DE2759973C2 - Imprägnierte und/oder kationengetauschte Aluminosilicat-Zeolithe - Google Patents
Imprägnierte und/oder kationengetauschte Aluminosilicat-ZeolitheInfo
- Publication number
- DE2759973C2 DE2759973C2 DE2759973A DE2759973A DE2759973C2 DE 2759973 C2 DE2759973 C2 DE 2759973C2 DE 2759973 A DE2759973 A DE 2759973A DE 2759973 A DE2759973 A DE 2759973A DE 2759973 C2 DE2759973 C2 DE 2759973C2
- Authority
- DE
- Germany
- Prior art keywords
- gallium
- zeolite
- zsm
- exchanged
- hydrocarbons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010457 zeolite Substances 0.000 title claims description 46
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims description 44
- 229910000323 aluminium silicate Inorganic materials 0.000 title claims description 17
- 229910021536 Zeolite Inorganic materials 0.000 claims description 28
- 229910052733 gallium Inorganic materials 0.000 claims description 28
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 22
- CHPZKNULDCNCBW-UHFFFAOYSA-N gallium nitrate Chemical compound [Ga+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CHPZKNULDCNCBW-UHFFFAOYSA-N 0.000 claims description 22
- -1 gallium ions Chemical class 0.000 claims description 17
- 229940044658 gallium nitrate Drugs 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 150000001768 cations Chemical class 0.000 claims description 7
- 150000002259 gallium compounds Chemical class 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000010992 reflux Methods 0.000 claims description 4
- AJNVQOSZGJRYEI-UHFFFAOYSA-N digallium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Ga+3].[Ga+3] AJNVQOSZGJRYEI-UHFFFAOYSA-N 0.000 claims description 3
- 229910001195 gallium oxide Inorganic materials 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 2
- 150000002258 gallium Chemical class 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 description 30
- 239000003054 catalyst Substances 0.000 description 29
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 22
- 238000006243 chemical reaction Methods 0.000 description 14
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 14
- 150000002430 hydrocarbons Chemical class 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000004215 Carbon black (E152) Substances 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 239000001282 iso-butane Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000004913 activation Effects 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000013078 crystal Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 229910000373 gallium sulfate Inorganic materials 0.000 description 1
- UPWPDUACHOATKO-UHFFFAOYSA-K gallium trichloride Chemical compound Cl[Ga](Cl)Cl UPWPDUACHOATKO-UHFFFAOYSA-K 0.000 description 1
- CKHJYUSOUQDYEN-UHFFFAOYSA-N gallium(3+) Chemical compound [Ga+3] CKHJYUSOUQDYEN-UHFFFAOYSA-N 0.000 description 1
- SBDRYJMIQMDXRH-UHFFFAOYSA-N gallium;sulfuric acid Chemical compound [Ga].OS(O)(=O)=O SBDRYJMIQMDXRH-UHFFFAOYSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/7057—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/7084—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB53012/76A GB1561590A (en) | 1976-12-20 | 1976-12-20 | Zeolites containing gallium |
Publications (1)
Publication Number | Publication Date |
---|---|
DE2759973C2 true DE2759973C2 (de) | 1987-01-02 |
Family
ID=10466275
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE2755901A Expired DE2755901C2 (de) | 1976-12-20 | 1977-12-15 | Verfahren zur Herstellung von aromatischen Kohlenwasserstoffen |
DE2759973A Expired DE2759973C2 (de) | 1976-12-20 | 1977-12-15 | Imprägnierte und/oder kationengetauschte Aluminosilicat-Zeolithe |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE2755901A Expired DE2755901C2 (de) | 1976-12-20 | 1977-12-15 | Verfahren zur Herstellung von aromatischen Kohlenwasserstoffen |
Country Status (12)
Families Citing this family (63)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IN154515B (US06650917-20031118-M00005.png) * | 1979-08-07 | 1984-11-03 | British Petroleum Co | |
CA1128914A (en) * | 1979-09-04 | 1982-08-03 | Clive D. Telford | Method of preparing improved catalysts and use thereof in hydrocarbon conversion reactions |
AU7243681A (en) * | 1980-07-04 | 1982-01-07 | British Petroleum Company Plc, The | Activation of gallium exchanged zeolite catalyst |
NZ198555A (en) * | 1980-10-11 | 1983-11-30 | British Petroleum Co | Catalytic production of aromatic hydrocarbons |
ZA817004B (en) * | 1980-10-17 | 1983-05-25 | British Petroleum Co | Upgrading gasoline derived from synthesis gas |
JPS57108023A (en) * | 1980-12-26 | 1982-07-05 | Toa Nenryo Kogyo Kk | Oligomerization catalyst for isobutene |
US4377504A (en) * | 1981-05-01 | 1983-03-22 | Phillips Petroleum Company | Cracking catalyst improvement with gallium compounds |
US4415440A (en) * | 1981-05-01 | 1983-11-15 | Phillips Petroleum Company | Cracking catalyst improvement with gallium compounds |
GB2117367A (en) * | 1982-03-20 | 1983-10-12 | British Petroleum Co Plc | Activation of zeolites |
GB2126246B (en) * | 1982-09-02 | 1986-12-10 | British Petroleum Co Plc | Preparation of motor spirit |
ZA837470B (en) * | 1982-10-28 | 1984-06-27 | Shell Res Ltd | Process for the preparation of an aromatic hydrocarbon mixture |
DE3381352D1 (de) * | 1982-10-28 | 1990-04-26 | Shell Int Research | Verfahren zur herstellung eines aromatischen kohlenwasserstoffgemisches. |
ZA837468B (en) * | 1982-10-28 | 1984-06-27 | Shell Res Ltd | Process for the preparation of an aromatic hydrocarbon mixture |
DE3381199D1 (de) * | 1982-10-28 | 1990-03-15 | Shell Int Research | Verfahren zur herstellung eines aromatischen kohlenwasserstoffgemisches. |
ZA837469B (en) * | 1982-10-28 | 1984-06-27 | Shell Res Ltd | Process for the preparation of an aromatic hydrocarbon mixture |
EP0107875B1 (en) * | 1982-10-28 | 1990-04-04 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of an aromatic hydrocarbon mixture |
US4524140A (en) * | 1983-02-14 | 1985-06-18 | Mobil Oil Corporation | Hydrothermal zeolite activation |
GB8306532D0 (en) * | 1983-03-09 | 1983-04-13 | British Petroleum Co Plc | Catalytic activity of aluminosilicate zeolites |
GB8306531D0 (en) * | 1983-03-09 | 1983-04-13 | British Petroleum Co Plc | Catalytic activity of aluminosilicate zeolites |
GB8308684D0 (en) * | 1983-03-29 | 1983-05-05 | British Petroleum Co Plc | Production of gallium loaded hydrocarbon conversion catalyst |
NL8301747A (nl) * | 1983-05-17 | 1984-12-17 | Shell Int Research | Werkwijze voor de bereiding van middeldestillaten. |
CA1243977A (en) * | 1983-08-08 | 1988-11-01 | Eduard P. Kieffer | Process for the preparation of an aromatic hydrocarbon mixture |
CA1231104A (en) * | 1983-08-08 | 1988-01-05 | Eduard P. Kieffer | Process for the preparation of an aromatic hydrocarbon mixture |
GB8334486D0 (en) * | 1983-12-24 | 1984-02-01 | British Petroleum Co Plc | Aromatic hydrocarbons |
CA1256122A (en) * | 1984-05-02 | 1989-06-20 | Eduard P. Kieffer | Process for the preparation of an aromatic hydrocarbon mixture |
NZ212649A (en) * | 1984-07-16 | 1988-06-30 | Mobil Oil Corp | Method for increasing zeolite catalytic activity |
JP2617291B2 (ja) * | 1984-08-15 | 1997-06-04 | 智行 乾 | 低級パラフイン系炭化水素の芳香族炭化水素への変換方法 |
CA1251436A (en) * | 1985-01-02 | 1989-03-21 | Clarence D. Chang | Preparation of gallosilicate zeolites |
US4590322A (en) * | 1985-06-12 | 1986-05-20 | Mobil Oil Corporation | Use of hydrogen sulfide to improve benzene production over zeolites |
US4590323A (en) * | 1985-06-12 | 1986-05-20 | Mobil Oil Corporation | Conversion of paraffins to aromatics over zeolites modified with oxides of group IIIA, IVA and VA elements |
US4590321A (en) * | 1985-06-12 | 1986-05-20 | Mobil Oil Corporation | Aromatization reactions with zeolites containing phosphorus oxide |
