DE2526805C3 - Phosphor enthaltende Flammschutzmittel, Verfahren zu deren Herstellung und deren Verwendung - Google Patents
Phosphor enthaltende Flammschutzmittel, Verfahren zu deren Herstellung und deren VerwendungInfo
- Publication number
- DE2526805C3 DE2526805C3 DE2526805A DE2526805A DE2526805C3 DE 2526805 C3 DE2526805 C3 DE 2526805C3 DE 2526805 A DE2526805 A DE 2526805A DE 2526805 A DE2526805 A DE 2526805A DE 2526805 C3 DE2526805 C3 DE 2526805C3
- Authority
- DE
- Germany
- Prior art keywords
- flame
- flame retardants
- phosphonate
- weight
- flame retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003063 flame retardant Substances 0.000 title claims description 55
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 title claims description 4
- 239000011574 phosphorus Substances 0.000 title claims description 4
- 238000000034 method Methods 0.000 title description 4
- 238000004519 manufacturing process Methods 0.000 title description 3
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 21
- 238000009835 boiling Methods 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000000178 monomer Substances 0.000 description 31
- 239000006260 foam Substances 0.000 description 28
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 27
- 239000000203 mixture Substances 0.000 description 16
- 238000012360 testing method Methods 0.000 description 13
- 230000032683 aging Effects 0.000 description 12
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 8
- 229920005830 Polyurethane Foam Polymers 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 239000011496 polyurethane foam Substances 0.000 description 8
- 230000004580 weight loss Effects 0.000 description 8
- -1 tris (2-chloroethyl) phosphite phosphonate Chemical compound 0.000 description 7
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- LUVCTYHBTXSAMX-UHFFFAOYSA-N tris(2-chloroethyl) phosphite Chemical compound ClCCOP(OCCCl)OCCCl LUVCTYHBTXSAMX-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 3
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 3
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 3
- 238000006317 isomerization reaction Methods 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 description 3
- XXIDKSWYSYEFAG-UHFFFAOYSA-N 1-chloro-2-[2-chloroethoxy(2-chloroethyl)phosphoryl]oxyethane Chemical compound ClCCOP(=O)(CCCl)OCCCl XXIDKSWYSYEFAG-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 238000003822 preparative gas chromatography Methods 0.000 description 2
- 239000003223 protective agent Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920006305 unsaturated polyester Polymers 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 102100027708 Astrotactin-1 Human genes 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 101000936741 Homo sapiens Astrotactin-1 Proteins 0.000 description 1
- 229920005479 Lucite® Polymers 0.000 description 1
- CJXGDWDDLMZNBC-UHFFFAOYSA-N P(O)(O)=O.P(O)(O)O Chemical compound P(O)(O)=O.P(O)(O)O CJXGDWDDLMZNBC-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 208000008765 Sciatica Diseases 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- JQZRVMZHTADUSY-UHFFFAOYSA-L di(octanoyloxy)tin Chemical compound [Sn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O JQZRVMZHTADUSY-UHFFFAOYSA-L 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920000140 heteropolymer Polymers 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- XAOIGBAYYHYZQA-UHFFFAOYSA-N tris(2-chloroethyl)phosphane Chemical group ClCCP(CCCl)CCCl XAOIGBAYYHYZQA-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0038—Use of organic additives containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/12—Organic materials containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US48317474A | 1974-01-30 | 1974-01-30 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2526805A1 DE2526805A1 (de) | 1976-01-15 |
| DE2526805B2 DE2526805B2 (de) | 1979-07-12 |
| DE2526805C3 true DE2526805C3 (de) | 1980-03-13 |
Family
ID=23918970
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2526805A Expired DE2526805C3 (de) | 1974-06-26 | 1975-06-16 | Phosphor enthaltende Flammschutzmittel, Verfahren zu deren Herstellung und deren Verwendung |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS6031218B2 (enrdf_load_stackoverflow) |
| CA (1) | CA1044854A (enrdf_load_stackoverflow) |
| DE (1) | DE2526805C3 (enrdf_load_stackoverflow) |
| FR (1) | FR2276345A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1503537A (enrdf_load_stackoverflow) |
| IT (1) | IT1039481B (enrdf_load_stackoverflow) |
| NL (1) | NL180516C (enrdf_load_stackoverflow) |
| ZA (1) | ZA754009B (enrdf_load_stackoverflow) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5958080A (ja) * | 1982-03-17 | 1984-04-03 | ペ・セ・ユ−・カ・プロデユイ・シミク・ユ−ジヌ・ク−ルマン | 含燐防火性化合物の混合物 |
| FR2532321B1 (fr) * | 1982-08-24 | 1985-09-13 | Ugine Kuhlmann | Melanges ignifugeants contenant du phosphore pour materiaux de synthese |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE790849Q (fr) * | 1970-02-02 | 1973-04-30 | Olin Corp | Nouveaux polyesters phosphoriques halogenes retardateurs d'inflammationet mousse de polyurethanne contenant ces polyesters |
-
1975
- 1975-05-23 CA CA227,613A patent/CA1044854A/en not_active Expired
- 1975-06-05 GB GB24272/75A patent/GB1503537A/en not_active Expired
- 1975-06-16 DE DE2526805A patent/DE2526805C3/de not_active Expired
- 1975-06-23 NL NLAANVRAGE7507483,A patent/NL180516C/xx not_active IP Right Cessation
- 1975-06-23 ZA ZA4009A patent/ZA754009B/xx unknown
- 1975-06-24 JP JP50077096A patent/JPS6031218B2/ja not_active Expired
- 1975-06-25 IT IT24765/75A patent/IT1039481B/it active
- 1975-06-26 FR FR7520132A patent/FR2276345A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| FR2276345B1 (enrdf_load_stackoverflow) | 1979-10-19 |
| FR2276345A1 (fr) | 1976-01-23 |
| AU8245975A (en) | 1977-01-06 |
| IT1039481B (it) | 1979-12-10 |
| DE2526805A1 (de) | 1976-01-15 |
| CA1044854A (en) | 1978-12-26 |
| JPS5118176A (enrdf_load_stackoverflow) | 1976-02-13 |
| GB1503537A (en) | 1978-03-15 |
| DE2526805B2 (de) | 1979-07-12 |
| NL180516C (nl) | 1987-03-02 |
| NL7507483A (nl) | 1975-12-30 |
| NL180516B (nl) | 1986-10-01 |
| JPS6031218B2 (ja) | 1985-07-20 |
| ZA754009B (en) | 1977-01-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2839710C2 (de) | Selbstverlöschende, polymere Massen | |
| DE2636133A1 (de) | Stabilisatoren fuer kunststoffe | |
| DE2501497A1 (de) | Polymerzusammensetzungen | |
| DE1273190B (de) | Verfahren zur Herstellung von Formkoerpern aus vernetzten Pfropfpolymerisaten | |
| EP0143175A1 (de) | Formaldehydfreie wässrige Kunststoffdispersionen auf Basis eines vernetzbaren Polymerisats, Verfahren zu ihrer Herstellung und ihre Verwendung | |
| DE2545789C3 (de) | Vernetzung von Polyolefinen | |
| DE3887551T2 (de) | Gebundene Antioxydationsvormischung. | |
| DE2928349B2 (de) | Flammschutzmittel für thermoplastische Kunststoffe | |
| DE2526805C3 (de) | Phosphor enthaltende Flammschutzmittel, Verfahren zu deren Herstellung und deren Verwendung | |
| DE2431434A1 (de) | Dielektrische polyolefinzusammensetzungen | |
| DE1136489B (de) | Verfahren zur Suspensionspolymerisation von Styrol | |
| DE1669669A1 (de) | Polyestermaterial und Verfahren zu seiner Herstellung | |
| DE2307387C3 (de) | Verwendung einer Dlcyclopentadienyleisenverbindung als Rauchunterdrückungszusatz in Polyvinylchlorid oder Polyurethan | |
| DE1469808C3 (de) | Thermoplastische Massen | |
| DE2152236C3 (de) | 23-Dibrompropyl-methyl-hydrogenphosphat, Verfahren zu dessen Herstellung sowie dasselbe enthaltende flammfeste Gemische | |
| DE69123400T2 (de) | Flammfeste Polyolefinfasern und Folien | |
| DE1914034C3 (de) | Verfahren zur Herstellung von vernetzten Polyolefinen | |
| DE3126179A1 (de) | Flammschutzmittel fuer polyphenylaetherharz | |
| EP0063768B1 (de) | Eine Kupferverbindung enthaltende Polyvinylchloridmischung | |
| DE1569444A1 (de) | Feste,stabilisierte Polymerenzusammensetzung | |
| DE2534793B2 (de) | Feuerhemmende Zubereitungen für Polyurethane | |
| DE2231243A1 (de) | Flammhemmende polymerisatzubereitungen | |
| DE1469899B2 (de) | Flammfeste Kunststoffe | |
| DE2512318C2 (de) | Verfahren zur Herstellung flammwidriger Formteile aus Harzfasermassen | |
| DE1669693B2 (de) | Flammverzögerungsmittel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8328 | Change in the person/name/address of the agent |
Free format text: KADOR, U., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 8000 MUENCHEN |
|
| 8327 | Change in the person/name/address of the patent owner |
Owner name: ALBRIGHT & WILSON, INC., RICHMOND, VA., US |
|
| 8328 | Change in the person/name/address of the agent |
Free format text: BERENDT, T., DIPL.-CHEM. DR. LEYH, H., DIPL.-ING. DR.-ING., PAT.-ANW., 8000 MUENCHEN |