DE2642564C2 - - Google Patents
Info
- Publication number
- DE2642564C2 DE2642564C2 DE19762642564 DE2642564A DE2642564C2 DE 2642564 C2 DE2642564 C2 DE 2642564C2 DE 19762642564 DE19762642564 DE 19762642564 DE 2642564 A DE2642564 A DE 2642564A DE 2642564 C2 DE2642564 C2 DE 2642564C2
- Authority
- DE
- Germany
- Prior art keywords
- polyester
- weight
- polymethacrylsäuremethylester
- polyvinyl acetate
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000728 polyester Polymers 0.000 claims description 29
- 239000000463 material Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 16
- 239000003365 glass fiber Substances 0.000 claims description 15
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 14
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 12
- 239000011118 polyvinyl acetate Substances 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 11
- 229920006305 unsaturated polyester Polymers 0.000 claims description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- 229920001225 polyester resin Polymers 0.000 claims description 9
- 239000004645 polyester resin Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 description 11
- 238000006116 polymerization reaction Methods 0.000 description 10
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 8
- 238000005507 spraying Methods 0.000 description 8
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 150000004702 methyl esters Chemical class 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 239000012783 reinforcing fiber Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229920006337 unsaturated polyester resin Polymers 0.000 description 2
- 229920005440 Altuglas® Polymers 0.000 description 1
- 241001550224 Apha Species 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 230000004043 responsiveness Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/08—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
- B29C70/086—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers and with one or more layers of pure plastics material, e.g. foam layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
- B29C70/305—Spray-up of reinforcing fibres with or without matrix to form a non-coherent mat in or on a mould
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7529312A FR2325505A1 (fr) | 1975-09-24 | 1975-09-24 | Produit complexe stratifie de polyacrylate et polyester, son procede de fabrication et ses applications |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2642564A1 DE2642564A1 (de) | 1977-04-07 |
| DE2642564C2 true DE2642564C2 (enExample) | 1989-09-07 |
Family
ID=9160398
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19762642564 Granted DE2642564A1 (de) | 1975-09-24 | 1976-09-22 | Zusammengesetztes, geschichtetes produkt aus polyacrylat und polyester, dessen herstellung und anwendung |
Country Status (10)
| Country | Link |
|---|---|
| BE (1) | BE846114A (enExample) |
| CH (1) | CH617887A5 (enExample) |
| DE (1) | DE2642564A1 (enExample) |
| ES (1) | ES451792A1 (enExample) |
| FR (1) | FR2325505A1 (enExample) |
| GB (1) | GB1562432A (enExample) |
| IE (1) | IE44032B1 (enExample) |
| IT (1) | IT1066305B (enExample) |
| LU (1) | LU75843A1 (enExample) |
| NL (1) | NL169974C (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2589393B1 (fr) * | 1985-11-05 | 1988-03-18 | Charbonnages Ste Chimique | Materiau stratifie complexe et son procede de fabrication |
| EP2026955B1 (en) * | 2006-05-23 | 2018-02-07 | Nu Cleer Systems Limited | Laminate material |
| CN108189433B (zh) * | 2018-01-03 | 2019-12-17 | 锦西化工研究院有限公司 | 一种制备均匀分布的大厚度涤纶增强丙烯酸酯板材的方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1152576A (fr) * | 1956-01-10 | 1958-02-20 | Houilleres Bassin Du Nord | Procédé de fabrication de nouveaux matériaux stratifiés |
| US3454417A (en) * | 1965-12-29 | 1969-07-08 | Du Pont | Colored reinforced laminates |
| US3707434A (en) * | 1970-11-30 | 1972-12-26 | Federal Huber Co | Rigidified resinous laminate |
| US3832268A (en) * | 1972-01-17 | 1974-08-27 | Rohm & Haas | Reinforced plastic structures containing cured polyester resin |
-
1975
- 1975-09-24 FR FR7529312A patent/FR2325505A1/fr active Granted
-
1976
- 1976-09-10 BE BE170565A patent/BE846114A/xx not_active IP Right Cessation
- 1976-09-20 NL NL7610434A patent/NL169974C/xx not_active IP Right Cessation
- 1976-09-22 LU LU75843A patent/LU75843A1/xx unknown
- 1976-09-22 DE DE19762642564 patent/DE2642564A1/de active Granted
- 1976-09-23 CH CH1209476A patent/CH617887A5/fr not_active IP Right Cessation
- 1976-09-23 IT IT5141776A patent/IT1066305B/it active
- 1976-09-23 IE IE211576A patent/IE44032B1/en not_active IP Right Cessation
- 1976-09-23 ES ES451792A patent/ES451792A1/es not_active Expired
- 1976-09-23 GB GB3952176A patent/GB1562432A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2325505B1 (enExample) | 1979-06-15 |
| DE2642564A1 (de) | 1977-04-07 |
| GB1562432A (en) | 1980-03-12 |
| NL7610434A (nl) | 1977-03-28 |
| IE44032L (en) | 1977-03-24 |
| IE44032B1 (en) | 1981-07-29 |
| LU75843A1 (enExample) | 1978-05-12 |
| NL169974C (nl) | 1982-09-16 |
| IT1066305B (it) | 1985-03-04 |
| CH617887A5 (en) | 1980-06-30 |
| ES451792A1 (es) | 1977-11-01 |
| BE846114A (fr) | 1977-03-10 |
| FR2325505A1 (fr) | 1977-04-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8101 | Request for examination as to novelty | ||
| 8105 | Search report available | ||
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8328 | Change in the person/name/address of the agent |
Free format text: LOTTERHOS, H., DIPL.-ING. DR.-ING. BARTSCH, E., DIPL.-CHEM. DR.RER.NAT., PAT.-ANWAELTE, 6000 FRANKFURT |