DE2361653A1 - Verfahren zur herstellung von schmieroelen mit hohem viskositaetsindex - Google Patents
Verfahren zur herstellung von schmieroelen mit hohem viskositaetsindexInfo
- Publication number
- DE2361653A1 DE2361653A1 DE19732361653 DE2361653A DE2361653A1 DE 2361653 A1 DE2361653 A1 DE 2361653A1 DE 19732361653 DE19732361653 DE 19732361653 DE 2361653 A DE2361653 A DE 2361653A DE 2361653 A1 DE2361653 A1 DE 2361653A1
- Authority
- DE
- Germany
- Prior art keywords
- fraction
- feed
- oil
- oils
- peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010687 lubricating oil Substances 0.000 title claims description 112
- 238000000034 method Methods 0.000 title claims description 54
- 238000004519 manufacturing process Methods 0.000 title claims description 25
- 230000008569 process Effects 0.000 title claims description 24
- 239000003921 oil Substances 0.000 claims description 112
- 238000009835 boiling Methods 0.000 claims description 93
- 150000002978 peroxides Chemical class 0.000 claims description 66
- 239000002480 mineral oil Substances 0.000 claims description 64
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 64
- 235000010446 mineral oil Nutrition 0.000 claims description 62
- 239000012188 paraffin wax Substances 0.000 claims description 51
- 239000000654 additive Substances 0.000 claims description 45
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 32
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 32
- 239000000047 product Substances 0.000 claims description 31
- 230000000996 additive effect Effects 0.000 claims description 26
- 239000000284 extract Substances 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 22
- 150000005673 monoalkenes Chemical class 0.000 claims description 19
- 239000002199 base oil Substances 0.000 claims description 17
- 238000004821 distillation Methods 0.000 claims description 15
- 239000010779 crude oil Substances 0.000 claims description 10
- 239000010721 machine oil Substances 0.000 claims description 9
- 239000001993 wax Substances 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 239000012263 liquid product Substances 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 6
- 238000003776 cleavage reaction Methods 0.000 claims description 4
- 239000003208 petroleum Substances 0.000 claims description 4
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 3
- 230000001050 lubricating effect Effects 0.000 claims description 3
- 230000004992 fission Effects 0.000 claims 1
- 239000007858 starting material Substances 0.000 description 12
- 230000015556 catabolic process Effects 0.000 description 10
- 150000003585 thioureas Chemical class 0.000 description 8
- 238000006731 degradation reaction Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000007789 gas Substances 0.000 description 6
- 239000010707 multi-grade lubricating oil Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000007670 refining Methods 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 229920000297 Rayon Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 150000001451 organic peroxides Chemical class 0.000 description 3
- 230000007017 scission Effects 0.000 description 3
- 239000010706 single-grade lubricating oil Substances 0.000 description 3
- 238000013459 approach Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- ZQMIGQNCOMNODD-UHFFFAOYSA-N diacetyl peroxide Chemical compound CC(=O)OOC(C)=O ZQMIGQNCOMNODD-UHFFFAOYSA-N 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 231100000989 no adverse effect Toxicity 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- ZMMYZOSYBMIWIR-UHFFFAOYSA-N 2,2,4-trimethyl-4-(2,4,4-trimethylpentan-2-ylperoxy)pentane Chemical compound CC(C)(C)CC(C)(C)OOC(C)(C)CC(C)(C)C ZMMYZOSYBMIWIR-UHFFFAOYSA-N 0.000 description 1
- MIISCOKFJAVBTF-UHFFFAOYSA-N 2-tert-butylperoxy-2-methylbutane;2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical compound CCC(C)(C)OOC(C)(C)C.CCC(C)(C)OOC(C)(C)CC MIISCOKFJAVBTF-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005069 Extreme pressure additive Substances 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- RHMZKSWPMYAOAZ-UHFFFAOYSA-N diethyl peroxide Chemical compound CCOOCC RHMZKSWPMYAOAZ-UHFFFAOYSA-N 0.000 description 1
