DE2212259A1 - Verfahren zur Herstellung stabiler Zahnreinigungsmittel - Google Patents
Verfahren zur Herstellung stabiler ZahnreinigungsmittelInfo
- Publication number
- DE2212259A1 DE2212259A1 DE19722212259 DE2212259A DE2212259A1 DE 2212259 A1 DE2212259 A1 DE 2212259A1 DE 19722212259 DE19722212259 DE 19722212259 DE 2212259 A DE2212259 A DE 2212259A DE 2212259 A1 DE2212259 A1 DE 2212259A1
- Authority
- DE
- Germany
- Prior art keywords
- water
- mixture
- sodium
- added
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 15
- 239000000551 dentifrice Substances 0.000 title claims description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 28
- 150000003839 salts Chemical class 0.000 claims description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 19
- 235000011187 glycerol Nutrition 0.000 claims description 14
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 12
- 229920002678 cellulose Polymers 0.000 claims description 12
- 235000010980 cellulose Nutrition 0.000 claims description 12
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 11
- 230000002421 anti-septic effect Effects 0.000 claims description 10
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 239000003906 humectant Substances 0.000 claims description 9
- 108700004121 sarkosyl Proteins 0.000 claims description 9
- 239000000600 sorbitol Substances 0.000 claims description 9
- 239000004094 surface-active agent Substances 0.000 claims description 9
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 8
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 8
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 8
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical group [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000005498 polishing Methods 0.000 claims description 7
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000012458 free base Substances 0.000 claims description 4
- 231100000252 nontoxic Toxicity 0.000 claims description 4
- 230000003000 nontoxic effect Effects 0.000 claims description 4
- 229910002027 silica gel Inorganic materials 0.000 claims description 4
- 239000008119 colloidal silica Substances 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 description 17
- 239000000499 gel Substances 0.000 description 16
- -1 dihydrogen fluorides Chemical class 0.000 description 10
- 239000012459 cleaning agent Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000000606 toothpaste Substances 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 125000004181 carboxyalkyl group Chemical group 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 235000003599 food sweetener Nutrition 0.000 description 4
- 239000003349 gelling agent Substances 0.000 description 4
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 4
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 4
- 239000003765 sweetening agent Substances 0.000 description 4
- 229940034610 toothpaste Drugs 0.000 description 4
- 229940123208 Biguanide Drugs 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 239000001110 calcium chloride Substances 0.000 description 3
- 229910001628 calcium chloride Inorganic materials 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- RBLGLDWTCZMLRW-UHFFFAOYSA-K dicalcium;phosphate;dihydrate Chemical compound O.O.[Ca+2].[Ca+2].[O-]P([O-])([O-])=O RBLGLDWTCZMLRW-UHFFFAOYSA-K 0.000 description 3
- 238000005189 flocculation Methods 0.000 description 3
- 230000016615 flocculation Effects 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 210000000214 mouth Anatomy 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000000741 silica gel Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 3
- OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
- 229910001491 alkali aluminosilicate Inorganic materials 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000001506 calcium phosphate Substances 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 229910002026 crystalline silica Inorganic materials 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- SNKKBYWIYDOXGC-IYEMJOQQSA-N hexane;(2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanoic acid Chemical compound CCCCCC.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O SNKKBYWIYDOXGC-IYEMJOQQSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 239000006072 paste Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- 239000011698 potassium fluoride Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000000429 sodium aluminium silicate Substances 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 229910001948 sodium oxide Inorganic materials 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- XOLCDONFCQIBGY-UHFFFAOYSA-N 1-[(4-chlorophenyl)methyl]-3-(diaminomethylidene)-1-(3-dodecoxypropyl)guanidine Chemical compound CCCCCCCCCCCCOCCCN(C(=N)NC(N)=N)CC1=CC=C(Cl)C=C1 XOLCDONFCQIBGY-UHFFFAOYSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- HTYFFCPFVMJTKM-UHFFFAOYSA-N 2-(4-chlorophenyl)-1-(diaminomethylidene)guanidine Chemical compound NC(N)=NC(N)=NC1=CC=C(Cl)C=C1 HTYFFCPFVMJTKM-UHFFFAOYSA-N 0.000 description 1
- LFJJOPDNPVFCNZ-UHFFFAOYSA-N 2-[hexadecanoyl(methyl)amino]acetic acid Chemical compound CCCCCCCCCCCCCCCC(=O)N(C)CC(O)=O LFJJOPDNPVFCNZ-UHFFFAOYSA-N 0.000 description 1
- XGRSAFKZAGGXJV-UHFFFAOYSA-N 3-azaniumyl-3-cyclohexylpropanoate Chemical compound OC(=O)CC(N)C1CCCCC1 XGRSAFKZAGGXJV-UHFFFAOYSA-N 0.000 description 1
- 125000006283 4-chlorobenzyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1Cl)C([H])([H])* 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- XNCOSPRUTUOJCJ-UHFFFAOYSA-N Biguanide Chemical compound NC(N)=NC(N)=N XNCOSPRUTUOJCJ-UHFFFAOYSA-N 0.000 description 1
- 244000223760 Cinnamomum zeylanicum Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- DUSWSURQSVBDKY-UHFFFAOYSA-N ClF.[Sn+2] Chemical compound ClF.[Sn+2] DUSWSURQSVBDKY-UHFFFAOYSA-N 0.000 description 1
- UDIPTWFVPPPURJ-UHFFFAOYSA-M Cyclamate Chemical compound [Na+].[O-]S(=O)(=O)NC1CCCCC1 UDIPTWFVPPPURJ-UHFFFAOYSA-M 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 description 1
- 239000005696 Diammonium phosphate Substances 0.000 description 1
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- 244000004281 Eucalyptus maculata Species 0.000 description 1
- 241000735588 Gaultheria Species 0.000 description 1
- SQSPRWMERUQXNE-UHFFFAOYSA-N Guanylurea Chemical compound NC(=N)NC(N)=O SQSPRWMERUQXNE-UHFFFAOYSA-N 0.000 description 1
- 240000001046 Lactobacillus acidophilus Species 0.000 description 1
- 235000013956 Lactobacillus acidophilus Nutrition 0.000 description 1
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- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
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- 244000246386 Mentha pulegium Species 0.000 description 1
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- 239000004909 Moisturizer Substances 0.000 description 1
- DAOANAATJZWTSJ-UHFFFAOYSA-N N-Decanoylmorpholine Chemical compound CCCCCCCCCC(=O)N1CCOCC1 DAOANAATJZWTSJ-UHFFFAOYSA-N 0.000 description 1
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical compound CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
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- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
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- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
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- 235000019204 saccharin Nutrition 0.000 description 1
- 235000002020 sage Nutrition 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical class C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229960001462 sodium cyclamate Drugs 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- AQMNWCRSESPIJM-UHFFFAOYSA-M sodium metaphosphate Chemical compound [Na+].[O-]P(=O)=O AQMNWCRSESPIJM-UHFFFAOYSA-M 0.000 description 1
- 229960004711 sodium monofluorophosphate Drugs 0.000 description 1
- QKEBHWZTVCFHCF-UHFFFAOYSA-M sodium;2-methoxycarbonylphenolate Chemical compound [Na+].COC(=O)C1=CC=CC=C1[O-] QKEBHWZTVCFHCF-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229940078499 tricalcium phosphate Drugs 0.000 description 1
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
- 235000019731 tricalcium phosphate Nutrition 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/43—Guanidines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12705171A | 1971-03-22 | 1971-03-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2212259A1 true DE2212259A1 (de) | 1972-10-05 |
Family
ID=22428074
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722212259 Pending DE2212259A1 (de) | 1971-03-22 | 1972-03-14 | Verfahren zur Herstellung stabiler Zahnreinigungsmittel |
Country Status (15)
| Country | Link |
|---|---|
| AR (1) | AR195663A1 (enExample) |
| AT (1) | AT327391B (enExample) |
| AU (1) | AU456855B2 (enExample) |
