DE2810597C2 - Elektrische Bauelementstruktur mit einer mehrschichtigen Isolierschicht - Google Patents
Elektrische Bauelementstruktur mit einer mehrschichtigen IsolierschichtInfo
- Publication number
- DE2810597C2 DE2810597C2 DE2810597A DE2810597A DE2810597C2 DE 2810597 C2 DE2810597 C2 DE 2810597C2 DE 2810597 A DE2810597 A DE 2810597A DE 2810597 A DE2810597 A DE 2810597A DE 2810597 C2 DE2810597 C2 DE 2810597C2
- Authority
- DE
- Germany
- Prior art keywords
- insulating layer
- interface
- band
- silicon
- sio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000009413 insulation Methods 0.000 title 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 20
- 229910052710 silicon Inorganic materials 0.000 claims description 20
- 239000010703 silicon Substances 0.000 claims description 20
- 239000000758 substrate Substances 0.000 claims description 10
- 238000002347 injection Methods 0.000 claims description 9
- 239000007924 injection Substances 0.000 claims description 9
- 230000005669 field effect Effects 0.000 claims description 7
- 238000003860 storage Methods 0.000 claims description 7
- 239000002800 charge carrier Substances 0.000 claims description 6
- 239000004065 semiconductor Substances 0.000 claims description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 12
- 229910008065 Si-SiO Inorganic materials 0.000 description 9
- 229910006405 Si—SiO Inorganic materials 0.000 description 9
- 229910052782 aluminium Inorganic materials 0.000 description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 230000015654 memory Effects 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- 230000006399 behavior Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000005468 ion implantation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009388 chemical precipitation Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000010893 electron trap Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000005524 hole trap Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000006386 memory function Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000005641 tunneling Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28158—Making the insulator
- H01L21/28167—Making the insulator on single crystalline silicon, e.g. using a liquid, i.e. chemical oxidation
- H01L21/28194—Making the insulator on single crystalline silicon, e.g. using a liquid, i.e. chemical oxidation by deposition, e.g. evaporation, ALD, CVD, sputtering, laser deposition
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C16/00—Erasable programmable read-only memories
- G11C16/02—Erasable programmable read-only memories electrically programmable
- G11C16/04—Erasable programmable read-only memories electrically programmable using variable threshold transistors, e.g. FAMOS
- G11C16/0466—Erasable programmable read-only memories electrically programmable using variable threshold transistors, e.g. FAMOS comprising cells with charge storage in an insulating layer, e.g. metal-nitride-oxide-silicon [MNOS], silicon-oxide-nitride-oxide-silicon [SONOS]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/3115—Doping the insulating layers
- H01L21/31155—Doping the insulating layers by ion implantation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/04—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body
- H01L27/08—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including only semiconductor components of a single kind
- H01L27/085—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including only semiconductor components of a single kind including field-effect components only
- H01L27/088—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including only semiconductor components of a single kind including field-effect components only the components being field-effect transistors with insulated gate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/51—Insulating materials associated therewith
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/51—Insulating materials associated therewith
- H01L29/511—Insulating materials associated therewith with a compositional variation, e.g. multilayer structures
- H01L29/513—Insulating materials associated therewith with a compositional variation, e.g. multilayer structures the variation being perpendicular to the channel plane
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/792—Field effect transistors with field effect produced by an insulated gate with charge trapping gate insulator, e.g. MNOS-memory transistors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/86—Types of semiconductor device ; Multistep manufacturing processes therefor controllable only by variation of the electric current supplied, or only the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched
- H01L29/92—Capacitors having potential barriers
- H01L29/94—Metal-insulator-semiconductors, e.g. MOS
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices having no potential barriers, and specially adapted for rectifying, amplifying, oscillating or switching
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- Non-Volatile Memory (AREA)
- Semiconductor Memories (AREA)
- Electrodes Of Semiconductors (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/808,501 US4104675A (en) | 1977-06-21 | 1977-06-21 | Moderate field hole and electron injection from one interface of MIM or MIS structures |
Publications (2)
Publication Number | Publication Date |
---|---|
DE2810597A1 DE2810597A1 (de) | 1979-01-11 |
DE2810597C2 true DE2810597C2 (de) | 1987-03-05 |
Family
ID=25198955
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE2810597A Expired DE2810597C2 (de) | 1977-06-21 | 1978-03-11 | Elektrische Bauelementstruktur mit einer mehrschichtigen Isolierschicht |
Country Status (5)
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4104675A (en) * | 1977-06-21 | 1978-08-01 | International Business Machines Corporation | Moderate field hole and electron injection from one interface of MIM or MIS structures |
US4323910A (en) * | 1977-11-28 | 1982-04-06 | Rca Corporation | MNOS Memory transistor |
