DE2521723C3 - Verfahren und Vorrichtung zur Herstellung von reinem Argon durch Fraktionierung der Luft - Google Patents
Verfahren und Vorrichtung zur Herstellung von reinem Argon durch Fraktionierung der LuftInfo
- Publication number
- DE2521723C3 DE2521723C3 DE2521723A DE2521723A DE2521723C3 DE 2521723 C3 DE2521723 C3 DE 2521723C3 DE 2521723 A DE2521723 A DE 2521723A DE 2521723 A DE2521723 A DE 2521723A DE 2521723 C3 DE2521723 C3 DE 2521723C3
- Authority
- DE
- Germany
- Prior art keywords
- column
- argon
- product stream
- crude argon
- cooled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 title claims description 108
- 229910052786 argon Inorganic materials 0.000 title claims description 54
- 238000000034 method Methods 0.000 title claims description 20
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 34
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 19
- 239000001301 oxygen Substances 0.000 claims description 19
- 229910052760 oxygen Inorganic materials 0.000 claims description 19
- 229910052757 nitrogen Inorganic materials 0.000 claims description 17
- 238000000926 separation method Methods 0.000 claims description 8
- 238000005194 fractionation Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims 2
- 238000004378 air conditioning Methods 0.000 claims 1
- 230000006835 compression Effects 0.000 claims 1
- 238000007906 compression Methods 0.000 claims 1
- 238000009795 derivation Methods 0.000 claims 1
- 239000003507 refrigerant Substances 0.000 claims 1
- 239000000047 product Substances 0.000 description 13
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 241001076960 Argon Species 0.000 description 1
- 208000001836 Firesetting Behavior Diseases 0.000 description 1
- 235000003403 Limnocharis flava Nutrition 0.000 description 1
- 244000278243 Limnocharis flava Species 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 235000013876 argon Nutrition 0.000 description 1
- 238000007084 catalytic combustion reaction Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04642—Recovering noble gases from air
- F25J3/04648—Recovering noble gases from air argon
- F25J3/04654—Producing crude argon in a crude argon column
- F25J3/04666—Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04333—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/04369—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams of argon or argon enriched stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04642—Recovering noble gases from air
- F25J3/04648—Recovering noble gases from air argon
- F25J3/04654—Producing crude argon in a crude argon column
- F25J3/0466—Producing crude argon in a crude argon column as a parallel working rectification column or auxiliary column system in a single pressure main column system
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04642—Recovering noble gases from air
- F25J3/04648—Recovering noble gases from air argon
- F25J3/04721—Producing pure argon, e.g. recovered from a crude argon column
- F25J3/04727—Producing pure argon, e.g. recovered from a crude argon column using an auxiliary pure argon column for nitrogen rejection
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S62/00—Refrigeration
- Y10S62/923—Inert gas
- Y10S62/924—Argon
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Separation By Low-Temperature Treatments (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT21663/75A IT1034545B (it) | 1975-03-26 | 1975-03-26 | Processo ed impianto per l otte nimento dell argon a partire da un processo di frazionamento dell aria |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2521723A1 DE2521723A1 (de) | 1976-10-07 |
| DE2521723B2 DE2521723B2 (de) | 1980-12-04 |
| DE2521723C3 true DE2521723C3 (de) | 1981-07-02 |
Family
ID=11185011
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2521723A Expired DE2521723C3 (de) | 1975-03-26 | 1975-05-15 | Verfahren und Vorrichtung zur Herstellung von reinem Argon durch Fraktionierung der Luft |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4057407A (enExample) |
| JP (1) | JPS51120978A (enExample) |
| CA (1) | CA1026227A (enExample) |
| DE (1) | DE2521723C3 (enExample) |
| FR (1) | FR2305701A1 (enExample) |
| GB (1) | GB1533144A (enExample) |
| IT (1) | IT1034545B (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4395310A (en) * | 1981-07-14 | 1983-07-26 | Exxon Research And Engineering Co. | Fractionation system |
| US4433990A (en) | 1981-12-08 | 1984-02-28 | Union Carbide Corporation | Process to recover argon from oxygen-only air separation plant |
| JPS59150286A (ja) * | 1983-02-15 | 1984-08-28 | 日本酸素株式会社 | アルゴンの製造方法 |
| US4623370A (en) * | 1984-09-11 | 1986-11-18 | Aeci Limited | Gas treatment process |
| GB8800842D0 (en) * | 1988-01-14 | 1988-02-17 | Boc Group Plc | Air separation |
| US4838913A (en) * | 1988-02-10 | 1989-06-13 | Union Carbide Corporation | Double column air separation process with hybrid upper column |
| US4838785A (en) * | 1988-07-05 | 1989-06-13 | Cameron Forge Company | Walking beam furnace insulation |
| DE3840506A1 (de) * | 1988-12-01 | 1990-06-07 | Linde Ag | Verfahren und vorrichtung zur luftzerlegung |
| CN1025067C (zh) * | 1989-02-23 | 1994-06-15 | 琳德股份公司 | 精馏分离空气的方法及装置 |
| US5207066A (en) * | 1991-10-22 | 1993-05-04 | Bova Vitaly I | Method of air separation |
| US5228296A (en) * | 1992-02-27 | 1993-07-20 | Praxair Technology, Inc. | Cryogenic rectification system with argon heat pump |
| DE4317916A1 (de) * | 1993-05-28 | 1994-12-01 | Linde Ag | Verfahren und Vorrichtung zur Gewinnung von Argon |
| RU2137994C1 (ru) * | 1998-01-05 | 1999-09-20 | Машанов Александр Михайлович | Установка разделения воздуха |
| RU2231723C2 (ru) * | 2002-07-29 | 2004-06-27 | Санкт-Петербургский государственный университет низкотемпературных и пищевых технологий | Способ получения чистого аргона методом ректификации воздуха |
| FR3074274B1 (fr) * | 2017-11-29 | 2020-01-31 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede et appareil de separation d'air par distillation cryogenique |
| CN110451467B (zh) * | 2019-08-30 | 2022-09-16 | 苏州成于思气体科技有限公司 | 一种多工况氩气回收装置 |
| EP4455588A1 (en) * | 2023-04-24 | 2024-10-30 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process and apparatus for the separation of air by cryogenic distillation |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2530602A (en) * | 1946-12-12 | 1950-11-21 | Air Reduction | Recovery of the constituents of gaseous mixtures |
| FR980658A (fr) * | 1948-02-12 | 1951-05-16 | British Oxygen Co Ltd | Procédé de séparation fractionnée de l'air |
| DE844017C (de) * | 1949-06-09 | 1952-07-14 | Linde Eismasch Ag | Verfahren zur Herstellung eines fuer die Fuellung von Gluehlampen geeigneten Argons |
| BE495886A (enExample) * | 1949-06-20 | |||
| DE930033C (de) * | 1953-04-12 | 1956-03-08 | Adolf Messer G M B H | Verfahren zur Argonerzeugung |
| US2909410A (en) * | 1955-05-19 | 1959-10-20 | Air Prod Inc | Recovery of argon from an oxygen containing crude argon mixture |
| US3037359A (en) * | 1958-10-21 | 1962-06-05 | American Messer Corp | Rare gas recovery process |
| JPS5241235B2 (enExample) * | 1971-12-23 | 1977-10-17 |
-
1975
- 1975-03-26 IT IT21663/75A patent/IT1034545B/it active
- 1975-05-15 DE DE2521723A patent/DE2521723C3/de not_active Expired
-
1976
- 1976-03-22 GB GB11537/76A patent/GB1533144A/en not_active Expired
- 1976-03-22 US US05/669,420 patent/US4057407A/en not_active Expired - Lifetime
- 1976-03-25 CA CA248,767A patent/CA1026227A/en not_active Expired
- 1976-03-26 JP JP51032712A patent/JPS51120978A/ja active Pending
- 1976-03-26 FR FR7608826A patent/FR2305701A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS51120978A (en) | 1976-10-22 |
| US4057407A (en) | 1977-11-08 |
| FR2305701B1 (enExample) | 1980-04-30 |
| IT1034545B (it) | 1979-10-10 |
| CA1026227A (en) | 1978-02-14 |
| GB1533144A (en) | 1978-11-22 |
| DE2521723A1 (de) | 1976-10-07 |
| FR2305701A1 (fr) | 1976-10-22 |
| DE2521723B2 (de) | 1980-12-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8328 | Change in the person/name/address of the agent |
Free format text: SPOTT, G., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 8000 MUENCHEN |
|
| 8339 | Ceased/non-payment of the annual fee |