DE2630398C3 - Kathode für die Elektrolyse in alkalischem Medium - Google Patents
Kathode für die Elektrolyse in alkalischem MediumInfo
- Publication number
- DE2630398C3 DE2630398C3 DE2630398A DE2630398A DE2630398C3 DE 2630398 C3 DE2630398 C3 DE 2630398C3 DE 2630398 A DE2630398 A DE 2630398A DE 2630398 A DE2630398 A DE 2630398A DE 2630398 C3 DE2630398 C3 DE 2630398C3
- Authority
- DE
- Germany
- Prior art keywords
- cathode
- metal
- nickel
- titanium
- electrolysis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005868 electrolysis reaction Methods 0.000 title claims description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 43
- 229910052751 metal Inorganic materials 0.000 claims description 34
- 239000002184 metal Substances 0.000 claims description 34
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 32
- 239000010936 titanium Substances 0.000 claims description 25
- 229910052759 nickel Inorganic materials 0.000 claims description 19
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 16
- 229910052742 iron Inorganic materials 0.000 claims description 16
- 229910052719 titanium Inorganic materials 0.000 claims description 13
- 239000011734 sodium Substances 0.000 claims description 12
- 229910045601 alloy Inorganic materials 0.000 claims description 11
- 239000000956 alloy Substances 0.000 claims description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 150000002602 lanthanoids Chemical class 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 229910002056 binary alloy Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- RHDUVDHGVHBHCL-UHFFFAOYSA-N niobium tantalum Chemical compound [Nb].[Ta] RHDUVDHGVHBHCL-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 17
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 16
- 239000003792 electrolyte Substances 0.000 description 15
- 238000000576 coating method Methods 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 12
- 239000002585 base Substances 0.000 description 11
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 10
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 239000003513 alkali Substances 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 125000004429 atom Chemical group 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000011775 sodium fluoride Substances 0.000 description 5
- 235000013024 sodium fluoride Nutrition 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 235000019270 ammonium chloride Nutrition 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 3
- 229910000990 Ni alloy Inorganic materials 0.000 description 3
- 229910001069 Ti alloy Inorganic materials 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- -1 lanthanides Chemical compound 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000001509 sodium citrate Substances 0.000 description 3
- GROMGGTZECPEKN-UHFFFAOYSA-N sodium metatitanate Chemical compound [Na+].[Na+].[O-][Ti](=O)O[Ti](=O)O[Ti]([O-])=O GROMGGTZECPEKN-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 239000010974 bronze Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- 229940038773 trisodium citrate Drugs 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910001868 water Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 241000080590 Niso Species 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- BYRRPYMBVHTVKO-UHFFFAOYSA-N [Na].[Ti] Chemical compound [Na].[Ti] BYRRPYMBVHTVKO-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- ATTFYOXEMHAYAX-UHFFFAOYSA-N magnesium nickel Chemical compound [Mg].[Ni] ATTFYOXEMHAYAX-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical class [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7521364A FR2317377A1 (fr) | 1975-07-08 | 1975-07-08 | Cathode pour cellule d'electrolyse |
| FR7613249A FR2350406A2 (fr) | 1976-05-04 | 1976-05-04 | Cathode pour cellule d'electrolyse |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2630398A1 DE2630398A1 (de) | 1977-05-26 |
| DE2630398B2 DE2630398B2 (de) | 1980-07-31 |
| DE2630398C3 true DE2630398C3 (de) | 1981-04-23 |
Family
ID=26218969
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2630398A Expired DE2630398C3 (de) | 1975-07-08 | 1976-07-06 | Kathode für die Elektrolyse in alkalischem Medium |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4080278A (enExample) |
| JP (1) | JPS5217374A (enExample) |
| BR (1) | BR7604417A (enExample) |
| CA (1) | CA1083082A (enExample) |
| CH (1) | CH614740A5 (enExample) |
| DE (1) | DE2630398C3 (enExample) |
| ES (1) | ES449701A1 (enExample) |
| GB (1) | GB1504110A (enExample) |
| IN (1) | IN145971B (enExample) |
| IT (1) | IT1065620B (enExample) |
| NL (1) | NL7607442A (enExample) |
| NO (1) | NO148648C (enExample) |
| SE (2) | SE7607779L (enExample) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4010085A (en) * | 1976-04-28 | 1977-03-01 | Ppg Industries, Inc. | Cathode electrocatalyst |
| FR2386616A1 (fr) * | 1977-04-05 | 1978-11-03 | Alsthom Atlantique | Electrolyseur |
| CA1128458A (en) * | 1977-06-06 | 1982-07-27 | Tokuyama Soda Kabushiki Kaisha | Electrolysis with cathode of iron or nickel with electroplate from s/n nickel bath |
| JPS5438277A (en) * | 1977-09-01 | 1979-03-22 | Osaka Soda Co Ltd | Cathode with low hydrogen overvoltage |
| CA1098076A (en) * | 1977-11-23 | 1981-03-24 | Kenneth E. Hine | Reduction of steel cathode overpotential |
| FR2418280A1 (fr) * | 1978-02-28 | 1979-09-21 | Comp Generale Electricite | Electrode bipolaire pour electrolyseur |
| US4208451A (en) * | 1978-02-28 | 1980-06-17 | Compagnie Generale D'electricite | Bipolar electrode for an electrolyzer |
| FR2419985A1 (fr) * | 1978-03-13 | 1979-10-12 | Rhone Poulenc Ind | Electrode pour electrolyse du chlorure de sodium |
| US4162204A (en) * | 1978-04-03 | 1979-07-24 | Olin Corporation | Plated metallic cathode |
| GB2023177B (en) * | 1978-06-13 | 1982-09-22 | Engelhard Min & Chem | Electrode for use in an electrolytic process |
| IN153057B (enExample) * | 1978-09-21 | 1984-05-26 | British Petroleum Co | |
| US4248680A (en) * | 1979-01-24 | 1981-02-03 | Ppg Industries, Inc. | Electrolytic process and apparatus |
| US4323595A (en) * | 1979-01-24 | 1982-04-06 | Ppg Industries, Inc. | Nickel-molybdenum cathode |
| US4248679A (en) * | 1979-01-24 | 1981-02-03 | Ppg Industries, Inc. | Electrolysis of alkali metal chloride in a cell having a nickel-molybdenum cathode |
| US4407908A (en) * | 1979-02-01 | 1983-10-04 | Compagnie Generale D'electricite | Cathode for an electrolyser |
| AU5889880A (en) * | 1979-07-02 | 1981-01-15 | Olin Corporation | Manufacture of low overvoltage electrodes by cathodic sputtering |
| US4251478A (en) * | 1979-09-24 | 1981-02-17 | Ppg Industries, Inc. | Porous nickel cathode |
| US4354915A (en) * | 1979-12-17 | 1982-10-19 | Hooker Chemicals & Plastics Corp. | Low overvoltage hydrogen cathodes |
| US4363706A (en) * | 1980-03-07 | 1982-12-14 | Imi Kynoch Limited | Anode |
| US4544473A (en) * | 1980-05-12 | 1985-10-01 | Energy Conversion Devices, Inc. | Catalytic electrolytic electrode |
| US4737249A (en) * | 1982-03-15 | 1988-04-12 | Inco Alloys International, Inc. | Electrolytic production of hydrogen |
| US4545883A (en) * | 1982-07-19 | 1985-10-08 | Energy Conversion Devices, Inc. | Electrolytic cell cathode |
| FI73246C (fi) * | 1982-11-30 | 1987-09-10 | Asahi Chemical Ind | Vaetealstrande elektrod och foerfarande foer dess framstaellning. |
| EP0222911B1 (en) * | 1985-04-10 | 1993-06-30 | Asahi Glass Company Ltd. | Highly durable low-hydrogen overvoltage cathode and a method of producing the same |
| US4877508A (en) * | 1985-04-10 | 1989-10-31 | Asahi Glass Company, Ltd. | Highly durable cathode of low hydrogen overvoltage and method for manufacturing the same |
| US4744878A (en) * | 1986-11-18 | 1988-05-17 | Kerr-Mcgee Chemical Corporation | Anode material for electrolytic manganese dioxide cell |
| DE69610391T2 (de) * | 1995-10-18 | 2001-03-15 | Tosoh Corp., Shinnanyo | Kathode mit niedriger Wasserstoffüberspannung und deren Herstellungsverfahren |
| RU2110619C1 (ru) * | 1996-09-09 | 1998-05-10 | Закрытое акционерное общество "Техно-ТМ" | Электрод для электрохимических процессов и способ его изготовления |
| KR20110033212A (ko) * | 2008-06-18 | 2011-03-30 | 메사추세츠 인스티튜트 오브 테크놀로지 | 물의 전기분해를 위한 촉매 물질, 전극 및 시스템, 및 다른 전기화학 기술 |
| US20110135562A1 (en) * | 2009-11-23 | 2011-06-09 | Terriss Consolidated Industries, Inc. | Two stage process for electrochemically generating hypochlorous acid through closed loop, continuous batch processing of brine |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1205704A (fr) * | 1958-08-07 | 1960-02-04 | Pechiney | Nouvelles anodes pour protection cathodique |
| US3291714A (en) * | 1961-01-13 | 1966-12-13 | Ici Australia Ltd | Electrodes |
| GB1047933A (en) * | 1962-09-12 | 1966-11-09 | Exxon Research Engineering Co | Catalysts |
| GB1164477A (en) * | 1965-12-28 | 1969-09-17 | Matsushita Electric Industrial Co Ltd | Electrochemical Electrode |
| DE1299287B (de) * | 1967-04-05 | 1969-07-17 | Metallgesellschaft Ag | Elektrode fuer die elektrolytische Zerlegung von Salzsaeure |
| US3616445A (en) * | 1967-12-14 | 1971-10-26 | Electronor Corp | Titanium or tantalum base electrodes with applied titanium or tantalum oxide face activated with noble metals or noble metal oxides |
| JPS5433239B2 (enExample) * | 1972-08-14 | 1979-10-19 | ||
| IT978528B (it) * | 1973-01-26 | 1974-09-20 | Oronzio De Nora Impianti | Elettrodi metallici e procedimen to per la loro attivazione |
| US3977958A (en) * | 1973-12-17 | 1976-08-31 | The Dow Chemical Company | Insoluble electrode for electrolysis |
| GB1433800A (en) * | 1973-12-27 | 1976-04-28 | Imi Refinery Holdings Ltd | Method of and anodes for use in electrowinning metals |
-
1976
- 1976-07-06 DE DE2630398A patent/DE2630398C3/de not_active Expired
- 1976-07-06 NO NO762359A patent/NO148648C/no unknown
- 1976-07-06 BR BR7604417A patent/BR7604417A/pt unknown
- 1976-07-06 US US05/702,847 patent/US4080278A/en not_active Expired - Lifetime
- 1976-07-06 GB GB28086/76A patent/GB1504110A/en not_active Expired
- 1976-07-06 NL NL7607442A patent/NL7607442A/xx not_active Application Discontinuation
- 1976-07-07 SE SE7607779A patent/SE7607779L/xx unknown
- 1976-07-07 IT IT50307-A/76A patent/IT1065620B/it active
- 1976-07-07 JP JP51080813A patent/JPS5217374A/ja active Granted
- 1976-07-07 CA CA256,467A patent/CA1083082A/fr not_active Expired
- 1976-07-07 CH CH871176A patent/CH614740A5/xx not_active IP Right Cessation
- 1976-07-08 ES ES449701A patent/ES449701A1/es not_active Expired
- 1976-08-06 IN IN1419/CAL/76A patent/IN145971B/en unknown
-
1980
- 1980-05-30 SE SE8004050A patent/SE436897B/sv not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| SE7607779L (sv) | 1977-01-09 |
| US4080278A (en) | 1978-03-21 |
| JPS5644955B2 (enExample) | 1981-10-22 |
| NO148648C (no) | 1983-11-16 |
| NO762359L (enExample) | 1977-01-11 |
| CA1083082A (fr) | 1980-08-05 |
| CH614740A5 (enExample) | 1979-12-14 |
| GB1504110A (en) | 1978-03-15 |
| SE436897B (sv) | 1985-01-28 |
| BR7604417A (pt) | 1978-01-31 |
| IT1065620B (it) | 1985-03-04 |
| IN145971B (enExample) | 1979-01-27 |
| NL7607442A (nl) | 1977-01-11 |
| DE2630398B2 (de) | 1980-07-31 |
| NO148648B (no) | 1983-08-08 |
| ES449701A1 (es) | 1977-08-01 |
| JPS5217374A (en) | 1977-02-09 |
| SE8004050L (sv) | 1980-05-30 |
| DE2630398A1 (de) | 1977-05-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: CHLOE CHIMIE, 92800 PUTEAUX, FR |
|
| 8339 | Ceased/non-payment of the annual fee |