DE1643810A1 - Verfahren zur Oligomerisation von konjugierten Diolefinen - Google Patents

Verfahren zur Oligomerisation von konjugierten Diolefinen

Info

Publication number
DE1643810A1
DE1643810A1 DE19671643810 DE1643810A DE1643810A1 DE 1643810 A1 DE1643810 A1 DE 1643810A1 DE 19671643810 DE19671643810 DE 19671643810 DE 1643810 A DE1643810 A DE 1643810A DE 1643810 A1 DE1643810 A1 DE 1643810A1
Authority
DE
Germany
Prior art keywords
organic
butadiene
molar ratio
nickel
lewis base
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19671643810
Other languages
German (de)
English (en)
Inventor
Arseneaux Arthur A
Lake Charles
Chappel Iii
Olechowski Jerome Robert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Columbian Carbon Co
Original Assignee
Columbian Carbon Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Columbian Carbon Co filed Critical Columbian Carbon Co
Publication of DE1643810A1 publication Critical patent/DE1643810A1/de
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/42—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons homo- or co-oligomerisation with ring formation, not being a Diels-Alder conversion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2291—Olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE19671643810 1966-10-05 1967-09-30 Verfahren zur Oligomerisation von konjugierten Diolefinen Pending DE1643810A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US584379A US3390195A (en) 1966-10-05 1966-10-05 Oligomericzation process

Publications (1)

Publication Number Publication Date
DE1643810A1 true DE1643810A1 (de) 1971-07-01

Family

ID=24337084

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19671643810 Pending DE1643810A1 (de) 1966-10-05 1967-09-30 Verfahren zur Oligomerisation von konjugierten Diolefinen

Country Status (4)

Country Link
US (1) US3390195A (enExample)
BE (1) BE704752A (enExample)
DE (1) DE1643810A1 (enExample)
NL (1) NL6713546A (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3544643A (en) * 1968-01-27 1970-12-01 Hoechst Ag Process for the catalytic cyclo-dimerization of 1,3-diolefins
US3446861A (en) * 1968-06-20 1969-05-27 Goodyear Tire & Rubber Cyclodimerization process
US3523981A (en) * 1969-02-27 1970-08-11 Olin Corp Dimers of alpha-methyl styrene and its homologues
US3692852A (en) * 1970-05-21 1972-09-19 Phillips Petroleum Co Semi-homogeneous liquid suspension catalyst complex for selective hydrogenation
US3800000A (en) * 1972-01-03 1974-03-26 Phillips Petroleum Co Process for recovering a nickel(0) oligomerization catalyst in the form of a nickel(ii) dimerization catalyst
US3846461A (en) * 1972-10-25 1974-11-05 Du Pont Process of preparing a zerovalent nickel complex with organic phosphorus compounds
US4144257A (en) * 1974-10-17 1979-03-13 Takasago Perfumery Co., Ltd. Process for preparing derivatives of conjugated diene dimers
US4270016A (en) * 1979-06-01 1981-05-26 Tolstikov Genrikh A Method of preparing trans-, trans-, trans-1,5,9-cyclododecatriene
US5221774A (en) * 1992-03-19 1993-06-22 Phillips Petroleum Company Ethylene oligomerization
US5233115A (en) * 1992-12-09 1993-08-03 Phillips Petroleum Company Ethylene oligomerization
RU2109717C1 (ru) * 1994-11-08 1998-04-27 Институт нефтехимии и катализа с опытным заводом АН Республики Башкортостан Способ совместного получения трео-5,6-дизамещенных гепт-1-енов и трео-5,6-дизамещенных дека-1,9-диенов
RU2145319C1 (ru) * 1995-12-13 2000-02-10 Институт нефтехимии и катализа с опытным заводом АН РБ Способ получения 4,5-диалкил(фенил)-1,4z,9-декатриенов

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2854458A (en) * 1954-07-15 1958-09-30 Basf Ag Complex heavy metal salts
US2809976A (en) * 1954-07-16 1957-10-15 Basf Ag Production of acrylic acid or its derivatives using a cationic complex nickel catalyst
US2969408A (en) * 1955-12-30 1961-01-24 Phillips Petroleum Co Process and catalyst for polymerization of olefins
US2886591A (en) * 1956-04-18 1959-05-12 Basf Ag Production of acrylic acid esters
NL135124C (enExample) * 1960-09-21 1900-01-01
US3326990A (en) * 1962-06-14 1967-06-20 Columbian Carbon Cycloolefin production using zieglertype reducing agent and a nickel chelate
GB977108A (en) * 1962-03-26 1964-12-02 Studiengesellschaft Kohle Mbh Process of co-oligomerisation
US3247270A (en) * 1962-06-14 1966-04-19 Columbian Carbon Cycloolefin production
US3277099A (en) * 1962-07-28 1966-10-04 Basf Ag Production of open-chain oligomers of 1, 3-dienes
NL286211A (enExample) * 1962-11-30 1900-01-01
US3296260A (en) * 1963-01-15 1967-01-03 Du Pont Neutral and singly charged derivatives of decaboranes and decaborates
US3309418A (en) * 1963-11-22 1967-03-14 Toyo Rayon Co Ltd Process for producing hexadienes
US3352931A (en) * 1965-08-16 1967-11-14 Phillips Petroleum Co Catalytic oligomerization of butadiene

Also Published As

Publication number Publication date
BE704752A (enExample) 1968-04-05
US3390195A (en) 1968-06-25
NL6713546A (enExample) 1968-04-08

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