elastomere auf Basis 1,1-Diphenylethylen
DE2215865A1 (de) Verfahren zur Herstellung eines Dien-Blockcopolymeren

Legal Events

Date Code Title Description
AC Divided out of

Ref country code: DE

Ref document number: 3023785

Format of ref document f/p: P

Q172 Divided out of (supplement):

Ref country code: DE

Ref document number: 3023785

8110 Request for examination paragraph 44
AC Divided out of

Ref country code: DE

Ref document number: 3023785

Format of ref document f/p: P

D2 Grant after examination
8363 Opposition against the patent
8365 Fully valid after opposition proceedings
8365 Fully valid after opposition proceedings
8339 Ceased/non-payment of the annual fee