DE2260978A1 - Katalysator auf der basis von raneynickel mit eisen - Google Patents
Katalysator auf der basis von raneynickel mit eisenInfo
- Publication number
- DE2260978A1 DE2260978A1 DE2260978A DE2260978A DE2260978A1 DE 2260978 A1 DE2260978 A1 DE 2260978A1 DE 2260978 A DE2260978 A DE 2260978A DE 2260978 A DE2260978 A DE 2260978A DE 2260978 A1 DE2260978 A1 DE 2260978A1
- Authority
- DE
- Germany
- Prior art keywords
- iron
- catalyst
- nickel
- chromium
- hydrogenation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 77
- 239000003054 catalyst Substances 0.000 title claims description 58
- 229910052742 iron Inorganic materials 0.000 title claims description 35
- 239000007868 Raney catalyst Substances 0.000 title description 6
- 229910000564 Raney nickel Inorganic materials 0.000 title description 3
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 title description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical class [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 98
- 239000011651 chromium Substances 0.000 claims description 43
- 238000005984 hydrogenation reaction Methods 0.000 claims description 33
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 31
- 229910045601 alloy Inorganic materials 0.000 claims description 30
- 239000000956 alloy Substances 0.000 claims description 30
- 229910052804 chromium Inorganic materials 0.000 claims description 30
- 229910052759 nickel Inorganic materials 0.000 claims description 30
- 229910052782 aluminium Inorganic materials 0.000 claims description 25
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 21
- 239000000843 powder Substances 0.000 claims description 20
- 238000011282 treatment Methods 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 150000002825 nitriles Chemical class 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 2
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 18
- 239000000243 solution Substances 0.000 description 14
- 235000011121 sodium hydroxide Nutrition 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000001257 hydrogen Substances 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 description 7
- 229910002804 graphite Inorganic materials 0.000 description 7
- 239000010439 graphite Substances 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 6
- 229910000604 Ferrochrome Inorganic materials 0.000 description 4
- 150000004985 diamines Chemical class 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- NSMYBPIHVACKQG-UHFFFAOYSA-N 2-aminocyclopentene-1-carbonitrile Chemical compound NC1=C(C#N)CCC1 NSMYBPIHVACKQG-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- QLNNMIUPRPKARZ-UHFFFAOYSA-N n'-cyclopentylmethanediamine Chemical compound NCNC1CCCC1 QLNNMIUPRPKARZ-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- QQHSIRTYSFLSRM-UHFFFAOYSA-N alumanylidynechromium Chemical compound [Al].[Cr] QQHSIRTYSFLSRM-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-OUBTZVSYSA-N aluminium-28 atom Chemical compound [28Al] XAGFODPZIPBFFR-OUBTZVSYSA-N 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000788 chromium alloy Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 210000002837 heart atrium Anatomy 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000009868 nickel metallurgy Methods 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- 239000011028 pyrite Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
- C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J25/00—Catalysts of the Raney type
- B01J25/02—Raney nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7144626A FR2164959A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1971-12-13 | 1971-12-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2260978A1 true DE2260978A1 (de) | 1973-06-20 |
Family
ID=9087342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2260978A Pending DE2260978A1 (de) | 1971-12-13 | 1972-12-13 | Katalysator auf der basis von raneynickel mit eisen |
Country Status (14)
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| HU170253B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1974-10-07 | 1977-05-28 | ||
| HU176794B (en) * | 1978-06-03 | 1981-05-28 | Chinoin Gyogyszer Es Vegyeszet | Process for producing alloy of aluminium of high reducing activity,containing discontinual heterodisperz alloy on the surface |
| JPS61156636A (ja) * | 1984-12-27 | 1986-07-16 | Muroran Kogyo Univ | 燃料電池水素電極とその製造方法 |
| US4607104A (en) * | 1985-07-11 | 1986-08-19 | Uniroyal Chemical Company, Inc. | Process for the production of 2,2,6,6-tetraalkyl-4-piperidylamines |
| US5464699A (en) * | 1988-04-18 | 1995-11-07 | Alloy Surfaces Co. Inc. | Pyrophoric materials and methods for making the same |
| CN1027191C (zh) * | 1990-01-31 | 1994-12-28 | 西屋电气公司 | 自动伪主相量发生器 |
| JP3340439B2 (ja) * | 1993-12-28 | 2002-11-05 | ローヌ−プーラン シミ | ドーピングさせたラニーニッケル型の触媒の存在におけるニトリルの、アミンへの接触水素添加方法 |
