DE2855696A1 - Waessrige polymerdispersion - Google Patents
Waessrige polymerdispersionInfo
- Publication number
 - DE2855696A1 DE2855696A1 DE19782855696 DE2855696A DE2855696A1 DE 2855696 A1 DE2855696 A1 DE 2855696A1 DE 19782855696 DE19782855696 DE 19782855696 DE 2855696 A DE2855696 A DE 2855696A DE 2855696 A1 DE2855696 A1 DE 2855696A1
 - Authority
 - DE
 - Germany
 - Prior art keywords
 - polymer
 - groups
 - poly
 - film
 - weight
 - Prior art date
 - Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
 - Withdrawn
 
Links
- 239000004815 dispersion polymer Substances 0.000 title claims description 14
 - 229920000642 polymer Polymers 0.000 claims description 68
 - 239000000178 monomer Substances 0.000 claims description 52
 - 229920000233 poly(alkylene oxides) Polymers 0.000 claims description 34
 - 150000001408 amides Chemical class 0.000 claims description 32
 - IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 24
 - XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
 - 150000001875 compounds Chemical class 0.000 claims description 20
 - 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 claims description 10
 - 239000002245 particle Substances 0.000 claims description 10
 - 125000003277 amino group Chemical group 0.000 claims description 9
 - HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 8
 - NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
 - JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical group CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 6
 - 229910052799 carbon Inorganic materials 0.000 claims description 5
 - FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 5
 - -1 methacrylyl group Chemical group 0.000 claims description 5
 - 150000001412 amines Chemical class 0.000 claims description 4
 - 125000004069 aziridinyl group Chemical group 0.000 claims description 4
 - 125000000217 alkyl group Chemical group 0.000 claims description 3
 - 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
 - 230000000295 complement effect Effects 0.000 claims description 3
 - 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
 - 229910052757 nitrogen Inorganic materials 0.000 claims description 3
 - RYECOJGRJDOGPP-UHFFFAOYSA-N Ethylurea Chemical compound CCNC(N)=O RYECOJGRJDOGPP-UHFFFAOYSA-N 0.000 claims 1
 - CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 1
 - 229920000575 polymersome Polymers 0.000 claims 1
 - 239000006185 dispersion Substances 0.000 description 125
 - 239000000463 material Substances 0.000 description 24
 - 229920003171 Poly (ethylene oxide) Polymers 0.000 description 21
 - 238000012360 testing method Methods 0.000 description 20
 - 238000000034 method Methods 0.000 description 11
 - 239000000203 mixture Substances 0.000 description 11
 - 239000011248 coating agent Substances 0.000 description 10
 - 238000000576 coating method Methods 0.000 description 10
 - 239000004094 surface-active agent Substances 0.000 description 8
 - 239000000853 adhesive Substances 0.000 description 6
 - 230000001070 adhesive effect Effects 0.000 description 6
 - 238000006243 chemical reaction Methods 0.000 description 6
 - 239000008199 coating composition Substances 0.000 description 6
 - 239000012153 distilled water Substances 0.000 description 6
 - 239000003973 paint Substances 0.000 description 6
 - CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
 - 239000007787 solid Substances 0.000 description 5
 - IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
 - ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
 - CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
 - 239000003795 chemical substances by application Substances 0.000 description 4
 - 238000004519 manufacturing process Methods 0.000 description 4
 - 230000008569 process Effects 0.000 description 4
 - 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
 - 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
 - XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
 - 239000000654 additive Substances 0.000 description 3
 - 239000002390 adhesive tape Substances 0.000 description 3
 - 125000002947 alkylene group Chemical group 0.000 description 3
 - 230000015572 biosynthetic process Effects 0.000 description 3
 - 230000000052 comparative effect Effects 0.000 description 3
 - 238000010790 dilution Methods 0.000 description 3
 - 239000012895 dilution Substances 0.000 description 3
 - 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
 - 150000002466 imines Chemical class 0.000 description 3
 - 238000011835 investigation Methods 0.000 description 3
 - 239000004816 latex Substances 0.000 description 3
 - 229920000126 latex Polymers 0.000 description 3
 - 239000000049 pigment Substances 0.000 description 3
 - 238000002360 preparation method Methods 0.000 description 3
 - 239000011541 reaction mixture Substances 0.000 description 3
 - 238000003756 stirring Methods 0.000 description 3
 - 238000004383 yellowing Methods 0.000 description 3
 - OZDGMOYKSFPLSE-UHFFFAOYSA-N 2-Methylaziridine Chemical compound CC1CN1 OZDGMOYKSFPLSE-UHFFFAOYSA-N 0.000 description 2
 - QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
 - SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
 - BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
 - GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
 - PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
 - GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
 - 229920004896 Triton X-405 Polymers 0.000 description 2
 - 125000003545 alkoxy group Chemical group 0.000 description 2
 - 229920000180 alkyd Polymers 0.000 description 2
 - 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
 - 230000009286 beneficial effect Effects 0.000 description 2
 - 125000004432 carbon atom Chemical group C* 0.000 description 2
 - 230000008859 change Effects 0.000 description 2
 - 230000000694 effects Effects 0.000 description 2
 - 238000009472 formulation Methods 0.000 description 2
 - 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
 - 125000000879 imine group Chemical group 0.000 description 2
 - 239000004615 ingredient Substances 0.000 description 2
 - UELAIMNOXLAYRW-UHFFFAOYSA-M sodium;1,4-dicyclohexyloxy-1,4-dioxobutane-2-sulfonate Chemical compound [Na+].C1CCCCC1OC(=O)C(S(=O)(=O)[O-])CC(=O)OC1CCCCC1 UELAIMNOXLAYRW-UHFFFAOYSA-M 0.000 description 2
 - 125000001424 substituent group Chemical group 0.000 description 2
 - STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
 - WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
 - YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
 - SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
 - BEWCNXNIQCLWHP-UHFFFAOYSA-N 2-(tert-butylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCNC(C)(C)C BEWCNXNIQCLWHP-UHFFFAOYSA-N 0.000 description 1
 - GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
 - YRGGDTFYCLUICG-UHFFFAOYSA-N 2-[tert-butyl(butylcarbamoyl)amino]ethyl 2-methylprop-2-enoate Chemical compound CCCCNC(=O)N(C(C)(C)C)CCOC(=O)C(C)=C YRGGDTFYCLUICG-UHFFFAOYSA-N 0.000 description 1
 - LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
 - QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
 - NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
 - NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
 - VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
 - VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
 - JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
 - 239000005977 Ethylene Substances 0.000 description 1
 - 239000004606 Fillers/Extenders Substances 0.000 description 1
 - VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
 - 239000005642 Oleic acid Substances 0.000 description 1
 - ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
 - RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 1
 - BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
 - 239000002253 acid Substances 0.000 description 1
 - 230000000996 additive effect Effects 0.000 description 1
 - 239000002318 adhesion promoter Substances 0.000 description 1
 - 150000001298 alcohols Chemical class 0.000 description 1
 - 229910021529 ammonia Inorganic materials 0.000 description 1
 - 235000011114 ammonium hydroxide Nutrition 0.000 description 1
 - BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
 - 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
 - 235000011130 ammonium sulphate Nutrition 0.000 description 1
 - 239000001166 ammonium sulphate Substances 0.000 description 1
 - 125000000129 anionic group Chemical group 0.000 description 1
 - 230000000844 anti-bacterial effect Effects 0.000 description 1
 - 239000003899 bactericide agent Substances 0.000 description 1
 - CNWSQCLBDWYLAN-UHFFFAOYSA-N butylurea Chemical compound CCCCNC(N)=O CNWSQCLBDWYLAN-UHFFFAOYSA-N 0.000 description 1
 - 239000000969 carrier Substances 0.000 description 1
 - 239000011093 chipboard Substances 0.000 description 1
 - 239000000084 colloidal system Substances 0.000 description 1
 - 239000013065 commercial product Substances 0.000 description 1
 - 239000007859 condensation product Substances 0.000 description 1
 - 230000003750 conditioning effect Effects 0.000 description 1
 - 230000036461 convulsion Effects 0.000 description 1
 - 229920001577 copolymer Polymers 0.000 description 1
 - 230000001419 dependent effect Effects 0.000 description 1
 - 239000012470 diluted sample Substances 0.000 description 1
 - GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
 - 238000005516 engineering process Methods 0.000 description 1
 - 150000002148 esters Chemical class 0.000 description 1
 - SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
 - 238000002474 experimental method Methods 0.000 description 1
 - 230000002349 favourable effect Effects 0.000 description 1
 - 210000003608 fece Anatomy 0.000 description 1
 - 238000005187 foaming Methods 0.000 description 1
 - VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
 - 238000010438 heat treatment Methods 0.000 description 1
 - 150000002500 ions Chemical class 0.000 description 1
 - QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
 - 238000009533 lab test Methods 0.000 description 1
 - 239000002932 luster Substances 0.000 description 1
 - 229910052751 metal Inorganic materials 0.000 description 1
 - 239000002184 metal Substances 0.000 description 1
 - 125000005395 methacrylic acid group Chemical group 0.000 description 1
 - 238000002156 mixing Methods 0.000 description 1
 - 230000004048 modification Effects 0.000 description 1
 - 238000012986 modification Methods 0.000 description 1
 - 239000002736 nonionic surfactant Substances 0.000 description 1
 - ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
 - 125000000466 oxiranyl group Chemical group 0.000 description 1
 - PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
 - 229920001223 polyethylene glycol Polymers 0.000 description 1
 - 230000001681 protective effect Effects 0.000 description 1
 - 230000009467 reduction Effects 0.000 description 1
 - 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
 - GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
 - 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
 - 239000003381 stabilizer Substances 0.000 description 1
 - 239000007858 starting material Substances 0.000 description 1
 - 229920001059 synthetic polymer Polymers 0.000 description 1
 - 238000010998 test method Methods 0.000 description 1
 - 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
 - 239000004753 textile Substances 0.000 description 1
 - 229920001187 thermosetting polymer Polymers 0.000 description 1
 - 230000008719 thickening Effects 0.000 description 1
 - 239000002562 thickening agent Substances 0.000 description 1
 - 239000004408 titanium dioxide Substances 0.000 description 1
 - 239000002966 varnish Substances 0.000 description 1
 - 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
 - 229920002554 vinyl polymer Polymers 0.000 description 1
 - 230000002087 whitening effect Effects 0.000 description 1
 
Classifications
- 
        
- C—CHEMISTRY; METALLURGY
 - C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
 - C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
 - C08F2/00—Processes of polymerisation
 - C08F2/12—Polymerisation in non-solvents
 - C08F2/16—Aqueous medium
 
 - 
        
- C—CHEMISTRY; METALLURGY
 - C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
 - C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
 - C08F246/00—Copolymers in which the nature of only the monomers in minority is defined
 
 - 
        
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
 - Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
 - Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
 - Y10T428/00—Stock material or miscellaneous articles
 - Y10T428/31504—Composite [nonstructural laminate]
 - Y10T428/31855—Of addition polymer from unsaturated monomers
 - Y10T428/31935—Ester, halide or nitrile of addition polymer
 
 
Landscapes
- Chemical & Material Sciences (AREA)
 - Health & Medical Sciences (AREA)
 - Chemical Kinetics & Catalysis (AREA)
 - Medicinal Chemistry (AREA)
 - Polymers & Plastics (AREA)
 - Organic Chemistry (AREA)
 - Paints Or Removers (AREA)
 - Compositions Of Macromolecular Compounds (AREA)
 - Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
 
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title | 
|---|---|---|---|
| AUPD288777 | 1977-12-23 | 
Publications (1)
| Publication Number | Publication Date | 
|---|---|
| DE2855696A1 true DE2855696A1 (de) | 1979-06-28 | 
Family
ID=3767340
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date | 
|---|---|---|---|
| DE19782855696 Withdrawn DE2855696A1 (de) | 1977-12-23 | 1978-12-22 | Waessrige polymerdispersion | 
Country Status (14)
| Country | Link | 
|---|---|
| US (1) | US4248754A (forum.php) | 
| JP (1) | JPS5495696A (forum.php) | 
| BE (1) | BE872973A (forum.php) | 
| CA (1) | CA1122339A (forum.php) | 
| DE (1) | DE2855696A1 (forum.php) | 
| ES (1) | ES476299A1 (forum.php) | 
| FR (1) | FR2412571A1 (forum.php) | 
| GB (1) | GB2027438B (forum.php) | 
| IT (1) | IT1102757B (forum.php) | 
| NL (1) | NL7812480A (forum.php) | 
| NZ (1) | NZ189084A (forum.php) | 
| PT (1) | PT68971A (forum.php) | 
| SE (1) | SE7813042L (forum.php) | 
| ZA (1) | ZA786813B (forum.php) | 
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| JPS55721A (en) * | 1978-06-19 | 1980-01-07 | Showa Denko Kk | Aqueous dispersion of water-soluble high polymer complex | 
| US4352916A (en) * | 1981-07-17 | 1982-10-05 | Hercules Incorporated | Use of hydrophobically modified water soluble polymers in suspension polymerization | 
| US4799962A (en) * | 1987-12-24 | 1989-01-24 | Aqualon Company | Water-soluble polymer dispersion | 
| US5312863A (en) * | 1989-07-05 | 1994-05-17 | Rohm And Haas Company | Cationic latex coatings | 
| GB9211760D0 (en) * | 1992-06-03 | 1992-07-15 | Gillette Co | Correction fluids | 
| DE4334178A1 (de) * | 1993-10-07 | 1995-04-13 | Basf Ag | Wäßrige Polymerisatzubereitungen | 
| ZA955550B (en) | 1994-07-08 | 1996-02-16 | Gillette Co | Aqueous correction fluids | 
| US5669750A (en) * | 1996-07-19 | 1997-09-23 | Vieselmeyer; Lee R. | Loader attachment | 
| US5922400A (en) * | 1997-01-09 | 1999-07-13 | The Gillette Company | Correction fluid | 
| US7528200B2 (en) * | 2006-02-01 | 2009-05-05 | Ardes Enterprises, Inc. | Epoxy hardener systems based on aminobis(methylene-ethyleneurea) | 
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| GB1383367A (en) * | 1972-03-14 | 1974-02-12 | American Cyanamid Co | Polymers | 
- 
        1978
        
- 1978-12-04 NZ NZ189084A patent/NZ189084A/xx unknown
 - 1978-12-05 ZA ZA00786813A patent/ZA786813B/xx unknown
 - 1978-12-05 US US05/967,254 patent/US4248754A/en not_active Expired - Lifetime
 - 1978-12-15 JP JP15427278A patent/JPS5495696A/ja active Pending
 - 1978-12-19 SE SE7813042A patent/SE7813042L/xx unknown
 - 1978-12-20 GB GB7849336A patent/GB2027438B/en not_active Expired
 - 1978-12-20 CA CA318,256A patent/CA1122339A/en not_active Expired
 - 1978-12-21 BE BE192488A patent/BE872973A/xx unknown
 - 1978-12-22 IT IT31288/78A patent/IT1102757B/it active
 - 1978-12-22 ES ES476299A patent/ES476299A1/es not_active Expired
 - 1978-12-22 NL NL7812480A patent/NL7812480A/xx not_active Application Discontinuation
 - 1978-12-22 DE DE19782855696 patent/DE2855696A1/de not_active Withdrawn
 - 1978-12-22 PT PT68971A patent/PT68971A/pt unknown
 - 1978-12-22 FR FR7836210A patent/FR2412571A1/fr active Pending
 
 
Also Published As
| Publication number | Publication date | 
|---|---|
| NZ189084A (en) | 1981-02-11 | 
| ZA786813B (en) | 1979-10-31 | 
| JPS5495696A (en) | 1979-07-28 | 
| GB2027438B (en) | 1982-09-29 | 
| CA1122339A (en) | 1982-04-20 | 
| FR2412571A1 (fr) | 1979-07-20 | 
| PT68971A (en) | 1979-01-01 | 
| IT1102757B (it) | 1985-10-07 | 
| IT7831288A0 (it) | 1978-12-22 | 
| NL7812480A (nl) | 1979-06-26 | 
| SE7813042L (sv) | 1979-06-24 | 
| BE872973A (forum.php) | 1979-04-17 | 
| GB2027438A (en) | 1980-02-20 | 
| ES476299A1 (es) | 1979-11-16 | 
| US4248754A (en) | 1981-02-03 | 
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