- SRXOCFMDUSFFAK-UHFFFAOYSA-N dimethyl peroxide Chemical compound COOC SRXOCFMDUSFFAK-UHFFFAOYSA-N 0.000 description 1
- -1 dipropyl peroxide Di-n-butyl peroxide Chemical compound 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 210000003918 fraction a Anatomy 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 238000005325 percolation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- KMIOJWCYOHBUJS-HAKPAVFJSA-N vorolanib Chemical compound C1N(C(=O)N(C)C)CC[C@@H]1NC(=O)C1=C(C)NC(\C=C/2C3=CC(F)=CC=C3NC\2=O)=C1C KMIOJWCYOHBUJS-HAKPAVFJSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5747272A GB1454498A (en) | 1972-12-13 | 1972-12-13 | Conversion of hydrocarbons to lubricating oils |
| GB3564673A GB1456858A (en) | 1972-12-13 | 1973-07-26 | Conversion of hydrocarbons to lubricating oils |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2361653A1 true DE2361653A1 (de) | 1974-06-20 |
Family
ID=26262807
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19732361653 Pending DE2361653A1 (de) | 1972-12-13 | 1973-12-11 | Verfahren zur herstellung von schmieroelen mit hohem viskositaetsindex |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS5024302A (enrdf_load_html_response) |
| DE (1) | DE2361653A1 (enrdf_load_html_response) |
| FR (1) | FR2210657A1 (enrdf_load_html_response) |
| IT (1) | IT1000819B (enrdf_load_html_response) |
| NL (1) | NL7316911A (enrdf_load_html_response) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017083086A1 (en) * | 2015-11-13 | 2017-05-18 | Exxonmobil Research And Engineering Company | High viscosity base stock compositions |
| US10301557B2 (en) | 2015-11-13 | 2019-05-28 | Exxonmobil Research And Engineering Company | High viscosity base stock compositions |
| US10301550B2 (en) | 2015-11-13 | 2019-05-28 | Exxonmobil Research And Engineering Company | High viscosity base stock compositions |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9637424B1 (en) | 2014-12-16 | 2017-05-02 | Exxonmobil Research And Engineering Company | High octane gasoline and process for making same |
| US10023533B2 (en) | 2014-12-16 | 2018-07-17 | Exxonmobil Research And Engineering Company | Process to produce paraffinic hydrocarbon fluids from light paraffins |
| US9688626B2 (en) | 2014-12-16 | 2017-06-27 | Exxonmobil Research And Engineering Company | Upgrading paraffins to distillates and lubricant basestocks |
| US9637423B1 (en) | 2014-12-16 | 2017-05-02 | Exxonmobil Research And Engineering Company | Integrated process for making high-octane gasoline |
-
1973
- 1973-12-07 IT IT295873A patent/IT1000819B/it active
- 1973-12-11 NL NL7316911A patent/NL7316911A/xx unknown
- 1973-12-11 JP JP13744373A patent/JPS5024302A/ja active Pending
- 1973-12-11 FR FR7344170A patent/FR2210657A1/fr not_active Withdrawn
- 1973-12-11 DE DE19732361653 patent/DE2361653A1/de active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017083086A1 (en) * | 2015-11-13 | 2017-05-18 | Exxonmobil Research And Engineering Company | High viscosity base stock compositions |
| CN109415641A (zh) * | 2015-11-13 | 2019-03-01 | 埃克森美孚研究工程公司 | 高粘度基础油料组合物 |
| US10294438B2 (en) | 2015-11-13 | 2019-05-21 | Exxonmobil Research And Engineering Company | High viscosity base stock compositions |
| US10301557B2 (en) | 2015-11-13 | 2019-05-28 | Exxonmobil Research And Engineering Company | High viscosity base stock compositions |
| US10301550B2 (en) | 2015-11-13 | 2019-05-28 | Exxonmobil Research And Engineering Company | High viscosity base stock compositions |
| US10450513B2 (en) | 2015-11-13 | 2019-10-22 | Exxonmobil Research And Engineering Company | High viscosity base stock compositions |
| US10557100B2 (en) | 2015-11-13 | 2020-02-11 | Exxonmobil Research And Engineering Company | High viscosity base stock compositions |
| CN109415641B (zh) * | 2015-11-13 | 2021-11-09 | 埃克森美孚研究工程公司 | 高粘度基础油料组合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5024302A (enrdf_load_html_response) | 1975-03-15 |
| IT1000819B (it) | 1976-04-10 |
| FR2210657A1 (en) | 1974-07-12 |
| NL7316911A (enrdf_load_html_response) | 1974-06-17 |
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