DE2729552A1 - Verfahren zum hydrierenden umwandeln von schweren kohlenwasserstoffen sowie hierfuer geeigneter katalysator - Google Patents
Verfahren zum hydrierenden umwandeln von schweren kohlenwasserstoffen sowie hierfuer geeigneter katalysatorInfo
- Publication number
- DE2729552A1 DE2729552A1 DE19772729552 DE2729552A DE2729552A1 DE 2729552 A1 DE2729552 A1 DE 2729552A1 DE 19772729552 DE19772729552 DE 19772729552 DE 2729552 A DE2729552 A DE 2729552A DE 2729552 A1 DE2729552 A1 DE 2729552A1
- Authority
- DE
- Germany
- Prior art keywords
- oil
- catalyst
- hydrogen
- conversion
- feedstock
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims description 124
- 238000006243 chemical reaction Methods 0.000 title claims description 112
- 238000000034 method Methods 0.000 title claims description 59
- 229930195733 hydrocarbon Natural products 0.000 title claims description 23
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 23
- 230000008569 process Effects 0.000 title claims description 20
- 230000000887 hydrating effect Effects 0.000 title description 2
- 229910052751 metal Inorganic materials 0.000 claims description 79
- 239000002184 metal Substances 0.000 claims description 79
- 229910052750 molybdenum Inorganic materials 0.000 claims description 75
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 74
- 239000011733 molybdenum Substances 0.000 claims description 73
- 229910052739 hydrogen Inorganic materials 0.000 claims description 69
- 239000007787 solid Substances 0.000 claims description 68
- 239000003921 oil Substances 0.000 claims description 67
- 239000000047 product Substances 0.000 claims description 65
- 239000001257 hydrogen Substances 0.000 claims description 62
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 57
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 57
- 239000007789 gas Substances 0.000 claims description 45
- 229910052742 iron Inorganic materials 0.000 claims description 37
- 150000002736 metal compounds Chemical class 0.000 claims description 34
- 229910052799 carbon Inorganic materials 0.000 claims description 29
- 150000002739 metals Chemical class 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 18
- 239000004215 Carbon black (E152) Substances 0.000 claims description 17
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 15
- 239000010426 asphalt Substances 0.000 claims description 14
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 229910052720 vanadium Inorganic materials 0.000 claims description 13
- -1 alicyclic aliphatic carboxylic acids Chemical class 0.000 claims description 12
- 238000005984 hydrogenation reaction Methods 0.000 claims description 12
- 238000011065 in-situ storage Methods 0.000 claims description 12
- 229910052804 chromium Inorganic materials 0.000 claims description 10
- 239000011651 chromium Substances 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 9
- 230000000737 periodic effect Effects 0.000 claims description 8
- 239000003245 coal Substances 0.000 claims description 4
- 150000002902 organometallic compounds Chemical class 0.000 claims description 4
- 125000002015 acyclic group Chemical class 0.000 claims description 3
- 239000002956 ash Substances 0.000 claims description 3
- 239000000295 fuel oil Substances 0.000 claims description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 2
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical class [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 239000006227 byproduct Substances 0.000 claims description 2
- 239000010881 fly ash Substances 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 2
- 235000013980 iron oxide Nutrition 0.000 claims description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 235000005985 organic acids Nutrition 0.000 claims description 2
- 238000011160 research Methods 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 239000010763 heavy fuel oil Substances 0.000 claims 2
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 claims 1
- 238000005555 metalworking Methods 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- 150000003682 vanadium compounds Chemical class 0.000 claims 1
- 238000002474 experimental method Methods 0.000 description 43
- 239000000571 coke Substances 0.000 description 36
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 27
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- 238000012360 testing method Methods 0.000 description 19
- 239000007788 liquid Substances 0.000 description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 15
- 230000000694 effects Effects 0.000 description 15
- 239000010779 crude oil Substances 0.000 description 12
- 229910052717 sulfur Inorganic materials 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 10
- 239000012263 liquid product Substances 0.000 description 10
- 239000011593 sulfur Substances 0.000 description 10
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 238000009835 boiling Methods 0.000 description 8
- 238000001914 filtration Methods 0.000 description 8
- 239000002253 acid Substances 0.000 description 6
- 239000008186 active pharmaceutical agent Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000002203 pretreatment Methods 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 238000004939 coking Methods 0.000 description 5
- 238000011010 flushing procedure Methods 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000007858 starting material Substances 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 4
- 239000010883 coal ash Substances 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000005078 molybdenum compound Substances 0.000 description 4
- 150000002752 molybdenum compounds Chemical class 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 244000127759 Spondias lutea Species 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 238000006477 desulfuration reaction Methods 0.000 description 3
- 230000023556 desulfurization Effects 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 125000005609 naphthenate group Chemical group 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- UVPKUTPZWFHAHY-UHFFFAOYSA-L 2-ethylhexanoate;nickel(2+) Chemical compound [Ni+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O UVPKUTPZWFHAHY-UHFFFAOYSA-L 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- GICWIDZXWJGTCI-UHFFFAOYSA-I molybdenum pentachloride Chemical compound Cl[Mo](Cl)(Cl)(Cl)Cl GICWIDZXWJGTCI-UHFFFAOYSA-I 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- 125000005608 naphthenic acid group Chemical group 0.000 description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 description 2
- 150000002830 nitrogen compounds Chemical class 0.000 description 2
- 238000004525 petroleum distillation Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000011949 solid catalyst Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PCTMTFRHKVHKIS-BMFZQQSSSA-N (1s,3r,4e,6e,8e,10e,12e,14e,16e,18s,19r,20r,21s,25r,27r,30r,31r,33s,35r,37s,38r)-3-[(2r,3s,4s,5s,6r)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-19,25,27,30,31,33,35,37-octahydroxy-18,20,21-trimethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10 Chemical compound C1C=C2C[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2.O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C=C/C=C/C=C/[C@H](C)[C@@H](O)[C@@H](C)[C@H](C)OC(=O)C[C@H](O)C[C@H](O)CC[C@@H](O)[C@H](O)C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 PCTMTFRHKVHKIS-BMFZQQSSSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- PWKSKIMOESPYIA-BYPYZUCNSA-N L-N-acetyl-Cysteine Chemical compound CC(=O)N[C@@H](CS)C(O)=O PWKSKIMOESPYIA-BYPYZUCNSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- WAIPAZQMEIHHTJ-UHFFFAOYSA-N [Cr].[Co] Chemical compound [Cr].[Co] WAIPAZQMEIHHTJ-UHFFFAOYSA-N 0.000 description 1
- KSECJOPEZIAKMU-UHFFFAOYSA-N [S--].[S--].[S--].[S--].[S--].[V+5].[V+5] Chemical compound [S--].[S--].[S--].[S--].[S--].[V+5].[V+5] KSECJOPEZIAKMU-UHFFFAOYSA-N 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001845 chromium compounds Chemical class 0.000 description 1
- 239000002864 coal component Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000012084 conversion product Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000004868 gas analysis Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- INHWXZFVSTUXPN-UHFFFAOYSA-J molybdenum(4+) disulfite Chemical compound [Mo+4].[O-]S([O-])=O.[O-]S([O-])=O INHWXZFVSTUXPN-UHFFFAOYSA-J 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 150000003455 sulfinic acids Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 239000011275 tar sand Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 229910021654 trace metal Inorganic materials 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/14—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles
- C10G45/16—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles suspended in the oil, e.g. slurries
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US70222776A | 1976-07-02 | 1976-07-02 | |
| US05/745,394 US4066530A (en) | 1976-07-02 | 1976-11-26 | Hydroconversion of heavy hydrocarbons |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2729552A1 true DE2729552A1 (de) | 1978-01-12 |
| DE2729552C2 DE2729552C2 (enrdf_load_stackoverflow) | 1989-08-03 |
Family
ID=27106934
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19772729552 Granted DE2729552A1 (de) | 1976-07-02 | 1977-06-30 | Verfahren zum hydrierenden umwandeln von schweren kohlenwasserstoffen sowie hierfuer geeigneter katalysator |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS535212A (enrdf_load_stackoverflow) |
| AU (1) | AU506641B2 (enrdf_load_stackoverflow) |
| BR (1) | BR7704090A (enrdf_load_stackoverflow) |
| CA (1) | CA1077917A (enrdf_load_stackoverflow) |
| DE (1) | DE2729552A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2356715A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1584785A (enrdf_load_stackoverflow) |
| IT (1) | IT1085831B (enrdf_load_stackoverflow) |
| NL (1) | NL189413C (enrdf_load_stackoverflow) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55106939A (en) * | 1979-02-05 | 1980-08-16 | Gadelius Kk | Powder transmitting device |
| DE2967599D1 (en) * | 1979-11-13 | 1986-07-03 | Exxon Research Engineering Co | High surface area catalysts, their preparation, and hydrocarbon processes using them |
| JPS5676247A (en) * | 1979-11-26 | 1981-06-23 | Exxon Research Engineering Co | High surface area catalyst |
| DE3071596D1 (en) * | 1980-12-30 | 1986-06-12 | Exxon Research Engineering Co | Catalysts and hydrocarbon treating processes utilizing the same |
| NL8203780A (nl) * | 1981-10-16 | 1983-05-16 | Chevron Res | Werkwijze voor de hydroverwerking van zware koolwaterstofhoudende olien. |
| JPS60123591A (ja) * | 1983-12-07 | 1985-07-02 | Asahi Chem Ind Co Ltd | ガス状オレフイン及び単環芳香族炭化水素の製造方法 |
| JPS60120791A (ja) * | 1983-12-02 | 1985-06-28 | Asahi Chem Ind Co Ltd | 重質炭化水素の軽質化方法 |
| FR2555192B1 (fr) * | 1983-11-21 | 1987-06-12 | Elf France | Procede de traitement thermique de charges hydrocarbonees en presence d'additifs qui diminuent la formation de coke |
| CA1244369A (en) * | 1983-12-02 | 1988-11-08 | Nobumitsu Ohtake | Process for converting heavy hydrocarbon into more valuable product |
| US4728417A (en) * | 1986-07-21 | 1988-03-01 | Phillips Petroleum Company | Hydrofining process for hydrocarbon containing feed streams |
| FR2616795B1 (fr) * | 1987-06-19 | 1989-10-27 | Inst Francais Du Petrole | Procede ameliore de production de chaleur par combustion d'un fuel lourd |
| US7670984B2 (en) * | 2006-01-06 | 2010-03-02 | Headwaters Technology Innovation, Llc | Hydrocarbon-soluble molybdenum catalyst precursors and methods for making same |
| CN109181730B (zh) * | 2018-09-30 | 2021-05-04 | 中国科学院山西煤炭化学研究所 | 一种煤油共炼残渣制备针状焦的方法 |
| WO2021001474A1 (en) | 2019-07-04 | 2021-01-07 | Haldor Topsøe A/S | Gas phase sulfidation of hydrotreating and hydrocracking catalysts |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3165463A (en) * | 1962-07-02 | 1965-01-12 | Universal Oil Prod Co | Hydrorefining of crude oil and catalyst therefor |
| US3196104A (en) * | 1962-07-02 | 1965-07-20 | Universal Oil Prod Co | Hydrorefining of crude oils |
| US3825488A (en) * | 1973-05-07 | 1974-07-23 | Universal Oil Prod Co | Process for hydrorefining a hydrocarbon charge stock |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR826454A (fr) * | 1936-09-19 | 1938-03-31 | Int Hydrogenation Patents Co | Procédé de fabrication de produits hydrocarburés de valeur par le traitement catalytique de produits d'extraction de matières carbonées solides par des gaz hydrogénants |
| DE1288718B (de) * | 1964-02-01 | 1969-02-06 | Universal Oil Prod Co | Verfahren zur Hydrofinierung von Roherdoel oder einer aus Erdoel gewonnenen hochsiedenden Kohlenwasserstofffraktion |
| US3657111A (en) * | 1970-02-24 | 1972-04-18 | Universal Oil Prod Co | Slurry process for hydrocarbonaceous black oil conversion |
| US3694352A (en) * | 1970-02-24 | 1972-09-26 | Universal Oil Prod Co | Slurry hydrorefining of black oils with mixed vanadium and manganese sulfides |
-
1977
- 1977-06-06 CA CA279,963A patent/CA1077917A/en not_active Expired
- 1977-06-08 AU AU25958/77A patent/AU506641B2/en not_active Expired
- 1977-06-15 GB GB2502177A patent/GB1584785A/en not_active Expired
- 1977-06-23 BR BR7704090A patent/BR7704090A/pt unknown
- 1977-06-28 IT IT2514677A patent/IT1085831B/it active
- 1977-06-29 NL NL7707215A patent/NL189413C/xx not_active IP Right Cessation
- 1977-06-30 DE DE19772729552 patent/DE2729552A1/de active Granted
- 1977-07-01 JP JP7799877A patent/JPS535212A/ja active Granted
- 1977-07-01 FR FR7720359A patent/FR2356715A1/fr active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3165463A (en) * | 1962-07-02 | 1965-01-12 | Universal Oil Prod Co | Hydrorefining of crude oil and catalyst therefor |
| US3196104A (en) * | 1962-07-02 | 1965-07-20 | Universal Oil Prod Co | Hydrorefining of crude oils |
| US3825488A (en) * | 1973-05-07 | 1974-07-23 | Universal Oil Prod Co | Process for hydrorefining a hydrocarbon charge stock |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6112960B2 (enrdf_load_stackoverflow) | 1986-04-10 |
| FR2356715B1 (enrdf_load_stackoverflow) | 1981-04-10 |
| NL189413B (nl) | 1992-11-02 |
| GB1584785A (en) | 1981-02-18 |
| NL189413C (nl) | 1993-04-01 |
| IT1085831B (it) | 1985-05-28 |
| JPS535212A (en) | 1978-01-18 |
| BR7704090A (pt) | 1978-02-21 |
| AU506641B2 (en) | 1980-01-17 |
| DE2729552C2 (enrdf_load_stackoverflow) | 1989-08-03 |
| CA1077917A (en) | 1980-05-20 |
| FR2356715A1 (fr) | 1978-01-27 |
| NL7707215A (nl) | 1978-01-04 |
| AU2595877A (en) | 1978-12-14 |
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| 8110 | Request for examination paragraph 44 | ||
| 8125 | Change of the main classification |
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Free format text: STOLBERG-WERNIGERODE, GRAF ZU, U., DIPL.-CHEM. DR.RER.NAT. SUCHANTKE, J., DIPL.-ING., PAT.-ANWAELTE, 2000 HAMBURG |