DE2527905A1 - Verfahren zur herstellung von stossfesten polymeren - Google Patents
Verfahren zur herstellung von stossfesten polymerenInfo
- Publication number
- DE2527905A1 DE2527905A1 DE19752527905 DE2527905A DE2527905A1 DE 2527905 A1 DE2527905 A1 DE 2527905A1 DE 19752527905 DE19752527905 DE 19752527905 DE 2527905 A DE2527905 A DE 2527905A DE 2527905 A1 DE2527905 A1 DE 2527905A1
- Authority
- DE
- Germany
- Prior art keywords
- polymerization
- zone
- carried out
- reactors
- elastomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000642 polymer Polymers 0.000 title claims description 25
- 238000000034 method Methods 0.000 title claims description 15
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 25
- 229920001971 elastomer Polymers 0.000 claims description 23
- 229920002554 vinyl polymer Polymers 0.000 claims description 15
- 239000000806 elastomer Substances 0.000 claims description 14
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 229920002857 polybutadiene Polymers 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000012662 bulk polymerization Methods 0.000 claims description 3
- 238000010924 continuous production Methods 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims description 3
- 239000011541 reaction mixture Substances 0.000 claims description 3
- 150000001491 aromatic compounds Chemical class 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- -1 vinyl aromatic compounds Chemical class 0.000 description 15
- 239000005060 rubber Substances 0.000 description 8
- 239000004793 Polystyrene Substances 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003085 diluting agent Substances 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- LLVWLCAZSOLOTF-UHFFFAOYSA-N 1-methyl-4-[1,4,4-tris(4-methylphenyl)buta-1,3-dienyl]benzene Chemical compound C1=CC(C)=CC=C1C(C=1C=CC(C)=CC=1)=CC=C(C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 LLVWLCAZSOLOTF-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C08F291/02—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to elastomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2812874 | 1974-06-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2527905A1 true DE2527905A1 (de) | 1976-01-08 |
Family
ID=10270709
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19752527905 Pending DE2527905A1 (de) | 1974-06-25 | 1975-06-23 | Verfahren zur herstellung von stossfesten polymeren |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4011284A (cg-RX-API-DMAC7.html) |
| AU (1) | AU8236175A (cg-RX-API-DMAC7.html) |
| BE (1) | BE830308A (cg-RX-API-DMAC7.html) |
| DE (1) | DE2527905A1 (cg-RX-API-DMAC7.html) |
| FI (1) | FI751855A7 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2278709A1 (cg-RX-API-DMAC7.html) |
| IT (1) | IT1039343B (cg-RX-API-DMAC7.html) |
| NL (1) | NL7507486A (cg-RX-API-DMAC7.html) |
| SE (1) | SE7507193L (cg-RX-API-DMAC7.html) |
| ZA (1) | ZA753990B (cg-RX-API-DMAC7.html) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES459128A1 (es) * | 1976-05-28 | 1978-04-01 | Monsanto Co | Un procedimiento industrial para preparar una polimezcla. |
| US4100227A (en) * | 1977-04-04 | 1978-07-11 | The Dow Chemical Company | Transparent impact-resistant polystyrene structure |
| US4100228A (en) * | 1977-04-04 | 1978-07-11 | The Dow Chemical Company | Transparent impact styrene polymer structure |
| US4187261A (en) * | 1978-05-23 | 1980-02-05 | Standard Oil Company (Indiana) | Vinyl aromatic polymerization process |
| US4198383A (en) * | 1978-08-21 | 1980-04-15 | Deryagina Galina M | Apparatus for continuous preparation of acrylonitrilebutadienstyrene copolymer |
| ZA803162B (en) * | 1979-06-01 | 1981-05-27 | Mobil Oil Corp | A continuous process for the preparation of rubber modified polymers |
| US4275319A (en) * | 1979-06-01 | 1981-06-23 | Trw Inc. | Oil-filled submergible electric pump motor with improved stator winding insulation |
| DE3065714D1 (en) * | 1979-11-07 | 1983-12-29 | Standard Oil Co Ohio | Manufacture of rubber-modified co-polymers in an extruder-type reactor |
| DE3018643C2 (de) * | 1980-05-16 | 1982-07-08 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von schlagfest modifizierten Styrolpolymerisaten |
| DE3047303A1 (de) * | 1980-12-16 | 1982-07-29 | Basf Ag, 6700 Ludwigshafen | Verfahren zur kontinuierlichen herstellung von mit kautschuk modifizierten polymerisaten von vinylaromaten, verwendung derselben zum spritzgiessen, sowie formteile aus diesen |
| DE3245293A1 (de) * | 1982-12-08 | 1984-06-14 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von schlagfesten polymerisaten von vinylaromaten |
| DE4110009A1 (de) * | 1991-03-27 | 1992-10-01 | Basf Ag | Verfahren zur herstellung von abs-formmassen |
| US6818189B1 (en) | 2000-05-05 | 2004-11-16 | Saudi Basic Industries Corporation | Tubular reactor with gas injector for gas phase catalytic reactions |
| US6977064B1 (en) | 2000-05-05 | 2005-12-20 | Saudi Basic Industries Corporation | Apparatus for the controlled optimized addition of reactants in continuous flow reaction systems |
| US8354069B2 (en) | 2005-03-08 | 2013-01-15 | Authentix, Inc. | Plug flow system for identification and authentication of markers |
| WO2006096761A1 (en) * | 2005-03-08 | 2006-09-14 | Authentix, Inc. | Microfluidic device for identification, quantification, and authentication of latent markers |
| US20070142594A1 (en) * | 2005-12-21 | 2007-06-21 | Fina Technology, Inc. | Horizontal boiling plug flow reactor |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3311675A (en) * | 1963-04-16 | 1967-03-28 | Rexall Drug Chemical | Bulk solvent polymerization process |
| US3513145A (en) * | 1966-02-25 | 1970-05-19 | Crawford & Russell Inc | Continuous mass polymerization processes |
| GB1175262A (en) | 1967-07-26 | 1969-12-23 | Shell Int Research | The Manufacture of Polyvinyl-Aromatic Compounds, and the Resulting Polymers. |
| DE1770392B2 (de) * | 1968-05-11 | 1980-07-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von schlagfesten kautschukhaltigen Polymerisaten |
| US3639372A (en) * | 1968-06-24 | 1972-02-01 | Dow Chemical Co | Method for the polymerization of alkenyl aromatic monomers |
| US3664977A (en) * | 1968-11-20 | 1972-05-23 | Asahi Dow Ltd | Bulk polymerized aromatic hydrocarbon in rubber and polyphenylene ether |
| US3903202A (en) * | 1973-09-19 | 1975-09-02 | Monsanto Co | Continuous mass polymerization process for polyblends |
-
1975
- 1975-06-17 BE BE1006732A patent/BE830308A/xx unknown
- 1975-06-23 ZA ZA00753990A patent/ZA753990B/xx unknown
- 1975-06-23 FR FR7519548A patent/FR2278709A1/fr not_active Withdrawn
- 1975-06-23 AU AU82361/75A patent/AU8236175A/en not_active Expired
- 1975-06-23 DE DE19752527905 patent/DE2527905A1/de active Pending
- 1975-06-23 SE SE7507193A patent/SE7507193L/xx unknown
- 1975-06-23 IT IT24688/75A patent/IT1039343B/it active
- 1975-06-23 NL NL7507486A patent/NL7507486A/xx unknown
- 1975-06-23 FI FI751855A patent/FI751855A7/fi unknown
- 1975-06-25 US US05/590,178 patent/US4011284A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ZA753990B (en) | 1976-05-26 |
| SE7507193L (sv) | 1975-12-29 |
| FR2278709A1 (fr) | 1976-02-13 |
| BE830308A (nl) | 1975-12-17 |
| IT1039343B (it) | 1979-12-10 |
| US4011284A (en) | 1977-03-08 |
| FI751855A7 (cg-RX-API-DMAC7.html) | 1975-12-26 |
| AU8236175A (en) | 1977-01-06 |
| NL7507486A (nl) | 1975-12-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OHJ | Non-payment of the annual fee |