DE2064488C3 - Verfahren zur Herstellung von Klebstoffgemischen - Google Patents
Verfahren zur Herstellung von KlebstoffgemischenInfo
- Publication number
- DE2064488C3 DE2064488C3 DE2064488A DE2064488A DE2064488C3 DE 2064488 C3 DE2064488 C3 DE 2064488C3 DE 2064488 A DE2064488 A DE 2064488A DE 2064488 A DE2064488 A DE 2064488A DE 2064488 C3 DE2064488 C3 DE 2064488C3
- Authority
- DE
- Germany
- Prior art keywords
- vinyl
- resin
- weight
- copolymers
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000853 adhesive Substances 0.000 title claims description 24
- 230000001070 adhesive effect Effects 0.000 title claims description 24
- 239000000203 mixture Substances 0.000 title claims description 18
- 238000000034 method Methods 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 28
- 150000001447 alkali salts Chemical class 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
- 229920001577 copolymer Polymers 0.000 claims description 18
- 239000006185 dispersion Substances 0.000 claims description 18
- 239000003784 tall oil Substances 0.000 claims description 15
- -1 vinyl compound Chemical class 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 14
- 239000011347 resin Substances 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000000178 monomer Substances 0.000 claims description 13
- 239000004094 surface-active agent Substances 0.000 claims description 12
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 9
- 239000005977 Ethylene Substances 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 7
- 125000000129 anionic group Chemical group 0.000 claims description 5
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 3
- 150000007519 polyprotic acids Polymers 0.000 claims description 3
- 150000001241 acetals Chemical class 0.000 claims 1
- 229920006163 vinyl copolymer Polymers 0.000 claims 1
- 239000000243 solution Substances 0.000 description 24
- 239000004372 Polyvinyl alcohol Substances 0.000 description 15
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 15
- 229920002451 polyvinyl alcohol Polymers 0.000 description 15
- 238000006116 polymerization reaction Methods 0.000 description 13
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 12
- 239000002253 acid Substances 0.000 description 11
- 239000000839 emulsion Substances 0.000 description 11
- 150000007513 acids Chemical class 0.000 description 9
- 150000002605 large molecules Chemical class 0.000 description 9
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000000123 paper Substances 0.000 description 6
- 239000011118 polyvinyl acetate Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 5
- 239000005038 ethylene vinyl acetate Substances 0.000 description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 5
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 229920001567 vinyl ester resin Polymers 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 229920000578 graft copolymer Polymers 0.000 description 4
- 239000002655 kraft paper Substances 0.000 description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000004908 Emulsion polymer Substances 0.000 description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 2
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000004815 dispersion polymer Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 150000002688 maleic acid derivatives Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920001290 polyvinyl ester Polymers 0.000 description 2
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000021736 acetylation Effects 0.000 description 1
- 238000006640 acetylation reaction Methods 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000008601 oleoresin Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000120 polyethyl acrylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920006327 polystyrene foam Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 150000003385 sodium Chemical class 0.000 description 1
- 239000000072 sodium resin Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C08F291/04—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to halogen-containing macromolecules
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP45018880A JPS4840890B1 (enExample) | 1970-03-05 | 1970-03-05 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2064488A1 DE2064488A1 (de) | 1971-09-23 |
| DE2064488B2 DE2064488B2 (de) | 1979-03-15 |
| DE2064488C3 true DE2064488C3 (de) | 1979-11-08 |
Family
ID=11983851
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2064488A Expired DE2064488C3 (de) | 1970-03-05 | 1970-12-30 | Verfahren zur Herstellung von Klebstoffgemischen |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3746677A (enExample) |
| JP (1) | JPS4840890B1 (enExample) |
| BE (1) | BE761403A (enExample) |
| CH (1) | CH530454A (enExample) |
| DE (1) | DE2064488C3 (enExample) |
| ES (1) | ES386972A1 (enExample) |
| FR (1) | FR2083873A5 (enExample) |
| GB (1) | GB1336641A (enExample) |
