FR2374283A1 - Composition de zeolite modifiee et son application a la production d'hydrocarbures aromatiques a partir d'hydrocarbures aliphatiques - Google Patents

Composition de zeolite modifiee et son application a la production d'hydrocarbures aromatiques a partir d'hydrocarbures aliphatiques

Info

Publication number
FR2374283A1
FR2374283A1 FR7737702A FR7737702A FR2374283A1 FR 2374283 A1 FR2374283 A1 FR 2374283A1 FR 7737702 A FR7737702 A FR 7737702A FR 7737702 A FR7737702 A FR 7737702A FR 2374283 A1 FR2374283 A1 FR 2374283A1
Authority
FR
France
Prior art keywords
hydrocarbons
composition
production
application
modified zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7737702A
Other languages
English (en)
Other versions
FR2374283B1 (fr
Inventor
Evan Ellis Davies
Alexander John Kolombos
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP PLC filed Critical BP PLC
Publication of FR2374283A1 publication Critical patent/FR2374283A1/fr
Application granted granted Critical
Publication of FR2374283B1 publication Critical patent/FR2374283B1/fr
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7057Zeolite Beta
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7084MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00Reforming naphtha
    • C10G35/04Catalytic reforming
    • C10G35/06Catalytic reforming characterised by the catalyst used
    • C10G35/095Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

Abstract

L'invention décrit une composition de zéolite et son utilisation comme catalyseur de transformation d'hydrocarbures. La composition de zéolite comprend un aluminosilicate présentant entre la silice et l'alumine un rapport molaire compris entre 20 : 1 et 70 : 1 et dont les cations ont été remplacés par échange avec des ions gallium. On peut mettre à une température élevée des hydrocarbures en C3 -C12 au contact de la composition du catalyseur pour transformer une partie des hydrocarbures en aromatiques, notamment pour traiter des essences de craquage.
FR7737702A 1976-12-20 1977-12-14 Composition de zeolite modifiee et son application a la production d'hydrocarbures aromatiques a partir d'hydrocarbures aliphatiques Granted FR2374283A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB53012/76A GB1561590A (en) 1976-12-20 1976-12-20 Zeolites containing gallium

Publications (2)

Publication Number Publication Date
FR2374283A1 true FR2374283A1 (fr) 1978-07-13
FR2374283B1 FR2374283B1 (fr) 1984-01-27

Family

ID=10466275

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7737702A Granted FR2374283A1 (fr) 1976-12-20 1977-12-14 Composition de zeolite modifiee et son application a la production d'hydrocarbures aromatiques a partir d'hydrocarbures aliphatiques

Country Status (12)

Country Link
US (1) US4175057A (fr)
JP (2) JPS5392717A (fr)
AU (1) AU509285B2 (fr)
BE (1) BE862051A (fr)
CA (1) CA1086292A (fr)
DE (2) DE2759973C2 (fr)
FR (1) FR2374283A1 (fr)
GB (1) GB1561590A (fr)
IT (1) IT1143787B (fr)
NL (1) NL187625C (fr)
NZ (1) NZ185817A (fr)
ZA (1) ZA777175B (fr)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0024930A1 (fr) * 1979-09-04 1981-03-11 The British Petroleum Company p.l.c. Procédé de préparation de catalyseurs zéolitiques activés par échange d'ions
EP0050499A2 (fr) * 1980-10-17 1982-04-28 The British Petroleum Company p.l.c. Amélioration d'essence obtenue à partir du gaz de synthèse
EP0107875A2 (fr) * 1982-10-28 1984-05-09 Shell Internationale Researchmaatschappij B.V. Procédé de préparation d'un mélange d'hydrocarbures aromatiques
EP0107877A2 (fr) * 1982-10-28 1984-05-09 Shell Internationale Researchmaatschappij B.V. Procédé de préparation d'un mélange d'hydrocarbures aromatiques
EP0107876A2 (fr) * 1982-10-28 1984-05-09 Shell Internationale Researchmaatschappij B.V. Procédé de préparation d'un mélange d'hydrocarbures aromatiques
EP0119027A2 (fr) * 1983-03-09 1984-09-19 The British Petroleum Company p.l.c. Activité catalytique d'une aluminosilicate zéolithique
WO1984003879A1 (fr) * 1983-03-29 1984-10-11 British Petroleum Co Plc Galloaluminosilicates cristallins et leur utilisation en catalyse
EP0147111A2 (fr) * 1983-12-24 1985-07-03 The British Petroleum Company p.l.c. Production d'hydrocarbures aromatiques
EP0160335A2 (fr) * 1984-05-02 1985-11-06 Shell Internationale Researchmaatschappij B.V. Procédé de préparation d'un mélange d'hydrocarbures aromatiques
EP0169026A2 (fr) * 1984-07-16 1986-01-22 Mobil Oil Corporation Activation de zéolites
EP0223345A1 (fr) * 1985-09-17 1987-05-27 Mobil Oil Corporation Procédé pour la conversion d'oléfines légères en hydrocarbures plus lourds
EP0430804A1 (fr) * 1989-12-01 1991-06-05 Institut Français du Pétrole Procédé et dispositif de production d'hydrocarbures à partir d'une charge d'hydrocarbures aliphatiques dans un réacteur chauffé par un lit fluidisé de particules
FR2655350A1 (fr) * 1989-12-01 1991-06-07 Inst Francais Du Petrole Procede de production d'hydrocarbures aromatiques a partir d'une charge d'hydrocarbures aliphatiques dans un reacteur chauffe par un lit fluidise de particules.
FR2655351A1 (fr) * 1989-12-01 1991-06-07 Inst Francais Du Petrole Dispositif de conversion d'hydrocarbures dans un reacteur chauffe par un lit fluidise de particules et son utilisation.

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IN154515B (fr) * 1979-08-07 1984-11-03 British Petroleum Co
AU7243681A (en) * 1980-07-04 1982-01-07 British Petroleum Company Plc, The Activation of gallium exchanged zeolite catalyst
NZ198555A (en) * 1980-10-11 1983-11-30 British Petroleum Co Catalytic production of aromatic hydrocarbons
JPS57108023A (en) * 1980-12-26 1982-07-05 Toa Nenryo Kogyo Kk Oligomerization catalyst for isobutene
US4415440A (en) * 1981-05-01 1983-11-15 Phillips Petroleum Company Cracking catalyst improvement with gallium compounds
US4377504A (en) * 1981-05-01 1983-03-22 Phillips Petroleum Company Cracking catalyst improvement with gallium compounds
GB2117367A (en) * 1982-03-20 1983-10-12 British Petroleum Co Plc Activation of zeolites
GB2126246B (en) * 1982-09-02 1986-12-10 British Petroleum Co Plc Preparation of motor spirit
ZA837468B (en) * 1982-10-28 1984-06-27 Shell Res Ltd Process for the preparation of an aromatic hydrocarbon mixture
ZA837469B (en) * 1982-10-28 1984-06-27 Shell Res Ltd Process for the preparation of an aromatic hydrocarbon mixture
ZA837470B (en) * 1982-10-28 1984-06-27 Shell Res Ltd Process for the preparation of an aromatic hydrocarbon mixture
US4524140A (en) * 1983-02-14 1985-06-18 Mobil Oil Corporation Hydrothermal zeolite activation
GB8306532D0 (en) * 1983-03-09 1983-04-13 British Petroleum Co Plc Catalytic activity of aluminosilicate zeolites
NL8301747A (nl) * 1983-05-17 1984-12-17 Shell Int Research Werkwijze voor de bereiding van middeldestillaten.
CA1231104A (fr) * 1983-08-08 1988-01-05 Eduard P. Kieffer Preparation d'un melange aromatique d'hydrocarbures
CA1243977A (fr) * 1983-08-08 1988-11-01 Eduard P. Kieffer Preparation d'un melange d'hydrocabure aromatique
JP2617291B2 (ja) * 1984-08-15 1997-06-04 智行 乾 低級パラフイン系炭化水素の芳香族炭化水素への変換方法
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US4590323A (en) * 1985-06-12 1986-05-20 Mobil Oil Corporation Conversion of paraffins to aromatics over zeolites modified with oxides of group IIIA, IVA and VA elements
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JPS62115088A (ja) * 1985-11-13 1987-05-26 Res Assoc Util Of Light Oil 芳香族炭化水素の製造方法
DE3774011D1 (de) * 1986-07-07 1991-11-28 Mobil Oil Corp Aromatisierung von aliphatischen verbindungen ueber galliumenthaltende zeolite.
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US5430211A (en) * 1993-10-29 1995-07-04 The Dow Chemical Company Process of preparing ethylbenzene or substituted derivatives thereof
US6593503B1 (en) * 1996-08-12 2003-07-15 Phillips Petroleum Company Process for making aromatic hydrocarbons using an acid treated zeolite
US6245219B1 (en) 1997-04-18 2001-06-12 Exxonmobil Chemical Patents Inc. Naphtha aromatization process
US6123834A (en) * 1997-04-18 2000-09-26 Exxon Chemical Patents Inc. Catalytic upgrade of naphtha
DE60028461T2 (de) * 1999-06-24 2006-09-28 Polimeri Europa S.P.A. Katalysatorzusammenzetsung zur Aromatisierung von Kohlenwasserstoffen
CN1257769C (zh) * 2003-10-31 2006-05-31 中国石油化工股份有限公司 一种含磷和金属组分的mfi结构分子筛及其应用
US8049051B2 (en) * 2006-08-07 2011-11-01 Nippon Oil Corporation Process for production of aromatic hydrocarbons
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CN106140267B (zh) * 2015-03-27 2019-02-01 中国石油化工股份有限公司 轻烃芳构化催化剂及其制备方法与应用
JP6953711B2 (ja) * 2016-12-26 2021-10-27 東ソー株式会社 金属含有mfi型ゼオライト及びそれよりなる芳香族化合物製造用触媒
CN111151292B (zh) 2020-01-13 2021-03-05 中国科学院山西煤炭化学研究所 一种芳构化催化剂及其制备方法与应用
CN111229299A (zh) * 2020-03-10 2020-06-05 广西华睿能源科技有限公司 一种直链烷烃高效异构化和芳构化催化剂及其制备方法

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Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0024930A1 (fr) * 1979-09-04 1981-03-11 The British Petroleum Company p.l.c. Procédé de préparation de catalyseurs zéolitiques activés par échange d'ions
EP0050499A2 (fr) * 1980-10-17 1982-04-28 The British Petroleum Company p.l.c. Amélioration d'essence obtenue à partir du gaz de synthèse
EP0050499A3 (en) * 1980-10-17 1982-08-04 The British Petroleum Company P.L.C. Upgrading gasoline derived from synthesis gas
EP0107875A3 (en) * 1982-10-28 1986-05-07 Shell Internationale Research Maatschappij B.V. Process for the preparation of an aromatic hydrocarbon mixture
EP0107875A2 (fr) * 1982-10-28 1984-05-09 Shell Internationale Researchmaatschappij B.V. Procédé de préparation d'un mélange d'hydrocarbures aromatiques
EP0107876A2 (fr) * 1982-10-28 1984-05-09 Shell Internationale Researchmaatschappij B.V. Procédé de préparation d'un mélange d'hydrocarbures aromatiques
EP0107877A2 (fr) * 1982-10-28 1984-05-09 Shell Internationale Researchmaatschappij B.V. Procédé de préparation d'un mélange d'hydrocarbures aromatiques
EP0107877A3 (en) * 1982-10-28 1986-05-07 Shell Internationale Research Maatschappij B.V. Process for the preparation of an aromatic hydrocarbon mixture
EP0107876A3 (en) * 1982-10-28 1986-05-07 Shell Internationale Research Maatschappij B.V. Process for the preparation of an aromatic hydrocarbon mixture
EP0119027A2 (fr) * 1983-03-09 1984-09-19 The British Petroleum Company p.l.c. Activité catalytique d'une aluminosilicate zéolithique
EP0119027A3 (en) * 1983-03-09 1985-09-18 The British Petroleum Company P.L.C. Improving catalytic activity of aluminosilicate zeolites
WO1984003879A1 (fr) * 1983-03-29 1984-10-11 British Petroleum Co Plc Galloaluminosilicates cristallins et leur utilisation en catalyse
EP0124271A1 (fr) * 1983-03-29 1984-11-07 The British Petroleum Company p.l.c. Galloaluminosilicates cristallins, galloaluminosilicates cristallins modifiés à la vapeur, leur préparation et leur utilisation comme catalyseurs et supports de catalyseurs
EP0147111A2 (fr) * 1983-12-24 1985-07-03 The British Petroleum Company p.l.c. Production d'hydrocarbures aromatiques
EP0147111A3 (en) * 1983-12-24 1986-06-04 The British Petroleum Company P.L.C. Production of aromatic hydrocarbons
EP0160335A3 (en) * 1984-05-02 1986-05-14 Internationale Research Maatschappij B.V. Shell Process for the preparation of an aromatic hydrocarbon mixture
EP0160335A2 (fr) * 1984-05-02 1985-11-06 Shell Internationale Researchmaatschappij B.V. Procédé de préparation d'un mélange d'hydrocarbures aromatiques
EP0169026A2 (fr) * 1984-07-16 1986-01-22 Mobil Oil Corporation Activation de zéolites
EP0169026A3 (en) * 1984-07-16 1986-06-04 Mobil Oil Corporation Activation of zeolites
EP0223345A1 (fr) * 1985-09-17 1987-05-27 Mobil Oil Corporation Procédé pour la conversion d'oléfines légères en hydrocarbures plus lourds
EP0430804A1 (fr) * 1989-12-01 1991-06-05 Institut Français du Pétrole Procédé et dispositif de production d'hydrocarbures à partir d'une charge d'hydrocarbures aliphatiques dans un réacteur chauffé par un lit fluidisé de particules
FR2655350A1 (fr) * 1989-12-01 1991-06-07 Inst Francais Du Petrole Procede de production d'hydrocarbures aromatiques a partir d'une charge d'hydrocarbures aliphatiques dans un reacteur chauffe par un lit fluidise de particules.
FR2655351A1 (fr) * 1989-12-01 1991-06-07 Inst Francais Du Petrole Dispositif de conversion d'hydrocarbures dans un reacteur chauffe par un lit fluidise de particules et son utilisation.

Also Published As

Publication number Publication date
AU509285B2 (en) 1980-05-01
BE862051A (fr) 1978-06-20
NZ185817A (en) 1979-12-11
NL7713589A (nl) 1978-06-22
JPS5392717A (en) 1978-08-15
AU3156477A (en) 1979-06-21
JPS632807A (ja) 1988-01-07
NL187625C (nl) 1991-12-02
IT1143787B (it) 1986-10-22
ZA777175B (en) 1979-07-25
DE2759973C2 (fr) 1987-01-02
DE2755901A1 (de) 1978-07-06
US4175057A (en) 1979-11-20
DE2755901C2 (de) 1986-12-11
JPS6261569B2 (fr) 1987-12-22
NL187625B (nl) 1991-07-01
FR2374283B1 (fr) 1984-01-27
CA1086292A (fr) 1980-09-23
GB1561590A (en) 1980-02-27

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