DE2214912B2 - Verfahren zum selektiven extrahieren von in einer waesserigen loesung enthaltenem nickel - Google Patents
Verfahren zum selektiven extrahieren von in einer waesserigen loesung enthaltenem nickelInfo
- Publication number
- DE2214912B2 DE2214912B2 DE19722214912 DE2214912A DE2214912B2 DE 2214912 B2 DE2214912 B2 DE 2214912B2 DE 19722214912 DE19722214912 DE 19722214912 DE 2214912 A DE2214912 A DE 2214912A DE 2214912 B2 DE2214912 B2 DE 2214912B2
- Authority
- DE
- Germany
- Prior art keywords
- nickel
- solution
- precipitate
- acetyl acetone
- ammonia
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 24
- 238000000605 extraction Methods 0.000 title claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 78
- 229910052759 nickel Inorganic materials 0.000 claims description 39
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 36
- 239000000243 solution Substances 0.000 claims description 29
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 24
- 239000002244 precipitate Substances 0.000 claims description 16
- 229910017052 cobalt Inorganic materials 0.000 claims description 15
- 239000010941 cobalt Substances 0.000 claims description 15
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 15
- 229910021529 ammonia Inorganic materials 0.000 claims description 12
- -1 ammonium ions Chemical class 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 238000002386 leaching Methods 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims description 3
- 238000011084 recovery Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000011572 manganese Substances 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 230000009918 complex formation Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 206010016256 fatigue Diseases 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000622 liquid--liquid extraction Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
- C22B23/0461—Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7110922A FR2131820B1 (enExample) | 1971-03-29 | 1971-03-29 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2214912A1 DE2214912A1 (de) | 1972-10-12 |
| DE2214912B2 true DE2214912B2 (de) | 1973-05-10 |
| DE2214912C3 DE2214912C3 (enExample) | 1973-11-29 |
Family
ID=9074288
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722214912 Granted DE2214912B2 (de) | 1971-03-29 | 1972-03-27 | Verfahren zum selektiven extrahieren von in einer waesserigen loesung enthaltenem nickel |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3821354A (enExample) |
| AU (1) | AU456118B2 (enExample) |
| BE (1) | BE781154A (enExample) |
| CA (1) | CA960872A (enExample) |
| DE (1) | DE2214912B2 (enExample) |
| ES (1) | ES401277A1 (enExample) |
| FR (1) | FR2131820B1 (enExample) |
| GB (1) | GB1368535A (enExample) |
| IT (1) | IT954242B (enExample) |
| NL (1) | NL7203774A (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3975497A (en) * | 1974-07-11 | 1976-08-17 | Freeport Minerals Company | Enhanced selectivity in the separation of nickel and cobalt from ammoniacal solutions |
| US4042665A (en) * | 1976-09-27 | 1977-08-16 | Falconbridge Nickel Mines Limited | Cobalt ion exchange process |
| US5650057A (en) * | 1993-07-29 | 1997-07-22 | Cominco Engineering Services Ltd. | Chloride assisted hydrometallurgical extraction of metal |
| RU2186138C2 (ru) * | 1999-09-07 | 2002-07-27 | Институт химии и химической технологии СО РАН | Способ разделения кобальта и никеля из аммиачно-карбонатных растворов |
| BRPI0604853B1 (pt) * | 2006-10-27 | 2016-03-08 | Vale Do Rio Doce Co | método para produção de cobalto metálico a partir de refinado de extração por solventes de níquel |
| EP2703505B1 (en) * | 2012-09-04 | 2015-10-14 | Canbekte, Hüsnü Sinan | Method for leaching nickel, cobalt and iron from a nickel laterite ore |
| CN114604910B (zh) * | 2022-03-15 | 2023-10-13 | 重庆大学 | 一种镁、镍溶液矿化co2同时得到碳酸镍的方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3088955A (en) * | 1958-08-11 | 1963-05-07 | Union Carbide Corp | Preparation of acetylacetonates from ores |
-
1971
- 1971-03-29 FR FR7110922A patent/FR2131820B1/fr not_active Expired
-
1972
- 1972-03-21 NL NL7203774A patent/NL7203774A/xx unknown
- 1972-03-23 BE BE781154A patent/BE781154A/xx unknown
- 1972-03-24 GB GB1406372A patent/GB1368535A/en not_active Expired
- 1972-03-27 DE DE19722214912 patent/DE2214912B2/de active Granted
- 1972-03-27 IT IT1256172A patent/IT954242B/it active
- 1972-03-28 CA CA138,305A patent/CA960872A/en not_active Expired
- 1972-03-28 AU AU40480/72A patent/AU456118B2/en not_active Expired
- 1972-03-28 US US23877572 patent/US3821354A/en not_active Expired - Lifetime
- 1972-03-28 ES ES401277A patent/ES401277A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2214912C3 (enExample) | 1973-11-29 |
| CA960872A (en) | 1975-01-14 |
| GB1368535A (en) | 1974-09-25 |
| BE781154A (fr) | 1972-07-17 |
| DE2214912A1 (de) | 1972-10-12 |
| IT954242B (it) | 1973-08-30 |
| AU456118B2 (en) | 1974-11-25 |
| FR2131820B1 (enExample) | 1973-12-07 |
| ES401277A1 (es) | 1975-02-16 |
| NL7203774A (enExample) | 1972-10-03 |
| US3821354A (en) | 1974-06-28 |
| FR2131820A1 (enExample) | 1972-11-17 |
| AU4048072A (en) | 1973-10-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| EHJ | Ceased/non-payment of the annual fee |