US4665251A (en) * | 1985-06-12 | 1987-05-12 | Mobil Oil Corporation | Aromatization reactions with zeolites containing phosphorus oxide |
US4968650A (en) * | 1985-09-17 | 1990-11-06 | Mobil Oil Corporation | ZSM-5 catalysts having predominantly framework gallium, methods of their preparation, and use thereof |
NZ217284A (en) * | 1985-09-17 | 1988-10-28 | Mobil Oil Corp | Conversion of olefins to higher molecular weight hydrocarbons using silicate catalyst with framework gallium |
JPS62115088A (ja) * | 1985-11-13 | 1987-05-26 | Res Assoc Util Of Light Oil | 芳香族炭化水素の製造方法 |
EP0252705B1 (en) * | 1986-07-07 | 1991-10-23 | Mobil Oil Corporation | Aromatisation of aliphatics over gallium-containing zeolites |
US4985384A (en) * | 1986-08-25 | 1991-01-15 | W. R. Grace & Co-Conn. | Cracking catalysts having aromatic selectivity |
JPH0829255B2 (ja) * | 1986-10-04 | 1996-03-27 | 出光興産株式会社 | 芳香族炭化水素製造用触媒およびこれを用いた芳香族炭化水素の製造方法 |
GB8626532D0 (en) * | 1986-11-06 | 1986-12-10 | British Petroleum Co Plc | Chemical process |
GB8708961D0 (en) * | 1987-04-14 | 1987-05-20 | Shell Int Research | Preparation of modified zeolites |
GB8803112D0 (en) * | 1988-02-11 | 1988-03-09 | British Petroleum Co Plc | Zeolite catalysts suitable for hydrocarbon conversion |
US5055437A (en) * | 1988-12-30 | 1991-10-08 | Mobil Oil Corporation | Multi-component catalyst mixture and process for catalytic cracking of heavy hydrocarbon feed to lighter products |
FR2646167B1 (fr) * | 1989-04-24 | 1991-07-12 | Inst Francais Du Petrole | Procede d'hydroreformage ou de production d'hydrocarbures aromatiques |
FR2655350A1 (fr) * | 1989-12-01 | 1991-06-07 | Inst Francais Du Petrole | Procede de production d'hydrocarbures aromatiques a partir d'une charge d'hydrocarbures aliphatiques dans un reacteur chauffe par un lit fluidise de particules. |
FR2655351B1 (fr) * | 1989-12-01 | 1994-04-29 | Inst Francais Du Petrole | Dispositif de conversion d'hydrocarbures dans un reacteur chauffe par un lit fluidise de particules et son utilisation. |
EP0430804B1 (fr) * | 1989-12-01 | 1995-02-15 | Institut Français du Pétrole | Procédé et dispositif de production d'hydrocarbures à partir d'une charge d'hydrocarbures aliphatiques dans un réacteur chauffé par un lit fluidisé de particules |
US5149679A (en) * | 1990-05-01 | 1992-09-22 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Gallium-containing zeolite catalysts |
GB9011106D0 (en) * | 1990-05-17 | 1990-07-04 | British Petroleum Co Plc | Catalyst |
US5238890A (en) * | 1990-10-31 | 1993-08-24 | Idemitsu Kosan Company Limited | Exhaust gas purifying catalyst and an exhaust gas purifying method using the catalyst |
US5292697A (en) * | 1992-11-23 | 1994-03-08 | Amoco Corporation | Nondestructive trivalent cation exchange of molecular sieves |
US5476823A (en) * | 1993-05-28 | 1995-12-19 | Mobil Oil Corp. | Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and method to increase the activity thereof |
US5430211A (en) * | 1993-10-29 | 1995-07-04 | The Dow Chemical Company | Process of preparing ethylbenzene or substituted derivatives thereof |
US6593503B1 (en) * | 1996-08-12 | 2003-07-15 | Phillips Petroleum Company | Process for making aromatic hydrocarbons using an acid treated zeolite |
US6245219B1 (en) | 1997-04-18 | 2001-06-12 | Exxonmobil Chemical Patents Inc. | Naphtha aromatization process |
US6123834A (en) * | 1997-04-18 | 2000-09-26 | Exxon Chemical Patents Inc. | Catalytic upgrade of naphtha |
EP1063013B1 (en) * | 1999-06-24 | 2005-10-12 | ENI S.p.A. | Catalytic composition for the aromatization of hydrocarbons |
CN1257769C (zh) * | 2003-10-31 | 2006-05-31 | 中国石油化工股份有限公司 | 一种含磷和金属组分的mfi结构分子筛及其应用 |
EP2050731B1 (en) * | 2006-08-07 | 2017-07-05 | Nippon Oil Corporation | Process for production of aromatic hydrocarbons |
