DE2148155C3 - Verfahren zur Sulfidierung von Katalysatoren für die hydrierende Verarbeitung von Kohlenwasserstoffen und deren Verwendung zur hydrierenden Umwandlung von Kohlenwasserstoffen - Google Patents
Verfahren zur Sulfidierung von Katalysatoren für die hydrierende Verarbeitung von Kohlenwasserstoffen und deren Verwendung zur hydrierenden Umwandlung von KohlenwasserstoffenInfo
- Publication number
- DE2148155C3 DE2148155C3 DE19712148155 DE2148155A DE2148155C3 DE 2148155 C3 DE2148155 C3 DE 2148155C3 DE 19712148155 DE19712148155 DE 19712148155 DE 2148155 A DE2148155 A DE 2148155A DE 2148155 C3 DE2148155 C3 DE 2148155C3
- Authority
- DE
- Germany
- Prior art keywords
- reaction stage
- hydrogen
- gas
- until
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims description 81
- 238000000034 method Methods 0.000 title claims description 47
- 230000008569 process Effects 0.000 title claims description 44
- 229930195733 hydrocarbon Natural products 0.000 title claims description 26
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 26
- 238000006243 chemical reaction Methods 0.000 claims description 117
- 239000007789 gas Substances 0.000 claims description 110
- 229910052739 hydrogen Inorganic materials 0.000 claims description 54
- 239000001257 hydrogen Substances 0.000 claims description 54
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 53
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 51
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 25
- 239000005864 Sulphur Substances 0.000 claims description 20
- 239000004215 Carbon black (E152) Substances 0.000 claims description 15
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 10
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 2
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000003921 oil Substances 0.000 description 46
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 26
- 238000004517 catalytic hydrocracking Methods 0.000 description 25
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- 238000000926 separation method Methods 0.000 description 12
- 238000005486 sulfidation Methods 0.000 description 12
- 238000009835 boiling Methods 0.000 description 9
- 238000005984 hydrogenation reaction Methods 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 238000001833 catalytic reforming Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000010687 lubricating oil Substances 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000002199 base oil Substances 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Inorganic materials O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- -1 hydrogenation Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4604570 | 1970-09-28 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2148155A1 DE2148155A1 (de) | 1972-03-30 |
| DE2148155B2 DE2148155B2 (de) | 1981-04-09 |
| DE2148155C3 true DE2148155C3 (de) | 1989-08-10 |
Family
ID=10439628
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712148155 Expired DE2148155C3 (de) | 1970-09-28 | 1971-09-27 | Verfahren zur Sulfidierung von Katalysatoren für die hydrierende Verarbeitung von Kohlenwasserstoffen und deren Verwendung zur hydrierenden Umwandlung von Kohlenwasserstoffen |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5428402B1 (enrdf_load_stackoverflow) |
| AU (1) | AU449016B2 (enrdf_load_stackoverflow) |
| BE (1) | BE770713A (enrdf_load_stackoverflow) |
| CA (1) | CA989759A (enrdf_load_stackoverflow) |
| DE (1) | DE2148155C3 (enrdf_load_stackoverflow) |
| FR (1) | FR2112984A5 (enrdf_load_stackoverflow) |
| GB (1) | GB1324034A (enrdf_load_stackoverflow) |
| NL (1) | NL171027C (enrdf_load_stackoverflow) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4176087A (en) * | 1977-06-20 | 1979-11-27 | Conoco Methanation Company | Method for activating a hydrodesulfurization catalyst |
| US4213850A (en) * | 1978-06-29 | 1980-07-22 | Union Oil Company Of California | Hydrodesulfurization of oil feedstock with presulfided catalyst |
| FR2784312B1 (fr) * | 1998-10-12 | 2000-11-10 | Eurecat Europ Retrait Catalys | Presulfuration hors site en presence de molecule hydrocarbonee |
| CN1102452C (zh) * | 2000-05-19 | 2003-03-05 | 中国石油化工集团公司 | 一种延长催化剂使用寿命的方法 |
| US6503864B2 (en) * | 2001-02-08 | 2003-01-07 | Catalytic Distillation Technologies | Process for sulfiding catalyst in a column |
| FR3002946B1 (fr) * | 2013-03-06 | 2016-09-16 | Eurecat Sa | Procede pour le demarrage d'unites d'hydrotraitement ou d'hydroconversion |
| JP7069921B2 (ja) | 2018-03-26 | 2022-05-18 | 株式会社リコー | 定着装置及び画像形成装置 |
| CN109954519A (zh) * | 2019-03-18 | 2019-07-02 | 山西潞安矿业(集团)有限责任公司 | 不停车进行升温硫化的一级加氢预转化器 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2298346A (en) * | 1939-10-30 | 1942-10-13 | Universal Oil Prod Co | Treatment of hydrocarbon oils |
| US2623007A (en) * | 1949-08-30 | 1952-12-23 | Phillips Petroleum Co | Catalytic desulfurization of hydrocarbons |
| NL71294C (enrdf_load_stackoverflow) * | 1949-09-22 | |||
| US2697683A (en) * | 1950-02-27 | 1954-12-21 | Shell Dev | Treatment of hydrocarbon oils |
| US2769756A (en) * | 1951-04-06 | 1956-11-06 | British Petroleum Co | Hydrodesulfurizing crude petroleum with a desulfurizing catalyst on trihydrate bauxite |
| BE609132A (enrdf_load_stackoverflow) * | 1960-10-13 | |||
| NL290755A (enrdf_load_stackoverflow) * | 1962-03-27 | |||
| NL129736C (enrdf_load_stackoverflow) * | 1963-08-29 | 1965-03-01 | ||
| FR1379062A (fr) * | 1963-10-10 | 1964-11-20 | Raffinage Cie Francaise | Procédé d'hydroraffinage des paraffines et des cires |
| US3291722A (en) * | 1963-11-19 | 1966-12-13 | Chevron Res | Hydrocarbon conversion process startup procedure |
| US3385781A (en) * | 1965-04-01 | 1968-05-28 | Exxon Research Engineering Co | Hydrocracking process |
| US3338819A (en) * | 1965-06-14 | 1967-08-29 | Union Oil Co | Integral hydrocracking-hydrotreating process |
| US3423307A (en) * | 1965-11-12 | 1969-01-21 | Gulf Research Development Co | Start-up of a hydrodesulfurization reaction |
| US3481862A (en) * | 1967-10-30 | 1969-12-02 | Sun Oil Co | Cs2 sulfiding of catalysts |
| US3519556A (en) * | 1967-12-18 | 1970-07-07 | Shell Oil Co | Pretreatment of hydroconversion catalysts |
-
1970
- 1970-09-28 GB GB1324034D patent/GB1324034A/en not_active Expired
-
1971
- 1971-07-30 BE BE770713A patent/BE770713A/nl not_active IP Right Cessation
- 1971-09-27 JP JP7472071A patent/JPS5428402B1/ja active Pending
- 1971-09-27 FR FR7134645A patent/FR2112984A5/fr not_active Expired
- 1971-09-27 AU AU33903/71A patent/AU449016B2/en not_active Expired
- 1971-09-27 CA CA123,785A patent/CA989759A/en not_active Expired
- 1971-09-27 DE DE19712148155 patent/DE2148155C3/de not_active Expired
- 1971-09-27 NL NL7113233A patent/NL171027C/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| GB1324034A (en) | 1973-07-18 |
| DE2148155A1 (de) | 1972-03-30 |
| JPS5428402B1 (enrdf_load_stackoverflow) | 1979-09-17 |
| FR2112984A5 (enrdf_load_stackoverflow) | 1972-06-23 |
| NL171027B (nl) | 1982-09-01 |
| BE770713A (nl) | 1972-01-31 |
| DE2148155B2 (de) | 1981-04-09 |
| AU449016B2 (en) | 1974-05-30 |
| AU3390371A (en) | 1973-04-05 |
| NL171027C (nl) | 1983-02-01 |
| CA989759A (en) | 1976-05-25 |
| NL7113233A (enrdf_load_stackoverflow) | 1972-03-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| 8263 | Opposition against grant of a patent | ||
| C3 | Grant after two publication steps (3rd publication) |