DE3018279A1 - Verfahren zur reinigung eines schwefelwasserstoff enthaltenden gases - Google Patents
Verfahren zur reinigung eines schwefelwasserstoff enthaltenden gasesInfo
- Publication number
- DE3018279A1 DE3018279A1 DE19803018279 DE3018279A DE3018279A1 DE 3018279 A1 DE3018279 A1 DE 3018279A1 DE 19803018279 DE19803018279 DE 19803018279 DE 3018279 A DE3018279 A DE 3018279A DE 3018279 A1 DE3018279 A1 DE 3018279A1
- Authority
- DE
- Germany
- Prior art keywords
- gas
- hydrogen sulfide
- oxygen
- regeneration
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000007789 gas Substances 0.000 title claims description 48
- 238000000034 method Methods 0.000 title claims description 31
- 239000011593 sulfur Substances 0.000 title description 12
- 229910052717 sulfur Inorganic materials 0.000 title description 11
- -1 SULFUR HYDROGEN Chemical class 0.000 title description 3
- 239000001257 hydrogen Substances 0.000 title description 2
- 229910052739 hydrogen Inorganic materials 0.000 title description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 48
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 48
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 41
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 26
- 229910052760 oxygen Inorganic materials 0.000 claims description 26
- 239000001301 oxygen Substances 0.000 claims description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 21
- 230000008929 regeneration Effects 0.000 claims description 17
- 238000011069 regeneration method Methods 0.000 claims description 17
- 230000008569 process Effects 0.000 claims description 16
- 238000007254 oxidation reaction Methods 0.000 claims description 13
- 230000003647 oxidation Effects 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 239000003245 coal Substances 0.000 claims description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims 2
- 240000007124 Brassica oleracea Species 0.000 claims 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 claims 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 claims 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 claims 1
- 230000004888 barrier function Effects 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 5
- 229910052976 metal sulfide Inorganic materials 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000003610 charcoal Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000003440 toxic substance Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 231100000925 very toxic Toxicity 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/48—Sulfur dioxide; Sulfurous acid
- C01B17/50—Preparation of sulfur dioxide
- C01B17/508—Preparation of sulfur dioxide by oxidation of sulfur compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Biomedical Technology (AREA)
- Treating Waste Gases (AREA)
- Catalysts (AREA)
- Industrial Gases (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7912542A FR2456543A1 (fr) | 1979-05-15 | 1979-05-15 | Procede d'epuration d'un gaz contenant du sulfure d'hydrogene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3018279A1 true DE3018279A1 (de) | 1980-11-27 |
Family
ID=9225574
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19803018279 Withdrawn DE3018279A1 (de) | 1979-05-15 | 1980-05-13 | Verfahren zur reinigung eines schwefelwasserstoff enthaltenden gases |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4310497A (enExample) |
| BE (1) | BE883203A (enExample) |
| DE (1) | DE3018279A1 (enExample) |
| FR (1) | FR2456543A1 (enExample) |
| GB (1) | GB2050332B (enExample) |
| IT (1) | IT1131487B (enExample) |
| NL (1) | NL8002768A (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0037944A3 (en) * | 1980-04-03 | 1981-11-11 | Fraunhofer-Gesellschaft Zur Forderung Der Angewandten Forschung E.V. | Method and agent for the adsorption and catalytic decomposition of stinking gases of intestines |
| DE20012867U1 (de) * | 2000-07-25 | 2001-12-06 | Anton Steinecker Maschinenfabrik GmbH, 85356 Freising | Filtervorrichtung |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2511663A1 (fr) * | 1981-08-19 | 1983-02-25 | Elf Aquitaine | Procede catalytique de production de soufre a partir d'un gaz renfermant h2s |
| FR2518424B1 (fr) * | 1981-12-17 | 1988-03-11 | Elf Aquitaine | Procede de desulfuration catalytique d'un gaz acide renfermant h2s, et eventuellement une quantite globale d'au plus 3 % en volume de cs2 et/ou cos |
| US4556547A (en) * | 1982-02-01 | 1985-12-03 | Takeda Chemical Industries, Ltd. | Process for treatment of gases |
| US4473541A (en) * | 1983-05-31 | 1984-09-25 | Standard Oil Company (Indiana) | Low water content sulfur recovery process |
| US4474739A (en) * | 1983-06-29 | 1984-10-02 | Teledyne Industries, Inc. | Method for removing gaseous pollutants in highly dilute concentrations from air at room temperatures |
| US4835043A (en) * | 1985-03-11 | 1989-05-30 | Irwin Fox | Sulfite-oxide process for scavenging hydrogen sulfide |
| US4857285A (en) * | 1987-06-04 | 1989-08-15 | General Electric Environmental Services, Inc. | Method and system for removal of sulfur compounds from gases and for regenerating spent sorbents |
| US5026528A (en) * | 1987-06-04 | 1991-06-25 | General Electric Environmental Services, Inc. | System for removal or sulfur compounds from gases and for regenerating spent sorbents |
| US5118480A (en) * | 1990-06-25 | 1992-06-02 | General Electric Environmental Services, Incorporated | Method for removing hcl and hf from coal derived fuel gas |
| US5401475A (en) * | 1991-07-08 | 1995-03-28 | G.E. Environmental Services, Inc. | Process and apparatus for generating elemental sulfur and re-usable metal oxide from spent metal sulfide sorbents |
| US5858912A (en) * | 1997-04-02 | 1999-01-12 | The Sulfatreat Company | Non-aqueous liquids for moistening an oxide-bearing carrier in sulfur sweetening |
| US5348921A (en) * | 1993-06-14 | 1994-09-20 | The United States Of America As Represented By The United States Department Of Energy | Method for reducing sulfate formation during regeneration of hot-gas desulfurization sorbents |
| US5417946A (en) * | 1993-12-30 | 1995-05-23 | Shell Oil Company | Process for removing total reduced sulfur compounds from gaseous stream |
| FR2747053B1 (fr) * | 1996-04-03 | 1998-10-02 | Rhone Poulenc Chimie | Utilisation pour l'oxydation directe des composes soufres en soufre et/ou sulfates a basse temperature d'un catalyseur a base de cuivre |
| US5792438A (en) * | 1996-08-20 | 1998-08-11 | The Sulfatreat Company | Process and composition for increasing the reactivity of sulfur scavenging iron oxides |
| US5756852A (en) * | 1996-10-15 | 1998-05-26 | Barton; Derek H. R. | Co-oxidation of H2 S and saturated hydrocarbons |
| US6887445B2 (en) * | 1998-08-04 | 2005-05-03 | M-I L.L.C. | Process for sulfur scavenging |
| FR2783818B1 (fr) * | 1998-09-24 | 2000-11-10 | Elf Exploration Prod | Procede pour oxyder directement en soufre, par voie catalytique et en phase vapeur, l'h2s contenu a faible teneur dans un gaz |
| US20070160517A1 (en) * | 2005-12-22 | 2007-07-12 | Foster Wheeler Energy Corporation | Catalyst, a method of using a catalyst, and an arrangement including a catalyst, for controlling NO and/or CO emissions from a combustion system without using external reagent |
| US20070149394A1 (en) * | 2005-12-22 | 2007-06-28 | Foster Wheeler Energy Corporation | Catalyst, a method of using a catalyst, and an arrangement including a catalyst, for controlling NO and/or CO emissions from a combustion system without using external reagent |
| US20120034154A1 (en) * | 2007-04-18 | 2012-02-09 | Orchard Material Technology Llc | Production of hydrogen through oxidation of metal sulfides |
| ES2568020T3 (es) * | 2012-01-18 | 2016-04-27 | Intramicron, Inc. | Método para eliminar compuestos que contienen azufre de flujos de combustible fluido |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE424964A (enExample) * | ||||
| GB498734A (en) * | 1937-06-07 | 1939-01-09 | Brimsdown Chemical Works Ltd | Improvements in and relating to methods and means for the treatment of gases |
| DE1193019B (de) * | 1963-06-20 | 1965-05-20 | Reinluft G M B H | Verfahren zur Adsorption von Schwefeloxyden sowie gleichzeitig von einer oder mehreren reduzierenden Schwefelverbindungen aus industriellen Gasen, insbesondere Abgasen |
| US3416293A (en) * | 1967-06-22 | 1968-12-17 | Catalysts & Chem Inc | Sulfur adsorption |
| GB1427112A (en) * | 1973-06-25 | 1976-03-10 | Yoshitomi Pharmaceutical | Antifouling compositions |
| US4008174A (en) * | 1973-06-25 | 1977-02-15 | Chevron Research Company | Process for regenerating a solid copper-chromium reactant used in the removal of hydrogen sulfide from hydrogen recycle gas |
| FR2295784A1 (fr) * | 1974-12-27 | 1976-07-23 | Inst Francais Du Petrole | Procede d'epuration d'un gaz contenant des composes du soufre |
| FR2295782A1 (fr) * | 1974-12-27 | 1976-07-23 | Inst Francais Du Petrole | Procede d'epuration d'un gaz contenant du sulfure d'hydrogene et masses de contact utilisables a cet effet |
| FR2432887A1 (fr) * | 1978-08-08 | 1980-03-07 | Inst Francais Du Petrole | Procede d'epuration d'un gaz contenant du sulfure d'hydrogene |
-
1979
- 1979-05-15 FR FR7912542A patent/FR2456543A1/fr active Granted
-
1980
- 1980-05-09 BE BE1/9813A patent/BE883203A/fr unknown
- 1980-05-13 NL NL8002768A patent/NL8002768A/nl not_active Application Discontinuation
- 1980-05-13 DE DE19803018279 patent/DE3018279A1/de not_active Withdrawn
- 1980-05-14 GB GB8015939A patent/GB2050332B/en not_active Expired
- 1980-05-14 IT IT22024/80A patent/IT1131487B/it active
-
1981
- 1981-01-30 US US06/230,174 patent/US4310497A/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0037944A3 (en) * | 1980-04-03 | 1981-11-11 | Fraunhofer-Gesellschaft Zur Forderung Der Angewandten Forschung E.V. | Method and agent for the adsorption and catalytic decomposition of stinking gases of intestines |
| DE20012867U1 (de) * | 2000-07-25 | 2001-12-06 | Anton Steinecker Maschinenfabrik GmbH, 85356 Freising | Filtervorrichtung |
Also Published As
| Publication number | Publication date |
|---|---|
| US4310497A (en) | 1982-01-12 |
| NL8002768A (nl) | 1980-11-18 |
| GB2050332B (en) | 1982-12-08 |
| FR2456543A1 (fr) | 1980-12-12 |
| FR2456543B1 (enExample) | 1984-02-10 |
| GB2050332A (en) | 1981-01-07 |
| IT1131487B (it) | 1986-06-25 |
| BE883203A (fr) | 1980-11-10 |
| IT8022024A0 (it) | 1980-05-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8141 | Disposal/no request for examination |