DE2117651A1 - Katalysator für die Umwandlung von Kohlenwasserstoffen, seine Herstellung und Verwendung - Google Patents
Katalysator für die Umwandlung von Kohlenwasserstoffen, seine Herstellung und VerwendungInfo
- Publication number
- DE2117651A1 DE2117651A1 DE19712117651 DE2117651A DE2117651A1 DE 2117651 A1 DE2117651 A1 DE 2117651A1 DE 19712117651 DE19712117651 DE 19712117651 DE 2117651 A DE2117651 A DE 2117651A DE 2117651 A1 DE2117651 A1 DE 2117651A1
- Authority
- DE
- Germany
- Prior art keywords
- platinum
- metal
- catalyst
- hydrocarbons
- ions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title claims description 76
- 238000006243 chemical reaction Methods 0.000 title claims description 21
- 229930195733 hydrocarbon Natural products 0.000 title claims description 21
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 21
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 161
- 229910052697 platinum Inorganic materials 0.000 claims description 59
- 229910052751 metal Inorganic materials 0.000 claims description 48
- 239000002184 metal Substances 0.000 claims description 48
- 239000010949 copper Substances 0.000 claims description 25
- 239000000243 solution Substances 0.000 claims description 23
- 150000002500 ions Chemical class 0.000 claims description 16
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 14
- 229910052802 copper Inorganic materials 0.000 claims description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims description 14
- 239000001257 hydrogen Substances 0.000 claims description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 13
- 239000011135 tin Substances 0.000 claims description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 10
- -1 PtCu Substances 0.000 claims description 9
- 150000002739 metals Chemical class 0.000 claims description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- 239000000956 alloy Substances 0.000 claims description 6
- 229910002847 PtSn Inorganic materials 0.000 claims description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 5
- 239000006104 solid solution Substances 0.000 claims description 5
- 229910052718 tin Inorganic materials 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 229910002837 PtCo Inorganic materials 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910002836 PtFe Inorganic materials 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 238000001833 catalytic reforming Methods 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 3
- 229910002844 PtNi Inorganic materials 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 2
- 229910052793 cadmium Inorganic materials 0.000 claims description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910052741 iridium Inorganic materials 0.000 claims description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 2
- 229910052753 mercury Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- 239000010948 rhodium Substances 0.000 claims description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 239000012876 carrier material Substances 0.000 claims 3
- 239000000463 material Substances 0.000 claims 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims 1
- 239000004917 carbon fiber Substances 0.000 claims 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 30
- 230000000694 effects Effects 0.000 description 17
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
- 239000007858 starting material Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 6
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000008096 xylene Substances 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 150000003738 xylenes Chemical class 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 238000006356 dehydrogenation reaction Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000969 carrier Substances 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- WBLJAACUUGHPMU-UHFFFAOYSA-N copper platinum Chemical class [Cu].[Pt] WBLJAACUUGHPMU-UHFFFAOYSA-N 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- WMWXXXSCZVGQAR-UHFFFAOYSA-N dialuminum;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3] WMWXXXSCZVGQAR-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000006317 isomerization reaction Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 150000004684 trihydrates Chemical class 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910021592 Copper(II) chloride Inorganic materials 0.000 description 1
- 238000004435 EPR spectroscopy Methods 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 101150003085 Pdcl gene Proteins 0.000 description 1
- 229910001260 Pt alloy Inorganic materials 0.000 description 1
- 229910018949 PtAu Inorganic materials 0.000 description 1
- 229910018883 Pt—Cu Inorganic materials 0.000 description 1
- 229910000629 Rh alloy Inorganic materials 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- FDTUSPNGYPXVIO-UHFFFAOYSA-N [B+]=O.[O-2].[Al+3].[O-2] Chemical compound [B+]=O.[O-2].[Al+3].[O-2] FDTUSPNGYPXVIO-UHFFFAOYSA-N 0.000 description 1
- CLBRCZAHAHECKY-UHFFFAOYSA-N [Co].[Pt] Chemical compound [Co].[Pt] CLBRCZAHAHECKY-UHFFFAOYSA-N 0.000 description 1
- KFOLLPUZRCFERL-UHFFFAOYSA-N [O-2].[Mg+2].O=[Si]=O Chemical compound [O-2].[Mg+2].O=[Si]=O KFOLLPUZRCFERL-UHFFFAOYSA-N 0.000 description 1
- HHUIAYDQMNHELC-UHFFFAOYSA-N [O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O HHUIAYDQMNHELC-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- DALDUXIBIKGWTK-UHFFFAOYSA-N benzene;toluene Chemical compound C1=CC=CC=C1.CC1=CC=CC=C1 DALDUXIBIKGWTK-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000012084 conversion product Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000002534 ethynyl group Chemical class [H]C#C* 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 238000001030 gas--liquid chromatography Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 230000009022 nonlinear effect Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 1
- HWLDNSXPUQTBOD-UHFFFAOYSA-N platinum-iridium alloy Chemical compound [Ir].[Pt] HWLDNSXPUQTBOD-UHFFFAOYSA-N 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/321—Catalytic processes
- C07C5/324—Catalytic processes with metals
- C07C5/325—Catalytic processes with metals of the platinum group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
- C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
- C07C5/41—Catalytic processes
- C07C5/415—Catalytic processes with metals
- C07C5/417—Catalytic processes with metals of the platinum group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
- C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1736170 | 1970-04-13 | ||
| GB3236870 | 1970-07-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2117651A1 true DE2117651A1 (de) | 1971-10-28 |
Family
ID=26252637
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19712117651 Pending DE2117651A1 (de) | 1970-04-13 | 1971-04-10 | Katalysator für die Umwandlung von Kohlenwasserstoffen, seine Herstellung und Verwendung |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3759823A (enExample) |
| BE (1) | BE765668A (enExample) |
| CA (1) | CA938278A (enExample) |
| DE (1) | DE2117651A1 (enExample) |
| FR (1) | FR2089516A5 (enExample) |
| GB (1) | GB1332361A (enExample) |
| NL (1) | NL7104741A (enExample) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4065514A (en) * | 1972-07-17 | 1977-12-27 | Texaco Inc. | Preparation of methane |
| US4297245A (en) * | 1972-07-17 | 1981-10-27 | Texaco Inc. | Catalyst for the preparation of methane |
| US3939060A (en) * | 1972-09-13 | 1976-02-17 | Universal Oil Products Company | Hydrocarbon conversion with a sulfided acidic catalytic composite |
| GB1456369A (en) * | 1972-11-30 | 1976-11-24 | Stamicarbon | Catalyst preparation |
| HU168073B (enExample) * | 1973-12-19 | 1976-02-28 | ||
| US4049576A (en) * | 1974-10-04 | 1977-09-20 | Ashland Oil, Inc. | Platinum-palladium catalyst for selective hydrogenation of aromatics and olefins in hydrocarbon fractions |
| US3943053A (en) * | 1974-10-04 | 1976-03-09 | Ashland Oil, Inc. | Selective hydrogenation of aromatics and olefins in hydrocarbon fractions |
| US4018668A (en) * | 1975-01-16 | 1977-04-19 | Universal Oil Products Company | Hydrocarbon conversion with an acidic multimetallic sulfur-free catalytic composite |
| US3950243A (en) * | 1975-03-14 | 1976-04-13 | Universal Oil Products Company | Hydrocarbon conversion with an acidic sulfur-free multimetallic catalytic composite |
| US3959121A (en) * | 1975-05-05 | 1976-05-25 | Universal Oil Products Company | Hydrocarbon conversion with an acidic multimetallic catalytic composite |
| US3998724A (en) * | 1975-05-12 | 1976-12-21 | Universal Oil Products Company | Hydrocarbon conversion with an acidic multimetallic catalytic composite |
| US3972806A (en) * | 1975-07-03 | 1976-08-03 | Universal Oil Products Company | Hydrocarbon conversion with an acidic multimetallic catalyst composite |
| US4036903A (en) * | 1975-08-08 | 1977-07-19 | Uop Inc. | Dehydrocyclization with an acidic multimetallic catalytic composite |
| US3981795A (en) * | 1975-08-08 | 1976-09-21 | Uop Inc. | Hydrocarbon conversion with an acidic multimetallic catalytic composite |
| US4139495A (en) * | 1976-08-27 | 1979-02-13 | Uop Inc. | Multimetallic catalytic composite |
| LU76107A1 (enExample) * | 1976-10-29 | 1978-05-16 | ||
| US4115252A (en) * | 1976-11-22 | 1978-09-19 | Uop Inc. | Hydrocarbon conversion with an acidic multimetallic catalytic composite |
| US4179406A (en) * | 1976-11-22 | 1979-12-18 | Uop Inc. | Acidic multimetallic catalytic composite |
| US4233185A (en) * | 1976-12-08 | 1980-11-11 | Johnson, Matthey & Co., Limited | Catalysts for oxidation and reduction |
| US4206042A (en) * | 1978-03-31 | 1980-06-03 | Uop Inc. | Hydrocarbon dehydrocyclization with an acidic multimetallic catalytic composite |
| US4295957A (en) * | 1979-04-30 | 1981-10-20 | Exxon Research & Engineering Co. | Reforming with multimetallic catalysts |
| US4251392A (en) * | 1979-04-30 | 1981-02-17 | Exxon Research & Engineering Co. | Reforming with multimetallic catalysts |
| FR2466279A1 (fr) * | 1979-07-02 | 1981-04-10 | Catalyse Soc Prod Francais | Nouveaux catalyseurs d'hydroreformage catalytique ou de production d'hydrocarbures aromatiques |
| FR2468406A1 (fr) * | 1979-11-05 | 1981-05-08 | Catalyse Soc Prod Francais | Nouveaux catalyseurs de conversion d'hydrocarbures |
| US5409877A (en) * | 1991-08-22 | 1995-04-25 | Director-General Of Agency Of Industrial Science And Technology | Catalyst for producing aldehyde and alcohol from olefin, carbon monoxide and hydrogen |
| US5905180A (en) | 1996-01-22 | 1999-05-18 | Regents Of The University Of Minnesota | Catalytic oxidative dehydrogenation process and catalyst |
| CA2260240A1 (en) * | 1996-07-15 | 1998-01-22 | James N. Ziemer | Sulfur resistant hydroconversion catalyst and hydroprocessing of sulfur-containing lube feedstock |
| CA2260104C (en) * | 1996-07-16 | 2003-12-30 | Chevron U.S.A. Inc. | Base stock lube oil manufacturing process |
| BR0012743A (pt) * | 1999-07-28 | 2002-04-02 | S D Chemie Inc | Catalisador de hidrogenação tolerante a enxofre, processo para fabricação e uso do mesmo |
| GB0311568D0 (en) * | 2003-05-20 | 2003-06-25 | Univ Coventry | Method for making a nano-particulate medium |
| US7811965B2 (en) * | 2004-08-18 | 2010-10-12 | Symyx Solutions, Inc. | Platinum-copper-nickel fuel cell catalyst |
| EP1834939A1 (en) * | 2006-03-15 | 2007-09-19 | MPG Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. | Hydrogenation process using catalyst comprising ordered intermetallic compound |
| EP2039669A1 (en) * | 2007-09-19 | 2009-03-25 | Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. | Use of a mixture of an ordered intermetallic compound and an inert material as a catalyst and corresponding hydrogenation processes |
| EP2598434B1 (en) | 2010-07-26 | 2018-03-21 | Council Of Scientific & Industrial Research | An improved process for the storage delivery of hydrogen using catalyst |
| US20160068973A1 (en) * | 2013-04-25 | 2016-03-10 | Technical University Of Denmark | Alloy Catalyst Material |
| US20210206632A1 (en) * | 2018-05-29 | 2021-07-08 | Saida Fds Inc. | Device and catalyst for use with same |
| CN114054023B (zh) * | 2020-07-31 | 2023-08-25 | 中国科学院大连化学物理研究所 | 一种合金单原子催化剂的制备方法和应用 |
-
1971
- 1971-03-25 CA CA108665A patent/CA938278A/en not_active Expired
- 1971-03-30 US US00129439A patent/US3759823A/en not_active Expired - Lifetime
- 1971-04-08 NL NL7104741A patent/NL7104741A/xx unknown
- 1971-04-09 FR FR7112811A patent/FR2089516A5/fr not_active Expired
- 1971-04-10 DE DE19712117651 patent/DE2117651A1/de active Pending
- 1971-04-13 BE BE765668A patent/BE765668A/xx unknown
- 1971-04-19 GB GB1736170A patent/GB1332361A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2089516A5 (enExample) | 1972-01-07 |
| NL7104741A (enExample) | 1971-10-15 |
| GB1332361A (en) | 1973-10-03 |
| CA938278A (en) | 1973-12-11 |
| BE765668A (fr) | 1971-10-13 |
| US3759823A (en) | 1973-09-18 |
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