DE1810866B2 - Verwendung von Stabilisatoren enthalten den pulverförmigen Copolymerisaten aus 90 bis 99 Gew % Vinylchlorid und 1 bis 10 Gew % Propylen mit einem K Wert von 50 bis 60 zur Herstellung von weichmacherfreien Formteilen nach dem Rotationsschmelzverfahren - Google Patents
Verwendung von Stabilisatoren enthalten den pulverförmigen Copolymerisaten aus 90 bis 99 Gew % Vinylchlorid und 1 bis 10 Gew % Propylen mit einem K Wert von 50 bis 60 zur Herstellung von weichmacherfreien Formteilen nach dem RotationsschmelzverfahrenInfo
- Publication number
- DE1810866B2 DE1810866B2 DE19681810866 DE1810866A DE1810866B2 DE 1810866 B2 DE1810866 B2 DE 1810866B2 DE 19681810866 DE19681810866 DE 19681810866 DE 1810866 A DE1810866 A DE 1810866A DE 1810866 B2 DE1810866 B2 DE 1810866B2
- Authority
- DE
- Germany
- Prior art keywords
- weight
- vinyl chloride
- plasticizer
- propylene
- molded parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001577 copolymer Polymers 0.000 title claims description 18
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 13
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims description 8
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title claims description 8
- 239000003381 stabilizer Substances 0.000 title claims description 8
- 238000000034 method Methods 0.000 title description 8
- 238000010309 melting process Methods 0.000 claims description 11
- 238000000465 moulding Methods 0.000 description 27
- 150000001875 compounds Chemical class 0.000 description 20
- 238000002844 melting Methods 0.000 description 14
- 230000008018 melting Effects 0.000 description 13
- -1 polyethylene Polymers 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000012778 molding material Substances 0.000 description 3
- 235000013872 montan acid ester Nutrition 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical class OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- MGFRKBRDZIMZGO-UHFFFAOYSA-N barium cadmium Chemical compound [Cd].[Ba] MGFRKBRDZIMZGO-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- MRJPLNTZAQOYFF-UHFFFAOYSA-N buta-1,3-diene;chloroethene;prop-2-enenitrile Chemical compound ClC=C.C=CC=C.C=CC#N MRJPLNTZAQOYFF-UHFFFAOYSA-N 0.000 description 1
- WWNGFHNQODFIEX-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;styrene Chemical compound C=CC=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WWNGFHNQODFIEX-UHFFFAOYSA-N 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000009750 centrifugal casting Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- NMAKPIATXQEXBT-UHFFFAOYSA-N didecyl phenyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OC1=CC=CC=C1 NMAKPIATXQEXBT-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000004206 montan acid ester Substances 0.000 description 1
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical class CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920005671 poly(vinyl chloride-propylene) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Moulding By Coating Moulds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19681810866 DE1810866B2 (de) | 1968-11-26 | 1968-11-26 | Verwendung von Stabilisatoren enthalten den pulverförmigen Copolymerisaten aus 90 bis 99 Gew % Vinylchlorid und 1 bis 10 Gew % Propylen mit einem K Wert von 50 bis 60 zur Herstellung von weichmacherfreien Formteilen nach dem Rotationsschmelzverfahren |
CH1739369A CH531546A (de) | 1968-11-26 | 1969-11-21 | Verfahren zur Herstellung von Formteilen aus pulvrigen weichmacherfreien Formmassen auf Basis von Vinylchloridpolymeren nach dem Rotationsschmelzverfahren |
FR6940356A FR2024245A1 (enrdf_load_stackoverflow) | 1968-11-26 | 1969-11-24 | |
CA068372A CA934117A (en) | 1968-11-26 | 1969-11-25 | Process for the preparation of mouldings |
AT1098969A AT293019B (de) | 1968-11-26 | 1969-11-25 | Verfahren zur Herstellung von Formteilen aus pulvigen weichmacherfreien Formmassen auf Basis von Vinylchloridpolymeren nach dem Rotationsschmelzverfahren |
GB1259214D GB1259214A (enrdf_load_stackoverflow) | 1968-11-26 | 1969-11-25 | |
NL6917726A NL6917726A (enrdf_load_stackoverflow) | 1968-11-26 | 1969-11-25 | |
BE742237D BE742237A (enrdf_load_stackoverflow) | 1968-11-26 | 1969-11-26 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19681810866 DE1810866B2 (de) | 1968-11-26 | 1968-11-26 | Verwendung von Stabilisatoren enthalten den pulverförmigen Copolymerisaten aus 90 bis 99 Gew % Vinylchlorid und 1 bis 10 Gew % Propylen mit einem K Wert von 50 bis 60 zur Herstellung von weichmacherfreien Formteilen nach dem Rotationsschmelzverfahren |
Publications (3)
Publication Number | Publication Date |
---|---|
DE1810866A1 DE1810866A1 (de) | 1970-07-23 |
DE1810866B2 true DE1810866B2 (de) | 1973-10-11 |
DE1810866C3 DE1810866C3 (enrdf_load_stackoverflow) | 1974-05-16 |
Family
ID=5714289
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19681810866 Granted DE1810866B2 (de) | 1968-11-26 | 1968-11-26 | Verwendung von Stabilisatoren enthalten den pulverförmigen Copolymerisaten aus 90 bis 99 Gew % Vinylchlorid und 1 bis 10 Gew % Propylen mit einem K Wert von 50 bis 60 zur Herstellung von weichmacherfreien Formteilen nach dem Rotationsschmelzverfahren |
Country Status (8)
Country | Link |
---|---|
AT (1) | AT293019B (enrdf_load_stackoverflow) |
BE (1) | BE742237A (enrdf_load_stackoverflow) |
CA (1) | CA934117A (enrdf_load_stackoverflow) |
CH (1) | CH531546A (enrdf_load_stackoverflow) |
DE (1) | DE1810866B2 (enrdf_load_stackoverflow) |
FR (1) | FR2024245A1 (enrdf_load_stackoverflow) |
GB (1) | GB1259214A (enrdf_load_stackoverflow) |
NL (1) | NL6917726A (enrdf_load_stackoverflow) |
-
1968
- 1968-11-26 DE DE19681810866 patent/DE1810866B2/de active Granted
-
1969
- 1969-11-21 CH CH1739369A patent/CH531546A/de not_active IP Right Cessation
- 1969-11-24 FR FR6940356A patent/FR2024245A1/fr not_active Withdrawn
- 1969-11-25 CA CA068372A patent/CA934117A/en not_active Expired
- 1969-11-25 AT AT1098969A patent/AT293019B/de not_active IP Right Cessation
- 1969-11-25 GB GB1259214D patent/GB1259214A/en not_active Expired
- 1969-11-25 NL NL6917726A patent/NL6917726A/xx unknown
- 1969-11-26 BE BE742237D patent/BE742237A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
FR2024245A1 (enrdf_load_stackoverflow) | 1970-08-28 |
DE1810866A1 (de) | 1970-07-23 |
CH531546A (de) | 1972-12-15 |
NL6917726A (enrdf_load_stackoverflow) | 1970-05-28 |
CA934117A (en) | 1973-09-25 |
BE742237A (enrdf_load_stackoverflow) | 1970-05-04 |
AT293019B (de) | 1971-09-27 |
GB1259214A (enrdf_load_stackoverflow) | 1972-01-05 |
DE1810866C3 (enrdf_load_stackoverflow) | 1974-05-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C3 | Grant after two publication steps (3rd publication) | ||
E77 | Valid patent as to the heymanns-index 1977 | ||
EHJ | Ceased/non-payment of the annual fee |