DE249225T1 - Verfahren zur herstellung eines pfropfcopolymers. - Google Patents

Verfahren zur herstellung eines pfropfcopolymers.

Info

Publication number
DE249225T1
DE249225T1 DE198787108424T DE87108424T DE249225T1 DE 249225 T1 DE249225 T1 DE 249225T1 DE 198787108424 T DE198787108424 T DE 198787108424T DE 87108424 T DE87108424 T DE 87108424T DE 249225 T1 DE249225 T1 DE 249225T1
Authority
DE
Germany
Prior art keywords
fluorine
methacrylate
copolymer
acrylate
process according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE198787108424T
Other languages
English (en)
Inventor
Kobayashi Hitachi-Shi Kengo
Ohwada Taga-Gun Ibaraki-Ken Takeo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Corp
Original Assignee
Hitachi Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Chemical Co Ltd filed Critical Hitachi Chemical Co Ltd
Publication of DE249225T1 publication Critical patent/DE249225T1/de
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/06—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6275—Polymers of halogen containing compounds having carbon-to-carbon double bonds; halogenated polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6279—Polymers of halogen containing compounds having carbon-to-carbon double bonds; halogenated polymers of compounds having carbon-to-carbon double bonds containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
    • C08G18/8116—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group esters of acrylic or alkylacrylic acid having only one isocyanate or isothiocyanate group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
    • C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
    • C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/92—Polyurethane having terminal ethylenic unsaturation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Paints Or Removers (AREA)
  • Graft Or Block Polymers (AREA)

Claims (8)

87 108 424.0: / 60 41 AW/ws PATENTANSPRÜCHE
1. Verfahren zur Herstellung eines Pfropfcopolymeren, dadurch gekenhz eichnet , daß man 99,5 bis 0,5 Gewichtsprozent eines ethylenisch ungesättigten Monomeren (B), das mit Doppelbindung des Harzes (A) copolymerisierbar ist,in Anwesenheit von 0,5 bis 99,5 Gewichtsprozent eines fluorenthaltenden Harzes (A), welches reaktive Doppelbindungen via eine Uranbindung in einer Menge von 0,001 bis 0f025 Mol pro 100 g des Harzes (A) enthält polymerisiert.
2. Verfahren nach Anspruch 1, dadurch gekennzeichnet , daß das fluorenthaltende Harz (A) durch Umsetzung eines fluorenthaltenden Copolymeren mit Hydroxylgruppen, einer mehrwertigen Isocyanatverbindung, die zwei oder mehr Isocyanatgruppen enthält, und eines ethylenisch ungesättigten Monomeren, das eine Hydroxylgruppe enthält, erhalten wird.
3. . Verfahren nach Anspruch 1, dadurch g e k e &eegr; &eegr; ze i c hn e t , daß das fluorenthaltende Harz (A) durch Umsetzung eines fluorenthaltenden Copolymeren mit Hydroxylgruppen mit einem ethylenisch ungesättigten Monomeren, das Isocyanatgruppen enthält, erhalten worden ist.
4. Verfahren nach Anspruch 2, dadurch gekennzeichnet , daß das fluorenthaltende Copolymere, welches Hydroxylgruppen enthält, eine Hydroxylzahl von 0,57 bis 250 und einen Fluorgehalt von 1 bis 60 Gewichtsprozent besitzt.
5. Verfahren nach Anspruch 4, dadurch gekennzeichnet, daß das fluorenthaltende Copolymere, das Hydroxylgruppen enthält, ein Copolymeres ist, welches
als wesentliche Komponenten ein Fluorolefin, einen Hydroxyalkylvinylether und einen Alkylvinylether oder einen Cycloalkylvinylether enthält.
6. Verfahren nach Anspruch 3, dadurch gekennzeichnet , daß das fluorenthaltende Copolymere, das Hydroxylgruppen enthält, eine Hydroxylzahl von 0,57 bis 250 und einen Fluorgehalt von 1 bis 60 Gewichtsprozent aufweist.
7. Verfahren nach Anspruch 6, dadurch g e ken &eegr; zeichnet , daß das fluorenthaltende Copolymere, das Hydroxylgruppen enthält, ein Copolymeres ist, das als wesentliche Komponenten ein Fluorolefin, einen Hydroxyalkylvinylether und einen Alkylvinylether oder einen Cycloalkylvinylether enthält.
8. Verfahren nach Anspruch 1, dadurch gekennzeichnet , daß das ethylenisch ungesättigte Monomere mindestens eine Verbindung, ausgewählt aus der Gruppe Methylacrylat, Ethylacrylat, Butylacrylat, Isopropylacrylat, 2-Ethylhexylacrylat, Methylmethacrylat, Ethylmethacrylat, Butylmethacrylat, Isopropylmethacrylat, 2-Ethylhexylmethacrylat, Styrol, Vinyltoluol, a-Methylstyrol, Chlorstyrol, Acrylnitril, Methacrylnitril, Vinylchlorid, Vinylacetat, Dimethylmaleat, 2-Hydroxyethylacrylat, 2-Hydroxyethylmethacrylat, 2-Hydroxypropylacrylat, 2-Hydroxypropylmethacrylat, Monoacrylat von Glycerin, Monomethacrylat von Glycerin, Monoacrylat von Trimethylolpropan, Monomethacrylat von Trimethylolpropan, N-Methylolacrylamid and N-Methylolmethacrylamid, ist.
DE198787108424T 1986-06-13 1987-06-11 Verfahren zur herstellung eines pfropfcopolymers. Pending DE249225T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61138724A JPS62295914A (ja) 1986-06-13 1986-06-13 グラフト共重合体の製造法

Publications (1)

Publication Number Publication Date
DE249225T1 true DE249225T1 (de) 1988-06-09

Family

ID=15228667

Family Applications (2)

Application Number Title Priority Date Filing Date
DE8787108424T Expired - Lifetime DE3768708D1 (de) 1986-06-13 1987-06-11 Verfahren zur herstellung eines pfropfcopolymers.
DE198787108424T Pending DE249225T1 (de) 1986-06-13 1987-06-11 Verfahren zur herstellung eines pfropfcopolymers.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE8787108424T Expired - Lifetime DE3768708D1 (de) 1986-06-13 1987-06-11 Verfahren zur herstellung eines pfropfcopolymers.

Country Status (4)

Country Link
US (2) US4923929A (de)
EP (1) EP0249225B1 (de)
JP (1) JPS62295914A (de)
DE (2) DE3768708D1 (de)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5202394A (en) * 1987-09-24 1993-04-13 Hoechst Ag Graft polymers with a polyurethane graft base, processes for their preparation and their use
JPH01113451A (ja) * 1987-10-27 1989-05-02 Dainippon Toryo Co Ltd 塗料用樹脂組成物
JPH02144179A (ja) * 1988-11-22 1990-06-01 Bou Kojima 被塗装物へのポリテトラフルオロエチレン系塗料のコーティング方法
KR940003863B1 (ko) * 1991-01-07 1994-05-04 한국과학기술연구원 혈액적합성이 개선된 불소화 폴리우레탄
JPH06113906A (ja) * 1992-10-02 1994-04-26 Maruzen Byora:Kk くつ鋲の製造方法
DE69402993T2 (de) * 1993-01-21 1997-10-23 Akzo Nobel Nv Wasserdispergierbares Hybridpolymer
JP2882737B2 (ja) * 1993-10-19 1999-04-12 昭和高分子株式会社 含フッ素重合体の製造方法
DE69435291D1 (de) * 1993-10-28 2010-06-10 Asahi Glass Co Ltd Fluorid-enthaltender Polymerklebstoff und diesen gebrauchendes Laminat
US5424364A (en) * 1994-05-17 1995-06-13 E. I. Du Pont De Nemours & Company Comb pigment dispersants
FR2733503B1 (fr) * 1995-04-28 1997-07-18 Gen Electric Plastics Abs Euro Utilisation d'alliage polymere a base de polymerisat de tetrafluorethylene comme auxiliaire de traitement de certaines resines
EP0812864A3 (de) * 1996-06-11 1998-09-23 Central Glass Company, Limited Fluor enthaltendes Harz für einen Aufstrichstoff
KR100466355B1 (ko) * 1996-07-31 2005-06-16 미쯔비시 레이온 가부시끼가이샤 폴리테트라플루오로에틸렌함유혼합분체,이를함유하는열가소성수지조성물및그성형체
KR20120110143A (ko) * 2009-12-28 2012-10-09 미쯔비시 레이온 가부시끼가이샤 방오 도료용 수지 분산체의 제조 방법
CN109485796B (zh) * 2018-10-17 2021-04-23 沈阳化工大学 一种橡胶制品表面涂覆水溶性固化特氟龙材料及其制备方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE570822A (de) * 1957-09-02
US3090664A (en) * 1958-03-31 1963-05-21 Du Pont Graft polymerizing an unsaturated organic acid or salt thereof onto a nitrogen containing polymer substrate
US3356628A (en) * 1964-12-01 1967-12-05 Minnesota Mining & Mfg Copolymers of perfluoro acrylates and hydroxy alkyl acrylates
US3488268A (en) * 1965-12-02 1970-01-06 Du Pont Irradiation process for preparing graft copolymers
US3632796A (en) * 1969-02-11 1972-01-04 Scm Corp Saturated linear polymers having plural pendant ethylenic unsaturation
US3607974A (en) * 1969-02-11 1971-09-21 Scm Corp Thermosetting resin containing pendant unsaturation and monomer where monomer and pendency have identical functionality
US3719638A (en) * 1969-10-29 1973-03-06 T Miranda Radiation curable acrylic urethane monomers
JPS4948190B1 (de) * 1971-03-04 1974-12-19
DE2638666A1 (de) * 1976-08-27 1978-03-02 Volkswagenwerk Ag Kraftstoff-einspritzeinrichtung
US4233425A (en) * 1978-11-15 1980-11-11 The Dow Chemical Company Addition polymerizable polyethers having pendant ethylenically unsaturated urethane groups
CA1156795A (en) * 1979-04-11 1983-11-08 Richard G. Newell Curable fluorocarbon substituted polyetherurethaneacrylates
JPS59230020A (ja) * 1983-06-14 1984-12-24 Showa Highpolymer Co Ltd 硬化可能な樹脂の製法
JPS59230019A (ja) * 1983-06-14 1984-12-24 Showa Highpolymer Co Ltd 硬化可能な樹脂の製法
JPS60197719A (ja) * 1984-03-19 1985-10-07 Showa Highpolymer Co Ltd 硬化可能な樹脂の製造方法
US4552932A (en) * 1984-04-30 1985-11-12 The B. F. Goodrich Company Radiation curable polyurethanes
US4572610A (en) * 1984-05-21 1986-02-25 Desoto, Inc. Optical fiber buffer coated with halogenated dihydroxy-terminated polybutadienes
JPS60245552A (ja) * 1984-05-21 1985-12-05 日本カーバイド工業株式会社 紫外線遮蔽性樹脂フイルム
JPH0635559B2 (ja) * 1985-06-25 1994-05-11 旭硝子株式会社 塗料用組成物

Also Published As

Publication number Publication date
EP0249225A3 (en) 1988-07-20
DE3768708D1 (de) 1991-04-25
JPH0228607B2 (de) 1990-06-25
EP0249225B1 (de) 1991-03-20
EP0249225A2 (de) 1987-12-16
US5087675A (en) 1992-02-11
JPS62295914A (ja) 1987-12-23
US4923929A (en) 1990-05-08

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