DE2502940C2 - Chrom- und phoshorhaltiger Trägerkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Polymerisation von Äthylen und zu deren Copolymerisation mit α-Olefinen - Google Patents
Chrom- und phoshorhaltiger Trägerkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Polymerisation von Äthylen und zu deren Copolymerisation mit α-OlefinenInfo
- Publication number
- DE2502940C2 DE2502940C2 DE2502940A DE2502940A DE2502940C2 DE 2502940 C2 DE2502940 C2 DE 2502940C2 DE 2502940 A DE2502940 A DE 2502940A DE 2502940 A DE2502940 A DE 2502940A DE 2502940 C2 DE2502940 C2 DE 2502940C2
- Authority
- DE
- Germany
- Prior art keywords
- chromium
- catalyst
- polymerization
- ethylene
- bar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims description 105
- 238000006116 polymerization reaction Methods 0.000 title description 47
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title description 29
- 239000005977 Ethylene Substances 0.000 title description 29
- 238000000034 method Methods 0.000 title description 12
- 238000007334 copolymerization reaction Methods 0.000 title description 4
- 238000002360 preparation method Methods 0.000 title description 4
- 239000004711 α-olefin Substances 0.000 title description 4
- ZTPQLYJGPLYBPS-UHFFFAOYSA-N phosphanylidynechromium Chemical compound [Cr]#P ZTPQLYJGPLYBPS-UHFFFAOYSA-N 0.000 title description 2
- 239000011651 chromium Substances 0.000 claims description 69
- 229910052804 chromium Inorganic materials 0.000 claims description 48
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 41
- 150000001845 chromium compounds Chemical class 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 description 37
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 35
- -1 phosphorus compound Chemical class 0.000 description 33
- 239000011148 porous material Substances 0.000 description 29
- 239000002904 solvent Substances 0.000 description 23
- 229910002027 silica gel Inorganic materials 0.000 description 22
- 239000000741 silica gel Substances 0.000 description 22
- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 22
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 20
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 18
- 239000000155 melt Substances 0.000 description 17
- 239000000243 solution Substances 0.000 description 17
- 239000004698 Polyethylene Substances 0.000 description 16
- 229910052782 aluminium Inorganic materials 0.000 description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 16
- 239000003638 chemical reducing agent Substances 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 16
- 239000000499 gel Substances 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 16
- 229920000573 polyethylene Polymers 0.000 description 16
- 239000011347 resin Substances 0.000 description 16
- 229920005989 resin Polymers 0.000 description 16
- 238000003756 stirring Methods 0.000 description 16
- WGLPBDUCMAPZCE-UHFFFAOYSA-N chromium trioxide Inorganic materials O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 15
- 229910052739 hydrogen Inorganic materials 0.000 description 14
- 239000001257 hydrogen Substances 0.000 description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 12
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 11
- 229910052796 boron Inorganic materials 0.000 description 11
- 230000000694 effects Effects 0.000 description 11
- 229940117975 chromium trioxide Drugs 0.000 description 10
- GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 10
- 239000001282 iso-butane Substances 0.000 description 10
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- 229910019142 PO4 Inorganic materials 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 235000021317 phosphate Nutrition 0.000 description 8
- 229910052698 phosphorus Inorganic materials 0.000 description 8
- 239000012298 atmosphere Substances 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 7
- 238000000265 homogenisation Methods 0.000 description 7
- 239000010452 phosphate Substances 0.000 description 7
- 239000011574 phosphorus Substances 0.000 description 7
- 239000000377 silicon dioxide Substances 0.000 description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 239000012876 carrier material Substances 0.000 description 5
- 229910000423 chromium oxide Inorganic materials 0.000 description 5
- 238000005336 cracking Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 238000000071 blow moulding Methods 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000008018 melting Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 230000037048 polymerization activity Effects 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 3
- OAKXLGLPTIXIQR-UHFFFAOYSA-N C(C)P(=O)(CC)[Cr] Chemical compound C(C)P(=O)(CC)[Cr] OAKXLGLPTIXIQR-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 241001233037 catfish Species 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 229910002028 silica xerogel Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JWEBUHOWLWXKGY-UHFFFAOYSA-N C(CCC)P(=O)(CCCC)[Cr] Chemical compound C(CCC)P(=O)(CCCC)[Cr] JWEBUHOWLWXKGY-UHFFFAOYSA-N 0.000 description 1
- UJDSUWSZINMRNB-UHFFFAOYSA-N C=C.CC(C)C.CC(C)C Chemical group C=C.CC(C)C.CC(C)C UJDSUWSZINMRNB-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 240000004385 Centaurea cyanus Species 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- JYFHYPJRHGVZDY-UHFFFAOYSA-N Dibutyl phosphate Chemical compound CCCCOP(O)(=O)OCCCC JYFHYPJRHGVZDY-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CQBWEBXPMRPCSI-UHFFFAOYSA-M O[Cr](O[SiH3])(=O)=O Chemical compound O[Cr](O[SiH3])(=O)=O CQBWEBXPMRPCSI-UHFFFAOYSA-M 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- QRRWWGNBSQSBAM-UHFFFAOYSA-N alumane;chromium Chemical compound [AlH3].[Cr] QRRWWGNBSQSBAM-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229940090961 chromium dioxide Drugs 0.000 description 1
- IAQWMWUKBQPOIY-UHFFFAOYSA-N chromium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Cr+4] IAQWMWUKBQPOIY-UHFFFAOYSA-N 0.000 description 1
- AYTAKQFHWFYBMA-UHFFFAOYSA-N chromium(IV) oxide Inorganic materials O=[Cr]=O AYTAKQFHWFYBMA-UHFFFAOYSA-N 0.000 description 1
- AHXGRMIPHCAXFP-UHFFFAOYSA-L chromyl dichloride Chemical compound Cl[Cr](Cl)(=O)=O AHXGRMIPHCAXFP-UHFFFAOYSA-L 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- GCPCLEKQVMKXJM-UHFFFAOYSA-N ethoxy(diethyl)alumane Chemical compound CCO[Al](CC)CC GCPCLEKQVMKXJM-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 229910002053 high pore volume silica gel Inorganic materials 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 150000002485 inorganic esters Chemical class 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920001179 medium density polyethylene Polymers 0.000 description 1
- 239000004701 medium-density polyethylene Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 229910003452 thorium oxide Inorganic materials 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US43626374A | 1974-01-24 | 1974-01-24 | |
| US05/532,131 US3985676A (en) | 1974-01-24 | 1974-12-16 | Catalyst composition and method for the preparation thereof |
| NLAANVRAGE7500761,A NL179912C (nl) | 1974-01-24 | 1975-01-22 | Werkwijze ter bereiding van een alkeenpolymerisatiekatalysator. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2502940A1 DE2502940A1 (de) | 1975-08-07 |
| DE2502940C2 true DE2502940C2 (de) | 1985-12-19 |
Family
ID=27351960
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2502940A Expired DE2502940C2 (de) | 1974-01-24 | 1975-01-24 | Chrom- und phoshorhaltiger Trägerkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Polymerisation von Äthylen und zu deren Copolymerisation mit α-Olefinen |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US3985676A (en, 2012) |
| JP (1) | JPS5821643B2 (en, 2012) |
| AT (1) | AT339040B (en, 2012) |
| AU (1) | AU7727775A (en, 2012) |
| BR (1) | BR7500466A (en, 2012) |
| CA (1) | CA1084480A (en, 2012) |
| CH (1) | CH606126A5 (en, 2012) |
| CS (2) | CS196260B2 (en, 2012) |