US8137535B2 (en) * | 2008-01-29 | 2012-03-20 | Kellogg Brown & Root Llc | Method for adjusting catalyst activity |
CN106140267B (zh) * | 2015-03-27 | 2019-02-01 | 中国石油化工股份有限公司 | 轻烃芳构化催化剂及其制备方法与应用 |
JP6953711B2 (ja) * | 2016-12-26 | 2021-10-27 | 東ソー株式会社 | 金属含有mfi型ゼオライト及びそれよりなる芳香族化合物製造用触媒 |
CN111151292B (zh) | 2020-01-13 | 2021-03-05 | 中国科学院山西煤炭化学研究所 | 一种芳构化催化剂及其制备方法与应用 |
CN111229299A (zh) * | 2020-03-10 | 2020-06-05 | 广西华睿能源科技有限公司 | 一种直链烷烃高效异构化和芳构化催化剂及其制备方法 |
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DE1567706A1 (de) * | 1965-05-28 | 1970-09-17 | Mobil Oil Corp | Verfahren zur Herstellung von kristallinen Aluminosilicaten |
DE1767235A1 (de) * | 1967-04-14 | 1971-09-09 | Mobil Oil Corp | Festes kristallines Aluminosilicat und Verfahren zu seiner Herstellung |
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DE1767235U (de) | 1956-03-10 | 1958-05-22 | Anton Langer | Geraet zur umwandlung der internationalen farbbezeichnungen von widerstaenden und kondensatoren in zahlenwerte. |
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US3431219A (en) * | 1967-03-08 | 1969-03-04 | Mobil Oil Corp | Crystalline galliosilicates |
US3702886A (en) * | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
US3709979A (en) * | 1970-04-23 | 1973-01-09 | Mobil Oil Corp | Crystalline zeolite zsm-11 |
US3832449A (en) * | 1971-03-18 | 1974-08-27 | Mobil Oil Corp | Crystalline zeolite zsm{14 12 |
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US4056575A (en) * | 1975-06-05 | 1977-11-01 | The British Petroleum Company Limited | Chemical process making aromatic hydrocarbons over gallium catalyst |
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JPS6261569A (ja) * | 1985-09-12 | 1987-03-18 | Morinaga & Co Ltd | 無色又は淡い色をした飲料の製造法 |
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1976
- 1976-12-20 GB GB53012/76A patent/GB1561590A/en not_active Expired
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1977
- 1977-11-28 CA CA291,867A patent/CA1086292A/en not_active Expired
- 1977-11-30 NZ NZ185817A patent/NZ185817A/xx unknown
- 1977-12-02 ZA ZA00777175A patent/ZA777175B/xx unknown
- 1977-12-02 US US05/856,668 patent/US4175057A/en not_active Expired - Lifetime
- 1977-12-08 NL NLAANVRAGE7713589,A patent/NL187625C/xx not_active IP Right Cessation
- 1977-12-14 FR FR7737702A patent/FR2374283A1/fr active Granted
- 1977-12-14 AU AU31564/77A patent/AU509285B2/en not_active Expired
- 1977-12-15 DE DE2755901A patent/DE2755901C2/de not_active Expired
- 1977-12-15 DE DE2759973A patent/DE2759973C2/de not_active Expired
- 1977-12-16 IT IT30869/77A patent/IT1143787B/it active
- 1977-12-19 JP JP15283277A patent/JPS5392717A/ja active Granted
- 1977-12-20 BE BE183616A patent/BE862051A/xx not_active IP Right Cessation
-
1987
- 1987-06-23 JP JP62156379A patent/JPS632807A/ja active Pending
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DE1567706A1 (de) * | 1965-05-28 | 1970-09-17 | Mobil Oil Corp | Verfahren zur Herstellung von kristallinen Aluminosilicaten |
DE1767235A1 (de) * | 1967-04-14 | 1971-09-09 | Mobil Oil Corp | Festes kristallines Aluminosilicat und Verfahren zu seiner Herstellung |
Also Published As
Publication number | Publication date |
---|---|
FR2374283B1 (US06650917-20031118-M00005.png) | 1984-01-27 |
NL7713589A (nl) | 1978-06-22 |
JPS6261569B2 (US06650917-20031118-M00005.png) | 1987-12-22 |
DE2755901C2 (de) | 1986-12-11 |
CA1086292A (en) | 1980-09-23 |
ZA777175B (en) | 1979-07-25 |
NL187625B (nl) | 1991-07-01 |
DE2755901A1 (de) | 1978-07-06 |
BE862051A (fr) | 1978-06-20 |
US4175057A (en) | 1979-11-20 |
FR2374283A1 (fr) | 1978-07-13 |
JPS632807A (ja) | 1988-01-07 |
IT1143787B (it) | 1986-10-22 |
GB1561590A (en) | 1980-02-27 |
JPS5392717A (en) | 1978-08-15 |
NZ185817A (en) | 1979-12-11 |
AU3156477A (en) | 1979-06-21 |
NL187625C (nl) | 1991-12-02 |
AU509285B2 (en) | 1980-05-01 |
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