| DE19548289A1 (de) * | 1995-12-22 | 1997-06-26 | Basf Ag | Verfahren zur gleichzeitigen Herstellung von Caprolactam und Hexamethylendiamin |
| US5888923A (en) * | 1996-04-15 | 1999-03-30 | Dairen Chemical Corporation | Modified Raney nickel catalyst and a process for preparing diols by using the same |
| DE19636765A1 (de) * | 1996-09-10 | 1998-03-12 | Basf Ag | Verfahren zur gleichzeitigen Herstellung von 6-Aminocapronitril und Hexamethylendiamin |
| US6265451B1 (en) * | 1999-09-21 | 2001-07-24 | Hydrocarbon Technologies, Inc. | Skeletal iron catalyst and its preparation for Fischer-Tropsch synthesis processes |
| US6087296A (en) * | 1998-11-05 | 2000-07-11 | E. I. Du Pont De Nemours & Co. | Raney iron catalyst and a process for hydrogenating organic compounds using said catalyst |
| KR100416404B1 (ko) * | 1999-04-29 | 2004-01-31 | 차이나 피트로케미컬 코포레이션 | 수소화 촉매 및 이의 제조 방법 |
| US20030120116A1 (en) * | 1999-07-08 | 2003-06-26 | Daniel Ostgard | Fixed-bed Raney-type catalysts |
| US6277895B1 (en) * | 1999-09-21 | 2001-08-21 | Hydrocarbon Technologies, Inc. | Skeletal iron catalyst having improved attrition resistance and product selectivity in slurry-phase synthesis processes |
| US6924394B2 (en) | 2003-06-05 | 2005-08-02 | Invista North America S.R.L. | Low pressure process for the manufacture of 2-(aminomethyl)-1-cyclopentylamine |
| US7001586B2 (en) * | 2003-09-23 | 2006-02-21 | Catalytic Materials, Llc | CO-free hydrogen from decomposition of methane |
| US6995115B2 (en) * | 2003-09-23 | 2006-02-07 | Catalytic Materials, Llc | Catalyst for the generation of CO-free hydrogen from methane |
| DE102005003315A1 (de) * | 2005-01-24 | 2006-08-03 | Basf Ag | Verfahren zur Herstellung eines Xylylendiamins |
| DE102005008929A1 (de) * | 2005-02-24 | 2006-08-31 | Basf Ag | Verfahren zur Herstellung eines Xylylendiamins |
| US7709541B2 (en) * | 2006-07-14 | 2010-05-04 | Headwaters Technology Innovation, Llc | Fischer-Tropsch catalysts incorporating promoter for increasing yields of C5+ hydrocarbons and methods for making and using same |
| DE102007011484A1 (de) * | 2007-03-07 | 2008-09-11 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Trimethylhexamethylendiamin |
| DE102007011483A1 (de) * | 2007-03-07 | 2008-09-18 | Evonik Degussa Gmbh | Verfahren zur Herstellung von 3-Aminomethyl-3,5,5-trimethylcyclohexylamin |
| JP2009106923A (ja) * | 2007-10-29 | 2009-05-21 | Emmellen Biotech Pharmaceuticals Ltd | 接触水素化方法及びそのための新規触媒 |
| FR2944789B1 (fr) * | 2009-04-22 | 2011-05-20 | Rhodia Operations | Procede de preparation d'un terpenylcyclohexanol |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR913997A (fr) * | 1944-11-20 | 1946-09-25 | Rhone Poulenc Sa | Nouveaux catalyseurs |
| US2502348A (en) * | 1944-11-20 | 1950-03-28 | Rhone Poulenc Sa | Catalysts |
| DE1156769B (de) * | 1961-02-07 | 1963-11-07 | Varta Ag | Verfahren zur Herstellung aktivierter Katalysatoren aus Raney-Legierungen |
| US3544485A (en) * | 1967-10-16 | 1970-12-01 | Toray Industries | Method of activating catalytic alloys |
| US3682709A (en) * | 1967-12-04 | 1972-08-08 | Allis Chalmers Mfg Co | Process for improving nickel base,nonnoble metal fuel cell catalysts |
-
0
- BE BE792649D patent/BE792649A/xx unknown
-
1971
- 1971-12-13 FR FR7144626A patent/FR2164959A5/fr not_active Expired
-
1972
- 1972-11-27 SU SU1851082A patent/SU450387A3/ru active
- 1972-12-05 NL NL7216479A patent/NL7216479A/xx not_active Application Discontinuation
- 1972-12-08 DD DD167406A patent/DD101566A5/xx unknown
- 1972-12-11 JP JP47123506A patent/JPS4866087A/ja active Pending
- 1972-12-12 US US314434A patent/US3862911A/en not_active Expired - Lifetime
- 1972-12-12 GB GB5733472A patent/GB1397576A/en not_active Expired
- 1972-12-12 BR BR8752/72A patent/BR7208752D0/pt unknown
- 1972-12-12 CA CA158,907A patent/CA992103A/fr not_active Expired
- 1972-12-12 LU LU66633A patent/LU66633A1/xx unknown
- 1972-12-12 CH CH1808072A patent/CH564372A5/xx not_active IP Right Cessation
- 1972-12-13 IT IT32852/72A patent/IT971820B/it active
- 1972-12-13 DE DE2260978A patent/DE2260978A1/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| LU66633A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1973-07-18 |
| GB1397576A (en) | 1975-06-11 |
| BE792649A (fr) | 1973-06-12 |
| CH564372A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1975-07-31 |
| FR2164959A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1973-08-03 |
| IT971820B (it) | 1974-05-10 |
| SU450387A3 (ru) | 1974-11-15 |
| US3862911A (en) | 1975-01-28 |
| DD101566A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1973-11-12 |
| JPS4866087A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1973-09-11 |
| NL7216479A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1973-06-15 |
| CA992103A (fr) | 1976-06-29 |
| BR7208752D0 (pt) | 1973-09-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| OHN | Withdrawal |