| NL (1) | NL7102941A (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4280942A (en) * | 1980-07-09 | 1981-07-28 | Formica Corporation | Aqueous acrylic contact adhesive |
| FR2492398A1 (fr) * | 1980-10-16 | 1982-04-23 | Rhone Poulenc Ind | Colles a prise rapide a base de latex aqueux de polyacetate de vinyle plastifie et leur procede de preparation |
| FR2508478A2 (fr) * | 1981-06-30 | 1982-12-31 | Rhone Poulenc Ind | Colles a prise rapide a base de latex aqueux de copolymere d'acetate de vinyle plastifie et leur procede de fabrication |
| EP0050548B1 (fr) * | 1980-10-16 | 1985-01-16 | Rhone-Poulenc Specialites Chimiques | Colles à prise rapide à base de latex aqueux de polymère d'acetate de vinyle plastifié |
| JPS57100107A (en) * | 1980-12-12 | 1982-06-22 | Daicel Chem Ind Ltd | Preparation of adhesive |
| GB2179949B (en) * | 1985-09-03 | 1989-08-31 | Scott Paper Co | Adhesive composition |
| DE3771093D1 (de) * | 1986-03-11 | 1991-08-08 | Nat Starch Chem Invest | Emulsionsartige, einbrennende rostschutzzusammensetzung. |
| DE4431343A1 (de) * | 1994-09-02 | 1996-03-07 | Hoechst Ag | Heterogene Polyvinylester-Dispersionen und -Pulver |
| DE10205893A1 (de) * | 2002-02-13 | 2003-08-21 | Henkel Kgaa | Emissionsarmer, wässriger Dispersions-Klebstoff |
| US20050113499A1 (en) * | 2002-02-13 | 2005-05-26 | Thomas Tamcke | Low-emission aqueous dispersion adhesive |
-
1970
- 1970-03-05 JP JP45018880A patent/JPS4840890B1/ja active Pending
- 1970-12-30 DE DE2064488A patent/DE2064488C3/de not_active Expired
- 1970-12-31 ES ES386972A patent/ES386972A1/es not_active Expired
-
1971
- 1971-01-07 GB GB79171A patent/GB1336641A/en not_active Expired
- 1971-01-11 BE BE761403A patent/BE761403A/xx unknown
- 1971-01-12 CH CH45471A patent/CH530454A/fr not_active IP Right Cessation
- 1971-01-15 FR FR7101295A patent/FR2083873A5/fr not_active Expired
- 1971-03-04 US US00121197A patent/US3746677A/en not_active Expired - Lifetime
- 1971-03-05 NL NL7102941A patent/NL7102941A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE761403A (fr) | 1971-06-16 |
| DE2064488A1 (de) | 1971-09-23 |
| GB1336641A (en) | 1973-11-07 |
| JPS4840890B1 (enExample) | 1973-12-03 |
| ES386972A1 (es) | 1973-12-16 |
| DE2064488B2 (de) | 1979-03-15 |
| US3746677A (en) | 1973-07-17 |
| FR2083873A5 (enExample) | 1971-12-17 |
| CH530454A (fr) | 1972-11-15 |
| NL7102941A (enExample) | 1971-09-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2529547C2 (de) | Verfahren zur herstellung von emulsionen durch polymerisation von waessrigen monomer-polymer-dispersionen | |
| DE2064488C3 (de) | Verfahren zur Herstellung von Klebstoffgemischen | |
| DE746788C (de) | Verfahren zur Herstellung von Polymerisationsprodukten aus Vinylestern | |
| DE697481C (de) | Verfahren zur Herstellung von in kaltem Wasser loeslichen hochmolekularen Polymerisationsprodukten | |
| EP0114834A1 (de) | Verfahren zur herstellung von polymerdispersionen und ihre verwendung | |
| CH345157A (de) | Verfahren zur Herstellung von Polyestern | |
| DE4431343A1 (de) | Heterogene Polyvinylester-Dispersionen und -Pulver | |
| EP0062906B1 (de) | Wässrige Polyvinylester-Dispersion, Verfahren zu ihrer Herstellung und ihre Verwendung | |
| EP0160257A2 (de) | Fluorhaltige Copolymerisate, Verfahren zu ihrer Herstellung und ihre Verwendung | |
| DE2938967C2 (enExample) | ||
| EP1012196B1 (de) | Verfahren zur herstellung lösemittelfreier polivinylester-dispersionen mit erhöhter wasserresistenz | |
| DE2201862C3 (de) | Verfahren zur Herstellung von wachsartigen Veresterungs- und Verseifungsprodukten oxidierter Polyäthylene | |
| DE69503764T2 (de) | Webverfahren unter verwendung von aus polyvinylalkoholcopolymer bestehenden schlichtemitteln mit hoher entschlichtbarkeit | |
| DE69503766T2 (de) | Textilschlichte auf basis von gemischten polyvinylalcoholpolymeren mit verbesserter entschlichtbarkeit | |
| DE1203958B (de) | Verfahren zur Herstellung von vollstaendig oder teilweise verseiften Vinylacetat-AEthylen- Mischpolymerisaten | |
| DE745031C (de) | Verfahren zur Herstellung von Kunststoffen | |
| DE1953307C3 (de) | Klebmasse aus einer hochmolekularen Polyvinylverbindung und einem anionischen oberflächenaktiven Mittel | |
| DE69500700T2 (de) | Poly(vinylalkohol)stärkemischungen für textilschlichten mit verbesserter fähigkeit zum entschlichten | |
| DE1696193B2 (de) | Satinweißhaltige Streichmassen mit guter Viskositätsstabilität | |
| DE2019233C3 (de) | Verfahren zur Herstellung von Vinylacetat-Äthylen-Copolymerisatemulsion | |
| DE957167C (de) | Verfahren zur Emulsionspolymerisation von Styrolen | |
| DE1201988B (de) | Polymerisatgemische zur Herstellung von Dispersionen in Weichmachern | |
| DE68916215T2 (de) | Klebemischung. | |
| DE69206197T2 (de) | Polymer Dispersionen von Vinylpivalat, Vinylacetat und Alkylen. | |
| DE1260145B (de) | Verfahren zur Herstellung von Polymerisatdispersionen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |