DE2303388A1 - Verfahren zum biohydrometallurgischen extrahieren von kobalt und nickel aus sulfidischen erzen, konzentraten und synthetischen sulfiden - Google Patents
Verfahren zum biohydrometallurgischen extrahieren von kobalt und nickel aus sulfidischen erzen, konzentraten und synthetischen sulfidenInfo
- Publication number
- DE2303388A1 DE2303388A1 DE2303388A DE2303388A DE2303388A1 DE 2303388 A1 DE2303388 A1 DE 2303388A1 DE 2303388 A DE2303388 A DE 2303388A DE 2303388 A DE2303388 A DE 2303388A DE 2303388 A1 DE2303388 A1 DE 2303388A1
- Authority
- DE
- Germany
- Prior art keywords
- leaching
- iron
- bacteria
- extraction
- carbon dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 35
- 238000000605 extraction Methods 0.000 title claims description 29
- 239000012141 concentrate Substances 0.000 title claims description 15
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 title claims description 8
- 150000003568 thioethers Chemical class 0.000 title claims 4
- 229910017052 cobalt Inorganic materials 0.000 title description 13
- 239000010941 cobalt Substances 0.000 title description 13
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 52
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 37
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 32
- 229910052742 iron Inorganic materials 0.000 claims description 26
- 229910052751 metal Inorganic materials 0.000 claims description 23
- 239000002184 metal Substances 0.000 claims description 23
- 238000002386 leaching Methods 0.000 claims description 21
- 239000002002 slurry Substances 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 18
- 229910052759 nickel Inorganic materials 0.000 claims description 18
- 241000894006 Bacteria Species 0.000 claims description 16
- 239000001569 carbon dioxide Substances 0.000 claims description 16
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 16
- 239000000725 suspension Substances 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 235000015097 nutrients Nutrition 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 8
- 241000605222 Acidithiobacillus ferrooxidans Species 0.000 claims description 6
- 229910052976 metal sulfide Inorganic materials 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 230000001651 autotrophic effect Effects 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- GDPKWKCLDUOTMP-UHFFFAOYSA-B iron(3+);dihydroxide;pentasulfate Chemical compound [OH-].[OH-].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GDPKWKCLDUOTMP-UHFFFAOYSA-B 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 150000004763 sulfides Chemical class 0.000 description 16
- 244000005700 microbiome Species 0.000 description 14
- 239000000243 solution Substances 0.000 description 12
- 230000001580 bacterial effect Effects 0.000 description 8
- 239000002609 medium Substances 0.000 description 8
- 239000003518 caustics Substances 0.000 description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 230000002906 microbiologic effect Effects 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- 235000010755 mineral Nutrition 0.000 description 5
- 239000010949 copper Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052954 pentlandite Inorganic materials 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- -1 sulfur halide Chemical class 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 241000605118 Thiobacillus Species 0.000 description 2
- 238000005273 aeration Methods 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 2
