DE2617282A1 - Verfahren zur herstellung einer loesung eines hydroximetallischen polymerisats und ihre verwendung bei der wasserbehandlung - Google Patents
Verfahren zur herstellung einer loesung eines hydroximetallischen polymerisats und ihre verwendung bei der wasserbehandlungInfo
- Publication number
- DE2617282A1 DE2617282A1 DE19762617282 DE2617282A DE2617282A1 DE 2617282 A1 DE2617282 A1 DE 2617282A1 DE 19762617282 DE19762617282 DE 19762617282 DE 2617282 A DE2617282 A DE 2617282A DE 2617282 A1 DE2617282 A1 DE 2617282A1
- Authority
- DE
- Germany
- Prior art keywords
- solution
- mol
- hydroximetallic
- water
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title description 24
- 239000000243 solution Substances 0.000 claims description 46
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 238000005189 flocculation Methods 0.000 claims description 17
- 230000016615 flocculation Effects 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 15
- 238000005345 coagulation Methods 0.000 claims description 9
- 230000015271 coagulation Effects 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims description 2
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- 241000243320 Hydrozoa Species 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 239000007900 aqueous suspension Substances 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 8
- 239000003153 chemical reaction reagent Substances 0.000 description 7
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 6
- 235000011941 Tilia x europaea Nutrition 0.000 description 6
- 239000004571 lime Substances 0.000 description 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 5
- 239000012476 oxidizable substance Substances 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- -1 basic Metal salts Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 229910052728 basic metal Inorganic materials 0.000 description 2
- 230000001112 coagulating effect Effects 0.000 description 2
- 239000003651 drinking water Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000012206 bottled water Nutrition 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
- C02F1/5245—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/34—Preparation of aluminium hydroxide by precipitation from solutions containing aluminium salts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/14—Pore volume
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7512975A FR2308594A1 (fr) | 1975-04-25 | 1975-04-25 | Solution de polymere, sa preparation et son utilisation dans le traitement des eaux |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2617282A1 true DE2617282A1 (de) | 1976-11-04 |
| DE2617282C2 DE2617282C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1988-03-17 |
Family
ID=9154489
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19762617282 Granted DE2617282A1 (de) | 1975-04-25 | 1976-04-21 | Verfahren zur herstellung einer loesung eines hydroximetallischen polymerisats und ihre verwendung bei der wasserbehandlung |
Country Status (4)
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0005419A1 (en) * | 1978-05-03 | 1979-11-14 | Boliden Aktiebolag | Aluminium sulphate compositions containing polynuclear complexes and a method of producing the same and the use thereof |
| EP0017634A1 (en) * | 1979-03-23 | 1980-10-15 | Boliden Aktiebolag | A solid flocculating agent, a method for its manufacture and its use |
| EP0062015A1 (en) * | 1981-03-23 | 1982-10-06 | Boliden Aktiebolag | Aluminium sulphate composition for water-purifying, paper-sizing and plant dewatering purposes and a method for producing the composition |
| EP0062016A1 (en) * | 1981-03-23 | 1982-10-06 | Boliden Aktiebolag | An aluminium chloride composition and a method for its manufacture |
| FR2505809A1 (fr) * | 1981-05-14 | 1982-11-19 | Tokuyama Soda Kk | Sulfate basique d'aluminium et procede de sa preparation |
| EP0069719A1 (en) * | 1981-07-03 | 1983-01-12 | Boliden Aktiebolag | A method for producing basic aluminium sulphate |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE436276B (sv) * | 1983-04-28 | 1984-11-26 | Boliden Ab | Stabil losning av basiskt aluminiumsulfat |
| US4566986A (en) * | 1984-08-31 | 1986-01-28 | Waldmann John J | Flocculating agents and processes for making them |
| US4655934A (en) * | 1985-09-12 | 1987-04-07 | Nalco Chemical Company | Dimeric aluminum compounds and their use |
| SE455943B (sv) * | 1986-05-27 | 1988-08-22 | Boliden Ab | Flerkernigt basiskt me?723?72+-hydroxisulfatkomplex i fast form samt forfarande for dess framstellning |
| US5171453A (en) * | 1986-09-19 | 1992-12-15 | Rhone-Poulenc Chimie | Water clarification/purification |
| US4795585A (en) * | 1987-04-24 | 1989-01-03 | General Chemical Corporation | Polyvinyl alcohol containing polyaluminum chloride flocculants |
| US4826606A (en) * | 1987-05-06 | 1989-05-02 | General Chemical Corporation | Manufacture and use of polymer modified aluminum hydroxide and basic aluminum sulfate |
| CA2229266C (en) * | 1995-09-18 | 2001-10-16 | Delta Chemical Corporation | Polyaluminum chlorides and polyaluminum chlorosulfates methods and compositions |
| US5916447A (en) * | 1996-10-15 | 1999-06-29 | Eka Chemicals Ab | Method for water treatment |
| US20030209499A1 (en) * | 2000-09-29 | 2003-11-13 | Haase Richard A. | Clarification of water and wastewater |
| AU2002332426A1 (en) * | 2001-07-25 | 2003-02-17 | Richard A. Haase | Processes and apparatus for the manufacture of polynuclear aluminum compounds and disinfectants, and polynuclear aluminum compounds and disinfectants from such processes and apparatus |
| US6537464B1 (en) * | 2001-10-31 | 2003-03-25 | General Chemical Corporation | Mid-basicity aluminum compounds and methods of making |
| FI117507B (fi) * | 2004-07-09 | 2006-11-15 | Kemira Oyj | Menetelmä ligniinin poistamiseksi vedestä |
| US8268269B2 (en) | 2006-01-24 | 2012-09-18 | Clearvalue Technologies, Inc. | Manufacture of water chemistries |
| US20200180972A1 (en) * | 2017-03-27 | 2020-06-11 | Nareshkumar Ishwarlal Nagar | Novel trialuminum hydroxy chloride of formula al3(oh)4cl5 and process for the preparation thereof from industrial waste |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2036685A1 (en) * | 1969-01-31 | 1970-12-31 | Taki Fertilizer Manufac | Basic salts as coagulants for use in aqueous - media |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2866759A (en) * | 1955-05-10 | 1958-12-30 | Warren C Horton | Composition for treating water |
| US3056725A (en) * | 1959-06-16 | 1962-10-02 | Agrashell Inc | Polymeric aluminum oxide hydroxides |
| US3066012A (en) * | 1960-04-04 | 1962-11-27 | Grace W R & Co | Process for preparing alumina gels |
| US3629229A (en) * | 1969-02-27 | 1971-12-21 | Chatten Drug & Chem Co | Water soluble basic aluminum polyhydroxyl hydrocarbon complexes |
| US3833718A (en) * | 1971-04-02 | 1974-09-03 | Chevron Res | Method of mixing an aqueous aluminum salt solution and an alkaline base solution in a jet mixer to form a hydroxy-aluminum solution |
-
1975
- 1975-04-25 FR FR7512975A patent/FR2308594A1/fr active Granted
-
1976
- 1976-04-21 DE DE19762617282 patent/DE2617282A1/de active Granted
- 1976-04-23 GB GB16602/76A patent/GB1548620A/en not_active Expired
- 1976-04-26 US US05/680,842 patent/US4051028A/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2036685A1 (en) * | 1969-01-31 | 1970-12-31 | Taki Fertilizer Manufac | Basic salts as coagulants for use in aqueous - media |
Non-Patent Citations (1)
| Title |
|---|
| Chem. Abstr., Bd. 79, 1973, Ref. Nr. 116680 g * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0005419A1 (en) * | 1978-05-03 | 1979-11-14 | Boliden Aktiebolag | Aluminium sulphate compositions containing polynuclear complexes and a method of producing the same and the use thereof |
| EP0017634A1 (en) * | 1979-03-23 | 1980-10-15 | Boliden Aktiebolag | A solid flocculating agent, a method for its manufacture and its use |
| EP0062015A1 (en) * | 1981-03-23 | 1982-10-06 | Boliden Aktiebolag | Aluminium sulphate composition for water-purifying, paper-sizing and plant dewatering purposes and a method for producing the composition |
| EP0062016A1 (en) * | 1981-03-23 | 1982-10-06 | Boliden Aktiebolag | An aluminium chloride composition and a method for its manufacture |
| FR2505809A1 (fr) * | 1981-05-14 | 1982-11-19 | Tokuyama Soda Kk | Sulfate basique d'aluminium et procede de sa preparation |
| EP0069719A1 (en) * | 1981-07-03 | 1983-01-12 | Boliden Aktiebolag | A method for producing basic aluminium sulphate |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1548620A (en) | 1979-07-18 |
| FR2308594A1 (fr) | 1976-11-19 |
| US4051028A (en) | 1977-09-27 |
| FR2308594B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1981-05-29 |
| DE2617282C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1988-03-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8125 | Change of the main classification |
Ipc: C01F 7/34 |
|
| D2 | Grant after examination | ||
| 8363 | Opposition against the patent | ||
| 8365 | Fully valid after opposition proceedings | ||
| 8328 | Change in the person/name/address of the agent |
Free format text: HERRMANN-TRENTEPOHL, W., DIPL.-ING., PAT.-ANW., 4690 HERNE |