DE2213412A1 - Verfahren zur herstellung von faeden, fasern und folien aus chlorhaltigen copolymerisaten des acrylnitrils - Google Patents
Verfahren zur herstellung von faeden, fasern und folien aus chlorhaltigen copolymerisaten des acrylnitrilsInfo
- Publication number
- DE2213412A1 DE2213412A1 DE19722213412 DE2213412A DE2213412A1 DE 2213412 A1 DE2213412 A1 DE 2213412A1 DE 19722213412 DE19722213412 DE 19722213412 DE 2213412 A DE2213412 A DE 2213412A DE 2213412 A1 DE2213412 A1 DE 2213412A1
- Authority
- DE
- Germany
- Prior art keywords
- phosphine
- cyanoethyl
- acrylonitrile
- solutions
- cyanoethylated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title claims description 18
- 239000000835 fiber Substances 0.000 title claims description 10
- 238000000034 method Methods 0.000 title claims description 10
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000004744 fabric Substances 0.000 title 1
- 239000000243 solution Substances 0.000 claims description 33
- 229920001577 copolymer Polymers 0.000 claims description 23
- 229920000642 polymer Polymers 0.000 claims description 22
- 238000009987 spinning Methods 0.000 claims description 18
- 150000003003 phosphines Chemical class 0.000 claims description 16
- BMNCJOAMYDWZAS-UHFFFAOYSA-N 3-(2-cyanoethylphosphanyl)propanenitrile Chemical compound N#CCCPCCC#N BMNCJOAMYDWZAS-UHFFFAOYSA-N 0.000 claims description 12
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 11
- 239000000460 chlorine Substances 0.000 claims description 11
- 229910052801 chlorine Inorganic materials 0.000 claims description 11
- CHZAMJVESILJGH-UHFFFAOYSA-N 3-[bis(2-cyanoethyl)phosphanyl]propanenitrile Chemical group N#CCCP(CCC#N)CCC#N CHZAMJVESILJGH-UHFFFAOYSA-N 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- MLONNEFSALVGGX-UHFFFAOYSA-N 3-[2-cyanoethyl(hexyl)phosphanyl]propanenitrile Chemical group CCCCCCP(CCC#N)CCC#N MLONNEFSALVGGX-UHFFFAOYSA-N 0.000 claims description 3
- 239000011888 foil Substances 0.000 claims description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 24
- FXJVNINSOKCNJP-UHFFFAOYSA-M 4-methylbenzenesulfinate Chemical compound CC1=CC=C(S([O-])=O)C=C1 FXJVNINSOKCNJP-UHFFFAOYSA-M 0.000 description 15
- 239000003381 stabilizer Substances 0.000 description 15
- 238000007792 addition Methods 0.000 description 13
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 10
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 7
- 229920002554 vinyl polymer Polymers 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 238000002845 discoloration Methods 0.000 description 5
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 231100000111 LD50 Toxicity 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 230000037396 body weight Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- QLOKJRIVRGCVIM-UHFFFAOYSA-N 1-[(4-methylsulfanylphenyl)methyl]piperazine Chemical compound C1=CC(SC)=CC=C1CN1CCNCC1 QLOKJRIVRGCVIM-UHFFFAOYSA-N 0.000 description 1
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 description 1
- FFSPYGVRSQKSRF-UHFFFAOYSA-N 3-[2-cyanoethyl(hydroxymethyl)phosphanyl]propanenitrile Chemical compound N#CCCP(CO)CCC#N FFSPYGVRSQKSRF-UHFFFAOYSA-N 0.000 description 1
- KNIUHBNRWZGIQQ-UHFFFAOYSA-N 7-diethoxyphosphinothioyloxy-4-methylchromen-2-one Chemical compound CC1=CC(=O)OC2=CC(OP(=S)(OCC)OCC)=CC=C21 KNIUHBNRWZGIQQ-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000699666 Mus <mouse, genus> Species 0.000 description 1
- 241000699670 Mus sp. Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000700159 Rattus Species 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- -1 alkyl bis (2-cyanoethyl) phosphines Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- PZGVVCOOWYSSGB-UHFFFAOYSA-L but-2-enedioate;dioctyltin(2+) Chemical compound CCCCCCCC[Sn]1(CCCCCCCC)OC(=O)C=CC(=O)O1 PZGVVCOOWYSSGB-UHFFFAOYSA-L 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000007278 cyanoethylation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- IMBKASBLAKCLEM-UHFFFAOYSA-L ferrous ammonium sulfate (anhydrous) Chemical compound [NH4+].[NH4+].[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O IMBKASBLAKCLEM-UHFFFAOYSA-L 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012673 precipitation polymerization Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- SZHIIIPPJJXYRY-UHFFFAOYSA-M sodium;2-methylprop-2-ene-1-sulfonate Chemical compound [Na+].CC(=C)CS([O-])(=O)=O SZHIIIPPJJXYRY-UHFFFAOYSA-M 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
- 230000008542 thermal sensitivity Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/50—Phosphorus bound to carbon only
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/38—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722213412 DE2213412A1 (de) | 1972-03-20 | 1972-03-20 | Verfahren zur herstellung von faeden, fasern und folien aus chlorhaltigen copolymerisaten des acrylnitrils |
| NL7303635A NL7303635A (enEXAMPLES) | 1972-03-20 | 1973-03-15 | |
| IT2181373A IT982558B (it) | 1972-03-20 | 1973-03-16 | Procedimento per la preparazione di fili fibre e fogli da copoli meri clorurati dell acrilonitrile |
| JP3104573A JPS4914562A (enEXAMPLES) | 1972-03-20 | 1973-03-19 | |
| AT239673A AT323879B (de) | 1972-03-20 | 1973-03-19 | Verfahren zur herstellung von fäden, fasern und folten aus chlorhaltigen copolymerisaten des acrylnitrils |
| SE7303849A SE382231B (sv) | 1972-03-20 | 1973-03-19 | Forfarande for framstellning av tradar, fibrer och folier av klorhaltiga sampolymerisat av akrylnitril genom spinning av en med en cyanoetylerad fosfin stabiliserad spinnlosning. |
| BE129018A BE797050A (fr) | 1972-03-20 | 1973-03-20 | Procede de fabrication de fils, de fibres ou de feuilles en copolymeres d'acrylonitrile contenant du chlore |
| GB1335573A GB1413360A (en) | 1972-03-20 | 1973-03-20 | Process for the stabilization of solutions of chlorine-containing acrylonitrile copolymers |
| FR7309930A FR2176943A1 (enEXAMPLES) | 1972-03-20 | 1973-03-20 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722213412 DE2213412A1 (de) | 1972-03-20 | 1972-03-20 | Verfahren zur herstellung von faeden, fasern und folien aus chlorhaltigen copolymerisaten des acrylnitrils |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2213412A1 true DE2213412A1 (de) | 1973-09-27 |
Family
ID=5839474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722213412 Pending DE2213412A1 (de) | 1972-03-20 | 1972-03-20 | Verfahren zur herstellung von faeden, fasern und folien aus chlorhaltigen copolymerisaten des acrylnitrils |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS4914562A (enEXAMPLES) |
| AT (1) | AT323879B (enEXAMPLES) |
| BE (1) | BE797050A (enEXAMPLES) |
| DE (1) | DE2213412A1 (enEXAMPLES) |
| FR (1) | FR2176943A1 (enEXAMPLES) |
| GB (1) | GB1413360A (enEXAMPLES) |
| IT (1) | IT982558B (enEXAMPLES) |
| NL (1) | NL7303635A (enEXAMPLES) |
| SE (1) | SE382231B (enEXAMPLES) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2558082A1 (de) * | 1974-12-23 | 1976-07-01 | Kanegafuchi Chemical Ind | Synthetische acrylfaser mit besserer nichtbrennbarkeit |
-
1972
- 1972-03-20 DE DE19722213412 patent/DE2213412A1/de active Pending
-
1973
- 1973-03-15 NL NL7303635A patent/NL7303635A/xx unknown
- 1973-03-16 IT IT2181373A patent/IT982558B/it active
- 1973-03-19 JP JP3104573A patent/JPS4914562A/ja active Pending
- 1973-03-19 AT AT239673A patent/AT323879B/de active
- 1973-03-19 SE SE7303849A patent/SE382231B/xx unknown