- 229910052951 chalcopyrite Inorganic materials 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical class N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 235000021538 Chard Nutrition 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 241001148470 aerobic bacillus Species 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000013048 microbiological method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- LVIYYTJTOKJJOC-UHFFFAOYSA-N nickel phthalocyanine Chemical compound [Ni+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 LVIYYTJTOKJJOC-UHFFFAOYSA-N 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 238000009931 pascalization Methods 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229910052952 pyrrhotite Inorganic materials 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000010187 selection method Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- VRRFSFYSLSPWQY-UHFFFAOYSA-N sulfanylidenecobalt Chemical compound [Co]=S VRRFSFYSLSPWQY-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/18—Extraction of metal compounds from ores or concentrates by wet processes with the aid of microorganisms or enzymes, e.g. bacteria or algae
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Geology (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA133,253A CA960463A (en) | 1972-01-26 | 1972-01-26 | Microbiological extraction of cobalt and nickel from sulphide ores and concentrates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2303388A1 true DE2303388A1 (de) | 1973-08-02 |
Family
ID=4092152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2303388A Pending DE2303388A1 (de) | 1972-01-26 | 1973-01-24 | Verfahren zum biohydrometallurgischen extrahieren von kobalt und nickel aus sulfidischen erzen, konzentraten und synthetischen sulfiden |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS4886724A (enrdf_load_html_response) |
| AU (1) | AU474361B2 (enrdf_load_html_response) |
| BE (1) | BE794526A (enrdf_load_html_response) |
| CA (1) | CA960463A (enrdf_load_html_response) |
| DE (1) | DE2303388A1 (enrdf_load_html_response) |
| FR (1) | FR2169263B1 (enrdf_load_html_response) |
| GB (1) | GB1382357A (enrdf_load_html_response) |
| ZA (1) | ZA728280B (enrdf_load_html_response) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PT69331A (en) * | 1978-03-23 | 1979-04-01 | Interox Chemicals Ltd | Leaching of minerals |
| JPS60500239A (ja) * | 1982-12-17 | 1985-02-28 | バイオテクノロジ−・オ−ストラリア・ピ−・テイ−・ワイ・リミテツド | 方法 |
| FR2640284B1 (fr) * | 1988-12-09 | 1992-01-17 | Commissariat Energie Atomique | Procede de fabrication d'un reactif acide oxydant pour la lixiviation de minerais |
| US6387239B1 (en) * | 1999-11-17 | 2002-05-14 | Bhp Minerals International, Inc. | Recovery of metals from ore |
| CA2353002C (en) | 2001-07-13 | 2009-12-01 | Teck Cominco Metals Ltd. | Heap bioleaching process for the extraction of zinc |
| US7455715B2 (en) | 2001-07-13 | 2008-11-25 | Teck Cominco Metals Ltd. | Heap bioleaching process for the extraction of zinc |
| WO2012017928A1 (ja) * | 2010-08-03 | 2012-02-09 | 株式会社アクアテック | 硫化ニッケル含有汚泥中の硫化ニッケルを酸化する方法、および硫化ニッケル含有汚泥から金属ニッケルを回収する方法 |
| WO2024213973A1 (en) * | 2023-04-11 | 2024-10-17 | Bactech Environmental Corporation | A process for treating a material containing iron and sulphur |
| CN117142734A (zh) * | 2023-09-21 | 2023-12-01 | 贵州大学 | 一种利用天然矿物提取液快速消除污泥恶臭气味的方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3305353A (en) * | 1964-03-30 | 1967-02-21 | British Columbia Res Council | Accelerated microbiological ore extraction process |
| US3607235A (en) * | 1968-02-23 | 1971-09-21 | British Columbia Res Council | Rapid bacteriological metal extraction method |
-
0
- BE BE794526D patent/BE794526A/xx unknown
-
1972
- 1972-01-26 CA CA133,253A patent/CA960463A/en not_active Expired
- 1972-11-22 ZA ZA728280A patent/ZA728280B/xx unknown
- 1972-12-06 GB GB5620872A patent/GB1382357A/en not_active Expired
- 1972-12-23 JP JP48004047A patent/JPS4886724A/ja active Pending
-
1973
- 1973-01-10 AU AU50970/73A patent/AU474361B2/en not_active Expired
- 1973-01-24 DE DE2303388A patent/DE2303388A1/de active Pending
- 1973-01-25 FR FR7302660A patent/FR2169263B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ZA728280B (en) | 1973-07-25 |
| CA960463A (en) | 1975-01-07 |
| AU5097073A (en) | 1974-07-11 |
| AU474361B2 (en) | 1976-07-22 |
| JPS4886724A (enrdf_load_html_response) | 1973-11-15 |
| GB1382357A (en) | 1975-01-29 |
| FR2169263A1 (enrdf_load_html_response) | 1973-09-07 |
| FR2169263B1 (enrdf_load_html_response) | 1978-01-06 |
| BE794526A (fr) | 1973-07-25 |
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