US4217601A (en) * | 1979-02-15 | 1980-08-12 | International Business Machines Corporation | Non-volatile memory devices fabricated from graded or stepped energy band gap insulator MIM or MIS structure |
USRE31083E (en) * | 1979-02-15 | 1982-11-16 | International Business Machines Corporation | Non-volatile memory devices fabricated from graded or stepped energy band gap insulator MIM or MIS structure |
US4291328A (en) * | 1979-06-15 | 1981-09-22 | Texas Instruments Incorporated | Interlevel insulator for integrated circuit with implanted resistor element in second-level polycrystalline silicon |
JPS5642375A (en) * | 1979-08-31 | 1981-04-20 | Fujitsu Ltd | Semiconductor nonvolatile memory |
US4253106A (en) * | 1979-10-19 | 1981-02-24 | Rca Corporation | Gate injected floating gate memory device |
US4334347A (en) * | 1979-10-19 | 1982-06-15 | Rca Corporation | Method of forming an improved gate member for a gate injected floating gate memory device |
EP0034653B1 (en) * | 1980-02-25 | 1984-05-16 | International Business Machines Corporation | Dual electron injector structures |
US4334292A (en) * | 1980-05-27 | 1982-06-08 | International Business Machines Corp. | Low voltage electrically erasable programmable read only memory |
US4336603A (en) * | 1980-06-18 | 1982-06-22 | International Business Machines Corp. | Three terminal electrically erasable programmable read only memory |
US4375085A (en) * | 1981-01-02 | 1983-02-22 | International Business Machines Corporation | Dense electrically alterable read only memory |
US4472726A (en) * | 1981-05-06 | 1984-09-18 | The United States Of America As Represented By The Secretary Of The Air Force | Two carrier dual injector apparatus |
EP0081626B1 (en) * | 1981-12-14 | 1988-10-19 | International Business Machines Corporation | Dual electron injector structure and semiconductor memory device including a dual electron injector structure |
US4729115A (en) * | 1984-09-27 | 1988-03-01 | International Business Machines Corporation | Non-volatile dynamic random access memory cell |
US4665417A (en) * | 1984-09-27 | 1987-05-12 | International Business Machines Corporation | Non-volatile dynamic random access memory cell |
JPS6180866A (ja) * | 1984-09-27 | 1986-04-24 | インタ−ナショナル ビジネス マシ−ンズ コ−ポレ−ション | 不揮発性半導体メモリ・セル |
US4752812A (en) * | 1987-01-12 | 1988-06-21 | International Business Machines Corporation | Permeable-base transistor |
US4870470A (en) * | 1987-10-16 | 1989-09-26 | International Business Machines Corporation | Non-volatile memory cell having Si rich silicon nitride charge trapping layer |
CA1276314C (en) * | 1988-03-24 | 1990-11-13 | Alexander Kalnitsky | Silicon ion implanted semiconductor device |
WO1991015033A1 (en) * | 1990-03-20 | 1991-10-03 | Fujitsu Limited | Electron device having a current channel of dielectric material |
US5432749A (en) * | 1994-04-26 | 1995-07-11 | National Semiconductor Corporation | Non-volatile memory cell having hole confinement layer for reducing band-to-band tunneling |
TW374196B (en) | 1996-02-23 | 1999-11-11 | Semiconductor Energy Lab Co Ltd | Semiconductor thin film and method for manufacturing the same and semiconductor device and method for manufacturing the same |
TW335503B (en) * | 1996-02-23 | 1998-07-01 | Semiconductor Energy Lab Kk | Semiconductor thin film and manufacturing method and semiconductor device and its manufacturing method |
US6548825B1 (en) | 1999-06-04 | 2003-04-15 | Matsushita Electric Industrial Co., Ltd. | Semiconductor device including barrier layer having dispersed particles |
US20090032861A1 (en) * | 2007-07-30 | 2009-02-05 | Zhong Dong | Nonvolatile memories with charge trapping layers containing silicon nitride with germanium or phosphorus |
US20090140318A1 (en) * | 2007-12-03 | 2009-06-04 | Zhong Dong | Nonvolatile memories with higher conduction-band edge adjacent to charge-trapping dielectric |
US20110039034A1 (en) * | 2009-08-11 | 2011-02-17 | Helen Maynard | Pulsed deposition and recrystallization and tandem solar cell design utilizing crystallized/amorphous material |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS497870B1 (US07534539-20090519-C00104.png) * | 1969-06-06 | 1974-02-22 | ||
BE756782A (fr) * | 1969-10-03 | 1971-03-01 | Western Electric Co | Organe de memoire ayant une structure comportant deux couches isolantesentre un semiconducteur et une couche de metal |
GB1360770A (en) * | 1972-05-30 | 1974-07-24 | Westinghouse Electric Corp | N-channel mos transistor |
US3972059A (en) * | 1973-12-28 | 1976-07-27 | International Business Machines Corporation | Dielectric diode, fabrication thereof, and charge store memory therewith |
US4047974A (en) * | 1975-12-30 | 1977-09-13 | Hughes Aircraft Company | Process for fabricating non-volatile field effect semiconductor memory structure utilizing implanted ions to induce trapping states |
US4104675A (en) * | 1977-06-21 | 1978-08-01 | International Business Machines Corporation | Moderate field hole and electron injection from one interface of MIM or MIS structures |
US4217601A (en) * | 1979-02-15 | 1980-08-12 | International Business Machines Corporation | Non-volatile memory devices fabricated from graded or stepped energy band gap insulator MIM or MIS structure |
-
1977
- 1977-06-21 US US05/808,501 patent/US4104675A/en not_active Expired - Lifetime
-
1978
- 1978-01-25 JP JP628278A patent/JPS548479A/ja active Granted
- 1978-02-15 FR FR7804977A patent/FR2395604A1/fr active Granted
- 1978-02-20 GB GB6607/78A patent/GB1596445A/en not_active Expired
- 1978-03-11 DE DE2810597A patent/DE2810597C2/de not_active Expired
-
1980
- 1980-07-25 US US06/172,058 patent/USRE31734E/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US4104675A (en) | 1978-08-01 |
DE2810597A1 (de) | 1979-01-11 |
USRE31734E (en) | 1984-11-13 |
FR2395604B1 (US07534539-20090519-C00104.png) | 1980-03-14 |
GB1596445A (en) | 1981-08-26 |
JPS5544468B2 (US07534539-20090519-C00104.png) | 1980-11-12 |
JPS548479A (en) | 1979-01-22 |
FR2395604A1 (fr) | 1979-01-19 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8110 | Request for examination paragraph 44 | ||
D2 | Grant after examination | ||
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |