DE2553356A1 - Wiederaufladbare elektrische energiespeichereinrichtung - Google Patents
Wiederaufladbare elektrische energiespeichereinrichtungInfo
- Publication number
- DE2553356A1 DE2553356A1 DE19752553356 DE2553356A DE2553356A1 DE 2553356 A1 DE2553356 A1 DE 2553356A1 DE 19752553356 DE19752553356 DE 19752553356 DE 2553356 A DE2553356 A DE 2553356A DE 2553356 A1 DE2553356 A1 DE 2553356A1
- Authority
- DE
- Germany
- Prior art keywords
- lithium
- positive electrode
- matrix
- transition metal
- sulfide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004146 energy storage Methods 0.000 title claims description 22
- 239000011159 matrix material Substances 0.000 claims description 46
- 229910052744 lithium Inorganic materials 0.000 claims description 44
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 41
- 150000003839 salts Chemical class 0.000 claims description 36
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 34
- 239000003792 electrolyte Substances 0.000 claims description 32
- -1 lithium halide Chemical class 0.000 claims description 31
- 150000004770 chalcogenides Chemical class 0.000 claims description 29
- 229910052723 transition metal Inorganic materials 0.000 claims description 27
- 239000000835 fiber Substances 0.000 claims description 23
- 229910002804 graphite Inorganic materials 0.000 claims description 19
- 239000010439 graphite Substances 0.000 claims description 19
- 229910052799 carbon Inorganic materials 0.000 claims description 18
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical group [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 14
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 claims description 10
- 150000003624 transition metals Chemical group 0.000 claims description 9
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 8
- GLNWILHOFOBOFD-UHFFFAOYSA-N lithium sulfide Chemical compound [Li+].[Li+].[S-2] GLNWILHOFOBOFD-UHFFFAOYSA-N 0.000 claims description 5
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 4
- 229910001416 lithium ion Inorganic materials 0.000 claims description 4
- 239000001103 potassium chloride Substances 0.000 claims description 4
- 235000011164 potassium chloride Nutrition 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 238000002955 isolation Methods 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 14
- 229920000049 Carbon (fiber) Polymers 0.000 description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- 239000011149 active material Substances 0.000 description 12
- 239000004917 carbon fiber Substances 0.000 description 12
- 239000007774 positive electrode material Substances 0.000 description 12
- 239000011593 sulfur Substances 0.000 description 11
- 229910052717 sulfur Inorganic materials 0.000 description 11
- 230000008018 melting Effects 0.000 description 10
- 238000002844 melting Methods 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000004744 fabric Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 229910000733 Li alloy Inorganic materials 0.000 description 7
- 239000006182 cathode active material Substances 0.000 description 7
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 6
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 239000011800 void material Substances 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 5
- 239000000374 eutectic mixture Substances 0.000 description 5
- 239000001989 lithium alloy Substances 0.000 description 5
- 229910052976 metal sulfide Inorganic materials 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 150000004763 sulfides Chemical class 0.000 description 5
- 230000007704 transition Effects 0.000 description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 4
- 229910052798 chalcogen Inorganic materials 0.000 description 4
- 150000001787 chalcogens Chemical class 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical compound [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Substances [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 4
- 125000006850 spacer group Chemical group 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- 238000009827 uniform distribution Methods 0.000 description 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000010406 cathode material Substances 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 230000005496 eutectics Effects 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 239000012212 insulator Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 210000002686 mushroom body Anatomy 0.000 description 3
- 229910000480 nickel oxide Inorganic materials 0.000 description 3
- 239000011255 nonaqueous electrolyte Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000007784 solid electrolyte Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 2
- 229910001508 alkali metal halide Inorganic materials 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 2
- HCQWRNRRURULEY-UHFFFAOYSA-L lithium;potassium;dichloride Chemical compound [Li+].[Cl-].[Cl-].[K+] HCQWRNRRURULEY-UHFFFAOYSA-L 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000009828 non-uniform distribution Methods 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000011833 salt mixture Substances 0.000 description 2
- 229910052706 scandium Inorganic materials 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- XNEKSUGZWNDIIL-UHFFFAOYSA-M B(Cl)(Cl)Cl.[Cl-].[Li+] Chemical compound B(Cl)(Cl)Cl.[Cl-].[Li+] XNEKSUGZWNDIIL-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910013618 LiCl—KCl Inorganic materials 0.000 description 1
- 229910013647 LiCl—LiF Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000158147 Sator Species 0.000 description 1
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- DXAFGPUPGYKAAR-UHFFFAOYSA-K [Cl-].[Ca+2].[Cl-].[Na+].[Cl-].[Li+] Chemical compound [Cl-].[Ca+2].[Cl-].[Na+].[Cl-].[Li+] DXAFGPUPGYKAAR-UHFFFAOYSA-K 0.000 description 1
- FRRFXFCSMTUEMZ-UHFFFAOYSA-K [Cl-].[K+].[Cl-].[Li+].[Cl-].[Ca+2] Chemical compound [Cl-].[K+].[Cl-].[Li+].[Cl-].[Ca+2] FRRFXFCSMTUEMZ-UHFFFAOYSA-K 0.000 description 1
- CIHHRNQZUFCQRG-UHFFFAOYSA-L [Li+].[K+].[Br-].[Br-] Chemical compound [Li+].[K+].[Br-].[Br-] CIHHRNQZUFCQRG-UHFFFAOYSA-L 0.000 description 1
- JDZCKJOXGCMJGS-UHFFFAOYSA-N [Li].[S] Chemical compound [Li].[S] JDZCKJOXGCMJGS-UHFFFAOYSA-N 0.000 description 1
- DQPHOFCRIBAMEE-UHFFFAOYSA-K [Na+].[Cl-].[Li]Cl.Cl[K] Chemical compound [Na+].[Cl-].[Li]Cl.Cl[K] DQPHOFCRIBAMEE-UHFFFAOYSA-K 0.000 description 1
- 229910052946 acanthite Inorganic materials 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910001615 alkaline earth metal halide Inorganic materials 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- SMBQBQBNOXIFSF-UHFFFAOYSA-N dilithium Chemical compound [Li][Li] SMBQBQBNOXIFSF-UHFFFAOYSA-N 0.000 description 1
- YTAGWKNZVDGLMG-UHFFFAOYSA-K dilithium sodium dibromide chloride Chemical compound [Cl-].[Li+].[Br-].[Na+].[Br-].[Li+] YTAGWKNZVDGLMG-UHFFFAOYSA-K 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000011262 electrochemically active material Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- WXWOAUXBQZMFJK-UHFFFAOYSA-L lithium rubidium(1+) dibromide Chemical compound [Br-].[Li+].[Rb+].[Br-] WXWOAUXBQZMFJK-UHFFFAOYSA-L 0.000 description 1
- LBEWFUFVQRYRPT-UHFFFAOYSA-L lithium rubidium(1+) difluoride Chemical compound [F-].[Rb+].[F-].[Li+] LBEWFUFVQRYRPT-UHFFFAOYSA-L 0.000 description 1
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 1
- KUJOABUXCGVGIY-UHFFFAOYSA-N lithium zinc Chemical compound [Li].[Zn] KUJOABUXCGVGIY-UHFFFAOYSA-N 0.000 description 1
- QNRUKMBLUVIEBO-UHFFFAOYSA-L lithium;magnesium;dichloride Chemical compound [Li+].[Mg+2].[Cl-].[Cl-] QNRUKMBLUVIEBO-UHFFFAOYSA-L 0.000 description 1
- IEGSXYJGFBDOLI-UHFFFAOYSA-L lithium;potassium;diiodide Chemical compound [Li+].[K+].[I-].[I-] IEGSXYJGFBDOLI-UHFFFAOYSA-L 0.000 description 1
- BSTYFOSOPXFJSH-UHFFFAOYSA-N lithium;sulfanylidenenickel Chemical compound [Li].[Ni]=S BSTYFOSOPXFJSH-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 description 1
- 239000005486 organic electrolyte Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 150000004771 selenides Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 description 1
- 229940056910 silver sulfide Drugs 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 150000004772 tellurides Chemical class 0.000 description 1
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/399—Cells with molten salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/581—Chalcogenides or intercalation compounds thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
- H01M4/72—Grids
- H01M4/74—Meshes or woven material; Expanded metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Cell Electrode Carriers And Collectors (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US527678A US3925098A (en) | 1974-11-27 | 1974-11-27 | Positive electrode for electrical energy storage device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2553356A1 true DE2553356A1 (de) | 1976-08-12 |
Family
ID=24102474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19752553356 Withdrawn DE2553356A1 (de) | 1974-11-27 | 1975-11-27 | Wiederaufladbare elektrische energiespeichereinrichtung |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3925098A (https=) |
| JP (1) | JPS5176531A (https=) |
| BE (1) | BE835130A (https=) |
| CA (1) | CA1043867A (https=) |
| DE (1) | DE2553356A1 (https=) |
| FR (1) | FR2293075A1 (https=) |
| GB (1) | GB1482850A (https=) |
| IT (1) | IT1047850B (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3533483A1 (de) * | 1984-09-21 | 1986-04-10 | Lilliwyte S.A., Luxemburg/Luxembourg | Elektrochemische zelle und kathode dafuer |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4013818A (en) * | 1974-09-28 | 1977-03-22 | National Research Development Corporation | High temperature secondary batteries |
| US3933520A (en) * | 1975-04-03 | 1976-01-20 | The United States Of America As Represented By The United States Energy Research And Development Administration | Method of preparing electrodes with porous current collector structures and solid reactants for secondary electrochemical cells |
| US4003753A (en) * | 1976-03-15 | 1977-01-18 | Rockwell International Corporation | Electrode structure for electrical energy storage device |
| US4065602A (en) * | 1977-03-24 | 1977-12-27 | The United States Of America As Represented By The United States Energy Research And Development Administration | Wick-and-pool electrodes for electrochemical cell |
| US4143217A (en) * | 1977-10-03 | 1979-03-06 | Great Lakes Carbon Corporation | Process for manufacture of positive electrode for lithium/metal sulfide secondary cell |
| US4144384A (en) * | 1978-07-03 | 1979-03-13 | Exxon Research & Engineering Co. | Cells having cathodes with vanadium-chalcogen-containing compounds |
| US4224390A (en) * | 1978-08-21 | 1980-09-23 | Haering Rudolph R | Lithium molybdenum disulphide battery cathode |
| US4264686A (en) * | 1978-09-01 | 1981-04-28 | Texas Instruments Incorporated | Graphite felt flowthrough electrode for fuel cell use |
| USRE30392E (en) * | 1978-09-07 | 1980-09-02 | The United States Of America As Represented By The United States Department Of Energy | Wick-and-pool electrodes for electrochemical cell |
| US4208474A (en) * | 1978-12-28 | 1980-06-17 | Exxon Research & Engineering Co. | Cell containing alkali metal anode, cathode and alkali metal-metal-chalcogenide compound solid electrolyte |
| EP0020061B1 (en) * | 1979-05-24 | 1983-11-16 | Chloride Silent Power Limited | Sodium sulphur cells, cathode structures therefor, and the manufacture of such cells and structures |
| US4367266A (en) * | 1979-06-28 | 1983-01-04 | Union Carbide Corporation | Cathode collectors for nonaqueous cell having a metal oxide catalyst |
| US4322317A (en) * | 1980-03-03 | 1982-03-30 | Exxon Research & Engineering Co. | Composition for chalcogenide electrodes |
| US4416915A (en) * | 1982-02-04 | 1983-11-22 | Combustion Engineering, Inc. | Method of making chalcogenide cathodes |
| US5436548A (en) * | 1992-11-25 | 1995-07-25 | Motorola, Inc. | Battery charging and discharging system and corresponding method |
| JPH11297358A (ja) * | 1998-04-14 | 1999-10-29 | Matsushita Electric Ind Co Ltd | リチウム二次電池 |
| GB9820109D0 (en) | 1998-09-15 | 1998-11-11 | Nat Power Plc | Vitrified carbon compositions |
| GB2351075A (en) * | 1999-06-17 | 2000-12-20 | Secr Defence | Producing lithiated transition metal sulphides |
| US6621687B2 (en) * | 2001-09-05 | 2003-09-16 | Northrop Grumman Corporation Tpl, Inc. | Micro-supercapacitor |
| KR100436712B1 (ko) * | 2001-12-19 | 2004-06-22 | 삼성에스디아이 주식회사 | 캐소드 전극, 그 제조방법 및 이를 채용한 리튬 전지 |
| US7692411B2 (en) | 2006-01-05 | 2010-04-06 | Tpl, Inc. | System for energy harvesting and/or generation, storage, and delivery |
| US7722991B2 (en) * | 2006-08-09 | 2010-05-25 | Toyota Motor Corporation | High performance anode material for lithium-ion battery |
| US7864507B2 (en) | 2006-09-06 | 2011-01-04 | Tpl, Inc. | Capacitors with low equivalent series resistance |
| US8859123B2 (en) * | 2009-05-08 | 2014-10-14 | Robert Bosch Gmbh | System and method for pressure determination in a Li-ion battery |
| DE102009036083A1 (de) * | 2009-08-04 | 2011-02-10 | Li-Tec Battery Gmbh | Verfahren zum Steuern einer Batterie und Vorrichtung zur Durchführung des Verfahrens |
| CN102906930B (zh) | 2010-05-31 | 2016-09-14 | 大川宏 | 固体电解质二次电池 |
| JP5804073B2 (ja) * | 2011-10-21 | 2015-11-04 | 株式会社村田製作所 | スイッチング電源装置 |
| RU2510548C1 (ru) * | 2012-08-16 | 2014-03-27 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Южно-Российский государственный университет экономики и сервиса" (ФГБОУ ВПО "ЮРГУЭС") | Способ изготовления основы электрода химического источника тока из углеродного войлока с использованием переменного асимметричного тока |
| US10164231B2 (en) * | 2013-02-05 | 2018-12-25 | Hrl Laboratories, Llc | Separators for lithium-sulfur batteries |
| WO2015076935A2 (en) * | 2013-09-30 | 2015-05-28 | The Regents Of The University Of Colorado, A Body Corporate | All-solid-state cathode materials, cathodes, batteries and methods |
| DE102014201836A1 (de) * | 2014-02-03 | 2015-08-06 | Robert Bosch Gmbh | Galvanische Batteriezelle, insbesondere wiederaufladbare Lithium-Schwefel-Batteriezelle, mit Volumenausgleichselement |
| US10170799B2 (en) * | 2014-12-15 | 2019-01-01 | Massachusetts Institute Of Technology | Multi-element liquid metal battery |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3811947A (en) * | 1971-03-22 | 1974-05-21 | Standard Oil Co | Electrical energy storage device utilizing an electrode composed of an amorphous carbon and sulfur-carbon complex |
| US3770503A (en) * | 1972-03-06 | 1973-11-06 | Us Air Force | Two compartmented electrochemical cell having aluminum anode bud powdered carbon suspended in the cathode compartment |
| GB1392911A (en) * | 1972-09-09 | 1975-05-07 | Yuasa Battery Co Ltd | Storage battery |
| US3852114A (en) * | 1973-12-28 | 1974-12-03 | Gen Electric | Cell casing and hermetically sealed primary sodium-sulfur cell |
-
1974
- 1974-11-27 US US527678A patent/US3925098A/en not_active Expired - Lifetime
-
1975
- 1975-09-22 CA CA236,297A patent/CA1043867A/en not_active Expired
- 1975-10-06 GB GB40830/75A patent/GB1482850A/en not_active Expired
- 1975-10-17 IT IT51835/75A patent/IT1047850B/it active
- 1975-10-31 BE BE161478A patent/BE835130A/xx unknown
- 1975-11-13 FR FR7534665A patent/FR2293075A1/fr active Granted
- 1975-11-14 JP JP50136414A patent/JPS5176531A/ja active Pending
- 1975-11-27 DE DE19752553356 patent/DE2553356A1/de not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3533483A1 (de) * | 1984-09-21 | 1986-04-10 | Lilliwyte S.A., Luxemburg/Luxembourg | Elektrochemische zelle und kathode dafuer |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5176531A (https=) | 1976-07-02 |
| IT1047850B (it) | 1980-10-20 |
| FR2293075A1 (fr) | 1976-06-25 |
| GB1482850A (en) | 1977-08-17 |
| CA1043867A (en) | 1978-12-05 |
| US3925098A (en) | 1975-12-09 |
| FR2293075B1 (https=) | 1979-07-13 |
| BE835130A (fr) | 1976-04-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2553356A1 (de) | Wiederaufladbare elektrische energiespeichereinrichtung | |
| DE2935686C2 (de) | Elektrochemische Zelle und hierfür verwendbare Anode | |
| DE2928863C2 (de) | Elektrochemische Zelle | |
| DE2628752C2 (de) | Elektrochemisches Element | |
| DE2427949A1 (de) | Sekundaeres element mit einer lithiumanode und mit einer salzschmelze | |
| EP0470492B1 (de) | Elektrochemisches Sekundärelement | |
| DE1671738C2 (de) | Galvanische Zelle | |
| DE2542406C2 (de) | Verfahren zur Herstellung einer sekundären elektrochemischen Zelle | |
| DE2716661C2 (de) | Elektrochemische stromliefernde Zelle und Verbindungen der Formel A↓x↓M(PS↓3↓)↓y↓ | |
| DE69314088T2 (de) | Positivelektrode für Lithium-Sekundärbatterie und Verfahren zu seiner Herstellung und eine nichtwässrige Elektrolyte Lithium-Sekundärbatterie unter Verwendung derselben | |
| DE2501881A1 (de) | Sekundaere elektronische zelle sowie kathode dafuer | |
| DE19722487C2 (de) | Verfahren zur Herstellung von chemisch modifizierten Graphitpartikeln und Verwendung solcher Partikel in einem elektrochemischen Graphit/Alkalimetall-Element | |
| DE2336666A1 (de) | Nichtwaessrige batterie | |
| DE1596077B2 (de) | Galvanisches element bestehend aus einer anodischen reaktions zone einer kathodischen reaktionszone und einem dazwischen angebrachten festen elektrolyten | |
| DE112011102079B4 (de) | Aktives Material für eine wiederaufladbare Batterie | |
| DE1771922A1 (de) | Elektrische Brennstoffzelle | |
| DE2810795A1 (de) | Elektrode fuer elektrische speichereinrichtungen | |
| DE2701708A1 (de) | Elektrode fuer eine einrichtung zur speicherung elektrischer energie | |
| DE1696546B2 (de) | Wiederaufladbares galvanisches thermalelement und verfahren zur herstellung einer elektrode dafuer | |
| CH639799A5 (de) | Festkoerperelement. | |
| DE2951167A1 (de) | Elektrochemische primaerzelle und verfahren zur herstellung eines kathodenstromkollektors dafuer | |
| DE3037060A1 (de) | Wiederaufladbares, nicht-waesseriges elektrochemisches element mit einer negativen elektrode aus einer silberlegierung | |
| DE2605899A1 (de) | Akkumulator | |
| DE2544882A1 (de) | Lithiumelektrode | |
| DE3311461A1 (de) | Elektronisch leitfaehiges tectosilikat |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8139 | Disposal/non-payment of the annual fee |