DE1694928A1 - Stabilisierte Mischungen auf der Grundlage von Mischpolymeren aus AEthylen und Propylen und Verfahren zu ihrer Herstellung - Google Patents
Stabilisierte Mischungen auf der Grundlage von Mischpolymeren aus AEthylen und Propylen und Verfahren zu ihrer HerstellungInfo
- Publication number
- DE1694928A1 DE1694928A1 DE19671694928 DE1694928A DE1694928A1 DE 1694928 A1 DE1694928 A1 DE 1694928A1 DE 19671694928 DE19671694928 DE 19671694928 DE 1694928 A DE1694928 A DE 1694928A DE 1694928 A1 DE1694928 A1 DE 1694928A1
- Authority
- DE
- Germany
- Prior art keywords
- propylene
- ethylene
- parts
- polymer
- mixed polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims description 33
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title claims description 33
- 239000000203 mixture Substances 0.000 title claims description 32
- 229920001577 copolymer Polymers 0.000 title claims description 29
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 19
- 239000005977 Ethylene Substances 0.000 title claims description 18
- 238000000034 method Methods 0.000 title claims description 4
- 229920000642 polymer Polymers 0.000 claims description 35
- 229920001897 terpolymer Polymers 0.000 claims description 30
- 229920001971 elastomer Polymers 0.000 claims description 12
- 239000000806 elastomer Substances 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 230000000087 stabilizing effect Effects 0.000 claims description 5
- 238000004898 kneading Methods 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 229920001021 polysulfide Polymers 0.000 claims 2
- WCIINKICRPVMDM-UHFFFAOYSA-N 2-methylthiirane;thiirane Chemical compound C1CS1.CC1CS1 WCIINKICRPVMDM-UHFFFAOYSA-N 0.000 claims 1
- 125000002897 diene group Chemical group 0.000 claims 1
- 230000032683 aging Effects 0.000 description 30
- 238000012360 testing method Methods 0.000 description 26
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 238000002474 experimental method Methods 0.000 description 13
- 239000003381 stabilizer Substances 0.000 description 12
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 5
- 229930003836 cresol Natural products 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 5
- 150000001993 dienes Chemical class 0.000 description 5
- VOVUARRWDCVURC-UHFFFAOYSA-N thiirane Chemical compound C1CS1 VOVUARRWDCVURC-UHFFFAOYSA-N 0.000 description 5
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 238000010348 incorporation Methods 0.000 description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- -1 ethylene, propylene Chemical group 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 238000004073 vulcanization Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- 241001441571 Hiodontidae Species 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- RRKODOZNUZCUBN-CCAGOZQPSA-N (1z,3z)-cycloocta-1,3-diene Chemical compound C1CC\C=C/C=C\C1 RRKODOZNUZCUBN-CCAGOZQPSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 description 1
- MBNVSWHUJDDZRH-UHFFFAOYSA-N 2-methylthiirane Chemical compound CC1CS1 MBNVSWHUJDDZRH-UHFFFAOYSA-N 0.000 description 1
- 101100162210 Aspergillus parasiticus (strain ATCC 56775 / NRRL 5862 / SRRC 143 / SU-1) aflM gene Proteins 0.000 description 1
- 101100102500 Caenorhabditis elegans ver-1 gene Proteins 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 150000003553 thiiranes Chemical class 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/06—Sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR63096A FR1489772A (fr) | 1966-05-26 | 1966-05-26 | Compositions stabilisées à base de copolymères d'éthylène et de propylène et leur procédé de fabrication |
| FR102239A FR93757E (fr) | 1966-05-26 | 1967-04-11 | Compositions stabilisées a base de copolymeres d'éthylene et de propylene et leur procédé de fabrication. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1694928A1 true DE1694928A1 (de) | 1971-08-12 |
Family
ID=26170918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19671694928 Pending DE1694928A1 (de) | 1966-05-26 | 1967-05-26 | Stabilisierte Mischungen auf der Grundlage von Mischpolymeren aus AEthylen und Propylen und Verfahren zu ihrer Herstellung |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE698556A (enrdf_load_stackoverflow) |
| DE (1) | DE1694928A1 (enrdf_load_stackoverflow) |
| FR (2) | FR1489772A (enrdf_load_stackoverflow) |
| GB (1) | GB1116018A (enrdf_load_stackoverflow) |
| NL (1) | NL6705801A (enrdf_load_stackoverflow) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE689546A (enrdf_load_stackoverflow) * | 1966-11-10 | 1967-05-10 |
-
1966
- 1966-05-26 FR FR63096A patent/FR1489772A/fr not_active Expired
-
1967
- 1967-04-11 FR FR102239A patent/FR93757E/fr not_active Expired
- 1967-04-25 NL NL6705801A patent/NL6705801A/xx unknown
- 1967-05-17 BE BE698556D patent/BE698556A/xx unknown
- 1967-05-23 GB GB23916/67A patent/GB1116018A/en not_active Expired
- 1967-05-26 DE DE19671694928 patent/DE1694928A1/de active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FR93757E (fr) | 1969-05-16 |
| BE698556A (enrdf_load_stackoverflow) | 1967-11-17 |
| NL6705801A (enrdf_load_stackoverflow) | 1967-11-27 |
| GB1116018A (en) | 1968-06-06 |
| FR1489772A (fr) | 1967-07-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1520463C2 (de) | Verfahren zur Herstellung von Mischpolymerisaten | |
| DE69018015T2 (de) | Thermoplastisches Elastomer aus Propylen-Polymer-Material und vernetztem Äthylen-Propylen-Kautschuk. | |
| DE2848448C2 (de) | Elastoplastische Formmasse und Verfahren zu ihrer Herstellung | |
| DE1130163B (de) | Verfahren zum Vernetzen von amorphem Polypropylen oder amorphen Mischpolymeren aus AEthylen und Propylen | |
| DE1264052B (de) | Verfahren zum Vernetzen von alpha-Olefinpolymeren | |
| DE2640850B2 (de) | Thermoplastisches, elastomeres Polymergemisch | |
| DE2262723A1 (de) | Verfahren zu der herstellung halogenhaltiger kautschukartiger mischpolymerisate | |
| DE1694806A1 (de) | Verfahren zum Vulkanisieren von Mischpolymerisaten | |
| DE1569270A1 (de) | Verfahren zur Herstellung von Butylkautschuk-Polyaethylen-Vulkanisaten | |
| DE69701976T2 (de) | Thermoplastisches elastomer | |
| DE1569131A1 (de) | Verfahren zum Vulkanisieren vulkanisierbarer Mischungen | |
| DE69604030T2 (de) | Propylenpolymer, Verfahren zu seiner Herstellung, Verwendung desselben und Objekte daraus | |
| DE1158252B (de) | Verfahren zum Vulkanisieren von elastomeren, im wesentlichen gesaettigten Mischpolymerisaten von ª‡-Monoolefinen | |
| DE1569400A1 (de) | Mit bis-Vinylidenverbindungen vernetztes Terpolymer aus AEthylen,Propylen und einem nichtkonjugierten Dien mit einer hohen Bestaendigkeit gegenueber Erweichung,Hart- oder Bruechigwerden bei hohen Temperaturen | |
| DE3880871T2 (de) | Flammhemmende Polyesterelastomermasse. | |
| DE1694928A1 (de) | Stabilisierte Mischungen auf der Grundlage von Mischpolymeren aus AEthylen und Propylen und Verfahren zu ihrer Herstellung | |
| DE2311093A1 (de) | Covulkanisierbare verbesserte kautschukmasse | |
| DE69204196T2 (de) | Kautschukzusammensetzung. | |
| DE2602689B2 (de) | Elektroisoliermassen auf der Basis von Äthylen-Vinylacetat-Copolymerisaten | |
| DE1273198B (de) | Verfahren zur Herstellung von halogenhaltigen AEthylen-Propylen-Dien-Polymeren | |
| DE2221329C2 (de) | Isoliermasse auf Elastomerbasis | |
| DE1295183B (de) | Vulkanisationsverfahren | |
| DE1136107B (de) | Verfahren zur Herstellung von Elastomeren | |
| DE69907994T2 (de) | Thermoplastische Elastomerzusammensetzungen, enthaltend ein Mittel gegen das Ausblühen | |
| DE202008014218U1 (de) | Thermoplastische Elastomere |