DE1596753A1 - Chemisch verstaerkte Glasgegenstaende - Google Patents
Chemisch verstaerkte GlasgegenstaendeInfo
- Publication number
- DE1596753A1 DE1596753A1 DE19661596753 DE1596753A DE1596753A1 DE 1596753 A1 DE1596753 A1 DE 1596753A1 DE 19661596753 DE19661596753 DE 19661596753 DE 1596753 A DE1596753 A DE 1596753A DE 1596753 A1 DE1596753 A1 DE 1596753A1
- Authority
- DE
- Germany
- Prior art keywords
- glass
- oxide
- silver
- abrasion
- ions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims description 99
- 238000005299 abrasion Methods 0.000 claims description 38
- 229910052709 silver Inorganic materials 0.000 claims description 27
- 239000004332 silver Substances 0.000 claims description 27
- -1 silver ions Chemical class 0.000 claims description 18
- 229910001415 sodium ion Inorganic materials 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 14
- 229910001416 lithium ion Inorganic materials 0.000 claims description 13
- 239000011734 sodium Substances 0.000 claims description 13
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 11
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- 229910052783 alkali metal Inorganic materials 0.000 claims description 9
- 150000001340 alkali metals Chemical class 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 239000002344 surface layer Substances 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 8
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 6
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 6
- 229910001947 lithium oxide Inorganic materials 0.000 claims description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 6
- 239000005368 silicate glass Substances 0.000 claims description 5
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 2
- 241000723368 Conium Species 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 1
- 241000656145 Thyrsites atun Species 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- 230000001427 coherent effect Effects 0.000 claims 1
- 238000005342 ion exchange Methods 0.000 description 47
- 208000035874 Excoriation Diseases 0.000 description 36
- 238000012360 testing method Methods 0.000 description 29
- 150000002500 ions Chemical class 0.000 description 20
- 230000002787 reinforcement Effects 0.000 description 17
- 238000011282 treatment Methods 0.000 description 16
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 14
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 8
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 8
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 229910004298 SiO 2 Inorganic materials 0.000 description 6
- 239000000292 calcium oxide Substances 0.000 description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 229910001414 potassium ion Inorganic materials 0.000 description 6
- 230000007547 defect Effects 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000003014 reinforcing effect Effects 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 230000003321 amplification Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000003199 nucleic acid amplification method Methods 0.000 description 3
- 230000008707 rearrangement Effects 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- 241001122767 Theaceae Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 229910052912 lithium silicate Inorganic materials 0.000 description 2
- 239000006132 parent glass Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 239000004323 potassium nitrate Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 2
- 239000005361 soda-lime glass Substances 0.000 description 2
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 2
- KKADPXVIOXHVKN-UHFFFAOYSA-N 4-hydroxyphenylpyruvic acid Chemical compound OC(=O)C(=O)CC1=CC=C(O)C=C1 KKADPXVIOXHVKN-UHFFFAOYSA-N 0.000 description 1
- 101710134784 Agnoprotein Proteins 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910008556 Li2O—Al2O3—SiO2 Inorganic materials 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002547 anomalous effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000004031 devitrification Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- FZFYOUJTOSBFPQ-UHFFFAOYSA-M dipotassium;hydroxide Chemical compound [OH-].[K+].[K+] FZFYOUJTOSBFPQ-UHFFFAOYSA-M 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 108700009872 mild silver Proteins 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229910001432 tin ion Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/005—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to introduce in the glass such metals or metallic ions as Ag, Cu
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
- Surface Treatment Of Glass (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US44365165A | 1965-03-29 | 1965-03-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1596753A1 true DE1596753A1 (de) | 1970-05-06 |
Family
ID=23761656
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19661596753 Pending DE1596753A1 (de) | 1965-03-29 | 1966-03-23 | Chemisch verstaerkte Glasgegenstaende |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE678612A (enrdf_load_stackoverflow) |
| DE (1) | DE1596753A1 (enrdf_load_stackoverflow) |
| FR (1) | FR1472668A (enrdf_load_stackoverflow) |
| GB (1) | GB1117957A (enrdf_load_stackoverflow) |
| NL (1) | NL6604122A (enrdf_load_stackoverflow) |
-
0
- FR FR1472668D patent/FR1472668A/fr not_active Expired
-
1966
- 1966-03-21 GB GB1233566A patent/GB1117957A/en not_active Expired
- 1966-03-23 DE DE19661596753 patent/DE1596753A1/de active Pending
- 1966-03-29 BE BE678612D patent/BE678612A/xx unknown
- 1966-03-29 NL NL6604122A patent/NL6604122A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL6604122A (enrdf_load_stackoverflow) | 1966-09-30 |
| BE678612A (enrdf_load_stackoverflow) | 1966-09-29 |
| FR1472668A (enrdf_load_stackoverflow) | 1967-05-25 |
| GB1117957A (en) | 1968-06-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE1421845C3 (de) | Verfestigter Glasgegenstand mit einer das Glasinnere umgebenden Oberflächen-Druckspannungsschicht und Verfahren zu seiner Herstellung | |
| DE69900721T2 (de) | Chemisch härtbare, borfreie float-glaszusammensetzungen | |
| DE3044768C2 (de) | Linse vom Lichtkonvergiertyp | |
| DE19616633C1 (de) | Chemisch vorspannbare Aluminosilicatgläser und deren Verwendung | |
| DE2635140C2 (de) | Mittels Ionenaustausch gehärtete Brillenglaslinsen | |
| DE112006002185B4 (de) | Glaszusammensetzung und Verfahren zum Herstellen einer Glaszusammensetzung | |
| DE1421842B2 (de) | Verfestigter glasgegenstand aus einem alkali aluminium silikatglas und verfahren zu seiner herstellung | |
| DE69302795T2 (de) | Schnell härtbare Glaslinsen | |
| DE1016908B (de) | Verfahren zum Herstellen von Glasgegenstaenden hoher mechanischer Festigkeit und danach hergestellte Glasgegenstaende | |
| DE19936699A1 (de) | Blei- und bariumfreies Kristallglas | |
| DE102010031114A1 (de) | Glas mit hervorragender Resistenz gegen Oberflächenbeschädigungen und Verfahren zu dessen Herstellung | |
| DE1284065B (de) | Verfahren zur Herstellung verstaerkter glaskeramischer Gegenstaende | |
| DE2755899A1 (de) | Optisches glas | |
| DE2808569C3 (de) | Gemenge zur Herstellung eines Glases mit einer Liquidustemperatur von 750 bis 900° C auf Basis des Systems SiO↓2↓-ZrO↓2↓-(TiO↓2↓↓)↓-B↓2↓O↓3↓-R↓2↓O-(Al↓2↓O↓3↓↓)↓ und F für alkalibeständige Glasfasern | |
| DE2625313C2 (de) | Mittels Ionenaustausch gehärtete Brillenglaslinse | |
| DE202010014985U1 (de) | Bororsilicatglas hoher chemischer Beständigkeit und geringer Entglasungsneigung | |
| DE19913227C1 (de) | Verwendung eines Glases für temperaturwechselbeständige Getränkebehälter | |
| DE1596753A1 (de) | Chemisch verstaerkte Glasgegenstaende | |
| DE2114074A1 (de) | Verfahren zur Herstellung von Glasgegenstaenden mit erhoehter und dauerhafterer mechanischer Festigkeit | |
| DE10004596A1 (de) | Verstärkte Glaslinse mit einem Brechungsindex von 1,7 | |
| AT258502B (de) | Verfahren zur Verbesserung der Oberflächenfestigkeit eines Glasgegenstandes | |
| AT258501B (de) | Verfahren zur Verbesserung der Oberflächenfestigkeit eines Glasgegenstandes | |
| DE1421846C (de) | Verfestigter Glasgegenstand mit einer das Glasinnere umgebenden Druckspannungs schicht an der Oberflache des Glases und Verfahren zu seiner Herstellung | |
| DE2020674A1 (de) | Verfahren zur Herstellung eines Glasgegenstandes mit guenstigem Bruchmodul | |
| AT259153B (de) | Verfahren zur Verbesserung der Oberflächenfestigkeit eines Gegenstandes aus alkalimetalloxydhaltigem Silikatglas |