DE3012369C2 - Verfahren zur Herstellung von Silanderivaten aus Sepiolith und Alkoxysilanen sowie deren Verwendung zur Härtesteigerung von Polymeren - Google Patents
Verfahren zur Herstellung von Silanderivaten aus Sepiolith und Alkoxysilanen sowie deren Verwendung zur Härtesteigerung von PolymerenInfo
- Publication number
- DE3012369C2 DE3012369C2 DE3012369A DE3012369A DE3012369C2 DE 3012369 C2 DE3012369 C2 DE 3012369C2 DE 3012369 A DE3012369 A DE 3012369A DE 3012369 A DE3012369 A DE 3012369A DE 3012369 C2 DE3012369 C2 DE 3012369C2
- Authority
- DE
- Germany
- Prior art keywords
- sepiolite
- silane
- polymers
- alkoxysilanes
- hardness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004113 Sepiolite Substances 0.000 title claims description 32
- 229910052624 sepiolite Inorganic materials 0.000 title claims description 32
- 235000019355 sepiolite Nutrition 0.000 title claims description 32
- 150000004756 silanes Chemical class 0.000 title claims description 16
- 229920000642 polymer Polymers 0.000 title claims description 13
- 238000000034 method Methods 0.000 title claims description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 230000008569 process Effects 0.000 title claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 230000008020 evaporation Effects 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 4
- 239000006227 byproduct Substances 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 230000009471 action Effects 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 description 12
- 238000004073 vulcanization Methods 0.000 description 4
- 230000036571 hydration Effects 0.000 description 3
- 238000006703 hydration reaction Methods 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 125000005372 silanol group Chemical group 0.000 description 3
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- CAUAWIFTTGVSNB-UHFFFAOYSA-N [S].C1=CC=C2S(=S)(=S)C(S)=NC2=C1 Chemical compound [S].C1=CC=C2S(=S)(=S)C(S)=NC2=C1 CAUAWIFTTGVSNB-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- -1 alkoxy silanes Chemical class 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical group CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- BSEUQTUSBWEPLY-UHFFFAOYSA-N methoxy-propyl-sulfanylsilane Chemical compound CCC[SiH](S)OC BSEUQTUSBWEPLY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000006884 silylation reaction Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Tires In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES482033A ES482033A1 (es) | 1979-06-28 | 1979-06-28 | Procedimiento de obtencion de derivados simlanicos de sepio-lita por reaccion con alcoxi-silanos para aumentar su poder reforzante en polimeros. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3012369A1 DE3012369A1 (de) | 1981-01-22 |
| DE3012369C2 true DE3012369C2 (de) | 1984-05-24 |
Family
ID=8478558
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3012369A Expired DE3012369C2 (de) | 1979-06-28 | 1980-03-29 | Verfahren zur Herstellung von Silanderivaten aus Sepiolith und Alkoxysilanen sowie deren Verwendung zur Härtesteigerung von Polymeren |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4302594A (OSRAM) |
| JP (1) | JPS5844603B2 (OSRAM) |
| BE (1) | BE882282A (OSRAM) |
| CH (1) | CH643866A5 (OSRAM) |
| DE (1) | DE3012369C2 (OSRAM) |
| DK (1) | DK90280A (OSRAM) |
| ES (1) | ES482033A1 (OSRAM) |
| FR (1) | FR2460309A1 (OSRAM) |
| GB (1) | GB2052458B (OSRAM) |
| IT (1) | IT1130958B (OSRAM) |
| NL (1) | NL8003754A (OSRAM) |