| BE (1) | BE780989A (enExample) |
| BR (1) | BR7201635D0 (enExample) |
| CA (1) | CA989735A (enExample) |
| CH (1) | CH567417A5 (enExample) |
| DE (1) | DE2212259A1 (enExample) |
| ES (1) | ES400927A1 (enExample) |
| FR (1) | FR2130198B1 (enExample) |
| GB (1) | GB1344042A (enExample) |
| IT (1) | IT1048968B (enExample) |
| NL (1) | NL7203851A (enExample) |
| ZA (1) | ZA721374B (enExample) |
| ZM (1) | ZM5672A1 (enExample) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2352008A1 (de) * | 1972-10-30 | 1974-05-09 | Colgate Palmolive Co | Zahnpasta |
| EP0185971A1 (de) * | 1984-12-10 | 1986-07-02 | Henkel Kommanditgesellschaft auf Aktien | Verwendung von Alkylglykosiden als Potenzierungsmittel in antiseptischen Mitteln sowie Desinfektions- und Reinigungsmittel mit verstärkter bakterizider Wirkung |
| US4942041A (en) * | 1987-12-21 | 1990-07-17 | Henkel Kommanditgesellschaft Auf Aktien | Pharmaceutical compositions effective for treating skin to destroy eggs of enterobius vermicularis |
| US6045817A (en) * | 1997-09-26 | 2000-04-04 | Diversey Lever, Inc. | Ultramild antibacterial cleaning composition for frequent use |
| US6083517A (en) * | 1997-09-26 | 2000-07-04 | Lever Brothers Company, Division Of Conopco, Inc. | Ultramild antibacterial cleaning composition for frequent use |
| EP2256182A2 (en) | 2001-08-24 | 2010-12-01 | The Clorox Company | Improved cleaning composition |
| US8648027B2 (en) | 2012-07-06 | 2014-02-11 | The Clorox Company | Low-VOC cleaning substrates and compositions comprising a cationic biocide |
| US9096821B1 (en) | 2014-07-31 | 2015-08-04 | The Clorox Company | Preloaded dual purpose cleaning and sanitizing wipe |
| US10975341B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes having particular MABDF characteristics |
| US10973386B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes system having particular performance characteristics |
| US10973385B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes having particular pore volume distribution characteristics |
| US10982177B2 (en) | 2017-09-18 | 2021-04-20 | The Clorox Company | Cleaning wipes with particular lotion retention and efficacy characteristics |
| US11273625B2 (en) | 2018-12-21 | 2022-03-15 | The Clorox Company | Process for manufacturing multi-layer substrates comprising sandwich layers and polyethylene |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4340583A (en) | 1979-05-23 | 1982-07-20 | J. M. Huber Corporation | High fluoride compatibility dentifrice abrasives and compositions |
| DE3542516A1 (de) * | 1985-12-02 | 1987-06-04 | Henkel Kgaa | Desinfektionsmittel |
-
1972
- 1972-03-01 ZA ZA721374A patent/ZA721374B/xx unknown
- 1972-03-03 AU AU39596/72A patent/AU456855B2/en not_active Expired
- 1972-03-14 DE DE19722212259 patent/DE2212259A1/de active Pending
- 1972-03-14 FR FR7208791A patent/FR2130198B1/fr not_active Expired
- 1972-03-16 GB GB1240472A patent/GB1344042A/en not_active Expired
- 1972-03-17 CH CH395072A patent/CH567417A5/xx not_active IP Right Cessation
- 1972-03-18 IT IT49095/72A patent/IT1048968B/it active
- 1972-03-18 ES ES400927A patent/ES400927A1/es not_active Expired
- 1972-03-20 ZM ZM56/72*UA patent/ZM5672A1/xx unknown
- 1972-03-21 AT AT237872A patent/AT327391B/de not_active IP Right Cessation
- 1972-03-21 BR BR1635/72A patent/BR7201635D0/pt unknown
- 1972-03-21 CA CA137,685A patent/CA989735A/en not_active Expired
- 1972-03-21 BE BE780989A patent/BE780989A/xx unknown
- 1972-03-22 NL NL7203851A patent/NL7203851A/xx unknown
- 1972-03-22 AR AR241078A patent/AR195663A1/es active
Cited By (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2352008A1 (de) * | 1972-10-30 | 1974-05-09 | Colgate Palmolive Co | Zahnpasta |
| EP0185971A1 (de) * | 1984-12-10 | 1986-07-02 | Henkel Kommanditgesellschaft auf Aktien | Verwendung von Alkylglykosiden als Potenzierungsmittel in antiseptischen Mitteln sowie Desinfektions- und Reinigungsmittel mit verstärkter bakterizider Wirkung |
| US4942041A (en) * | 1987-12-21 | 1990-07-17 | Henkel Kommanditgesellschaft Auf Aktien | Pharmaceutical compositions effective for treating skin to destroy eggs of enterobius vermicularis |
| US6045817A (en) * | 1997-09-26 | 2000-04-04 | Diversey Lever, Inc. | Ultramild antibacterial cleaning composition for frequent use |
| US6083517A (en) * | 1997-09-26 | 2000-07-04 | Lever Brothers Company, Division Of Conopco, Inc. | Ultramild antibacterial cleaning composition for frequent use |
