DE2003579A1 - Verfahren zur Herstellung von Polyester-Diacrylaten - Google Patents
Verfahren zur Herstellung von Polyester-DiacrylatenInfo
- Publication number
- DE2003579A1 DE2003579A1 DE19702003579 DE2003579A DE2003579A1 DE 2003579 A1 DE2003579 A1 DE 2003579A1 DE 19702003579 DE19702003579 DE 19702003579 DE 2003579 A DE2003579 A DE 2003579A DE 2003579 A1 DE2003579 A1 DE 2003579A1
- Authority
- DE
- Germany
- Prior art keywords
- acid
- reaction
- water
- amount
- benzene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 21
- 229920000728 polyester Polymers 0.000 title claims description 17
- 125000004386 diacrylate group Chemical group 0.000 title claims description 15
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 24
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 19
- 238000006116 polymerization reaction Methods 0.000 claims description 19
- 239000003112 inhibitor Substances 0.000 claims description 15
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 claims description 13
- 239000012024 dehydrating agents Substances 0.000 claims description 13
- 229950000688 phenothiazine Drugs 0.000 claims description 13
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 10
- 150000002009 diols Chemical class 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 9
- 238000005886 esterification reaction Methods 0.000 claims description 9
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 8
- 230000032050 esterification Effects 0.000 claims description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 60
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 34
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 25
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 24
- 239000000203 mixture Substances 0.000 description 17
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 16
- 239000011541 reaction mixture Substances 0.000 description 14
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 7
- 238000006482 condensation reaction Methods 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 6
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 4
- -1 dicarboxylic acids Dicarboxylic acids Chemical class 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- LAQYHRQFABOIFD-UHFFFAOYSA-N 2-methoxyhydroquinone Chemical compound COC1=CC(O)=CC=C1O LAQYHRQFABOIFD-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
- HQHCYKULIHKCEB-UHFFFAOYSA-N tetradecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCC(O)=O HQHCYKULIHKCEB-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical compound C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- YCCCTDWBNCWPAX-UHFFFAOYSA-N OC(=O)C=C.OC(=O)C=C.OC(=O)C1=CC=CC=C1C(O)=O Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C1=CC=CC=C1C(O)=O YCCCTDWBNCWPAX-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- CWZCATCQVVCHRH-UHFFFAOYSA-N butanedioic acid;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CC(=C)C(O)=O.OC(=O)CCC(O)=O CWZCATCQVVCHRH-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000013051 drainage agent Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/46—Polyesters chemically modified by esterification
- C08G63/47—Polyesters chemically modified by esterification by unsaturated monocarboxylic acids or unsaturated monohydric alcohols or reactive derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP565969A JPS4836956B1 (enrdf_load_stackoverflow) | 1969-01-28 | 1969-01-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2003579A1 true DE2003579A1 (de) | 1970-07-30 |
| DE2003579B2 DE2003579B2 (enrdf_load_stackoverflow) | 1974-01-10 |
Family
ID=11617226
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19702003579 Pending DE2003579A1 (de) | 1969-01-28 | 1970-01-27 | Verfahren zur Herstellung von Polyester-Diacrylaten |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS4836956B1 (enrdf_load_stackoverflow) |
| DE (1) | DE2003579A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2029567A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1246601A (enrdf_load_stackoverflow) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0126341A3 (en) * | 1983-05-06 | 1987-02-04 | Basf Aktiengesellschaft | Process for the preparation of esters of (meth)-acrylic acid, and their use |
| US6583214B1 (en) | 1999-04-01 | 2003-06-24 | Basf Coatings Ag | Aqueous coating material that is cured thermally and/or by actinic radiation, and its use |
| WO2005047401A2 (de) | 2003-11-17 | 2005-05-26 | Basf Coatings Ag | Strukturviskose, wässrige dispersionen, verfahren zu ihrer herstellung und ihre verwendung |
| EP1897894A1 (de) | 2001-06-01 | 2008-03-12 | BASF Coatings AG | Pulverlacksuspensionen (Pulverslurries) und Pulverlacke, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE102007013242A1 (de) | 2007-03-15 | 2008-09-18 | Basf Coatings Ag | Hochkratzfeste Beschichtung mit guter Witterungs- und Rissbeständigkeit |
| DE102007013262A1 (de) | 2007-03-15 | 2008-09-18 | Basf Coatings Ag | Beschichtungsmittel enthaltend Addukte mit Silanfunktionalität und daraus hergestellte hochkratzfeste Beschichtungen mit verbesserter Rissbeständigkeit |
| US7968199B2 (en) | 2005-05-03 | 2011-06-28 | Basf Coatings Ag | Method for producing films having a coating the films obtained in this way and their use for producing molded parts in particular for use in automobile construction |
| US7985478B2 (en) | 2004-11-04 | 2011-07-26 | Basf Coatings Ag | Method for producing moulded parts, in particular for use in the car industry, and a film comprising a coating which is suitable therefor |
| US8147923B2 (en) | 2001-06-27 | 2012-04-03 | Basf Coatings Gmbh | Method for producing coatings from coating materials that can be cured by the action of heat or actinic radiation |
| US9403297B2 (en) | 2004-11-04 | 2016-08-02 | Basf Coatings Gmbh | Method for producing molded parts, especially for use in automobile manufacture, and corresponding appropriate films comprising a coating |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4984171U (enrdf_load_stackoverflow) * | 1972-11-07 | 1974-07-20 | ||
| JPS56130273A (en) * | 1980-03-19 | 1981-10-13 | Nippon Steel Corp | Manufacture of precoated steel plate |
| JPS5760662U (enrdf_load_stackoverflow) * | 1980-09-29 | 1982-04-10 | ||
| AT368179B (de) * | 1980-12-10 | 1982-09-27 | Vianova Kunstharz Ag | Verfahren zur herstellung von (meth)acrylsaeuremodifiziertenpolyerstern |
| JPS6227670U (enrdf_load_stackoverflow) * | 1985-08-01 | 1987-02-19 | ||
| DE19709465C2 (de) | 1997-03-07 | 2001-07-12 | Basf Coatings Ag | Beschichtungsmittel, Verfahren zur Herstellung von Mehrschichtlackierungen und Verwendung der Beschichtungsmittel hierfür |
| DE102008036685A1 (de) | 2008-08-06 | 2010-02-11 | Basf Coatings Ag | Zweischicht-Beschichtungssysteme mit verbesserter Zwischenhaftung |
| DE102008054283A1 (de) | 2008-11-03 | 2010-06-02 | Basf Coatings Japan Ltd., Yokohama | Farb- und/oder effektgebende Mehrschichtlackierungen mit pigmentfreien Lackierungen als Füller-Ersatz, ihre Herstellung und Verwendung |
| DE102014007805A1 (de) | 2014-05-27 | 2015-12-03 | WindplusSonne GmbH | Solarabsorber, Verfahren zu seiner Herstellung und seine Verwendung |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1081450B (de) * | 1958-03-05 | 1960-05-12 | Basf Ag | Verfahren zur Herstellung von Chloralkylestern der Acrylsaeure und ihren Substitutionsprodukten |
| US2978501A (en) * | 1958-06-02 | 1961-04-04 | Goodrich Co B F | Stabilized carboxylic monomers |
| GB920353A (en) * | 1959-12-10 | 1963-03-06 | Knapsack Ag | Process for stabilizing acrylic acid alkyl esters |
-
1969
- 1969-01-28 JP JP565969A patent/JPS4836956B1/ja active Pending
-
1970
- 1970-01-21 GB GB304870A patent/GB1246601A/en not_active Expired
- 1970-01-27 DE DE19702003579 patent/DE2003579A1/de active Pending
- 1970-01-27 FR FR7002874A patent/FR2029567A1/fr not_active Withdrawn
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0126341A3 (en) * | 1983-05-06 | 1987-02-04 | Basf Aktiengesellschaft | Process for the preparation of esters of (meth)-acrylic acid, and their use |
| US6583214B1 (en) | 1999-04-01 | 2003-06-24 | Basf Coatings Ag | Aqueous coating material that is cured thermally and/or by actinic radiation, and its use |
| EP1897894A1 (de) | 2001-06-01 | 2008-03-12 | BASF Coatings AG | Pulverlacksuspensionen (Pulverslurries) und Pulverlacke, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US8147923B2 (en) | 2001-06-27 | 2012-04-03 | Basf Coatings Gmbh | Method for producing coatings from coating materials that can be cured by the action of heat or actinic radiation |
| WO2005047401A2 (de) | 2003-11-17 | 2005-05-26 | Basf Coatings Ag | Strukturviskose, wässrige dispersionen, verfahren zu ihrer herstellung und ihre verwendung |
| US7985478B2 (en) | 2004-11-04 | 2011-07-26 | Basf Coatings Ag | Method for producing moulded parts, in particular for use in the car industry, and a film comprising a coating which is suitable therefor |
| US9403297B2 (en) | 2004-11-04 | 2016-08-02 | Basf Coatings Gmbh | Method for producing molded parts, especially for use in automobile manufacture, and corresponding appropriate films comprising a coating |
| US7968199B2 (en) | 2005-05-03 | 2011-06-28 | Basf Coatings Ag | Method for producing films having a coating the films obtained in this way and their use for producing molded parts in particular for use in automobile construction |
| DE102007013242A1 (de) | 2007-03-15 | 2008-09-18 | Basf Coatings Ag | Hochkratzfeste Beschichtung mit guter Witterungs- und Rissbeständigkeit |
| DE102007013262A1 (de) | 2007-03-15 | 2008-09-18 | Basf Coatings Ag | Beschichtungsmittel enthaltend Addukte mit Silanfunktionalität und daraus hergestellte hochkratzfeste Beschichtungen mit verbesserter Rissbeständigkeit |
| US8603587B2 (en) | 2007-03-15 | 2013-12-10 | Basf Coatings Gmbh | Coating agent containing addition compounds with silane functionality, and highly scratch-resistant coatings with improved crack resistance |
| US9169405B2 (en) | 2007-03-15 | 2015-10-27 | Basf Coatings Gmbh | Highly scratch-resistant coatings having good weathering and crack resistance |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4836956B1 (enrdf_load_stackoverflow) | 1973-11-08 |
| DE2003579B2 (enrdf_load_stackoverflow) | 1974-01-10 |
| FR2029567A1 (enrdf_load_stackoverflow) | 1970-10-23 |
| GB1246601A (en) | 1971-09-15 |
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