| DE (1) | DE2502940C2 (en, 2012) |
| DK (2) | DK20075A (en, 2012) |
| FI (1) | FI60879C (en, 2012) |
| FR (1) | FR2259112B1 (en, 2012) |
| GB (1) | GB1490141A (en, 2012) |
| NL (1) | NL179912C (en, 2012) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5159667A (en, 2012) * | 1974-11-21 | 1976-05-24 | Suwa Seikosha Kk | |
| US4049896A (en) * | 1975-03-14 | 1977-09-20 | National Petro Chemicals Corporation | Olefin polymerization catalyst |
| US4184028A (en) * | 1975-03-14 | 1980-01-15 | National Petro Chemicals Corporation | Olefin Polymerization catalyst |
| US4192775A (en) * | 1975-03-14 | 1980-03-11 | National Petro Chemicals Corporation | Olefin polymerization catalyst |
| US4053437A (en) * | 1976-03-04 | 1977-10-11 | Chemplex Company | Polyolefin catalyst and method for its preparation |
| US4234709A (en) * | 1976-05-07 | 1980-11-18 | National Petro Chemicals Corporation | Catalyst composition, method for producing same and method for polymerization of 1-olefins with same |
| NL171273C (nl) * | 1976-05-24 | 1983-03-01 | Stamicarbon | Werkwijze voor het polymeriseren van alkenen en werkwijze voor het bereiden van een chroomoxyde-op drager-katalysator. |
| US4118340A (en) * | 1976-06-07 | 1978-10-03 | National Distillers And Chemical Corporation | Novel polymerization catalyst |
| US4290914A (en) * | 1977-01-13 | 1981-09-22 | National Petro Chemicals Corp. | Catalytic materials as for olefin polymerization |
| US4100104A (en) * | 1977-01-13 | 1978-07-11 | National Petro Chemicals Corporation | Catalytic materials as for olefin polymerization |
| AU3589578A (en) * | 1977-05-25 | 1979-11-15 | Nat Petro Chem | Supported heat activated chromium containing catalyst containing polymeric h/c aluminate |
| US4593079A (en) * | 1977-05-25 | 1986-06-03 | National Distillers And Chemical Corporation | Resin rheology control process and catalyst therefor |
| US4115318A (en) * | 1977-06-09 | 1978-09-19 | National Petro Chemicals Corporation | Olefin polymerization catalyst |
| US4238353A (en) * | 1978-07-14 | 1980-12-09 | National Petro Chemicals Corp. | Olefin polymerization catalyst |
| US4252926A (en) * | 1978-08-07 | 1981-02-24 | National Petro Chemicals Corp. | Process for polymerizing olefins and polymerization catalysts used therefor |
| US4312786A (en) * | 1978-08-07 | 1982-01-26 | National Petro Chemicals Corp. | Process for polymerizing olefins and polymerization catalysts used therefor |
| US4297461A (en) * | 1979-06-08 | 1981-10-27 | National Petro Chemicals Corp. | Olefin polymerization catalyst |
| US4260706A (en) * | 1979-06-21 | 1981-04-07 | National Petro Chemicals Corp. | Olefin polymerization catalyst |
| US4356294A (en) * | 1980-10-24 | 1982-10-26 | National Petro Chemicals Corp. | Production of polyolefins having improved ESCR |
| US4444963A (en) * | 1980-12-31 | 1984-04-24 | Phillips Petroleum Company | Polymerization process using catalysts comprising chromium on silica/phosphate support |
| US4364839A (en) * | 1980-12-31 | 1982-12-21 | Phillips Petroleum Company | Catalyst comprising chromium on silica/phosphate support |
| US4328124A (en) * | 1981-01-26 | 1982-05-04 | National Petro Chemicals Corp. | Olefin polymerization catalyst and process |
| US4404340A (en) * | 1981-01-26 | 1983-09-13 | National Petro Chemicals Corporation | Process for polymerizing olefins in the presence of a titanium-phosphorus-chromium catalyst |
| US4496699A (en) * | 1981-03-13 | 1985-01-29 | National Distillers And Chemical Corporation | Process for polymerizing high melt index olefins and polymerization catalysts used therefore |
| EP0067607B1 (en) * | 1981-06-02 | 1987-01-21 | Asahi Kasei Kogyo Kabushiki Kaisha | A catalyst for polymerization of olefins |
| US4460698A (en) * | 1981-11-13 | 1984-07-17 | Standard Oil Company (Indiana) | Hydrocarbon conversion catalyst |
| US4540755A (en) * | 1982-09-30 | 1985-09-10 | National Petro Chemicals Corporation | Inclusion of oxygen in the polymerization of olefins |
| DE3618259A1 (de) * | 1986-05-30 | 1987-12-03 | Basf Ag | Verfahren zum herstellen von homo- sowie copolymerisaten des ethens durch phillips-katalyse |
| JPS63176463U (en, 2012) * | 1987-05-01 | 1988-11-16 | ||
| US5081089A (en) * | 1987-05-20 | 1992-01-14 | National Distillers And Chemical Corporation | Chromium catalyst compositions and polymerization utilizing same |
| US5310834A (en) * | 1987-05-20 | 1994-05-10 | Quantum Chemical Corporation | Mixed chromium catalysts and polymerizations utilizing same |
| US5198400A (en) * | 1987-05-20 | 1993-03-30 | Quantum Chemical Corporation | Mixed chromium catalysts and polymerizations utilizing same |
| US5486575A (en) * | 1994-03-08 | 1996-01-23 | Quantum Chemical Corporation | High performance blow molding resins and process for their preparation |
| USH1600H (en) * | 1995-03-27 | 1996-10-01 | Quantum Chemical Company | High density polyethylenes with improved processing stability |
| US7238765B2 (en) * | 2003-02-06 | 2007-07-03 | Equistar Chemicals, Lp | High density polyethylene and insulation compositions for wire and cable |
| US7151073B2 (en) * | 2004-01-16 | 2006-12-19 | Exxonmobil Chemical Patents Inc. | Mesoporous catalyst support, a catalyst system, and method of making and using same for olefin polymerization |
| GB0720983D0 (en) * | 2007-10-26 | 2007-12-05 | Ineos Silicas Ltd | Catalyst particles their preparation and use |
| US8247342B2 (en) * | 2008-07-23 | 2012-08-21 | Al-Arifi Abdullah Saad N | Polymer supported chrome catalyst for olefins polymerization |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE553439A (en, 2012) * | 1955-12-16 | 1900-01-01 | ||
| US3474080A (en) * | 1966-06-27 | 1969-10-21 | Nat Distillers Chem Corp | Catalytic process for olefin polymerization |
| US3704287A (en) * | 1970-09-17 | 1972-11-28 | Union Carbide Corp | High temperature reduced catalyst and process |
| US3907849A (en) * | 1972-12-29 | 1975-09-23 | Anderson Dev Co | Chromium tris-diorgano-orthophosphates and their preparation |
-
1974
- 1974-12-16 US US05/532,131 patent/US3985676A/en not_active Expired - Lifetime
-
1975
- 1975-01-10 CA CA217,694A patent/CA1084480A/en not_active Expired
- 1975-01-14 AU AU77277/75A patent/AU7727775A/en not_active Expired
- 1975-01-17 FR FR7501492A patent/FR2259112B1/fr not_active Expired
- 1975-01-22 NL NLAANVRAGE7500761,A patent/NL179912C/xx not_active IP Right Cessation
- 1975-01-23 AT AT50775A patent/AT339040B/de not_active IP Right Cessation
- 1975-01-23 BR BR466/75A patent/BR7500466A/pt unknown
- 1975-01-23 DK DK20075*#A patent/DK20075A/da unknown
- 1975-01-24 CS CS75503A patent/CS196260B2/cs unknown
- 1975-01-24 CH CH88375A patent/CH606126A5/xx not_active IP Right Cessation
- 1975-01-24 CS CS75503A patent/CS205138B2/cs unknown
- 1975-01-24 JP JP50009927A patent/JPS5821643B2/ja not_active Expired
- 1975-01-24 FI FI750190A patent/FI60879C/fi not_active IP Right Cessation
- 1975-01-24 GB GB3249/75A patent/GB1490141A/en not_active Expired
- 1975-01-24 DE DE2502940A patent/DE2502940C2/de not_active Expired
- 1975-12-29 DK DK592275A patent/DK592275A/da not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| NL179912C (nl) | 1986-12-01 |
| NL7500761A (nl) | 1975-07-28 |
| FI60879B (fi) | 1981-12-31 |
| CH606126A5 (en, 2012) | 1978-11-15 |
| GB1490141A (en) | 1977-10-26 |
| AU7727775A (en) | 1976-07-15 |
| FI60879C (fi) | 1982-04-13 |
| DE2502940A1 (de) | 1975-08-07 |
| CS196260B2 (en) | 1980-03-31 |
| CS205138B2 (en) | 1981-04-30 |
| FR2259112B1 (en, 2012) | 1980-04-04 |
| AT339040B (de) | 1977-09-26 |
| ATA50775A (de) | 1977-01-15 |
| BR7500466A (pt) | 1975-12-16 |
| FR2259112A1 (en, 2012) | 1975-08-22 |
| JPS5821643B2 (ja) | 1983-05-02 |
| DK592275A (da) | 1975-12-29 |
| CA1084480A (en) | 1980-08-26 |
| US3985676A (en) | 1976-10-12 |
| FI750190A7 (en, 2012) | 1975-07-25 |
| DK20075A (en, 2012) | 1975-09-22 |
| JPS50108189A (en, 2012) | 1975-08-26 |
| NL179912B (nl) | 1986-07-01 |
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