DE1642921C3 - Vanadium- und titanhaltiger Trägerkatalysator - Google Patents
Vanadium- und titanhaltiger TrägerkatalysatorInfo
- Publication number
- DE1642921C3 DE1642921C3 DE1967B0090594 DEB0090594A DE1642921C3 DE 1642921 C3 DE1642921 C3 DE 1642921C3 DE 1967B0090594 DE1967B0090594 DE 1967B0090594 DE B0090594 A DEB0090594 A DE B0090594A DE 1642921 C3 DE1642921 C3 DE 1642921C3
- Authority
- DE
- Germany
- Prior art keywords
- vanadium
- titanium dioxide
- carrier
- weight
- supported catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims description 26
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims description 6
- 239000010936 titanium Substances 0.000 title claims description 6
- 229910052719 titanium Inorganic materials 0.000 title claims description 6
- 229910052720 vanadium Inorganic materials 0.000 title claims description 6
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 25
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 22
- 239000004408 titanium dioxide Substances 0.000 claims description 12
- 150000003682 vanadium compounds Chemical class 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- 238000000576 coating method Methods 0.000 description 15
- 239000011248 coating agent Substances 0.000 description 14
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 3
- 229940078552 o-xylene Drugs 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- LXASOGUHMSNFCR-UHFFFAOYSA-D [V+5].[V+5].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O Chemical compound [V+5].[V+5].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O LXASOGUHMSNFCR-UHFFFAOYSA-D 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- OGUCKKLSDGRKSH-UHFFFAOYSA-N oxalic acid oxovanadium Chemical compound [V].[O].C(C(=O)O)(=O)O OGUCKKLSDGRKSH-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 235000021395 porridge Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0221—Coating of particles
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1967B0090594 DE1642921C3 (de) | 1965-05-18 | 1967-01-04 | Vanadium- und titanhaltiger Trägerkatalysator |
| BE708692D BE708692A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1965-05-18 | 1967-12-28 | |
| ES348752A ES348752A2 (es) | 1965-05-18 | 1967-12-29 | Procedimiento para la oxidacion de hidrocarburos etilenica-mente insaturados. |
| GB41768A GB1203321A (en) | 1965-05-18 | 1968-01-03 | Oxidation catalysts containing vanadium pentoxide and titanium dioxide |
| FR134698A FR94476E (fr) | 1965-05-18 | 1968-01-03 | Catalyseur d'oxydation au vanadium et au titane. |
| AT8768A AT291204B (de) | 1965-05-18 | 1968-01-04 | Verfahren zur Herstellung von Vanadinpentoxyd und Titandioxyd in der aktiven Masse enthaltende Trägerkatalysatoren |
| SE11468A SE345441B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1965-05-18 | 1968-01-04 | |
| NL6800134A NL159597B (nl) | 1965-05-18 | 1968-01-04 | Werkwijze ter bereiding van een vanadium en titaan bevat- tende oxydatiekatalysator en volgens deze werkwijze bereide gevormde katalysator. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB0081979 | 1965-05-18 | ||
| DE1967B0090594 DE1642921C3 (de) | 1965-05-18 | 1967-01-04 | Vanadium- und titanhaltiger Trägerkatalysator |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1642921A1 DE1642921A1 (de) | 1971-05-19 |
| DE1642921B2 DE1642921B2 (de) | 1978-03-02 |
| DE1642921C3 true DE1642921C3 (de) | 1978-11-23 |
Family
ID=6985379
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1967B0090594 Expired DE1642921C3 (de) | 1965-05-18 | 1967-01-04 | Vanadium- und titanhaltiger Trägerkatalysator |
Country Status (8)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6197365B1 (en) * | 1999-03-30 | 2001-03-06 | Xcellsis Gmbh | Process for manufacturing a catalytic material |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1769998B2 (de) * | 1968-08-20 | 1977-01-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von phthalsaeureanhydrid |
| DE2106796C3 (de) * | 1971-02-12 | 1981-09-24 | Wacker-Chemie GmbH, 8000 München | Verfahren zur Herstellung Festbettkatalysatoren mit einem Überzug aus Vanadiumpentoxid und Titandioxid |
| US5169820A (en) * | 1990-03-16 | 1992-12-08 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Catalyst for producing phthalic anhydride |
| US5235071A (en) * | 1991-07-10 | 1993-08-10 | Nippon Shokubai Co., Ltd. | Catalyst for producing phthalic anhydride and process by using the same |
| DE4442346A1 (de) | 1994-11-29 | 1996-05-30 | Basf Ag | Verfahren zur Herstellung eines Katalysators, bestehend aus einem Trägerkörper und einer auf der Oberfläche des Trägerkörpers aufgebrachten katalytisch aktiven Oxidmasse |
| KR101175371B1 (ko) | 2003-08-06 | 2012-08-20 | 바스프 에스이 | 하나 이상의 유기 화합물의 연속 불균일 촉매적 기체상부분 산화 수행 방법 |
| DE102005010645A1 (de) | 2005-03-08 | 2005-08-04 | Basf Ag | Verfahren zum Befüllen eines Reaktors |
| DE102007010422A1 (de) | 2007-03-01 | 2008-09-04 | Basf Se | Verfahren zur Herstellung eines Katalysators bestehend aus einem Trägerkörper und einer auf der Oberfläche des Trägerkörpers aufgebrachten katalytisch aktiven Masse |
| TW200948474A (en) | 2008-04-09 | 2009-12-01 | Basf Se | Coated catalysts comprising a multimetal oxide comprising molybdenum |
| US9399606B2 (en) | 2012-12-06 | 2016-07-26 | Basf Se | Catalyst and process for the oxidative dehydrogenation of N-butenes to butadiene |
| EA201591089A1 (ru) | 2012-12-06 | 2016-01-29 | Басф Се | Катализатор и способ окислительного дегидрирования н-бутенов в бутадиен |
| WO2014086768A1 (de) | 2012-12-06 | 2014-06-12 | Basf Se | Verfahren zur oxidativen dehydrierung von n-butenen zu butadien |
| US10144681B2 (en) | 2013-01-15 | 2018-12-04 | Basf Se | Process for the oxidative dehydrogenation of N-butenes to butadiene |
| EA201690165A1 (ru) | 2013-07-10 | 2016-06-30 | Басф Се | Способ окислительного дегидрирования н-бутенов в бутадиен |
| WO2016177764A1 (de) | 2015-05-06 | 2016-11-10 | Basf Se | Verfahren zur herstellung chrom enthaltender katalysatoren für die oxidehydrierung von n-butenen zu butadien unter vermeidung von cr(vi)-intermediaten |
-
1967
- 1967-01-04 DE DE1967B0090594 patent/DE1642921C3/de not_active Expired
- 1967-12-28 BE BE708692D patent/BE708692A/xx unknown
- 1967-12-29 ES ES348752A patent/ES348752A2/es not_active Expired
-
1968
- 1968-01-03 FR FR134698A patent/FR94476E/fr not_active Expired
- 1968-01-03 GB GB41768A patent/GB1203321A/en not_active Expired
- 1968-01-04 AT AT8768A patent/AT291204B/de not_active IP Right Cessation
- 1968-01-04 SE SE11468A patent/SE345441B/xx unknown
- 1968-01-04 NL NL6800134A patent/NL159597B/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6197365B1 (en) * | 1999-03-30 | 2001-03-06 | Xcellsis Gmbh | Process for manufacturing a catalytic material |
Also Published As
| Publication number | Publication date |
|---|---|
| AT291204B (de) | 1971-07-12 |
| ES348752A2 (es) | 1969-03-16 |
| NL159597B (nl) | 1979-03-15 |
| DE1642921A1 (de) | 1971-05-19 |
| BE708692A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1968-06-28 |
| SE345441B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1972-05-29 |
| GB1203321A (en) | 1970-08-26 |
| DE1642921B2 (de) | 1978-03-02 |
| NL6800134A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1968-07-05 |
| FR94476E (fr) | 1969-08-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) |