DE19744102A1 - Katalysatorsystem - Google Patents
KatalysatorsystemInfo
- Publication number
- DE19744102A1 DE19744102A1 DE19744102A DE19744102A DE19744102A1 DE 19744102 A1 DE19744102 A1 DE 19744102A1 DE 19744102 A DE19744102 A DE 19744102A DE 19744102 A DE19744102 A DE 19744102A DE 19744102 A1 DE19744102 A1 DE 19744102A1
- Authority
- DE
- Germany
- Prior art keywords
- formula
- compound
- catalyst system
- indenyl
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 229920000098 polyolefin Polymers 0.000 title claims description 6
- 239000012968 metallocene catalyst Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract description 100
- 239000003054 catalyst Substances 0.000 claims abstract description 56
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 29
- 125000003118 aryl group Chemical group 0.000 claims abstract description 29
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 23
- 125000004104 aryloxy group Chemical group 0.000 claims abstract description 18
- 125000002877 alkyl aryl group Chemical group 0.000 claims abstract description 16
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 10
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 claims description 65
- 238000006116 polymerization reaction Methods 0.000 claims description 33
- 229910052799 carbon Inorganic materials 0.000 claims description 25
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 24
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 22
- 125000005843 halogen group Chemical group 0.000 claims description 21
- 229940126062 Compound A Drugs 0.000 claims description 19
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims description 19
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 claims description 18
- 125000001188 haloalkyl group Chemical group 0.000 claims description 17
- 150000001336 alkenes Chemical class 0.000 claims description 16
- 125000003106 haloaryl group Chemical group 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 11
- 125000006492 halo alkyl aryl group Chemical group 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 6
- 125000002034 haloarylalkyl group Chemical group 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 claims description 3
- -1 aluminum compound Chemical class 0.000 abstract description 61
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 60
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 36
- 238000006243 chemical reaction Methods 0.000 abstract description 32
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 abstract description 28
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract description 23
- 125000001931 aliphatic group Chemical group 0.000 abstract description 13
- 239000003849 aromatic solvent Substances 0.000 abstract description 13
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract description 11
- 125000004122 cyclic group Chemical group 0.000 abstract description 4
- 125000003545 alkoxy group Chemical group 0.000 abstract description 3
- 239000000178 monomer Substances 0.000 abstract description 2
- 125000001475 halogen functional group Chemical group 0.000 abstract 4
- 229910000085 borane Inorganic materials 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 230000004044 response Effects 0.000 description 28
- 239000002904 solvent Substances 0.000 description 17
- 239000000243 solution Substances 0.000 description 14
- 239000000126 substance Substances 0.000 description 12
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 8
- 229910052731 fluorine Inorganic materials 0.000 description 8
- 239000011737 fluorine Substances 0.000 description 8
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 230000035484 reaction time Effects 0.000 description 7
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 239000007858 starting material Substances 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 5
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 5
- 229910052726 zirconium Inorganic materials 0.000 description 5
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- QXALIERKYGCHHA-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenyl)borane Chemical compound BC1=C(F)C(F)=C(F)C(F)=C1F QXALIERKYGCHHA-UHFFFAOYSA-N 0.000 description 3
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 3
- 125000002524 organometallic group Chemical group 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- VASOMTXTRMYSKD-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenyl)boronic acid Chemical compound OB(O)C1=C(F)C(F)=C(F)C(F)=C1F VASOMTXTRMYSKD-UHFFFAOYSA-N 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 2
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- 125000004361 3,4,5-trifluorophenyl group Chemical group [H]C1=C(F)C(F)=C(F)C([H])=C1* 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 125000006374 C2-C10 alkenyl group Chemical group 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000005189 alkyl hydroxy group Chemical group 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 125000005018 aryl alkenyl group Chemical group 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 125000003262 carboxylic acid ester group Chemical group [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 238000012674 dispersion polymerization Methods 0.000 description 2
- 125000003709 fluoroalkyl group Chemical group 0.000 description 2
- 125000004407 fluoroaryl group Chemical group 0.000 description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 2
- 125000002541 furyl group Chemical group 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 150000007517 lewis acids Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004076 pyridyl group Chemical group 0.000 description 2
- 125000005493 quinolyl group Chemical group 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 239000011877 solvent mixture Substances 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- 125000006736 (C6-C20) aryl group Chemical group 0.000 description 1
- ABIPLJQFLRXYES-UHFFFAOYSA-N 1,2,3,3a-tetrahydropentalene Chemical class C1=CC=C2CCCC21 ABIPLJQFLRXYES-UHFFFAOYSA-N 0.000 description 1
- BIEBZGCKLFWMCR-UHFFFAOYSA-N 2,3,3a,4-tetrahydro-1h-indene Chemical class C1C=CC=C2CCCC21 BIEBZGCKLFWMCR-UHFFFAOYSA-N 0.000 description 1
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
- VSYZXASVWVQEMR-UHFFFAOYSA-N 2-methylbuta-1,3-dienylalumane Chemical compound CC(=C[AlH2])C=C VSYZXASVWVQEMR-UHFFFAOYSA-N 0.000 description 1
- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- NWLATAZBCUUHBV-UHFFFAOYSA-N CC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC=CC=C5)=C4C=C3C)=[Si](C)C)=CC1=C2C1=CC=CC=C1.CC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC6=CC=CC=C6C=C5)=C4C=C3C)=[Si](C)C)=CC1=C2C1=CC2=CC=CC=C2C=C1.Cl.Cl.Cl.Cl Chemical compound CC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC=CC=C5)=C4C=C3C)=[Si](C)C)=CC1=C2C1=CC=CC=C1.CC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC6=CC=CC=C6C=C5)=C4C=C3C)=[Si](C)C)=CC1=C2C1=CC2=CC=CC=C2C=C1.Cl.Cl.Cl.Cl NWLATAZBCUUHBV-UHFFFAOYSA-N 0.000 description 1
- HNLHIFWNMSJZTF-UHFFFAOYSA-N CC(C)C1=C(C=C(C)C2[Zr](C3C4=CC=CC(C(C)C)=C4C=C3C)=[Si](C)C)C2=CC=C1.CC(C)(C)C1=C(C=C(C)C2[Zr](C3C4=CC=CC(C(C)(C)C)=C4C=C3C)=[Si](C)C)C2=CC=C1.Cl.Cl.Cl.Cl Chemical compound CC(C)C1=C(C=C(C)C2[Zr](C3C4=CC=CC(C(C)C)=C4C=C3C)=[Si](C)C)C2=CC=C1.CC(C)(C)C1=C(C=C(C)C2[Zr](C3C4=CC=CC(C(C)(C)C)=C4C=C3C)=[Si](C)C)C2=CC=C1.Cl.Cl.Cl.Cl HNLHIFWNMSJZTF-UHFFFAOYSA-N 0.000 description 1
- GEBHAPKJACULJB-UHFFFAOYSA-J CC(C)C1=CC(C(C)C)=C(C=C(C)C2[Zr](C3C4=CC(C(C)C)=CC(C(C)C)=C4C=C3C)=[Si](C)C)C2=C1.CC(C)C1=CC=C(C(C(C)=C2)[Zr](C3C4=CC=C(C(C)C)C(C(C)C)=C4C=C3C)=[Si](C)C)C2=C1C(C)C.[Cl-].[Cl-].[Cl-].[Cl-].Cl.Cl.[Zr+4] Chemical compound CC(C)C1=CC(C(C)C)=C(C=C(C)C2[Zr](C3C4=CC(C(C)C)=CC(C(C)C)=C4C=C3C)=[Si](C)C)C2=C1.CC(C)C1=CC=C(C(C(C)=C2)[Zr](C3C4=CC=C(C(C)C)C(C(C)C)=C4C=C3C)=[Si](C)C)C2=C1C(C)C.[Cl-].[Cl-].[Cl-].[Cl-].Cl.Cl.[Zr+4] GEBHAPKJACULJB-UHFFFAOYSA-J 0.000 description 1
- WUUJIJLSJCGQKS-UHFFFAOYSA-N CC(C)CC1=CC=C(C(C(C)=C2)[Zr](C3C4=CC=C(CC(C)C)C=C4C=C3C)=[Si](C)C)C2=C1.CC(C)(C)C1=CC=C(C(C(C)=C2)[Zr](C3C4=CC=C(C(C)(C)C)C=C4C=C3C)=[Si](C)C)C2=C1.Cl.Cl.Cl.Cl.Cl.Cl Chemical compound CC(C)CC1=CC=C(C(C(C)=C2)[Zr](C3C4=CC=C(CC(C)C)C=C4C=C3C)=[Si](C)C)C2=C1.CC(C)(C)C1=CC=C(C(C(C)=C2)[Zr](C3C4=CC=C(C(C)(C)C)C=C4C=C3C)=[Si](C)C)C2=C1.Cl.Cl.Cl.Cl.Cl.Cl WUUJIJLSJCGQKS-UHFFFAOYSA-N 0.000 description 1
- VWTVXOSCPQSDLG-UHFFFAOYSA-L CC(C)c1cccc2C(C(C)=Cc12)[Zr](Cl)(Cl)(C1C(C)=Cc2c1cccc2C(C)C)=[Si](C)c1ccccc1 Chemical compound CC(C)c1cccc2C(C(C)=Cc12)[Zr](Cl)(Cl)(C1C(C)=Cc2c1cccc2C(C)C)=[Si](C)c1ccccc1 VWTVXOSCPQSDLG-UHFFFAOYSA-L 0.000 description 1
- UINHOCLEQOISNK-UHFFFAOYSA-J CC(CC1=C(C2=CC=CC3=CC=CC4=C23)C4=C2)=CC1=C2[Zr](C1=C(C=C(C)C2)C2=C(C2=CC=CC3=CC=CC4=C23)C4=C1)=[Si](C)C1=CC=CC=C1.CC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1C)=[Si](C)C1=CC=CC=C1.[Cl-].[Cl-].[Cl-].[Cl-].Cl.Cl.[Zr+4] Chemical compound CC(CC1=C(C2=CC=CC3=CC=CC4=C23)C4=C2)=CC1=C2[Zr](C1=C(C=C(C)C2)C2=C(C2=CC=CC3=CC=CC4=C23)C4=C1)=[Si](C)C1=CC=CC=C1.CC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1C)=[Si](C)C1=CC=CC=C1.[Cl-].[Cl-].[Cl-].[Cl-].Cl.Cl.[Zr+4] UINHOCLEQOISNK-UHFFFAOYSA-J 0.000 description 1
- OXLXAPYJCPFBFT-UHFFFAOYSA-L CC1=CC(C)(C=C1)[Zr](Cl)(Cl)C1(C)C=CC(C)=C1 Chemical compound CC1=CC(C)(C=C1)[Zr](Cl)(Cl)C1(C)C=CC(C)=C1 OXLXAPYJCPFBFT-UHFFFAOYSA-L 0.000 description 1
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- QJUAXGQDGMCGBZ-UHFFFAOYSA-N CC1=CC2=CC=C(C=CC=C3)C3=C2C1[Zr](C1C2=C(C=CC=C3)C3=CC=C2C=C1C)=[Si](C)C.C[Si](C)=[Zr](C1C2=CC=CC=C2C=C1)C1C2=CC=CC=C2C=C1.C[Si](C)=[Zr](C1C2=CC=CC(C3=CC=CC4=CC=CC=C34)=C2C=C1)C1C2=CC=CC(C3=CC=CC4=CC=CC=C34)=C2C=C1.Cl.Cl.Cl.Cl.Cl.Cl Chemical compound CC1=CC2=CC=C(C=CC=C3)C3=C2C1[Zr](C1C2=C(C=CC=C3)C3=CC=C2C=C1C)=[Si](C)C.C[Si](C)=[Zr](C1C2=CC=CC=C2C=C1)C1C2=CC=CC=C2C=C1.C[Si](C)=[Zr](C1C2=CC=CC(C3=CC=CC4=CC=CC=C34)=C2C=C1)C1C2=CC=CC(C3=CC=CC4=CC=CC=C34)=C2C=C1.Cl.Cl.Cl.Cl.Cl.Cl QJUAXGQDGMCGBZ-UHFFFAOYSA-N 0.000 description 1
- IZYXSTPBQMPZGT-UHFFFAOYSA-N CC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1C)=[Si](C)C.CC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC=CC6=CC=CC=C56)=C4C=C3C)=[Si](C)C)=CC1=C2C1=CC=CC2=CC=CC=C12.Cl.Cl.Cl.Cl Chemical compound CC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1C)=[Si](C)C.CC(C(C1=CC=C2)[Zr](C3C4=CC=CC(C5=CC=CC6=CC=CC=C56)=C4C=C3C)=[Si](C)C)=CC1=C2C1=CC=CC2=CC=CC=C12.Cl.Cl.Cl.Cl IZYXSTPBQMPZGT-UHFFFAOYSA-N 0.000 description 1
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- ZQVDTPHKVJVFGG-UHFFFAOYSA-L CCC1=Cc2c(cccc2-c2ccccc2)C1[Zr](Cl)(Cl)(C1C(CC)=Cc2c1cccc2-c1ccccc1)=[Si](C)C Chemical compound CCC1=Cc2c(cccc2-c2ccccc2)C1[Zr](Cl)(Cl)(C1C(CC)=Cc2c1cccc2-c1ccccc1)=[Si](C)C ZQVDTPHKVJVFGG-UHFFFAOYSA-L 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- AZBVUMJQAKFEJA-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=CC(=CC=C12)CC(C)C)C)C1C(=CC2=CC(=CC=C12)CC(C)C)C)C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].C[Si](=[Zr+2](C1C(=CC2=CC(=CC=C12)CC(C)C)C)C1C(=CC2=CC(=CC=C12)CC(C)C)C)C1=CC=CC=C1 AZBVUMJQAKFEJA-UHFFFAOYSA-L 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- ORVACBDINATSAR-UHFFFAOYSA-N dimethylaluminum Chemical compound C[Al]C ORVACBDINATSAR-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000005151 nonafluorobutanesulfonyl group Chemical group FC(C(C(S(=O)(=O)*)(F)F)(F)F)(C(F)(F)F)F 0.000 description 1
- 150000002899 organoaluminium compounds Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- XBFJAVXCNXDMBH-UHFFFAOYSA-N tetracyclo[6.2.1.1(3,6).0(2,7)]dodec-4-ene Chemical compound C1C(C23)C=CC1C3C1CC2CC1 XBFJAVXCNXDMBH-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
- 125000005147 toluenesulfonyl group Chemical group C=1(C(=CC=CC1)S(=O)(=O)*)C 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- RVOMEIZTHYMDKM-UHFFFAOYSA-N triethylalumane;trimethylalumane Chemical compound C[Al](C)C.CC[Al](CC)CC RVOMEIZTHYMDKM-UHFFFAOYSA-N 0.000 description 1
- 125000004044 trifluoroacetyl group Chemical group FC(C(=O)*)(F)F 0.000 description 1
- 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19744102A DE19744102A1 (de) | 1997-10-06 | 1997-10-06 | Katalysatorsystem |
| EP98949985A EP1023334B1 (de) | 1997-10-06 | 1998-09-03 | Katalysatorsystem |
| PCT/EP1998/005589 WO1999018135A1 (de) | 1997-10-06 | 1998-09-03 | Katalysatorsystem |
| US09/509,787 US6500908B1 (en) | 1997-10-06 | 1998-09-03 | Catalyst system |
| JP2000514941A JP2001519443A (ja) | 1997-10-06 | 1998-09-03 | 触媒系 |
| DE59807331T DE59807331D1 (de) | 1997-10-06 | 1998-09-03 | Katalysatorsystem |
| BR9812853-1A BR9812853A (pt) | 1997-10-06 | 1998-09-03 | Sistema catalizador, processo para preparar uma poliolefina, e, uso de um sistema catalisador |
| ES98949985T ES2193564T3 (es) | 1997-10-06 | 1998-09-03 | Sistema catalizador. |
| US10/289,338 US20030109652A1 (en) | 1997-10-06 | 2002-11-07 | Catalyst system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19744102A DE19744102A1 (de) | 1997-10-06 | 1997-10-06 | Katalysatorsystem |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19744102A1 true DE19744102A1 (de) | 1999-04-15 |
Family
ID=7844737
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19744102A Withdrawn DE19744102A1 (de) | 1997-10-06 | 1997-10-06 | Katalysatorsystem |
| DE59807331T Expired - Lifetime DE59807331D1 (de) | 1997-10-06 | 1998-09-03 | Katalysatorsystem |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE59807331T Expired - Lifetime DE59807331D1 (de) | 1997-10-06 | 1998-09-03 | Katalysatorsystem |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US6500908B1 (https=) |
| EP (1) | EP1023334B1 (https=) |
| JP (1) | JP2001519443A (https=) |
| BR (1) | BR9812853A (https=) |
| DE (2) | DE19744102A1 (https=) |
| ES (1) | ES2193564T3 (https=) |
| WO (1) | WO1999018135A1 (https=) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6953829B2 (en) | 1999-12-23 | 2005-10-11 | Basell Polyolefine Gmbh | Catalyst system and the use thereof |
| US7101940B2 (en) | 1999-12-23 | 2006-09-05 | Basell Polyolefine Gmbh | Chemical compound, method for the production thereof and its use in catalyst systems for producing polyolefins |
| EP2172493A1 (en) * | 2008-10-02 | 2010-04-07 | Total Petrochemicals Research Feluy | Activating supports based on perfluorinated boronic acids |
Families Citing this family (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19744102A1 (de) * | 1997-10-06 | 1999-04-15 | Targor Gmbh | Katalysatorsystem |
| DE59913148D1 (de) * | 1998-05-23 | 2006-04-27 | Basell Polyolefine Gmbh | Katalysatorsystem und seine verwendung zur polymerisation von propylen |
| US6495484B1 (en) * | 2000-08-28 | 2002-12-17 | Univation Technologies, Llc | Catalyst system and its use in a polymerization process |
| CN1131246C (zh) * | 2000-12-14 | 2003-12-17 | 中国石油化工股份有限公司 | 用于烯烃聚合或共聚合的催化剂组份及其催化剂和应用 |
| US7569647B2 (en) * | 2002-10-10 | 2009-08-04 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
| ES2394304T3 (es) | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| BRPI0418117B1 (pt) | 2003-12-23 | 2015-10-13 | Basell Polyolefine Gmbh | preparação de cocatalisadores suportados |
| NZ549262A (en) | 2004-03-17 | 2010-08-27 | Dow Global Technologies Inc | Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation |
| JP5159302B2 (ja) | 2004-03-17 | 2013-03-06 | ダウ グローバル テクノロジーズ エルエルシー | エチレンコポリマーを形成するためのシャトリング剤を含む触媒組成物 |
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| IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
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| ATE137770T1 (de) | 1989-10-10 | 1996-05-15 | Fina Technology | Metallocenkatalysator mit lewissäure und alkylaluminium |
| DK0426637T4 (da) | 1989-10-30 | 2002-01-14 | Fina Technology | Fremgangsmåde til fremstilling af metallocenkatalysatorer til polymerisation af olefiner |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5348299A (en) | 1992-05-06 | 1994-09-20 | Ltb Game Enterprises | Electronic gaming apparatus |
| US5449650A (en) * | 1992-12-08 | 1995-09-12 | Mitsubishi Petrochemical Company Limited | Catalyst components for polymerization of olefins and use thereof |
| US5332706A (en) * | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| US6271164B1 (en) * | 1995-09-28 | 2001-08-07 | Cornelia Fritze | Supported catalyst system, process for its production and its use in polymerizing olefins |
| DE19744102A1 (de) * | 1997-10-06 | 1999-04-15 | Targor Gmbh | Katalysatorsystem |
-
1997
- 1997-10-06 DE DE19744102A patent/DE19744102A1/de not_active Withdrawn
-
1998
- 1998-09-03 JP JP2000514941A patent/JP2001519443A/ja active Pending
- 1998-09-03 BR BR9812853-1A patent/BR9812853A/pt not_active Application Discontinuation
- 1998-09-03 EP EP98949985A patent/EP1023334B1/de not_active Expired - Lifetime
- 1998-09-03 WO PCT/EP1998/005589 patent/WO1999018135A1/de not_active Ceased
- 1998-09-03 ES ES98949985T patent/ES2193564T3/es not_active Expired - Lifetime
- 1998-09-03 US US09/509,787 patent/US6500908B1/en not_active Expired - Lifetime
- 1998-09-03 DE DE59807331T patent/DE59807331D1/de not_active Expired - Lifetime
-
2002
- 2002-11-07 US US10/289,338 patent/US20030109652A1/en not_active Abandoned
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6953829B2 (en) | 1999-12-23 | 2005-10-11 | Basell Polyolefine Gmbh | Catalyst system and the use thereof |
| US7101940B2 (en) | 1999-12-23 | 2006-09-05 | Basell Polyolefine Gmbh | Chemical compound, method for the production thereof and its use in catalyst systems for producing polyolefins |
| EP2172493A1 (en) * | 2008-10-02 | 2010-04-07 | Total Petrochemicals Research Feluy | Activating supports based on perfluorinated boronic acids |
| WO2010037808A1 (en) * | 2008-10-02 | 2010-04-08 | Total Petrochemicals Research Feluy | Activating supports based on perfluorinated boronic acids |
| EA019145B1 (ru) * | 2008-10-02 | 2014-01-30 | Тотал Петрокемикалз Ресерч Фелюи | Активирующие подложки на основе перфторированных бороновых кислот |
Also Published As
| Publication number | Publication date |
|---|---|
| US20030109652A1 (en) | 2003-06-12 |
| US6500908B1 (en) | 2002-12-31 |
| BR9812853A (pt) | 2000-08-08 |
| EP1023334B1 (de) | 2003-02-26 |
| DE59807331D1 (de) | 2003-04-03 |
| EP1023334A1 (de) | 2000-08-02 |
| JP2001519443A (ja) | 2001-10-23 |
| ES2193564T3 (es) | 2003-11-01 |
| WO1999018135A1 (de) | 1999-04-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8127 | New person/name/address of the applicant |
Owner name: BASELL POLYOLEFINE GMBH, 77694 KEHL, DE |
|
| 8127 | New person/name/address of the applicant |
Owner name: BASELL POLYOLEFINE GMBH, 50389 WESSELING, DE |
|
| 8141 | Disposal/no request for examination |