FR2374283A1 - Composition de zeolite modifiee et son application a la production d'hydrocarbures aromatiques a partir d'hydrocarbures aliphatiques - Google Patents
Composition de zeolite modifiee et son application a la production d'hydrocarbures aromatiques a partir d'hydrocarbures aliphatiquesInfo
- Publication number
- FR2374283A1 FR2374283A1 FR7737702A FR7737702A FR2374283A1 FR 2374283 A1 FR2374283 A1 FR 2374283A1 FR 7737702 A FR7737702 A FR 7737702A FR 7737702 A FR7737702 A FR 7737702A FR 2374283 A1 FR2374283 A1 FR 2374283A1
- Authority
- FR
- France
- Prior art keywords
- hydrocarbons
- composition
- production
- application
- modified zeolite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title abstract 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 title 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 title 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- -1 gallium ions Chemical class 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/7057—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/7084—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
Abstract
L'invention décrit une composition de zéolite et son utilisation comme catalyseur de transformation d'hydrocarbures. La composition de zéolite comprend un aluminosilicate présentant entre la silice et l'alumine un rapport molaire compris entre 20 : 1 et 70 : 1 et dont les cations ont été remplacés par échange avec des ions gallium. On peut mettre à une température élevée des hydrocarbures en C3 -C12 au contact de la composition du catalyseur pour transformer une partie des hydrocarbures en aromatiques, notamment pour traiter des essences de craquage.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB53012/76A GB1561590A (en) | 1976-12-20 | 1976-12-20 | Zeolites containing gallium |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2374283A1 true FR2374283A1 (fr) | 1978-07-13 |
FR2374283B1 FR2374283B1 (fr) | 1984-01-27 |
Family
ID=10466275
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7737702A Granted FR2374283A1 (fr) | 1976-12-20 | 1977-12-14 | Composition de zeolite modifiee et son application a la production d'hydrocarbures aromatiques a partir d'hydrocarbures aliphatiques |
Country Status (12)
Country | Link |
---|---|
US (1) | US4175057A (fr) |
JP (2) | JPS5392717A (fr) |
AU (1) | AU509285B2 (fr) |
BE (1) | BE862051A (fr) |
CA (1) | CA1086292A (fr) |
DE (2) | DE2759973C2 (fr) |
FR (1) | FR2374283A1 (fr) |
GB (1) | GB1561590A (fr) |
IT (1) | IT1143787B (fr) |
NL (1) | NL187625C (fr) |
NZ (1) | NZ185817A (fr) |
ZA (1) | ZA777175B (fr) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0024930A1 (fr) * | 1979-09-04 | 1981-03-11 | The British Petroleum Company p.l.c. | Procédé de préparation de catalyseurs zéolitiques activés par échange d'ions |
EP0050499A2 (fr) * | 1980-10-17 | 1982-04-28 | The British Petroleum Company p.l.c. | Amélioration d'essence obtenue à partir du gaz de synthèse |
EP0107875A2 (fr) * | 1982-10-28 | 1984-05-09 | Shell Internationale Researchmaatschappij B.V. | Procédé de préparation d'un mélange d'hydrocarbures aromatiques |
EP0107877A2 (fr) * | 1982-10-28 | 1984-05-09 | Shell Internationale Researchmaatschappij B.V. | Procédé de préparation d'un mélange d'hydrocarbures aromatiques |
EP0107876A2 (fr) * | 1982-10-28 | 1984-05-09 | Shell Internationale Researchmaatschappij B.V. | Procédé de préparation d'un mélange d'hydrocarbures aromatiques |
EP0119027A2 (fr) * | 1983-03-09 | 1984-09-19 | The British Petroleum Company p.l.c. | Activité catalytique d'une aluminosilicate zéolithique |
WO1984003879A1 (fr) * | 1983-03-29 | 1984-10-11 | British Petroleum Co Plc | Galloaluminosilicates cristallins et leur utilisation en catalyse |
EP0147111A2 (fr) * | 1983-12-24 | 1985-07-03 | The British Petroleum Company p.l.c. | Production d'hydrocarbures aromatiques |
EP0160335A2 (fr) * | 1984-05-02 | 1985-11-06 | Shell Internationale Researchmaatschappij B.V. | Procédé de préparation d'un mélange d'hydrocarbures aromatiques |
EP0169026A2 (fr) * | 1984-07-16 | 1986-01-22 | Mobil Oil Corporation | Activation de zéolites |
EP0223345A1 (fr) * | 1985-09-17 | 1987-05-27 | Mobil Oil Corporation | Procédé pour la conversion d'oléfines légères en hydrocarbures plus lourds |
EP0430804A1 (fr) * | 1989-12-01 | 1991-06-05 | Institut Français du Pétrole | Procédé et dispositif de production d'hydrocarbures à partir d'une charge d'hydrocarbures aliphatiques dans un réacteur chauffé par un lit fluidisé de particules |
FR2655350A1 (fr) * | 1989-12-01 | 1991-06-07 | Inst Francais Du Petrole | Procede de production d'hydrocarbures aromatiques a partir d'une charge d'hydrocarbures aliphatiques dans un reacteur chauffe par un lit fluidise de particules. |
FR2655351A1 (fr) * | 1989-12-01 | 1991-06-07 | Inst Francais Du Petrole | Dispositif de conversion d'hydrocarbures dans un reacteur chauffe par un lit fluidise de particules et son utilisation. |
Families Citing this family (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IN154515B (fr) * | 1979-08-07 | 1984-11-03 | British Petroleum Co | |
AU7243681A (en) * | 1980-07-04 | 1982-01-07 | British Petroleum Company Plc, The | Activation of gallium exchanged zeolite catalyst |
NZ198555A (en) * | 1980-10-11 | 1983-11-30 | British Petroleum Co | Catalytic production of aromatic hydrocarbons |
JPS57108023A (en) * | 1980-12-26 | 1982-07-05 | Toa Nenryo Kogyo Kk | Oligomerization catalyst for isobutene |
US4415440A (en) * | 1981-05-01 | 1983-11-15 | Phillips Petroleum Company | Cracking catalyst improvement with gallium compounds |
US4377504A (en) * | 1981-05-01 | 1983-03-22 | Phillips Petroleum Company | Cracking catalyst improvement with gallium compounds |
GB2117367A (en) * | 1982-03-20 | 1983-10-12 | British Petroleum Co Plc | Activation of zeolites |
GB2126246B (en) * | 1982-09-02 | 1986-12-10 | British Petroleum Co Plc | Preparation of motor spirit |
ZA837468B (en) * | 1982-10-28 | 1984-06-27 | Shell Res Ltd | Process for the preparation of an aromatic hydrocarbon mixture |
ZA837469B (en) * | 1982-10-28 | 1984-06-27 | Shell Res Ltd | Process for the preparation of an aromatic hydrocarbon mixture |
ZA837470B (en) * | 1982-10-28 | 1984-06-27 | Shell Res Ltd | Process for the preparation of an aromatic hydrocarbon mixture |
US4524140A (en) * | 1983-02-14 | 1985-06-18 | Mobil Oil Corporation | Hydrothermal zeolite activation |
GB8306532D0 (en) * | 1983-03-09 | 1983-04-13 | British Petroleum Co Plc | Catalytic activity of aluminosilicate zeolites |
NL8301747A (nl) * | 1983-05-17 | 1984-12-17 | Shell Int Research | Werkwijze voor de bereiding van middeldestillaten. |
CA1231104A (fr) * | 1983-08-08 | 1988-01-05 | Eduard P. Kieffer | Preparation d'un melange aromatique d'hydrocarbures |
CA1243977A (fr) * | 1983-08-08 | 1988-11-01 | Eduard P. Kieffer | Preparation d'un melange d'hydrocabure aromatique |
JP2617291B2 (ja) * | 1984-08-15 | 1997-06-04 | 智行 乾 | 低級パラフイン系炭化水素の芳香族炭化水素への変換方法 |
CA1251436A (fr) * | 1985-01-02 | 1989-03-21 | Clarence D. Chang | Preparation des zeolites de gallosilicate |
US4590323A (en) * | 1985-06-12 | 1986-05-20 | Mobil Oil Corporation | Conversion of paraffins to aromatics over zeolites modified with oxides of group IIIA, IVA and VA elements |
US4590322A (en) * | 1985-06-12 | 1986-05-20 | Mobil Oil Corporation | Use of hydrogen sulfide to improve benzene production over zeolites |
US4665251A (en) * | 1985-06-12 | 1987-05-12 | Mobil Oil Corporation | Aromatization reactions with zeolites containing phosphorus oxide |
US4590321A (en) * | 1985-06-12 | 1986-05-20 | Mobil Oil Corporation | Aromatization reactions with zeolites containing phosphorus oxide |
US4968650A (en) * | 1985-09-17 | 1990-11-06 | Mobil Oil Corporation | ZSM-5 catalysts having predominantly framework gallium, methods of their preparation, and use thereof |
JPS62115088A (ja) * | 1985-11-13 | 1987-05-26 | Res Assoc Util Of Light Oil | 芳香族炭化水素の製造方法 |
DE3774011D1 (de) * | 1986-07-07 | 1991-11-28 | Mobil Oil Corp | Aromatisierung von aliphatischen verbindungen ueber galliumenthaltende zeolite. |
US4985384A (en) * | 1986-08-25 | 1991-01-15 | W. R. Grace & Co-Conn. | Cracking catalysts having aromatic selectivity |
JPH0829255B2 (ja) * | 1986-10-04 | 1996-03-27 | 出光興産株式会社 | 芳香族炭化水素製造用触媒およびこれを用いた芳香族炭化水素の製造方法 |
GB8626532D0 (en) * | 1986-11-06 | 1986-12-10 | British Petroleum Co Plc | Chemical process |
GB8708961D0 (en) * | 1987-04-14 | 1987-05-20 | Shell Int Research | Preparation of modified zeolites |
GB8803112D0 (en) * | 1988-02-11 | 1988-03-09 | British Petroleum Co Plc | Zeolite catalysts suitable for hydrocarbon conversion |
US5055437A (en) * | 1988-12-30 | 1991-10-08 | Mobil Oil Corporation | Multi-component catalyst mixture and process for catalytic cracking of heavy hydrocarbon feed to lighter products |
FR2646167B1 (fr) * | 1989-04-24 | 1991-07-12 | Inst Francais Du Petrole | Procede d'hydroreformage ou de production d'hydrocarbures aromatiques |
US5149679A (en) * | 1990-05-01 | 1992-09-22 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Gallium-containing zeolite catalysts |
GB9011106D0 (en) * | 1990-05-17 | 1990-07-04 | British Petroleum Co Plc | Catalyst |
US5238890A (en) * | 1990-10-31 | 1993-08-24 | Idemitsu Kosan Company Limited | Exhaust gas purifying catalyst and an exhaust gas purifying method using the catalyst |
US5292697A (en) * | 1992-11-23 | 1994-03-08 | Amoco Corporation | Nondestructive trivalent cation exchange of molecular sieves |
US5476823A (en) * | 1993-05-28 | 1995-12-19 | Mobil Oil Corp. | Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and method to increase the activity thereof |
US5430211A (en) * | 1993-10-29 | 1995-07-04 | The Dow Chemical Company | Process of preparing ethylbenzene or substituted derivatives thereof |
US6593503B1 (en) * | 1996-08-12 | 2003-07-15 | Phillips Petroleum Company | Process for making aromatic hydrocarbons using an acid treated zeolite |
US6245219B1 (en) | 1997-04-18 | 2001-06-12 | Exxonmobil Chemical Patents Inc. | Naphtha aromatization process |
US6123834A (en) * | 1997-04-18 | 2000-09-26 | Exxon Chemical Patents Inc. | Catalytic upgrade of naphtha |
DE60028461T2 (de) * | 1999-06-24 | 2006-09-28 | Polimeri Europa S.P.A. | Katalysatorzusammenzetsung zur Aromatisierung von Kohlenwasserstoffen |
CN1257769C (zh) * | 2003-10-31 | 2006-05-31 | 中国石油化工股份有限公司 | 一种含磷和金属组分的mfi结构分子筛及其应用 |
US8049051B2 (en) * | 2006-08-07 | 2011-11-01 | Nippon Oil Corporation | Process for production of aromatic hydrocarbons |
US8137535B2 (en) * | 2008-01-29 | 2012-03-20 | Kellogg Brown & Root Llc | Method for adjusting catalyst activity |
CN106140267B (zh) * | 2015-03-27 | 2019-02-01 | 中国石油化工股份有限公司 | 轻烃芳构化催化剂及其制备方法与应用 |
JP6953711B2 (ja) * | 2016-12-26 | 2021-10-27 | 東ソー株式会社 | 金属含有mfi型ゼオライト及びそれよりなる芳香族化合物製造用触媒 |
CN111151292B (zh) | 2020-01-13 | 2021-03-05 | 中国科学院山西煤炭化学研究所 | 一种芳构化催化剂及其制备方法与应用 |
CN111229299A (zh) * | 2020-03-10 | 2020-06-05 | 广西华睿能源科技有限公司 | 一种直链烷烃高效异构化和芳构化催化剂及其制备方法 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
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DE1767235U (de) | 1956-03-10 | 1958-05-22 | Anton Langer | Geraet zur umwandlung der internationalen farbbezeichnungen von widerstaenden und kondensatoren in zahlenwerte. |
US3010789A (en) * | 1957-12-05 | 1961-11-28 | Union Carbide Corp | Crystalline zeolite h |
GB1129042A (en) * | 1965-05-28 | 1968-10-02 | Mobil Oil Corp | Improved crystalline zeolites and method of preparing same |
US3431219A (en) * | 1967-03-08 | 1969-03-04 | Mobil Oil Corp | Crystalline galliosilicates |
GB1161974A (en) * | 1967-04-14 | 1969-08-20 | Mobil Oil Corp | Synthetic Crystalline Aluminosilicate and method of preparing the same |
US3702886A (en) * | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
US3709979A (en) * | 1970-04-23 | 1973-01-09 | Mobil Oil Corp | Crystalline zeolite zsm-11 |
US3832449A (en) * | 1971-03-18 | 1974-08-27 | Mobil Oil Corp | Crystalline zeolite zsm{14 12 |
JPS5034309A (fr) * | 1973-07-11 | 1975-04-02 | ||
US3970544A (en) * | 1974-05-06 | 1976-07-20 | Mobil Oil Corporation | Hydrocarbon conversion with ZSM-12 |
US4056575A (en) * | 1975-06-05 | 1977-11-01 | The British Petroleum Company Limited | Chemical process making aromatic hydrocarbons over gallium catalyst |
US4025571A (en) * | 1976-05-12 | 1977-05-24 | Mobil Oil Corporation | Manufacture of hydrocarbons |
JPS6261569A (ja) * | 1985-09-12 | 1987-03-18 | Morinaga & Co Ltd | 無色又は淡い色をした飲料の製造法 |
-
1976
- 1976-12-20 GB GB53012/76A patent/GB1561590A/en not_active Expired
-
1977
- 1977-11-28 CA CA291,867A patent/CA1086292A/fr not_active Expired
- 1977-11-30 NZ NZ185817A patent/NZ185817A/xx unknown
- 1977-12-02 ZA ZA00777175A patent/ZA777175B/xx unknown
- 1977-12-02 US US05/856,668 patent/US4175057A/en not_active Expired - Lifetime
- 1977-12-08 NL NLAANVRAGE7713589,A patent/NL187625C/xx not_active IP Right Cessation
- 1977-12-14 AU AU31564/77A patent/AU509285B2/en not_active Expired
- 1977-12-14 FR FR7737702A patent/FR2374283A1/fr active Granted
- 1977-12-15 DE DE2759973A patent/DE2759973C2/de not_active Expired
- 1977-12-15 DE DE2755901A patent/DE2755901C2/de not_active Expired
- 1977-12-16 IT IT30869/77A patent/IT1143787B/it active
- 1977-12-19 JP JP15283277A patent/JPS5392717A/ja active Granted
- 1977-12-20 BE BE183616A patent/BE862051A/fr not_active IP Right Cessation
-
1987
- 1987-06-23 JP JP62156379A patent/JPS632807A/ja active Pending
Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0024930A1 (fr) * | 1979-09-04 | 1981-03-11 | The British Petroleum Company p.l.c. | Procédé de préparation de catalyseurs zéolitiques activés par échange d'ions |
EP0050499A2 (fr) * | 1980-10-17 | 1982-04-28 | The British Petroleum Company p.l.c. | Amélioration d'essence obtenue à partir du gaz de synthèse |
EP0050499A3 (en) * | 1980-10-17 | 1982-08-04 | The British Petroleum Company P.L.C. | Upgrading gasoline derived from synthesis gas |
EP0107875A3 (en) * | 1982-10-28 | 1986-05-07 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of an aromatic hydrocarbon mixture |
EP0107875A2 (fr) * | 1982-10-28 | 1984-05-09 | Shell Internationale Researchmaatschappij B.V. | Procédé de préparation d'un mélange d'hydrocarbures aromatiques |
EP0107876A2 (fr) * | 1982-10-28 | 1984-05-09 | Shell Internationale Researchmaatschappij B.V. | Procédé de préparation d'un mélange d'hydrocarbures aromatiques |
EP0107877A2 (fr) * | 1982-10-28 | 1984-05-09 | Shell Internationale Researchmaatschappij B.V. | Procédé de préparation d'un mélange d'hydrocarbures aromatiques |
EP0107877A3 (en) * | 1982-10-28 | 1986-05-07 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of an aromatic hydrocarbon mixture |
EP0107876A3 (en) * | 1982-10-28 | 1986-05-07 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of an aromatic hydrocarbon mixture |
EP0119027A2 (fr) * | 1983-03-09 | 1984-09-19 | The British Petroleum Company p.l.c. | Activité catalytique d'une aluminosilicate zéolithique |
EP0119027A3 (en) * | 1983-03-09 | 1985-09-18 | The British Petroleum Company P.L.C. | Improving catalytic activity of aluminosilicate zeolites |
WO1984003879A1 (fr) * | 1983-03-29 | 1984-10-11 | British Petroleum Co Plc | Galloaluminosilicates cristallins et leur utilisation en catalyse |
EP0124271A1 (fr) * | 1983-03-29 | 1984-11-07 | The British Petroleum Company p.l.c. | Galloaluminosilicates cristallins, galloaluminosilicates cristallins modifiés à la vapeur, leur préparation et leur utilisation comme catalyseurs et supports de catalyseurs |
EP0147111A2 (fr) * | 1983-12-24 | 1985-07-03 | The British Petroleum Company p.l.c. | Production d'hydrocarbures aromatiques |
EP0147111A3 (en) * | 1983-12-24 | 1986-06-04 | The British Petroleum Company P.L.C. | Production of aromatic hydrocarbons |
EP0160335A3 (en) * | 1984-05-02 | 1986-05-14 | Internationale Research Maatschappij B.V. Shell | Process for the preparation of an aromatic hydrocarbon mixture |
EP0160335A2 (fr) * | 1984-05-02 | 1985-11-06 | Shell Internationale Researchmaatschappij B.V. | Procédé de préparation d'un mélange d'hydrocarbures aromatiques |
EP0169026A2 (fr) * | 1984-07-16 | 1986-01-22 | Mobil Oil Corporation | Activation de zéolites |
EP0169026A3 (en) * | 1984-07-16 | 1986-06-04 | Mobil Oil Corporation | Activation of zeolites |
EP0223345A1 (fr) * | 1985-09-17 | 1987-05-27 | Mobil Oil Corporation | Procédé pour la conversion d'oléfines légères en hydrocarbures plus lourds |
EP0430804A1 (fr) * | 1989-12-01 | 1991-06-05 | Institut Français du Pétrole | Procédé et dispositif de production d'hydrocarbures à partir d'une charge d'hydrocarbures aliphatiques dans un réacteur chauffé par un lit fluidisé de particules |
FR2655350A1 (fr) * | 1989-12-01 | 1991-06-07 | Inst Francais Du Petrole | Procede de production d'hydrocarbures aromatiques a partir d'une charge d'hydrocarbures aliphatiques dans un reacteur chauffe par un lit fluidise de particules. |
FR2655351A1 (fr) * | 1989-12-01 | 1991-06-07 | Inst Francais Du Petrole | Dispositif de conversion d'hydrocarbures dans un reacteur chauffe par un lit fluidise de particules et son utilisation. |
Also Published As
Publication number | Publication date |
---|---|
AU509285B2 (en) | 1980-05-01 |
BE862051A (fr) | 1978-06-20 |
NZ185817A (en) | 1979-12-11 |
NL7713589A (nl) | 1978-06-22 |
JPS5392717A (en) | 1978-08-15 |
AU3156477A (en) | 1979-06-21 |
JPS632807A (ja) | 1988-01-07 |
NL187625C (nl) | 1991-12-02 |
IT1143787B (it) | 1986-10-22 |
ZA777175B (en) | 1979-07-25 |
DE2759973C2 (fr) | 1987-01-02 |
DE2755901A1 (de) | 1978-07-06 |
US4175057A (en) | 1979-11-20 |
DE2755901C2 (de) | 1986-12-11 |
JPS6261569B2 (fr) | 1987-12-22 |
NL187625B (nl) | 1991-07-01 |
FR2374283B1 (fr) | 1984-01-27 |
CA1086292A (fr) | 1980-09-23 |
GB1561590A (en) | 1980-02-27 |
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