DE2307852C3 - Luft- und Lagerbeständige Katalysatoren für die kathodische Wasserstoffentwicklung - Google Patents
Luft- und Lagerbeständige Katalysatoren für die kathodische WasserstoffentwicklungInfo
- Publication number
- DE2307852C3 DE2307852C3 DE2307852A DE2307852A DE2307852C3 DE 2307852 C3 DE2307852 C3 DE 2307852C3 DE 2307852 A DE2307852 A DE 2307852A DE 2307852 A DE2307852 A DE 2307852A DE 2307852 C3 DE2307852 C3 DE 2307852C3
- Authority
- DE
- Germany
- Prior art keywords
- mol
- concentration
- nickel
- catalysts
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims description 24
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 16
- 239000001257 hydrogen Substances 0.000 title claims description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 13
- 238000003860 storage Methods 0.000 title claims description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 33
- 229910021645 metal ion Inorganic materials 0.000 claims description 15
- 229910052759 nickel Inorganic materials 0.000 claims description 14
- 239000008139 complexing agent Substances 0.000 claims description 13
- 230000008021 deposition Effects 0.000 claims description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 9
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 238000005868 electrolysis reaction Methods 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 239000003638 chemical reducing agent Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000007868 Raney catalyst Substances 0.000 claims description 2
- 229910000564 Raney nickel Inorganic materials 0.000 claims description 2
- 230000003197 catalytic effect Effects 0.000 claims description 2
- 230000035945 sensitivity Effects 0.000 claims description 2
- 150000001639 boron compounds Chemical class 0.000 claims 3
- 229910001429 cobalt ion Inorganic materials 0.000 claims 3
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 claims 3
- 239000003792 electrolyte Substances 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- 229910052751 metal Inorganic materials 0.000 claims 3
- 239000007769 metal material Substances 0.000 claims 3
- 238000000926 separation method Methods 0.000 claims 3
- 229910000062 azane Inorganic materials 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 229910017052 cobalt Inorganic materials 0.000 claims 2
- 239000010941 cobalt Substances 0.000 claims 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 229910001453 nickel ion Inorganic materials 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 229910045601 alloy Inorganic materials 0.000 claims 1
- 239000000956 alloy Substances 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- JBANFLSTOJPTFW-UHFFFAOYSA-N azane;boron Chemical compound [B].N JBANFLSTOJPTFW-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 230000006866 deterioration Effects 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 239000000446 fuel Substances 0.000 claims 1
- 229910002804 graphite Inorganic materials 0.000 claims 1
- 239000010439 graphite Substances 0.000 claims 1
- 238000010310 metallurgical process Methods 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- 229920003023 plastic Polymers 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 238000001953 recrystallisation Methods 0.000 claims 1
- 239000012266 salt solution Substances 0.000 claims 1
- 229940095064 tartrate Drugs 0.000 claims 1
- 230000012010 growth Effects 0.000 description 5
- QDWJUBJKEHXSMT-UHFFFAOYSA-N boranylidynenickel Chemical compound [Ni]#B QDWJUBJKEHXSMT-UHFFFAOYSA-N 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Metallurgy (AREA)
- Catalysts (AREA)
- Inert Electrodes (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Chemically Coating (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2307852A DE2307852C3 (de) | 1973-02-17 | 1973-02-17 | Luft- und Lagerbeständige Katalysatoren für die kathodische Wasserstoffentwicklung |
| GB677274A GB1453480A (en) | 1973-02-17 | 1974-02-14 | Catalysts for the cathodic evoluation of hydrogen |
| IT4841374A IT1008239B (it) | 1973-02-17 | 1974-02-15 | Perfezionamento nei catalizzatori per lo sviluppo catodico di idroge no |
| FR7405192A FR2218137B1 (enExample) | 1973-02-17 | 1974-02-15 | |
| US443195A US3926844A (en) | 1973-02-17 | 1974-02-19 | Catalysts for the cathodic hydrogen development |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2307852A DE2307852C3 (de) | 1973-02-17 | 1973-02-17 | Luft- und Lagerbeständige Katalysatoren für die kathodische Wasserstoffentwicklung |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2307852A1 DE2307852A1 (de) | 1974-09-05 |
| DE2307852B2 DE2307852B2 (de) | 1975-04-10 |
| DE2307852C3 true DE2307852C3 (de) | 1975-12-11 |
Family
ID=5872209
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2307852A Expired DE2307852C3 (de) | 1973-02-17 | 1973-02-17 | Luft- und Lagerbeständige Katalysatoren für die kathodische Wasserstoffentwicklung |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3926844A (enExample) |
| DE (1) | DE2307852C3 (enExample) |
| FR (1) | FR2218137B1 (enExample) |
| GB (1) | GB1453480A (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL50217A (en) * | 1976-08-06 | 1980-01-31 | Israel State | Electrocatalytically acitve spinel type mixed oxides |
| CA1106797A (en) * | 1977-07-22 | 1981-08-11 | Electrolyser Corporation Ltd. (The) | Active cobalt electrode for the cathodic evolution of hydrogen |
| US4214954A (en) * | 1978-12-04 | 1980-07-29 | Olin Corporation | Plated metallic cathode with porous copper subplating |
| US4251344A (en) * | 1980-01-22 | 1981-02-17 | E. I. Du Pont De Nemours And Company | Porous nickel coated electrodes |
| US4544473A (en) * | 1980-05-12 | 1985-10-01 | Energy Conversion Devices, Inc. | Catalytic electrolytic electrode |
| US4430188A (en) | 1980-09-17 | 1984-02-07 | Engelhard Corporation | Electrodes for use in an electrolytic process |
| NL8302590A (nl) * | 1983-07-20 | 1985-02-18 | Unilever Nv | Nikkelboride in olie katalysator. |
| US4659687A (en) * | 1984-12-17 | 1987-04-21 | Phillips Petroleum Company | Hydrogenation catalysts and process of making said catalyst |
| US4734534A (en) * | 1984-12-17 | 1988-03-29 | Phillips Petroleum Company | Preparing cis-olefinic compounds from acetylenic compounds |
| DE3532866A1 (de) * | 1985-09-14 | 1987-03-26 | Basf Ag | Verfahren zur herstellung von elektroden |
| US5431804A (en) * | 1990-10-09 | 1995-07-11 | Diamond Technologies Company | Nickel-cobalt-boron alloy deposited on a substrate |
| US6746496B1 (en) * | 2002-01-15 | 2004-06-08 | Sandia Corporation | Compact solid source of hydrogen gas |
| US7097933B2 (en) * | 2003-06-09 | 2006-08-29 | Ovonic Battery Company, Inc. | Catalyst for fuel cell oxygen electrodes |
| JP6698629B2 (ja) * | 2014-08-11 | 2020-05-27 | ニューサウス・イノベーションズ・ピーティーワイ・リミテッド | 触媒アセンブリ |
| DE102014226464B4 (de) * | 2014-12-18 | 2023-05-25 | RUHR-UNIVERSITäT BOCHUM | Mit Stickstoff dotierte Metallboride für Wasserspaltung und Sauerstoffreduktion |
| CN107240716B (zh) * | 2016-03-28 | 2019-12-20 | 比亚迪股份有限公司 | 一种电解液、正极及其制备方法和一种锂离子电池 |
| CN107988617A (zh) * | 2017-11-24 | 2018-05-04 | 复旦大学 | 水电解高效、双功能催化电极及其制备方法 |
| CN112337479B (zh) * | 2020-11-25 | 2022-05-31 | 派尔森环保科技有限公司 | 一种利用废弃铝箔制备高活性三元金属硼化物析氢催化剂的方法 |
| CN115404509A (zh) * | 2022-08-09 | 2022-11-29 | 电子科技大学 | 一种自修复型析氧催化剂及其制备方法与应用 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3210157A (en) * | 1962-01-29 | 1965-10-05 | Metal Hydrides Inc | Method for generating hydrogen |
| US3322686A (en) * | 1963-02-05 | 1967-05-30 | Herbert C Brown | Hydrogenation of chemical compounds and catalysts therefor |
-
1973
- 1973-02-17 DE DE2307852A patent/DE2307852C3/de not_active Expired
-
1974
- 1974-02-14 GB GB677274A patent/GB1453480A/en not_active Expired
- 1974-02-15 FR FR7405192A patent/FR2218137B1/fr not_active Expired
- 1974-02-19 US US443195A patent/US3926844A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE2307852A1 (de) | 1974-09-05 |
| GB1453480A (en) | 1976-10-20 |
| US3926844A (en) | 1975-12-16 |
| FR2218137B1 (enExample) | 1980-03-28 |
| FR2218137A1 (enExample) | 1974-09-13 |
| DE2307852B2 (de) | 1975-04-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| 8320 | Willingness to grant licences declared (paragraph 23) | ||
| 8330 | Complete disclaimer |