| EP2256182A2 (en) | 2001-08-24 | 2010-12-01 | The Clorox Company | Improved cleaning composition |
| US10647949B2 (en) | 2012-07-06 | 2020-05-12 | The Clorox Company | Low-voc cleaning substrates and compositions comprising a cationic biocide/alkylpolyglycoside mixture |
| US11485937B2 (en) | 2012-07-06 | 2022-11-01 | The Clorox Company | Low-VOC cleaning substrates and compositions comprising a quat and solvent mixture |
| US9234165B2 (en) | 2012-07-06 | 2016-01-12 | The Clorox Company | Low-VOC cleaning substrates and compositions consisting of a solvent mixture |
| US9988594B2 (en) | 2012-07-06 | 2018-06-05 | The Clorox Company | Low-VOC cleaning substrates and compositions containing a non-ionic surfactant |
| US10358623B1 (en) | 2012-07-06 | 2019-07-23 | The Clorox Company | Low-voc cleaning substrates and compositions comprising a mixed ethoxy/propoxy alcohol or fatty acid |
| US10358624B1 (en) | 2012-07-06 | 2019-07-23 | The Clorox Company | Low-VOC cleaning substrates and compositions |
| US10421929B2 (en) | 2012-07-06 | 2019-09-24 | The Clorox Company | Low-VOC cleaning substrates comprising a quat and ethoxylated/propdxylated fatty alcohol |
| US8648027B2 (en) | 2012-07-06 | 2014-02-11 | The Clorox Company | Low-VOC cleaning substrates and compositions comprising a cationic biocide |
| US10822576B2 (en) | 2012-07-06 | 2020-11-03 | The Clorox Company | Low-VOC cleaning substrates and compositions comprising a mixed ethoxy/propoxy alcohol or fatty acid |
| US10822575B2 (en) | 2012-07-06 | 2020-11-03 | The Clorox Company | Low-VOC cleaning substrates and compositions containing a quaternary ammonium compound |
| US9006165B2 (en) | 2012-07-06 | 2015-04-14 | The Clorox Company | Low-VOC cleaning substrates and compositions comprising a cationic biocide and glycol ether solvent |
| US12312565B2 (en) | 2012-07-06 | 2025-05-27 | The Clorox Company | Low-VOC cleaning substrates and compositions comprising an eo-po block copolymer non-ionic surfactant |
| US9096821B1 (en) | 2014-07-31 | 2015-08-04 | The Clorox Company | Preloaded dual purpose cleaning and sanitizing wipe |
| US10975341B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes having particular MABDF characteristics |
| US10982177B2 (en) | 2017-09-18 | 2021-04-20 | The Clorox Company | Cleaning wipes with particular lotion retention and efficacy characteristics |
| US10973385B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes having particular pore volume distribution characteristics |
| US11643621B2 (en) | 2017-09-18 | 2023-05-09 | The Clorox Company | Cleaning wipes with particular lotion retention and efficacy characteristics |
| US12152221B2 (en) | 2017-09-18 | 2024-11-26 | The Clorox Company | Cleaning wipes with particular lotion retention and efficacy characteristics |
| US10973386B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes system having particular performance characteristics |
| US11273625B2 (en) | 2018-12-21 | 2022-03-15 | The Clorox Company | Process for manufacturing multi-layer substrates comprising sandwich layers and polyethylene |
| US11364711B2 (en) | 2018-12-21 | 2022-06-21 | The Clorox Company | Multi-layer substrates comprising sandwich layers and polyethylene |
| US11472164B2 (en) | 2018-12-21 | 2022-10-18 | The Clorox Company | Multi-layer substrates comprising sandwich layers and polyethylene |
| US11826989B2 (en) | 2018-12-21 | 2023-11-28 | The Clorox Company | Multi-layer substrates comprising sandwich layers and polyethylene |
| US11858238B2 (en) | 2018-12-21 | 2024-01-02 | The Clorox Company | Process for manufacturing multi-layer substrates comprising sandwich layers and polyethylene |
Also Published As
| Publication number | Publication date |
|---|---|
| ATA237872A (de) | 1975-04-15 |
| GB1344042A (en) | 1974-01-16 |
| AU456855B2 (en) | 1974-12-12 |
| BE780989A (fr) | 1972-07-17 |
| ES400927A1 (es) | 1975-02-16 |
| IT1048968B (it) | 1980-12-20 |
| FR2130198B1 (enExample) | 1977-07-15 |
| AR195663A1 (es) | 1973-10-31 |
| AT327391B (de) | 1976-01-26 |
| ZA721374B (en) | 1973-10-31 |
| CH567417A5 (enExample) | 1975-10-15 |
| NL7203851A (enExample) | 1972-09-26 |
| ZM5672A1 (en) | 1973-11-21 |
| AU3959672A (en) | 1973-09-06 |
| FR2130198A1 (enExample) | 1972-11-03 |
| CA989735A (en) | 1976-05-25 |
| BR7201635D0 (pt) | 1973-06-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OHJ | Non-payment of the annual fee |