| SE (1) | SE439016B (OSRAM) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4824950A (en) * | 1985-09-16 | 1989-04-25 | Sandoz Pharm. Corp. | Chiral stationary phases and columns for chromatographic resolution |
| AT387970B (de) * | 1986-01-22 | 1989-04-10 | Naintsch Mineralwerke | Verwendung von mit trialkoxysilanen beschichteten silikatischen fuellstoffen |
| US4810578A (en) * | 1986-10-20 | 1989-03-07 | E.C.C. America Inc. | Surface modified pigments and methods for producing same and elastomers containing same |
| AU3123793A (en) * | 1991-11-08 | 1993-06-07 | Calling Communications Corporation | Terrestrial antennas for satellite communication system |
| GB9726636D0 (en) * | 1997-12-17 | 1998-02-18 | Dow Corning | Method for preparing hydrophobic clay |
| GB0808680D0 (en) * | 2008-05-14 | 2008-06-18 | Dow Corning | Silicone rubber compositions |
| ES2386711B1 (es) * | 2011-02-01 | 2013-07-09 | Tolsa, S.A. | Método de obtención de un compuesto basado en silicatos pseudolaminares y su uso como carga para materiales poliméricos. |
| CN116751411B (zh) * | 2023-07-10 | 2023-12-08 | 青岛众祥高分子材料有限公司 | 一种改性海泡石在橡胶中的应用 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1520663A (fr) * | 1967-02-28 | 1968-04-12 | Rhone Poulenc Sa | Traitement de charges minérales par des dérivés organosiliciques |
| GB1312665A (en) * | 1969-06-13 | 1973-04-04 | Cabot Corp | Surface metal and metalloid oxides |
| US4164509A (en) * | 1970-11-24 | 1979-08-14 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Process for preparing finely divided hydrophobic oxide particles |
| FR2135793A5 (OSRAM) * | 1971-04-29 | 1972-12-22 | Pechiney Saint Gobain | |
| SU765271A1 (ru) * | 1977-12-06 | 1980-09-23 | Предприятие П/Я В-2913 | Способ получени пероксидированных минеральных наполнителей дл полимеров |
-
1979
- 1979-06-28 ES ES482033A patent/ES482033A1/es not_active Expired
-
1980
- 1980-03-03 DK DK90280A patent/DK90280A/da not_active Application Discontinuation
- 1980-03-11 IT IT20494/80A patent/IT1130958B/it active
- 1980-03-14 FR FR8005802A patent/FR2460309A1/fr active Granted
- 1980-03-18 BE BE0/199838A patent/BE882282A/fr not_active IP Right Cessation
- 1980-03-24 US US06/132,832 patent/US4302594A/en not_active Expired - Lifetime
- 1980-03-29 DE DE3012369A patent/DE3012369C2/de not_active Expired
- 1980-04-01 SE SE8002518A patent/SE439016B/sv not_active IP Right Cessation
- 1980-04-11 GB GB8012108A patent/GB2052458B/en not_active Expired
- 1980-04-16 CH CH294980A patent/CH643866A5/fr not_active IP Right Cessation
- 1980-05-02 JP JP55058046A patent/JPS5844603B2/ja not_active Expired
- 1980-06-27 NL NL8003754A patent/NL8003754A/nl active Search and Examination
Non-Patent Citations (1)
| Title |
|---|
| NICHTS-ERMITTELT |
Also Published As
| Publication number | Publication date |
|---|---|
| DK90280A (da) | 1980-12-29 |
| IT1130958B (it) | 1986-06-18 |
| CH643866A5 (fr) | 1984-06-29 |
| DE3012369A1 (de) | 1981-01-22 |
| SE8002518L (sv) | 1980-12-29 |
| SE439016B (sv) | 1985-05-28 |
| GB2052458B (en) | 1983-01-19 |
| FR2460309A1 (fr) | 1981-01-23 |
| BE882282A (fr) | 1980-07-16 |
| ES482033A1 (es) | 1980-04-01 |
| FR2460309B1 (OSRAM) | 1984-09-07 |
| JPS5844603B2 (ja) | 1983-10-04 |
| JPS568395A (en) | 1981-01-28 |
| NL8003754A (nl) | 1980-12-30 |
| US4302594A (en) | 1981-11-24 |
| GB2052458A (en) | 1981-01-28 |
| IT8020494A0 (it) | 1980-03-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8125 | Change of the main classification |
Ipc: C07F 7/18 |
|
| 8126 | Change of the secondary classification |
Ipc: C08K 9/06 |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |