CA1077917A - Hydroconversion of heavy hydrocarbons - Google Patents
Hydroconversion of heavy hydrocarbonsInfo
- Publication number
- CA1077917A CA1077917A CA279,963A CA279963A CA1077917A CA 1077917 A CA1077917 A CA 1077917A CA 279963 A CA279963 A CA 279963A CA 1077917 A CA1077917 A CA 1077917A
- Authority
- CA
- Canada
- Prior art keywords
- oil
- catalyst
- chargestock
- hydrogen
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims description 16
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 16
- 239000003054 catalyst Substances 0.000 claims abstract description 85
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 77
- 239000007787 solid Substances 0.000 claims abstract description 59
- 239000001257 hydrogen Substances 0.000 claims abstract description 54
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 53
- 238000000034 method Methods 0.000 claims abstract description 53
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 47
- 229910052742 iron Inorganic materials 0.000 claims abstract description 38
- 150000002736 metal compounds Chemical class 0.000 claims abstract description 36
- 150000001875 compounds Chemical class 0.000 claims abstract description 18
- 239000005078 molybdenum compound Substances 0.000 claims abstract description 3
- 150000002752 molybdenum compounds Chemical class 0.000 claims abstract description 3
- 239000003921 oil Substances 0.000 claims description 102
- 229910052751 metal Inorganic materials 0.000 claims description 61
- 239000002184 metal Substances 0.000 claims description 61
- 229910052750 molybdenum Inorganic materials 0.000 claims description 46
- 239000011733 molybdenum Substances 0.000 claims description 45
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 36
- 239000007789 gas Substances 0.000 claims description 34
- 238000006243 chemical reaction Methods 0.000 claims description 30
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 21
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims description 14
- 150000002739 metals Chemical class 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 11
- 229910052720 vanadium Inorganic materials 0.000 claims description 11
- 239000010426 asphalt Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- -1 acyclic aliphatic carboxylic acids Chemical class 0.000 claims description 9
- 238000011065 in-situ storage Methods 0.000 claims description 9
- 230000000737 periodic effect Effects 0.000 claims description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 7
- 239000011651 chromium Substances 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 239000000470 constituent Substances 0.000 claims description 6
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical class [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims description 3
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 239000002956 ash Substances 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- 239000010881 fly ash Substances 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 235000005985 organic acids Nutrition 0.000 claims description 2
- 150000002902 organometallic compounds Chemical class 0.000 claims description 2
- 238000007670 refining Methods 0.000 claims description 2
- 239000000306 component Substances 0.000 claims 6
- 239000000295 fuel oil Substances 0.000 claims 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims 2
- 235000013980 iron oxide Nutrition 0.000 claims 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims 2
- 239000006227 byproduct Substances 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 150000001845 chromium compounds Chemical class 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- 150000003682 vanadium compounds Chemical class 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 abstract description 6
- 235000016768 molybdenum Nutrition 0.000 description 43
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 24
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- 229910052799 carbon Inorganic materials 0.000 description 21
- 239000000571 coke Substances 0.000 description 20
- 230000000694 effects Effects 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- 239000002253 acid Substances 0.000 description 10
- 239000012018 catalyst precursor Substances 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 8
- 229940045605 vanadium Drugs 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 238000005755 formation reaction Methods 0.000 description 7
- 150000002431 hydrogen Chemical class 0.000 description 7
- 239000012263 liquid product Substances 0.000 description 7
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 7
- 238000009835 boiling Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 235000012721 chromium Nutrition 0.000 description 5
- 229940107218 chromium Drugs 0.000 description 5
- 238000004939 coking Methods 0.000 description 5
- 239000003208 petroleum Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 4
- 239000000356 contaminant Substances 0.000 description 4
- 239000010779 crude oil Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- 239000008186 active pharmaceutical agent Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 238000006477 desulfuration reaction Methods 0.000 description 3
- 230000023556 desulfurization Effects 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 125000005609 naphthenate group Chemical group 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 239000011949 solid catalyst Substances 0.000 description 3
- 230000001629 suppression Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 125000002015 acyclic group Chemical group 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000010883 coal ash Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 2
- GICWIDZXWJGTCI-UHFFFAOYSA-I molybdenum pentachloride Chemical compound Cl[Mo](Cl)(Cl)(Cl)Cl GICWIDZXWJGTCI-UHFFFAOYSA-I 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- AOSZTAHDEDLTLQ-AZKQZHLXSA-N (1S,2S,4R,8S,9S,11S,12R,13S,19S)-6-[(3-chlorophenyl)methyl]-12,19-difluoro-11-hydroxy-8-(2-hydroxyacetyl)-9,13-dimethyl-6-azapentacyclo[10.8.0.02,9.04,8.013,18]icosa-14,17-dien-16-one Chemical compound C([C@@H]1C[C@H]2[C@H]3[C@]([C@]4(C=CC(=O)C=C4[C@@H](F)C3)C)(F)[C@@H](O)C[C@@]2([C@@]1(C1)C(=O)CO)C)N1CC1=CC=CC(Cl)=C1 AOSZTAHDEDLTLQ-AZKQZHLXSA-N 0.000 description 1
- QIJNJJZPYXGIQM-UHFFFAOYSA-N 1lambda4,2lambda4-dimolybdacyclopropa-1,2,3-triene Chemical compound [Mo]=C=[Mo] QIJNJJZPYXGIQM-UHFFFAOYSA-N 0.000 description 1
- UVPKUTPZWFHAHY-UHFFFAOYSA-L 2-ethylhexanoate;nickel(2+) Chemical compound [Ni+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O UVPKUTPZWFHAHY-UHFFFAOYSA-L 0.000 description 1
- 241001279686 Allium moly Species 0.000 description 1
- 229940126657 Compound 17 Drugs 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- PWKSKIMOESPYIA-BYPYZUCNSA-N L-N-acetyl-Cysteine Chemical compound CC(=O)N[C@@H](CS)C(O)=O PWKSKIMOESPYIA-BYPYZUCNSA-N 0.000 description 1
- 229910017333 Mo(CO)6 Inorganic materials 0.000 description 1
- 101100168115 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) con-6 gene Proteins 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 244000127759 Spondias lutea Species 0.000 description 1
- WAIPAZQMEIHHTJ-UHFFFAOYSA-N [Cr].[Co] Chemical compound [Cr].[Co] WAIPAZQMEIHHTJ-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000012084 conversion product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 238000004868 gas analysis Methods 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 230000007775 late Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 239000012685 metal catalyst precursor Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052961 molybdenite Inorganic materials 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- HBVFXTAPOLSOPB-UHFFFAOYSA-N nickel vanadium Chemical compound [V].[Ni] HBVFXTAPOLSOPB-UHFFFAOYSA-N 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000011027 product recovery Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 229910021654 trace metal Inorganic materials 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/14—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles
- C10G45/16—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles suspended in the oil, e.g. slurries
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US70222776A | 1976-07-02 | 1976-07-02 | |
| US05/745,394 US4066530A (en) | 1976-07-02 | 1976-11-26 | Hydroconversion of heavy hydrocarbons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1077917A true CA1077917A (en) | 1980-05-20 |
Family
ID=27106934
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA279,963A Expired CA1077917A (en) | 1976-07-02 | 1977-06-06 | Hydroconversion of heavy hydrocarbons |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS535212A (enrdf_load_stackoverflow) |
| AU (1) | AU506641B2 (enrdf_load_stackoverflow) |
| BR (1) | BR7704090A (enrdf_load_stackoverflow) |
| CA (1) | CA1077917A (enrdf_load_stackoverflow) |
| DE (1) | DE2729552A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2356715A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1584785A (enrdf_load_stackoverflow) |
| IT (1) | IT1085831B (enrdf_load_stackoverflow) |
| NL (1) | NL189413C (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109181730A (zh) * | 2018-09-30 | 2019-01-11 | 中国科学院山西煤炭化学研究所 | 一种煤油共炼残渣制备针状焦的方法 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55106939A (en) * | 1979-02-05 | 1980-08-16 | Gadelius Kk | Powder transmitting device |
| DE2967599D1 (en) * | 1979-11-13 | 1986-07-03 | Exxon Research Engineering Co | High surface area catalysts, their preparation, and hydrocarbon processes using them |
| JPS5676247A (en) * | 1979-11-26 | 1981-06-23 | Exxon Research Engineering Co | High surface area catalyst |
| DE3071596D1 (en) * | 1980-12-30 | 1986-06-12 | Exxon Research Engineering Co | Catalysts and hydrocarbon treating processes utilizing the same |
| NL8203780A (nl) * | 1981-10-16 | 1983-05-16 | Chevron Res | Werkwijze voor de hydroverwerking van zware koolwaterstofhoudende olien. |
| JPS60123591A (ja) * | 1983-12-07 | 1985-07-02 | Asahi Chem Ind Co Ltd | ガス状オレフイン及び単環芳香族炭化水素の製造方法 |
| JPS60120791A (ja) * | 1983-12-02 | 1985-06-28 | Asahi Chem Ind Co Ltd | 重質炭化水素の軽質化方法 |
| FR2555192B1 (fr) * | 1983-11-21 | 1987-06-12 | Elf France | Procede de traitement thermique de charges hydrocarbonees en presence d'additifs qui diminuent la formation de coke |
| CA1244369A (en) * | 1983-12-02 | 1988-11-08 | Nobumitsu Ohtake | Process for converting heavy hydrocarbon into more valuable product |
| US4728417A (en) * | 1986-07-21 | 1988-03-01 | Phillips Petroleum Company | Hydrofining process for hydrocarbon containing feed streams |
| FR2616795B1 (fr) * | 1987-06-19 | 1989-10-27 | Inst Francais Du Petrole | Procede ameliore de production de chaleur par combustion d'un fuel lourd |
| US7670984B2 (en) * | 2006-01-06 | 2010-03-02 | Headwaters Technology Innovation, Llc | Hydrocarbon-soluble molybdenum catalyst precursors and methods for making same |
| WO2021001474A1 (en) | 2019-07-04 | 2021-01-07 | Haldor Topsøe A/S | Gas phase sulfidation of hydrotreating and hydrocracking catalysts |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR826454A (fr) * | 1936-09-19 | 1938-03-31 | Int Hydrogenation Patents Co | Procédé de fabrication de produits hydrocarburés de valeur par le traitement catalytique de produits d'extraction de matières carbonées solides par des gaz hydrogénants |
| US3165463A (en) * | 1962-07-02 | 1965-01-12 | Universal Oil Prod Co | Hydrorefining of crude oil and catalyst therefor |
| US3196104A (en) * | 1962-07-02 | 1965-07-20 | Universal Oil Prod Co | Hydrorefining of crude oils |
| DE1288718B (de) * | 1964-02-01 | 1969-02-06 | Universal Oil Prod Co | Verfahren zur Hydrofinierung von Roherdoel oder einer aus Erdoel gewonnenen hochsiedenden Kohlenwasserstofffraktion |
| US3657111A (en) * | 1970-02-24 | 1972-04-18 | Universal Oil Prod Co | Slurry process for hydrocarbonaceous black oil conversion |
| US3694352A (en) * | 1970-02-24 | 1972-09-26 | Universal Oil Prod Co | Slurry hydrorefining of black oils with mixed vanadium and manganese sulfides |
| US3825488A (en) * | 1973-05-07 | 1974-07-23 | Universal Oil Prod Co | Process for hydrorefining a hydrocarbon charge stock |
-
1977
- 1977-06-06 CA CA279,963A patent/CA1077917A/en not_active Expired
- 1977-06-08 AU AU25958/77A patent/AU506641B2/en not_active Expired
- 1977-06-15 GB GB2502177A patent/GB1584785A/en not_active Expired
- 1977-06-23 BR BR7704090A patent/BR7704090A/pt unknown
- 1977-06-28 IT IT2514677A patent/IT1085831B/it active
- 1977-06-29 NL NL7707215A patent/NL189413C/xx not_active IP Right Cessation
- 1977-06-30 DE DE19772729552 patent/DE2729552A1/de active Granted
- 1977-07-01 JP JP7799877A patent/JPS535212A/ja active Granted
- 1977-07-01 FR FR7720359A patent/FR2356715A1/fr active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109181730A (zh) * | 2018-09-30 | 2019-01-11 | 中国科学院山西煤炭化学研究所 | 一种煤油共炼残渣制备针状焦的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6112960B2 (enrdf_load_stackoverflow) | 1986-04-10 |
| FR2356715B1 (enrdf_load_stackoverflow) | 1981-04-10 |
| NL189413B (nl) | 1992-11-02 |
| GB1584785A (en) | 1981-02-18 |
| NL189413C (nl) | 1993-04-01 |
| IT1085831B (it) | 1985-05-28 |
| JPS535212A (en) | 1978-01-18 |
| BR7704090A (pt) | 1978-02-21 |
| AU506641B2 (en) | 1980-01-17 |
| DE2729552A1 (de) | 1978-01-12 |
| DE2729552C2 (enrdf_load_stackoverflow) | 1989-08-03 |
| FR2356715A1 (fr) | 1978-01-27 |
| NL7707215A (nl) | 1978-01-04 |
| AU2595877A (en) | 1978-12-14 |
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