DE2342486C2 - Verfahren zur Herstellung von Pfropfpolymerisaten - Google Patents
Verfahren zur Herstellung von PfropfpolymerisatenInfo
- Publication number
- DE2342486C2 DE2342486C2 DE2342486A DE2342486A DE2342486C2 DE 2342486 C2 DE2342486 C2 DE 2342486C2 DE 2342486 A DE2342486 A DE 2342486A DE 2342486 A DE2342486 A DE 2342486A DE 2342486 C2 DE2342486 C2 DE 2342486C2
- Authority
- DE
- Germany
- Prior art keywords
- ethylene
- ethylenically unsaturated
- unsaturated carboxylic
- mixture
- copolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 14
- 229920000578 graft copolymer Polymers 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title description 7
- 229920001038 ethylene copolymer Polymers 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 13
- 150000001735 carboxylic acids Chemical class 0.000 claims description 11
- 239000007870 radical polymerization initiator Substances 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 7
- PZWQOGNTADJZGH-SNAWJCMRSA-N (2e)-2-methylpenta-2,4-dienoic acid Chemical compound OC(=O)C(/C)=C/C=C PZWQOGNTADJZGH-SNAWJCMRSA-N 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 229920001567 vinyl ester resin Polymers 0.000 claims description 3
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000008187 granular material Substances 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- 239000011888 foil Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 1
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- -1 vinylpropio- Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2342486A DE2342486C2 (de) | 1973-08-23 | 1973-08-23 | Verfahren zur Herstellung von Pfropfpolymerisaten |
| IT25677/74A IT1017700B (it) | 1973-08-23 | 1974-07-29 | Processo per la preparazione di polimeri ad innesto |
| US05/497,572 US3949019A (en) | 1973-08-23 | 1974-08-15 | Process for the manufacture of graft polymers |
| BE147687A BE818938A (fr) | 1973-08-23 | 1974-08-16 | Procede de preparation de polymeres greffes |
| JP49095606A JPS5050489A (enExample) | 1973-08-23 | 1974-08-22 | |
| FR7428832A FR2257614B1 (enExample) | 1973-08-23 | 1974-08-22 | |
| GB3689074A GB1471345A (en) | 1973-08-23 | 1974-08-22 | Process for the manufacture of graft polymers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2342486A DE2342486C2 (de) | 1973-08-23 | 1973-08-23 | Verfahren zur Herstellung von Pfropfpolymerisaten |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2342486A1 DE2342486A1 (de) | 1975-03-13 |
| DE2342486C2 true DE2342486C2 (de) | 1982-03-11 |
Family
ID=5890453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2342486A Expired DE2342486C2 (de) | 1973-08-23 | 1973-08-23 | Verfahren zur Herstellung von Pfropfpolymerisaten |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3949019A (enExample) |
| JP (1) | JPS5050489A (enExample) |
| BE (1) | BE818938A (enExample) |
| DE (1) | DE2342486C2 (enExample) |
| FR (1) | FR2257614B1 (enExample) |
| GB (1) | GB1471345A (enExample) |
| IT (1) | IT1017700B (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4064198A (en) * | 1973-08-17 | 1977-12-20 | Basf Aktiengesellschaft | Process for the manufacture of shaped articles by graft polymerization |
| DE2450672A1 (de) * | 1974-10-25 | 1976-05-06 | Basf Ag | Verfahren zur herstellung von pfropfpolymerisaten |
| JPS5853003B2 (ja) * | 1975-09-08 | 1983-11-26 | 三菱油化株式会社 | シンキジユウゴウタイリユウシノセイゾウホウ |
| JPS52112692A (en) * | 1976-03-19 | 1977-09-21 | Toyo Soda Mfg Co Ltd | Method for carboxylation of ethylene-vinyl acetate copolymers |
| US4107109A (en) * | 1977-03-22 | 1978-08-15 | E. I. Du Pont De Nemours And Company | Reactive compositions and polymers made therefrom |
| DE3033001A1 (de) * | 1980-09-02 | 1982-04-01 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von anhydrid- oder carboxylgruppen enthaltenden ethylen-pfropfcopolymerisaten |
| US4639495A (en) * | 1981-12-21 | 1987-01-27 | E. I. Du Pont De Nemours And Company | Extruding process for preparing functionalized polyolefin polymers |
| DE3306202A1 (de) * | 1983-02-23 | 1984-08-23 | Bayer Ag, 5090 Leverkusen | Verwendung von gepfropften ethylen-vinylacetat-copolymeren zur herstellung von schmelzklebstoffen |
| FI79124C (fi) * | 1986-05-28 | 1989-11-10 | Neste Oy | Modifierad polyolefin. |
| DE4030565A1 (de) * | 1990-09-27 | 1992-04-02 | Hoechst Ag | Pfropfmischpolymer auf basis eines ultrahochmolekularen polyethylens und eines ethylen-copolymers |
| DE102008019804B4 (de) | 2008-04-15 | 2019-11-14 | Byk-Chemie Gmbh | Funktionalisierte Ethylenpolymere mit hohem Haftvermögen und Verfahren zu ihrer Herstellung |
| EP2995631A1 (en) | 2014-09-12 | 2016-03-16 | Borealis AG | Process for producing graft copolymers on polyolefin backbone |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3177269A (en) * | 1960-10-10 | 1965-04-06 | Dow Chemical Co | Graft copolymers of polyolefins and acrylic and methacrylic acid and method of making the same |
| US3177270A (en) * | 1960-10-10 | 1965-04-06 | Dow Chemical Co | Graft copolymers of polyolefins and monovinyl aromatic compounds and method of making the same |
| US3862265A (en) * | 1971-04-09 | 1975-01-21 | Exxon Research Engineering Co | Polymers with improved properties and process therefor |
-
1973
- 1973-08-23 DE DE2342486A patent/DE2342486C2/de not_active Expired
-
1974
- 1974-07-29 IT IT25677/74A patent/IT1017700B/it active
- 1974-08-15 US US05/497,572 patent/US3949019A/en not_active Expired - Lifetime
- 1974-08-16 BE BE147687A patent/BE818938A/xx unknown
- 1974-08-22 JP JP49095606A patent/JPS5050489A/ja active Pending
- 1974-08-22 FR FR7428832A patent/FR2257614B1/fr not_active Expired
- 1974-08-22 GB GB3689074A patent/GB1471345A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IT1017700B (it) | 1977-08-10 |
| JPS5050489A (enExample) | 1975-05-06 |
| US3949019A (en) | 1976-04-06 |
| FR2257614B1 (enExample) | 1979-06-01 |
| GB1471345A (en) | 1977-04-21 |
| BE818938A (fr) | 1975-02-17 |
| DE2342486A1 (de) | 1975-03-13 |
| FR2257614A1 (enExample) | 1975-08-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| D2 | Grant after examination | ||
| 8330 | Complete disclaimer |