- 1973-03-20 FR FR7309930A patent/FR2176943A1/fr not_active Withdrawn
- 1973-03-20 BE BE129018A patent/BE797050A/xx unknown
- 1973-03-20 GB GB1335573A patent/GB1413360A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2558082A1 (de) * | 1974-12-23 | 1976-07-01 | Kanegafuchi Chemical Ind | Synthetische acrylfaser mit besserer nichtbrennbarkeit |
Also Published As
| Publication number | Publication date |
|---|---|
| BE797050A (fr) | 1973-09-20 |
| AT323879B (de) | 1975-08-11 |
| GB1413360A (en) | 1975-11-12 |
| JPS4914562A (enEXAMPLES) | 1974-02-08 |
| SE382231B (sv) | 1976-01-19 |
| NL7303635A (enEXAMPLES) | 1973-09-24 |
| IT982558B (it) | 1974-10-21 |
| FR2176943A1 (enEXAMPLES) | 1973-11-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1165258B (de) | Stabilisieren von N-Vinylpyrrolidonpolymerisaten | |
| DE2716100A1 (de) | Neue stabilisatoren | |
| DE2213412A1 (de) | Verfahren zur herstellung von faeden, fasern und folien aus chlorhaltigen copolymerisaten des acrylnitrils | |
| DE2306510A1 (de) | Wasserunloesliche fluessige phosphazenpolymere, verfahren zu ihrer herstellung und ihre verwendung als flammfestausruestungsmittel fuer textilgut aus regenerierter cellulose | |
| DE2436826C2 (de) | Farbbeständige Copolymerisat-Masse auf der Basis von Copolymerisaten des Acrylnitrils | |
| DE2311041A1 (de) | Fluessige phosphazengemische, verfahren zu deren herstellung und deren verwendung zum flammfestausruesten von textilien aus regenerierter cellulose | |
| DE2722571C3 (de) | Acrylsäureester von Dihalogenneopentylglykolphosphaten und sie enthaltende PoIyacry !zusammensetzungen | |
| DE69131195T2 (de) | Stabilisierte Acrylfasern und Verfahren zur Herstellung derselben | |
| DE1544882C3 (de) | Stabilisierte Spinnlösungen von Copolymerisaten des Acrylnitril mit Vinylidenchlorid | |
| DE1175431B (de) | Stabilisieren von Acrylnitrilpolymerisaten | |
| DE2213411A1 (de) | Verfahren zur herstellung von faeden, fasern und folien aus polyacrylnitril- und modacrylnitrilpolymeren | |
| DE2402957A1 (de) | Stabilisierung halogenhaltiger acrylnitrilpolymerer | |
| DE3106217C2 (de) | Einen geradkettigen Fettsäureester des N-(&beta;-Hydroxyethyl)-2,2,3,4,5,5-hexamethylpyrrolidins enthaltende Zusammensetzungen und die Verwendung dieser Ester als Anti-UV-Stabilisatoren in Polyolefinpolymeren | |
| DE1946330C3 (de) | Verfahren zur Herstellung von Fäden aus einer stabilisierten, wäßrigen Spinnlösung eines Acrylnitrilcopolymerisates aus Acrylnitril und halogenierten Vinylmonomeren und Stabilisatoren und Mittel zur Durchführung des Verfahrens | |
| DE2043402C3 (de) | Fasern und Fäden aus chlorhaltigen Modacrylpolymerisaten mit verbesserter Flammfestigkeit | |
| DE2558082A1 (de) | Synthetische acrylfaser mit besserer nichtbrennbarkeit | |
| DE2443572A1 (de) | Loesungen von neuen antimonkomplexen | |
| DE1694107C3 (de) | Stabilisierte Acrylnitrilpolymerisat-Lösungen | |
| DE1946008A1 (de) | Verfahren zum Stabilisieren von Loesungen von chlorhaltigen Copolymeren des Acrylnitrils | |
| DE1495018A1 (de) | Licht-stabilisiertes Nylon | |
| DE1544885C (de) | Stabilisieren von Losungen von Copoly meren des Acrylnitril mit Vinylidenchlorid | |
| DE2631518A1 (de) | Verfahren zur herstellung cellulosischer fasern mit hoher festigkeit gegen verbrennen und nach diesem verfahren hergestellte fasern und textilprodukte | |
| DE1544883C (de) | Stabilisieren von Losungen von Copolymeren des Acrylnitril mit Vinylidenchlorid gegen Verfärbung | |
| DE1694233C3 (de) | Stabilisierte Lösungen von Acrylnitril-Vinylidenchlorid-Copolymerisaten | |
| DE2456278B2 (de) | Thermoplastische transparente und schlagfeste Masse auf der Grundlage von Vinylchlorid-Polymerisaten |