DE2632209C2 - Verfahren zur kontinuierlichen Herstellung von duktiler Eisenfolie - Google Patents
Verfahren zur kontinuierlichen Herstellung von duktiler EisenfolieInfo
- Publication number
- DE2632209C2 DE2632209C2 DE2632209A DE2632209A DE2632209C2 DE 2632209 C2 DE2632209 C2 DE 2632209C2 DE 2632209 A DE2632209 A DE 2632209A DE 2632209 A DE2632209 A DE 2632209A DE 2632209 C2 DE2632209 C2 DE 2632209C2
- Authority
- DE
- Germany
- Prior art keywords
- electrolyte
- iron
- temperature
- storage tank
- heat exchanger
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 36
- 238000000034 method Methods 0.000 title claims description 15
- 229910001141 Ductile iron Inorganic materials 0.000 title claims description 5
- 238000010924 continuous production Methods 0.000 title claims description 3
- 239000003792 electrolyte Substances 0.000 claims description 70
- 238000003860 storage Methods 0.000 claims description 27
- 229910052742 iron Inorganic materials 0.000 claims description 14
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 7
- 230000008929 regeneration Effects 0.000 claims description 7
- 238000011069 regeneration method Methods 0.000 claims description 7
- 238000005868 electrolysis reaction Methods 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 2
- PMVSDNDAUGGCCE-TYYBGVCCSA-L Ferrous fumarate Chemical compound [Fe+2].[O-]C(=O)\C=C\C([O-])=O PMVSDNDAUGGCCE-TYYBGVCCSA-L 0.000 claims 1
- 239000010802 sludge Substances 0.000 description 9
- 238000000151 deposition Methods 0.000 description 8
- 230000008021 deposition Effects 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 6
- -1 iron (III) ions Chemical class 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000011888 foil Substances 0.000 description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N iron (II) ion Substances [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
- 239000002826 coolant Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004070 electrodeposition Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 2
- 230000006911 nucleation Effects 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910001447 ferric ion Inorganic materials 0.000 description 1
- 229960002089 ferrous chloride Drugs 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/06—Operating or servicing
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Treatment Of Sludge (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB30080/75A GB1497309A (en) | 1975-07-17 | 1975-07-17 | Continuous production of iron by electrolysis of a ferrous electrolyte |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2632209A1 DE2632209A1 (de) | 1977-02-10 |
| DE2632209C2 true DE2632209C2 (de) | 1985-01-31 |
Family
ID=10301947
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2632209A Expired DE2632209C2 (de) | 1975-07-17 | 1976-07-16 | Verfahren zur kontinuierlichen Herstellung von duktiler Eisenfolie |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4083759A (ref) |
| JP (1) | JPS5245519A (ref) |
| AU (1) | AU497450B2 (ref) |
| BE (1) | BE844247A (ref) |
| BR (1) | BR7604663A (ref) |
| CA (1) | CA1088023A (ref) |
| DE (1) | DE2632209C2 (ref) |
| FR (1) | FR2318243A1 (ref) |
| GB (1) | GB1497309A (ref) |
| IT (1) | IT1069519B (ref) |
| NL (1) | NL178800B (ref) |
| SE (1) | SE424341B (ref) |
| ZA (1) | ZA764174B (ref) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6251514A (ja) * | 1985-08-30 | 1987-03-06 | Ace Denken:Kk | 景品払出装置の景品補給装置 |
| JPH086192B2 (ja) * | 1986-01-08 | 1996-01-24 | 昭和電工株式会社 | 電解鉄粉の製造方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1023545A (en) * | 1911-06-12 | 1912-04-16 | Harry H Bates | Electrolytic process. |
| GB197066A (en) * | 1922-02-15 | 1923-05-10 | Thomas William Stainfr Hutchin | Improvements relating to the electro-deposition of metals |
| DE446720C (de) * | 1924-03-24 | 1927-07-08 | Le Fer Sa | Anlage und Vorrichtung zur elektrolytischen Gewinnung von Eisen mittels eines aus einer Eisensalzloesung bestehenden, im Kreislauf gefuehrten Elektrolyten |
| US2480156A (en) * | 1944-11-24 | 1949-08-30 | Buel Metals Company | Electrodeposition of iron |
| US2464889A (en) * | 1945-03-19 | 1949-03-22 | Tacoma Powdered Metals Company | Process for making electrolytic iron |
| DE878279C (de) * | 1951-04-28 | 1953-06-01 | Siemens Ag | Verfahren zur Herstellung von pulverfoermigem Eisen durch Elektrolyse einer eisensulfathaltigen Loesung |
| US3118826A (en) * | 1959-09-17 | 1964-01-21 | Frank E Smith | Process and apparatus for the electrolytic production of high-purity iron |
| FR2222452A2 (en) * | 1973-03-20 | 1974-10-18 | Electricity Council | Electrolytic deposition of thin sheet iron - produced as a continuous band by robust simplified appts. |
-
1975
- 1975-07-17 GB GB30080/75A patent/GB1497309A/en not_active Expired
-
1976
- 1976-07-14 ZA ZA00764174A patent/ZA764174B/xx unknown
- 1976-07-15 AU AU15939/76A patent/AU497450B2/en not_active Expired
- 1976-07-16 JP JP51084871A patent/JPS5245519A/ja active Granted
- 1976-07-16 US US05/705,980 patent/US4083759A/en not_active Expired - Lifetime
- 1976-07-16 FR FR7621741A patent/FR2318243A1/fr active Granted
- 1976-07-16 BR BR7604663A patent/BR7604663A/pt unknown
- 1976-07-16 SE SE7608145A patent/SE424341B/xx not_active IP Right Cessation
- 1976-07-16 DE DE2632209A patent/DE2632209C2/de not_active Expired
- 1976-07-16 BE BE169007A patent/BE844247A/xx not_active IP Right Cessation
- 1976-07-16 NL NLAANVRAGE7607913,A patent/NL178800B/xx not_active IP Right Cessation
- 1976-07-19 CA CA257,229A patent/CA1088023A/en not_active Expired
- 1976-07-19 IT IT68800/76A patent/IT1069519B/it active
Also Published As
| Publication number | Publication date |
|---|---|
| SE424341B (sv) | 1982-07-12 |
| FR2318243A1 (fr) | 1977-02-11 |
| NL178800B (nl) | 1985-12-16 |
| BE844247A (fr) | 1976-11-16 |
| BR7604663A (pt) | 1977-08-02 |
| FR2318243B1 (ref) | 1981-12-18 |
| US4083759A (en) | 1978-04-11 |
| ZA764174B (en) | 1978-02-22 |
| AU497450B2 (en) | 1978-12-14 |
| NL7607913A (nl) | 1977-01-19 |
| GB1497309A (en) | 1978-01-05 |
| JPS5245519A (en) | 1977-04-11 |
| AU1593976A (en) | 1978-01-19 |
| IT1069519B (it) | 1985-03-25 |
| SE7608145L (sv) | 1977-01-18 |
| DE2632209A1 (de) | 1977-02-10 |
| JPS579436B2 (ref) | 1982-02-22 |
| CA1088023A (en) | 1980-10-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |